ɄɊɂɋɌȺɅɅɈɏɂɆɂɑȿɋɄɂȿɈɋɈȻȿɇɇɈɋɌɂɌɊȬɏɇɈȼɕɏ ɉɈɊɂɋɌɕɏ

ɌȿɅɅɍɊɂɌɈȼɆȿȾɂTl+2 [Cu2+2Te6+Te4+6O18], Cu+[Cu2+2(TeO3)]Cl3,

ʠu+2[Cu2+4O(TeO3)2]Cl4
ɆɚɪɤɨɜɫɤɢɆɊ, ɋɢɣɞɪɚɈɂ, ɇɚɡɚɪɱɭɤȿȼ

Ʉɚɮɟɞɪɚɤɪɢɫɬɚɥɥɨɝɪɚɮɢɢɋɚɧɤɬ-ɉɟɬɟɪɛɭɪɝɫɤɢɣȽɨɫɭɞɚɪɫɬɜɟɧɧɵɣɍɧɢɜɟɪɫɢɬɟɬ
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Ƚɢɞɪɨɬɟɪɦɚɥɶɧɵɦ ɦɟɬɨɞɨɦ ɜ ɫɬɚɥɶɧɨɦ ɚɜɬɨɤɥɚɜɟ ɫɢɧɬɟɡɢɪɨɜɚɧ ɩɟɪɜɵɣ ɬɟɥɥɭɪɢɬ-

