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Kc =
At
a
certain
temperature
the
values
of
[A],
[B]
and
[C]
are
all
0.2
mol
dm–3.
What
happens
to
the
value
of
Kc
when
all
three
values
are
doubled
to
0.4
mol
dm–3?
A. It is halved.
C. It doubles.
D.
a
magnesium
electrode
(Total
1
mark)
1
4. The unbalanced equation for the conversion of sulfur dioxide to sulfuric acid is given below.
Which other species are used, and on which side of the equation, to balance it?
A. The more positive the value of Eο, the greater the driving force for reduction.
B. The more negative the value of Eο, the greater the driving force for reduction.
C. The more positive the value of Eο, the greater the rate of reaction.
D.
The
more
negative
the
value
of
Eο,
the
greater
the
rate
of
reaction.
(Total
1
mark)
6.
A
metallic
object
is
electroplated
with
copper
using
a
solution
of
copper(II)
sulfate.
Which
statement
is
correct?
D.
The
reaction
occurring
at
the
negative
electrode
is
Cu2+
+
2e–
®
Cu.
(Total
1
mark)
7.
Which
equation
represents
the
reduction
process
occurring
in
the
standard
hydrogen
electrode?
2
(Total
1
mark)
8.
A
voltaic
cell
is
made
from
copper
and
zinc
half-‐cells.
The
equation
for
the
reaction
occurring
in
the
cell
is
C. Electrons flow from the copper half-‐cell to the zinc half-‐cell.
D.
Negative
ions
flow
through
the
salt
bridge
from
the
zinc
half-‐cell
to
the
copper
half-‐cell.
(Total
1
mark)
I. Sn(s) + Fe2+(aq)
A. I only
B. II only
C. III only
10.
Aqueous
solutions
containing
different
concentrations
of
NaCl
were
electrolysed
using
platinum
electrodes.
What
is
the
major
product
at
the
positive
electrode
in
each
case?
3
A.
H2
Na
B. H2 H2
C. O2 Cl2
D.
Cl2
O2
(Total
1
mark)
11. The table shows the concentrations of reactants and products during this reaction.
2A + B ® C + 2D
[A]
/
mol
dm–3
[B]
/
mol
dm–3
[C]
/
mol
dm–3
[D]
/
mol
dm–3
at
the
start
6
3
0
0
after
1
min
4
2
1
2
The
rate
of
reaction
can
be
measured
by
reference
to
any
reactant
or
product.
Which
rates
are
correct
for
this
reaction?
12.
Aqueous
solutions
of
AgNO3,
Cu(NO3)2
and
Cr(NO3)3
are
electrolyzed
using
the
same
quantity
of
electricity.
How
do
the
number
of
moles
of
metal
formed
compare?
A. Ag = Cu = Cr
13. What occurs during the operation of a voltaic cell based on the following reaction?
4
External
circuit
Ion
movement
in
solution
A.
electrons
move
from
Ni
to
Pb
Pb2+(aq)
move
away
from
Pb(s)
B.
electrons
move
from
Ni
to
Pb
Pb2+(aq)
move
toward
Pb(s)
C.
electrons
move
from
Pb
to
Ni
Ni2+(aq)
move
away
from
Ni(s)
D.
electrons
move
from
Pb
to
Ni
Ni2+(aq)
move
toward
Ni(s)
(Total
1
mark)
14.
A
sealed
container
at
room
temperature
is
half
full
of
water.
The
temperature
of
the
container
is
increased
and
left
for
equilibrium
to
re-‐establish.
Which
statement
is
correct
when
the
equilibrium
is
re-‐established
at
the
higher
temperature?
A. The rate of vaporization is greater than the rate of condensation.
B. The amount of water vapour is greater than the amount of liquid water.
C. The amount of water vapour is greater than it is at the lower temperature.
D.
The
rate
of
condensation
is
greater
than
the
rate
of
vaporization.
(Total
1
mark)
15. Hydrogen and carbon dioxide react as shown in the equation below.
For this reaction the values of Kc with different temperatures are
Temperature / K Kc
500
7.76×10–3
700
1.23×10–1
900
6.01×10–1
B. H2O(g) and CO(g) are more stable than H2(g) and CO2(g).
16. Which statement(s) is/are true for a mixture of ice and water at equilibrium?
5
II.
