SOLUTIONS & ANSWERS FOR AIEEE-2011 [11-05-2011]

VERSION – D
PART A − CHEMISTRY Sol: p–nitrophenol is the most acidic among
the given phenols.
1. Ans: 22.05 g
12. Ans: 2–Methyl–2–pentene
Cr2O72− + 6Fe → Cr + Fe
2+ 3+ 3+
Sol:
3 Sol: CH3 C CH CH2 CH3
75 750 cm
m.mols 0.6 M CH3
Wt. of potassium dichromate = 75 × 0.294 ozonolysis
= 22.05 g
O
2. Ans: One sigma, two pi
CH3 + CH3 CH2 CHO
CH3 C
− −
C ≡ C
2+ 3+
Sol: Ca 13. Ans: [Co(NH3)2(en)2]
– 3+
3. Ans: NH3 < en < CN < CO Sol: [Co(NH3)2(en)2] exists in cis & trans
isomers.
Sol: The correct increasing order of field
strength for the ligands is 14. Ans: For lead +2, for tin +4
–
NH3 < en < CN < CO
+2 +4
Sol: Pb is more stable than Pb , since
5.55 × 10
–4
4. Ans: m ∆r G° is negative.
+4 +2
Sn is more stable than Sn , since
0.01
Sol: m= = 5.55 × 10 m
–4
∆r G° is positive.
60 × 0.3
15. Ans: n = 2 to n = 1
5. Ans: 4 1.6 × 10−30 / 27
Sol: At. no. of H = 1 and He = 2
+
4 For He n = 4 to n = 2
Sol: Ksp = 27S 4 2
K sp For H n= to n =
S= 4 2 2
27
6.25 × 10
–4 2 –1
16. Ans: S m mol
6. Ans: –219 kJ
l
Sol: K=C×
Sol: ∆rH = –111 –2 × 54 kJ a
= –219 kJ l
= 1.3 × 50 S m
–1

7. Ans: 68.4 a
l 10 −3
5 1 ∧=C× ×
Sol: = a M
342 w
1 10 −3
w = 68.4 = × 1.3 × 50 ×
260 0. 4
= 6.25 × 10 S m mol
–4 2 –1
8. Ans: Ozone absorbs infrared radiation

Sol: Ozone does not absorb I.R radiation 17. Ans: Oxide ion accepts sharing in a pair of
electrons
2– –
9. Ans: Sol: O becomes OH by sharing a pair of
2 electrons between hydrogen & oxygen.

Sol: Cyclopentadiene is not aromatic. 18. Ans: HCHO

10. Ans: mutarotation Sol: The monomers of bakelite are phenol and
formaldehyde.
Sol: It is the definition of mutarotation

11. Ans: D>C>A>B

19. Ans: 128 pm Ea2 − Ea1
k1 A
= 1 −e RT
Sol: 2 a = 4r k2 A2
Ea1
2 × 361
r= = 128 pm k1 = A k 2 − e RT
4
28. Ans: Acetylene
20. Ans: XeF2
Sol: Acetylene is not formed by treating
Sol: Compound Lone pairs
ethanol with con.H2SO4.
XeF4 2
XeF6 1
29. Ans: directly proportional to square root of
XeF2 3
temperature
XeO3 1

RS( − ) is less basic but more nucleophilic

T
21. Ans: Sol: Vα
M
than RO( − )
30. Ans: –1364.0 kJ
Sol: Since RSH is more acidic than ROH,
RS( − ) will be less basic than RO( − ) . Sol: ∆H = ∆U + ∆nRT
–1366.5 = ∆H – 8.314 × 10 × 300
–3
Since the negative charge on sulphur is
more polarisable, RS( − ) is more ∆H = –1364 kJ

nucleophilic than RO( − ) PART C − MATHEMATICS

22. Ans: 1 × 10
–10 ρ
31. Ans: 0
[H ] = Cα
+
Sol:
Sol: (a + 3b) + 6c = (k1 + 6) c = (1 + 3k2)a
α = 10
–5

C & a are non − collinear

Ka = Cα = 10
2 –10

∴ coefficients are zero

23. Ans: Cl > F > Br > I a + 3b + 6c = 0

Sol: The electron gain enthalpies of I, Br, F & 32. Ans: R − {2, −3}
1 −k 1
–1
Cl are –295, –325, –328 & –349 kJ mol
Sol: k 3 −k ≠0
24. Ans: Li2O + NO2 + O2
3 1 −1
2k + 2k − 12 ≠ 0
2
Sol: 4LiNO3 → 2Li2O + 4NO2 + O2
k +k−6≠0
2