ɬɟɥɥɭɪɚɬ ɬɚɥɥɢɹ ɢ ɦɟɞɢ Tl+2[Cu2+2Te6+Te4+6O18] (1). ɋɨɟɞɢɧɟɧɢɹ Cu+[Cu2+2(TeO3)]Cl3 (2 ɢ
ɋu+2[Cu2+4O(TeO3)2]Cl4 (3) ɩɨɥɭɱɟɧɵ ɦɟɬɨɞɨɦ ɝɚɡɨɜɨɝɨ ɬɪɚɧɫɩɨɪɬɚ ɜ ɜɚɤɭɭɦɟ ɜ ɤɜɚɪɰɟɜɵɯ
ɬɪɭɛɤɚɯ ɢ ɹɜɥɹɸɬɫɹ ɩɟɪɜɵɦɢ ɬɟɥɥɭɪɢɬ-ɯɥɨɪɢɞɚɦɢ ɦɟɞɢ ɜ ɪɚɡɧɵɯ ɫɬɟɩɟɧɹɯ ɨɤɢɫɥɟɧɢɹ
ɋu+/Cu2+. ɉɨ ɞɚɧɧɵɦ ɪɟɧɬɝɟɧɨɫɬɪɭɤɬɭɪɧɨɝɨ ɚɧɚɥɢɡɚ ɤɪɢɫɬɚɥɥɨɝɪɚɮɢɱɟɫɤɢɟ ɩɚɪɚɦɟɬɪɵ
ɫɨɟɞɢɧɟɧɢɣ ɫɥɟɞɭɸɳɢɟ 1 P21/n, a=7.605(2)Å, b=11.825(3)Å, c=9.849(3)Å, ȕ=90.978(8)°,
V=885.(42)Å3, R1 = 0.03; 2 P-1, a=6.247(1)Å, b=6.250(1)Å, c=9.408(2)Å, Į=80.674(6)°,
ȕ=75.611(6)° Ȗ=80.849(6)°, V=348.4(1)Å3, R1 = 0.04; 3 Pbam, a=8.1233(14)Å, b=9.4560(16)Å,
c=11.5015(19)Å, ȕ=103.823(4)°, R1 = 0.048. ȼ ɫɬɪɭɤɬɭɪɟ 1 ɜ ɩɨɪɚɯ a.5×6.2Å) ɤɚɪɤɚɫɚ
[Cu2+2Te6+Te4+6O18]2- ɪɚɫɩɨɥɚɝɚɸɬɫɹ ɤɚɬɢɨɧɵ 7O+. 5s2 ɢ V2 ɧɟɩɨɞɟɥɟɧɧɵɟ ɷɥɟɤɬɪɨɧɧɵɟ ɩɚɪɵ
ɚɫɫɨɰɢɢɪɭɸɬɜɦɟɫɬɟɋɬɪɭɤɬɭɪɵ 2 ɢ3 ɦɨɝɭɬɛɵɬɶɨɩɢɫɚɧɵɜɬɟɪɦɢɧɚɯ ɨɤɫɨɰɟɧɬɪɢɪɨɜɚɧɧɵɯ
ɤɨɦɩɥɟɤɫɨɜ ȼ ɨɫɧɨɜɟ ɫɬɪɭɤɬɭɪɵ 2 ɥɟɠɚɬ ɩɨɪɢɫɬɵɟ ~7.7×5.7Å ɫɥɨɢ ɫɥɨɠɟɧɧɵɟ
ɨɤɫɨɰɟɧɬɪɢɪɨɜɚɧɧɵɦɢɬɪɟɭɝɨɥɶɧɢɤɚɦɢ[OCu2+2Te]ȼɩɨɪɚɯɪɚɫɩɨɥɚɝɚɸɬɫɹɞɢɦɟɪɵ>ɋX+2Cl6].
Ⱥɧɢɨɧɵ ɯɥɨɪɚ ɢ s2 ɧɟɩɨɞɟɥɟɧɧɵɟ ɷɥɟɤɬɪɨɧɧɵɟ ɩɚɪɵ ɧɚ ɤɚɬɢɨɧɚɯ Te4+ ɚɫɫɨɰɢɢɪɭɸɬ ɜ
ɦɟɠɫɥɨɟɜɨɦ ɩɪɨɫɬɪɚɧɫɬɜɟ Ʉɚɪɤɚɫ [Cu2+4O(TeO3)2] ɜ ɫɨɟɞɢɧɟɧɢɢ 3 ɫɥɨɠɟɧ
ɨɤɫɨɰɟɧɬɪɢɪɨɜɚɧɧɵɦɢ ɬɟɬɪɚɷɞɪɚɦɢ 2&X2+4 ɢ ɬɪɟɭɝɨɥɶɧɢɤɚɦɢ 2&X2+Te2. ɑɚɫɬɢɱɧɨ-
ɡɚɫɟɥɟɧɧɵɟɩɨɡɢɰɢɢɋX+ ɢɋO- ɪɚɫɩɪɟɞɟɥɹɸɬɫɹɜɲɢɪɨɤɢɯɩɨɥɨɫɬɹɯɤɚɪɤɚɫɚɉɨɪɟɡɭɥɶɬɚɬɚɦ
ɩɪɨɜɟɞɟɧɧɵɯ ɷɤɫɩɟɪɢɦɟɧɬɨɜ ɩɨ ɫɢɧɬɟɡɭ ɜɵɪɚɛɨɬɚɧ ɨɛɳɢɣ ɩɨɞɯɨɞ ɞɥɹ ɫɢɧɬɟɡɚ ɦɚɬɟɪɢɚɥɨɜ
ɬɟɥɥɭɪɢɬɨɜ ɫ ɩɨɪɢɫɬɵɦɢ ɫɥɨɹɦɢ ɢ ɤɚɪɤɚɫɚɦɢ ȼ ɞɚɥɶɧɟɣɲɟɦ ɩɥɚɧɢɪɭɟɬɫɹ ɩɪɨɜɟɞɟɧɢɟ
ɷɤɫɩɟɪɢɦɟɧɬɨɜɩɨɤɚɬɢɨɧɧɨɦɭɢɚɧɢɨɧɧɨɦɭɨɛɦɟɧɭɨɩɢɫɚɧɧɵɯɜɵɲɟɫɨɟɞɢɧɟɧɢɣ
Ɋɚɛɨɬɚ ɜɵɩɨɥɧɟɧɚ ɩɪɢ ɮɢɧɚɧɫɨɜɨɣ ɩɨɞɞɟɪɠɤɟ ɝɪɚɧɬɚ ɊɇɎ -17-10085.
Ɋɟɧɬɝɟɧɨɫɬɪɭɤɬɭɪɧɵɟ ɢɫɫɥɟɞɨɜɚɧɢɹ ɜɵɩɨɥɧɟɧɵ ɜ ɪɟɫɭɪɫɧɨɦ ɰɟɧɬɪɟ ɋɉɛȽɍ
©Ɋɟɧɬɝɟɧɨɞɢɮɪɚɤɰɢɨɧɧɵɟɦɟɬɨɞɵɢɫɫɥɟɞɨɜɚɧɢɹª

ɊɢɫɄɪɢɫɬɚɥɥɢɱɟɫɤɚɹɫɬɪɭɤɬɭɪɚ ɫɨɟɞɢɧɟɧɢɣ 2, 1 ɢ 3.

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