The
amounts
of
ice
and
water
are
equal.
III. The same position of equilibrium can be reached by cooling water and heating ice.
A. I only
C. II only
D.
III
only
(Total
1
mark)
17.
A
liquid
and
its
vapour
are
at
equilibrium
inside
a
sealed
container.
Which
change
would
alter
the
equilibrium
vapour
pressure
of
the
liquid
in
the
container?
18.
Values
of
a
rate
constant,
k,
and
absolute
temperature,
T,
can
be
used
to
determine
the
activation
energy
of
a
reaction
by
a
graphical
method.
Which
graph
produces
a
straight
line?
A. k versus T
B. k versus
C. ln k versus T
D.
ln
k
versus
(Total
1
mark)
19.
At
25°C,
100
cm3
of
1.0
mol
dm–3
hydrochloric
acid
is
added
to
3.5
g
of
magnesium
carbonate.
If
the
sample
of
magnesium
carbonate
is
kept
constant,
which
conditions
will
not
increase
the
initial
rate
of
reaction?
Volume
of
HCl
/
cm3
Concentration
of
HCl
/
mol
dm–3
Temperature
/
°C
A.
200
1.0
25
B.
100
2.0
25
C.
100
1.0
35
D.
200
2.0
25
(Total
1
mark)
20 Which statement is correct about the rate expression for a chemical reaction?
6
A.
It
can
be
determined
from
its
chemical
equation.
B. It can be predicted from the value of ΔHӨ for the reaction.
C. It can be calculated from the effect of temperature on the reaction.
D.
It
can
be
determined
by
measuring
the
change
in
concentration
of
a
reactant
or
product
over
time.
21.
What
happens
to
the
rate
constant
(k)
and
activation
energy
(Ea)
of
a
reaction
when
the
temperature
is
increased?
Rate = k[P][Q]
Which of the units below is a possible unit for k?
23. The reaction 2X(g) + Y(g) ® 3Z(g) has the rate expression
rate = k [X]2[Y]0
The
concentration
of
X
is
increased
by
a
factor
of
three
and
the
concentration
of
Y
is
increased
by
a
factor
of
two.
By
what
factor
will
the
reaction
rate
increase?
A. 6
B. 9
C. 12
D.
18
(Total
1
mark)
7
24.
Separate
solutions
of
HCl(aq)
and
H2SO4(aq)
of
the
same
concentration
and
same
volume
were
completely
neutralized
by
NaOH(aq).
X
kJ
and
Y
kJ
of
heat
were
evolved
respectively.
Which
statement
is
correct?
A. X = Y
B. Y = 2X
C. X = 2Y
D.
Y
=
3X
(Total
1
mark)
25. Which step in a multi-‐step reaction is the rate determining step?
26. Consider the specific heat capacity of the following metals.
Which
metal
will
show
the
greatest
temperature
increase
if
50
J
of
heat
is
supplied
to
a
0.001
kg
sample
of
each
metal
at
the
same
initial
temperature?
A. Cu
B. Ag
C. Au
D.
Pt
(Total
1
mark)
27. An equation for a reaction in which hydrogen is formed is
Which energy change occurs when 1 mol of hydrogen is formed in this reaction?
8
A.
70
kJ
of
energy
are
absorbed
from
the
surroundings.
I. The enthalpy of the products is less than the enthalpy of the reactants.
III. The bond enthalpy total for the reactants is greater than for the products.
A.
Bond
enthalpies
have
positive
values
for
strong
bonds
and
negative
values
for
weak
bonds.
9
B.
Bond
enthalpy
values
are
greater
for
ionic
bonds
than
for
covalent
bonds.
D.
The
carbon–carbon
bond
enthalpy
values
are
the
same
in
ethane
and
ethene.
(Total
1
mark)
31.
Which
of
the
quantities
in
the
enthalpy
level
diagram
below
is
(are)
affected
by
the
use
of
a
catalyst?
Time
A. I only
B. III only
10
O–H
z
Which calculation will give the value, in kJ mol–1, of DHӨ for the reaction?
A. 2x + y –2z
B. 4z – 2x – y
C. 2x + y – 4z
D.
2z
–2x
–
y
(Total
1
mark)
34. What is the molecular geometry and the Cl–I–Cl bond angle in the ICl4– ion?
C. Tetrahedral 109°
35.