1 k ≠ − 3, 2
25. Ans: (PA / PB ) (MB / MA ) 2
33. Ans: Statement-1 is true, Statement-2 is true;
1 statement-2 is a correct explanation for
Sol: rA α PA statement-1.
MA
f(x) = f− (x), this point lies on f(x) = x
1
rA PA MB Sol:
= ⇔ f(x) = x
rB PB MA
(x − 1) + 1 = x ⇒ x − 3x + 2 = 0
2 2

⇒ x = 1, 2
26. Ans: Benzene diazonium chloride and
benzonitrile Statement-1 is true
f(x) is a bijection and f− (x) = 1 + x −1
1

+ − Statement 2 is true
Sol: A : C6H5 N2 Cl
and Statement-1 follows from Statement-2
B : C6H5 – CN

Ea1
27. Ans: k1 = A k 2 − e RT f(x)

Sol: k1 = A1e −Ea1 / RT

k2 = A 2e −Ea 2 / RT
34. Ans: Statement-1 is true, statement-2 is false

∫ [ ]
1. 5 1 2 1.5

1
x x 2 dx = x × 0 dx +∫ ∫ x dx + ∫ 2x + dx
Sol: lim sin does not exist 0 0 1 2
x→0 x
2 1.5
∴ f2(x) is not continuous at x = 0 x 2
= 1 + x2
Statement-2 is false 2 2
1
35. Ans: [A ∧ (A → B)] → B = + 2.25 − 2
2
Sol: Using following truth table we can see that 3
=
only 4
A ∧ (A → B) → B is tautology
41. Ans: N ≤ 100
A B A →B A ∩ (A →B) (A∩(A→ B))→B
1 2 3 1∩3=4 4 →2 Sol: Maximum number of triangles are possible if
T T T T T rest of the points are non-collinear.
Then Nmax = C3 − C3 = 100
10 6
T F F T T
F T T F T ∴ N ≤ 100
F F T F T
42. Ans: 32, 2
36. Ans: x + y − x − y = 0
2 2
Sol: Mean = 30 + 2 = 32
Standard deviation remains same = 2
Sol: (x − 1) x + y (y − 1) = 0
x +y −x−y=0
2 2

43. Ans: 53
37. Ans: 18
Sol: General point on line Q (2λ, 3λ + 2, 4λ + 3)
Sol: P(x) = f(x) − g(x) = A x + Bx + C
2
⇒2(2λ − 3) + 3 (3λ + 3) + 4 (4λ − 8) = 0
Since P−1) = 0 is the only one root ⇒λ=1
∴ P(x) = k(x + 1)
2
∴ point Q (2, 5, 7) given point P (3, −1, 11)
Given P(−2) = 2 ⇒ k = 2 ∴ length PQ = 53
∴ P(2) = 18
44. Ans: 2af(a) − a f’(a)
2
38. Ans: [1, ∞)

x 2 f (a ) − a 2 f ( x ) 0
Sol: x + y |x|, ax − y = 1 Sol: lim  
a +1 a +1
x →a x−a 0
x= , y= a −
a +1 a +1 lim f (a)2 x − a2f ' ( x )
x →a
a a −1 ⇒2af(a) − a f’(a)
2
=
a +1
If x > 0 ⇒ a + 1 > 0 ⇒ a > − 1 45. Ans: Statement-1 is true and Statement-2 is
y > 0 ⇒ a |a| − 1 > 0 ⇒ a |a| > 1 false.
If − 1 < a < 0 − a > 1 no soln
2
Sol: Statement-1 is true
If a ≥ 0 In Statement-2
T
a ≥ 1 ⇒ |a| ≥ 1
2
Det (A ) = det(A) But
∴ a ∈ [1, ∞) Det(−A) = − Det (A) only for
odd order so it is not true.
39. Ans: Statement-1 is true, Statement-2 is true;
46. Ans: P(A ) − P(B)
C
statement-2 is a correct explanation for
statement-1.

