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# c c

## PRÁCTICA: PODER REDUCTOR DE LOS METALES. VOLUMETRIAS REDOX.

c
A) PODER REDUCTOR DE LOS METALES

INTRODUCCIÓN
c
ccc
  c c
c cc c c c c c c
c  cc c c ccc c cc  c c
c  cc c  cc

c  ccc c cc c cc c cc c c cc c c
c   c c   c c   c c c c  c  c  c c  c  c
c  cc  cc
c  c  c c cc  c  c
c
 cc!c" £#!c c \$ ccc  c cc
c
#! &!
% £% c!c cc
cc%#!c%#!c c cc  c
c
' c cccc  c   c  c cc  c  cc  c
cc( c) c*cDc*#!c!c# c'cccc  cc cc  ccc c
c c  c c c c +c c c c  c  c c  c   c c  c  c
  c  c  c  c  c c  c  ,c c  c c c c c  c   c
-.c) cc  cc c c
c. c.c ccc cc c/c c
c
0  c c) c c c 0 cc*c 10 .cc cc c c   23c c
c 10 .c c  c c c  c  c c c c c
2c 
c c
  ,c  c c c  c  ,c c  c c c c c *#!c c   c  c  c c   c
c
c c c c ccc cc c cc0 #!cc  c cc cc
  cc*ccc c c0 c. c 4 c cc c  cc*c c c c
cc0 c ccc*cc ccc
 c cc0 c
c
( c cc c. c  c 5cc c c c) cc+ cc c
 c c c  c  c c
c c + c 6%c °c %#!c !c # 7c  c c  c c c
+  cc+ c  c#8!c!c# °c8#c'c  cccc c  c4 cc c
 c   c  c c c 8!c 'c c 
c   c  c %c !c 8#- °c %- 67c !c 8#67c  c
 c  ccc cc  cc c c  c cc8#67ccccc+ c c c
 5cc. c  ccc
 c c ccc  c c  cc c  c
 cc
ccc cc  c. c ccc+  c
c
PARTE EXPERIMENTAL
c
c c c c c \$5 c
c9c c , cc  c c c  cc0 - c:;cc
c<  c c c c c c  cc*- c:;cc
c= cc cc c c c  cc>>&c:;cc
c   c c c c c c  cc8#- #:cc
c c c c c c c0c6c7c c c c c
c c c c c c c0 ,c6c,7c c c c c c
c c

PROCEDIMIENTO

## c (c?c , cc  c #"c'cc c   cc c   c5 cc@c c

  ccc ccc,c
c A , c
c ;c #c &c c "c ?c
  c 8 - c 8 - c >> c >> c 0 - c *- c
# # & &
c *c 0 c *c 0 c *c 0 c
c
c , 5c c , cc c cc  c, c ccc c  c)c c c
 , c c c  cc cc(B\$Ac<7cc c.cBcc , 5cc c  c
  c c+c  c c    cC c c  ccc
c

## B) VOLUMETRIAS REDOX: DETERMINACION DE HIERRO (II) EN DISOLUCIONES

INTRODUCCIÓN
c 'cccc cc c  cc c
c cc c  c c  c
 cc ,cc5 c
c(c5 c c   c cc c
 c c  c
D c D#0#Ec D<&c c 06- 7#c -c c c D c c 5 c c c c c c
 c  c c   c 5 c c   c  c c   c c  5c   c  c  c c
 c  .  c  c c   c 5 c  c  c  c c  c 6FF7c c    c c  c
. c c+c cc  c
c  c c c@ccc  cc5 c
c c c  c ) c  c Bc !c ,<c £c 0c !c c  c Bc c
c c <c c   c c
 ccc  cc 5c cc
c ,G/cc  cc
cHcG/cc  cc  c
c c cc ,G=
l
cHcG=lc

 c cc   c cc  c  c cc  c6c cc
c cc
  7c
c

## PARTE EXPERIMENTAL: permanganimetría de Fe (II) en disoluciones

c
c c c
 c c5.cc, cc5 cc c  ccD c c
 c  c
6c 7c  c  c+c  cccc5  4cc%c6FF7cc
c  c c ,c
c
c c c c \$5 c
cc#":c'c c
 c  c60# >#7c
(cc;:c'cc c c B c  c#::cc
< cc#"c'c c c   cc6D 7c::#::cc6 7c
(   c c c   c ,cc  c c c+
+ cc
= cc cc":'c c c%6>8 7#6- 7#l?8#c6-cc +7c
   c
0 c
( ,cc;::c'c
c
c c  c  .  c  c c 5 c  c  c c c ,   c c 5   c c

  c 6c c  c  7c -c c c c c
c 4 c c c
 c. ccc c cc#!c
c c

## B.FACTORIZACIÓN DE LA DISOLUCION DE PERMANGANATO CON OXALATO DE SODIO

c c

c cc
 c60# # 7c c
cc
 cc,  c60#7c
c ( c c c
 cc:;::cc:;#:ccc
 c  c5c  c c
 c+  cc;:"/c0cc 5cc  c?:c'cc c cB@c  c;Ic'cc. c  c#::c
c6;I7c cc   ccc  cI:/c0ccc,@ c  cc5 c cc  cc
 c  c c c , c + c ,c c 4,c   c  c  c  c
  c
c \$ c  c  c  c 5   c  c   c c   c c c  c
 c c   c c 5 c  c . c  c   c c   c c c c  c ,) c c
cccc , 5c
cc5)cc  c c. ccc c5   cc
 c c<cc0c
c 'c c c c  c c c
 c ,c + c c c c  c c
5 cccc'cc
c ,c6 c) 7c c , c  c  c
0# # c!c c!c8!Dc#!c!c0#c!c8#c
c
C. DETERMINACION DE HIERRO (II) EN UNA DISOLUCION ACUOSA DE SAL DE MOHR
c
c 0 c cc cc
c;:c'ccc  c ,cc5 c 4  cc
ccc#":c'cB@c  cE"c'cc c c c c ,cc;I'cc. c  c
#::cc c c   c= c cc  cc c ccc, c+ c cc
  ccc  c cc c\$cc5 c'cc
c ,c6 c) 7c c
 c!c%#!c!c8!Dc#!c!c%&!c!c8#c