Which
equation
represents
an
acid-‐base
reaction
according
to
the
Lewis
theory
but
not
the
Brønsted-‐Lowry
theory?
A. NaF
B. CsF
C. MgF2
D.
BaF2
(Total
1
mark)
11
B.
CH4(g)
+
1½O2(g)
→
CO(g)
+
2H2O(l)
38. The Ka value for an acid is 1.0×10–2. What is the Kb value for its conjugate base?
A. 1.0×10–2
B. 1.0×10–6
C. 1.0×10–10
D.
1.0×10–12
(Total
1
mark)
A. CO2
B. PF3
C. CH4
D.
BF3
(Total
1
mark)
A. SiO2
B. Na2O
C. MgCl2
D.
CsF
(Total
1
mark)
41.
Which
one
of
the
following
species
can
act
as
both
a
Brønsted-‐Lowry
acid
and
base
in
aqueous
solution?
A. CH3COOH
12
B.
NO3–
C. H2PO4–
D.
OH–
(Total
1
mark)
42. Which types of hybridization are shown by the carbon atoms in the compound CH2 = CH-‐CH3?
I. sp
II. sp2
III. sp3
II. It has two lone pairs of electrons on the N atom.
44. Based on electronegativity values, which bond is the most polar?
A. B―C
13
B.
C―O
C. N―O
D.
O―F
(Total
1
mark)
A. H2CO
B. SO3
C. NF3
D.
CHCl3
(Total
1
mark)
A. H2CO
B. SO3
C. NF3
D.
CHCl3
(Total
1
mark)
47. Which combination of ion charge and ion size produces the greatest lattice enthalpy?
48. Which statement is correct about multiple bonding between carbon atoms?
49. Which of the following contain a bond angle of 90°?
I. PC14+
14
II.
PCl5
III. PCl6–
50.
Which
of
the
following
increase(s)
for
the
bonding
between
carbon
atoms
in
the
sequence
of
molecules
C2H6,
C2H4
and
C2H2?
A. I only
C. III only
51. Which combination is correct for the complex ion in [Co(NH3)4(H2O)Cl]Br?
52. Which salts form coloured solutions when dissolved in water?
I.
FeCl3
II.
NiCl2
III.
ZnCl2
15
D.
I,
II
and
III
(Total
1
mark)
53. Which general trends are correct for the oxides of the period 3 elements (Na2O to Cl2O)?
A. a negative charge
55. Which of the following salts form coloured solutions when dissolved in water?
I. ScCL3
II. FeCl3
III. NiCl2
IV. ZnCl2
16
(Total
1
mark)
56. Which ion would undergo the greatest deflection in a mass spectrometer?
16 +
A.
O
16 2+
B.
O
18 2+
C.
O
D.
(16O18O)+
(Total
1
mark)
When the oxidation-‐reduction equation above is balanced, what is the coefficient for H+(aq)?+
A. 1
B. 2
C. 3
D.
4
(Total
1
mark)
58. Which statement(s) is/are generally true about the melting points of substances?
I.
Melting
points
are
higher
for
compounds
containing
ions
than
for
compounds
containing
molecules.
II.
A
compound
with
a
low
melting
point
is
less
volatile
than
a
compound
with
a
high
melting
point.
III. The melting point of a compound is decreased by the presence of impurities.
A. I only
59. Which of the following contains the greatest number of molecules?
A. 1 g of CH3Cl
B. 1 g of CH2Cl2
C. 1 g of CHCl3
D.
1
g
of
CCl4
(Total
1
mark)
17
60.
When
excess
BaCl2(aq)
was
added
to
a
sample
of
Fe(NH4)2(SO4)2(aq)
to
determine
the
amount
in
moles
of
sulfate
present,
5.02×10–3
mol
of
BaSO4
was
obtained.
How
many
moles
of
sulfate
ions
and
iron
ions
were
in
the
sample
of
Fe(NH4)2(SO4)2?
Amount
of
sulfate
ions
/
moles
Amount
of
iron
ions
/
moles
A.
5.02×10–3
2.51×10–3
B.
10.04×10–3
5.02×10–3
C.
2.51×10–3
5.02×10–3
D.
10.04×10–3
2.51×10–3
(Total
1
mark)
61.
Which
contains
the
same
number
of
ions
as
the
value
of
Avogadro’s
constant?
18