Sol: R is an equivalence relation since

(
Sol: P A C ∩ BC C )
P(C) − P(B ∩ C) − P( A ∩ C)
reflexivity, symmetry, transitivity are =
satisfied. ∴ Statement-1 is true P(C)
Statement-2 is always true = 1 − P(B) − P(A)
And it is correct explanation of Statement-1 = 1 − P(A) − P(B)
= P(A ) − P(B)
C

3
40. Ans: 47. Ans: 3
4

Sol: Sol: lim

(f ( x ))2 − 9 = 0
x →5 1x − 51
 (f ( x ))2 − 9 = 0 −1 1 −1 1
∫ y3
y y
lim ∴ xe = e dy z=
x →5 x−5 y
lim (f ( x ))2 − 9 = 0 −z −1
x →5 ∫ z.e − dy dz =
y2
dy
lim f ( x ) = 3
x →5 [
− ze− z + e − zdz ∫ ] dy = y dz
2

16 −1
y
= ze− + e− + C
z z
48. Ans: xe
3 −1
y
x= z + 1 + ce
2
Sol: y = 9 ax 1
2 1 y
x = 9by x= + 1 + ce
16 1 y
A= ab =
3 3 y = 1 ⇒ x = 1 ⇒ 1 = 2 + ce
16 1
∴ Required Area = ⇒c= −
3 e
1 1 1
∴x= +1− − e y
49. Ans: 3x − y = 3
2 2
y e
1
Sol: e = 2 1 e y
ae = 2 ⇒ a =1 x=1+ −
y e
b2 2
e= 1+ ⇒b =3
a2 2π π 4 π π 3 π 8 π
53. Ans: , , , , ,
2
y 9 4 9 2 4 9
∴ required equation is x −
2
=1
3
Sol: sin θ + sin 4θ + sin 7θ = 0
3x − y = 3
2 2
⇒ sin 4θ + 2 sin 4θ cos 3θ = 0
⇒ sin 4θ (1 + 2 cos 3θ) = 0
50. Ans: H
1 2π
⇒ sin 4θ = 0 cos 3θ = − = cos
ω 0  2 3
Sol: H=   = ωI 2π
 0 ω ⇒ 4θ = n π 3θ = 2nπ ±
3
∴ H = ω I = ωI = H
70 70
nπ 2nπ 2π
⇒θ= ,θ = ±
4 3 9
51. Ans: 10 3
π π 3 π 8 π 4 π 2π
, , , , ,
2 4 4 9 9 9
Sol: Equation of the lime through (1, − 5, 9)
parallel to x = y = 12 is 54. Ans: −2
x −1 y + 5 z − 9
= = =λ
1 1 1
p 1 1
p(λ + 1, λ − 5, λ + 9)
Sol: 1 q 1 = 0 ⇒ pqr − (p + q + r) = − 2
(λ + 1) − (λ − 5) + (λ + 9) = 5
1 1 r
⇒ λ = − 10
∴ p(− 9, −15, − 1)
55. Ans: 6, 1
∴ distance = 10 3
Sol: Sum of roots = 4 + 3 = 7
1 product = 3 × 2 = 6
1 e y ∴ correct equation is x − 7x + 6 = 0
2
52. Ans: 1 + −
y e Roots are 6, 1

1 56. Ans: 2x + 3y =1
Sol: y dx + xdy − dy = 0
2
y
Sol: Let (x, y) be coordinates of centroid
⇒
dx 1 1
+ n. 2 = 3 2 − 2 + x3 −3 + 1 + y 3
x= y=
dy y y 3 3
−1 x3 2 − y3
I. F = e y =
3 3
x3 = 3x y3 = 3Y + 2
 2x3 + 3y3 = 9 ⇒ 6x + 9y + 6 = 9 Statement-1 is true and follows from
2x + 3y = 1 Statement-2

6 PART C − PHYSICS
57. Ans: y=
4
61. Ans: 2
Sol:
Sol: Ι1 = 4Ι, for coherent light
B
Ι2 = Ι + Ι = 2Ι for incoherent light
Ι 4Ι
∴ 1 = =2
P(x1, y1) Ι 2 2Ι

