T1= 293,5K C0a =0,02M CHCl=0,05 M C0b = 0,0303М

t, min Vm,b, ml V0,b, ml V0, ml Vt,,b, ml Vt, ml V¥,b, ml V¥, ml

0 16.5 6.5 6.061 6.5 6.061 11.6 2.9704
5 6.5 6.061 7.7 5.3338 11.6 2.9704
10 6.5 6.061 8.5 4.849 11.6 2.9704
15 6.5 6.061 8.9 4.6066 11.6 2.9704
25 6.5 6.061 9.5 4.243 11.6 2.9704
35 6.5 6.061 10.1 3.8794 11.6 2.9704
45 6.5 6.061 10.7 3.5158 11.6 2.9704
60 6.5 6.061 11 3.334 11.6 2.9704

t, min v0 tgα = 0,0111

2.5 0.0005
7.5 Dependența grafică v=f(t)
12.5
0.0004
20
30 0.00035 f(x) = − 1.30713913716278E-08 x³ + 1.26865334527072E-06 x² − 3.868149617634
+ 0.000453728026571
40 0.0003
52.5 0.00025

0.0002

0.00015

0.0001

5E-05

0
0 10 20 30 40 50
 v, mol/l*min lg(Vt*(V0-V¥)/V0*(Vt-V¥)) kcalc, l/mol*min kgraf, l/mol*min k(T1), L/mol*min

0.0003636 0.060998012102419 3.44240506329 3.333422190172

0.0002424 0.119316382369178
0.0001212 0.157042631187768 3.24687296549
9.09E-05 0.230479629120623 2.85911438656
9.09E-05 0.337699194492715 2.99227134361
9.09E-05 0.516807544452252 3.56168349904
3.03E-05 0.669840237196269 3.46225439057
3.22443931705

ă v=f(t) Dependența grafică lg(Vt-V∞)/V0*(Vt-V∞)=f(t)

0.8

527072E-06 x² − 3.86814961763484E-05 x 0.7

0.6 f(x) = 0.011116313988431 x − 0.010785370974691

0.5

0.4

0.3

0.2

0.1

40 50 60 0
0 10 20 30 40 50 60 70
∞)=f(t)

60 70
T2= K C0a = M C0b = M CHCl=0,05 M

t, min Vm,b, ml V0,b, ml V0, ml Vt,,b, ml Vt, ml V¥,b, ml V¥, ml

0
5
10
15
25
35
CHCl=0,05 M

lg(Vt*(V0-V¥)/V0*(Vt-V¥)) kcalc, l/mol*min kgraf, l/mol*min k(T2), L/mol*min k(T1), L/mol*min

Ea, J/mol