P
62. Ans: ,T
2
A
Sol: There is no heat loss and no work is done
Let m be the slope of taught at P(x1, y1)
⇒ U is same ⇒ T is same.
∴ Equation of AB is
P
y − y1 = m(x − x1) V ⇒ 2 V, so P ⇒ for T to be same
− y1 2
∴ A is (0 y1 − mx1) and B is (x1 , 8) (Θ PV = constant for T to be constant)
m
∴ and point of AB (x1, y1) P
∴ , T is the final state.
y dx dy 2
⇒ 2x1 = x1 − 1 ⇒ + =0
m x y
63. Ans: NOR gate
⇒ xy = k it passes in (2, 3)
6 Sol: Becomes combination of OR gate and
xy = 6 ⇒ y =
4 NOT gate
⇒ NOR gate
α −β
58. Ans: 64. Ans: 3
100
Sol: It is assumed that F1 and F2 are applied
100
∑ (a2r − a2r −1)
parallel to the plane.
Sol: α−β=
F1 = mg sinθ + µmg cosθ
1
F2 = mg sinθ − µmg cosθ
100
α −β F1 tan θ + µ 2µ + µ 3
= ∑ d = 100 d ⇒d = 100
= =
F2 tan θ − µ 2µ − µ 1
=
1

59. Ans: Statement-1 is true, Statement-2 is true; GM

statement-2 is a correct explanation for 65. Ans:
4R
statement-1.

Sol: Statement- 2 is true mv 2 Gm2

Clearly f(x) has minimum at x = 0 at Sol: =
minimum point f’(x) = 0
R 4 R2
∴ follows from 1 GM
v= w.r.t centre of circle, which also
4R
60. Ans: Statement-1 is true, Statement-2 is true;
statement-2 is a correct explanation for is centre of mass of system.
statement-1. Centre of mass of system is at rest.

Sol: Statement-2 66. Ans: λ

By induction p(1) is true
Let p(m) be true Sol: Considering the nucleus to be at rest
Then (m + 1) : (m + 1) − (m + 1)
7
initially, total linear momentum = zero for
= m + 7 C1 , m + ….. + 7m + 1 − m − 1
7 6
system
= (m − m) + 7k divisible by 7
7
⇒ p of m1 and p of 5 m, are equal in
∴ p(n) is true magnitude but opposite in direction.
Statement-2 is true h
∴ (n + 1 − (n + 1) divisible by 7
7 λ = = same for both
p
Also, n − n divisibly by 7
7

Subtracting, (n + 1) − n − 1 divisible by 7
7 7
 0.1 V m−
1
67. Ans: 2.5 second 71. Ans:

Sol: ρλ
Sol: R= ; V = iR
A
iρλ V iρ
V= ⇒ =
A λ A
V 0.2 × 4 × 10 −7
∴ =
λ 8 × 10 −7
= 0.1 V m−
1

τP = RC’ = 2 RC
t 72. Ans: Statement – 1 is true, statement – 2 is
−
τP true, statement – 2 is not the correct
V = V0e
explanation of statement – 1.
10
−
1
⇒ = e τP Sol: Statement – 1 is correct. Statement 2 is
2
correct but doest not explain 1.
−10
⇒ −λn 2 =
τP 73. Ans: Statement – 1 is true, statement – 2 is
−10 10 true, statement – 2 is the correct
⇒ τP = = = 2 RC explanation of statement – 1.
− λn2 λn2
RC 2 RC 5
τS = RC’’ = = = Sol: Statement – 1 is true, statement – 2 is true
2 4 2λn2 and explain 1.
t
−
1 t × 2λn2
⇒ = e τ S ⇒ −λn2 = − λd
2 5 74. Ans: 2π
5 ρg
⇒t= = 2.5 s ⇒ t = 2.5 second
2
m=λ d
3
Sol:
∆F = −λ ρgx
2
πR 4
68. Ans: σω ∆F −ρgx
4 ∴a= =
m λd
ρg
⇒ω =
Sol: dq = (2πrdr)σ for an elemental ring of 2

radius r and width dr. λd

(dq)ω = ωrσdr 2π λd
di = (dq)f = T= = 2π
2π ω ρg
dM = πr di = πωσr dr
2 3

R 1
πωσR 4
∴M= ∫ dM = 4
75. Ans:
t
0

Sol: u = 0 at t = 0
69. Ans: A standing wave having nodes at
1
 1 λ mv 2 = kt
x =  n +  , (n = 0, 1, 2, …..) 2
 2 2
2kt
⇒ v2 = , k = +ve constant
m
Sol: y1 = A sin (ωt − kx)
2kt
y2 = A sin (ωt + kx) ⇒ v=
m
y = y1 + y2
dv B 1
= A [2 sinωt cos(−kx)] a= = ⇒ F = ma ∝
= 2 A cos kx sinωt ⇒ standing wave; dt E t
2π
k= Nodes are at
2 πr T
8/3 2
λ 76. Ans:
 1 λ
x =  n +  , (n = 0, 1, 2, …..) Sol: R=2 r
1/3
 2 2 2
E = 4πR T
2 2/3 2
70. Ans: Y∝t = 2 .π.2 .r T
= 2 πr T
8/3 2

Sol: Thermal stress = Y ∝ t

77. Ans: 11q 2qQ  1 
∴ U1 = 1 −  ; VB = 0 ⇒ U2 = 0
Sol: F = qE + q v × B ( ) 4πε0  5

(
= 3q î + q ĵ + 2qk̂ ) ∴ KE2 = ∆U = U1 =
2qQ 
1 −
1 

+ q(3 î + 4 ĵ + k̂ )(î + ĵ − 3k̂ )
4πε0a  5

[F = qĵ + (9qĵ + qĵ)] = 11qĵ

y
83. Ans:
5
k
2
3 mv 3
78. Ans: 1 1
16 g Sol: k∝ ∝
N λ
⇒ kλ = constant
3v kA λA = kλ
Sol: vH = v cos30° =
2 kλ 5λ 5k
⇒ kA = =k =
3 λA 2λ 2
p = mvH = mv
2
v 2 sin2 30° v 2 6.25 × 10− cm s−
4 1
84. Ans:
Hmax = =
2g 8g
∴ LH = p Hmax 2r 2g(ρ − σ )
Sol: v=
3 mv 3 9η
= v 2 η1 (7.8 − 1.2 )
16 g =
v1 η2 (7.8 − 1.0 )
79. Ans: Increase η1 6.6
⇒ v2 = v1 ×
η2 6.8
Sol:
δr 10 × 8.5 × 10 −4 6.6
× = 6.25 × 10− cm s−
4 1
δv =
13.2 6 .8
fv fr
 1  1 
85. Ans: 1 − h1 + 1 − 
 µ   µ h2
fr > fv  1  2

80. Ans: 20% Sol: S = S1 + S2

 1  1 
Sol: R = 4 R1 = 1 − h1 + 1 − h2

∆R ∆R1  µ1   µ2 
=4
R R1
86. Ans: 28.9 cc
= 4 × 5 = 20%
Sol: ∆V = V0γ∆θ
81. Ans: To reduce the time lag between
transmission and reception of the = V0 [3 ∝ ∆θ]
π
information signal. = D3 [3 ∝ ∆θ]
6
1 2qQ  1  π
= × 203 [3 × 23 × 10− × 100]
6
82. Ans: 1 − 
4 πε0 a  5 6
3
= 28.9 cm
Sol:
2a 87. Ans: 3 mV
−q −q
Sol: λ = 20 m
v = 5 m s−
1
2a •B Bh = 0.3 × 10− Wb m−
4 2

E = Bh vλ
= 0.3 × 10− × 5 × 20 = 0.3 × 10− V
4 2
+q • +q
A = 3 mV
2q 2q 2q  1 
VA = − = 1 −  88. Ans: between 0.148 kJ and 0.028 kJ
4πε0a 4 πε0 5 a 4πε0a  5
Sol: dQ = −mS dT
 32 T 3 89. Ans: Statement – 1 is correct, statement – 2 is
dT (kJ)
100
= − ×
1000 (400 )3 correct and statement – 2 is not the correct
explanation of statement-1.
1 32
= − × T3 dT
10 64 × 106
Sol: Statement – 1 is correct as energy of
1
= −
3
T dT (kJ) antineutrino is negligible.
2 × 107 Statement – 2 is also correct but does not
4K 4 20

− T3dT T4 explain-1.
∴Q= dQ = ∫
2 × 10 7
kJ = ∫ 
8 × 10  4
7
90. Ans: 2:1
20 K 20

=
[20 4
−4 4
kJ
] kJ = 19968 × 10 −7 Sol: ΙP = 4Ι
7
8 × 10 ΙQ = Ι + Ι + 2Ι cos90°
= 0.0019968 kJ = 2Ι
Q T2 Q(T1 − T2 ) Ι
∴ P =
4Ι
COP = = ⇒W= =2:1
W (T1 − T2 ) T2 ΙQ 2Ι
0.0019968 × (300 − 4 ) (Path difference
λ
W max =
4 4
= 0.148 kJ π
= phase difference rad)
0.0019968 × (300 − 20 ) 2
W min =
20
= 0.028 kJ