Analisis de una ecuacion de una variable no lineal

No.
1

P(atm) 10
a(atm L2/mol2) 4.1991104
b(L/mol K) 0.0373767
R(atm L/mol K) 0.08206
T(K) 523.15
Tc(K) 405.65
Pc(atm) 111.32494

h 0.01

Declaración cambio de variabloe. x=V

x f(x) Metodo del punto fijo

4 -2.263487 g(x) g´(x)
4.01 -2.166056 4.220560253 0.0534888694
4.02 -2.068613 4.22109321 0.053103229
4.03 -1.971157 4.22162233 0.0527212542
4.04 -1.873688 4.222147647 0.0523429018
4.05 -1.776207 4.2226692 0.0519681294
4.06 -1.678713 4.223187022 0.0515968952
4.07 -1.581208 4.223701149 0.0512291579
4.08 -1.48369 4.224211616 0.0508648768
4.09 -1.386161 4.224718458 0.0505040117
4.1 -1.288619 4.225221708 0.050146523
4.11 -1.191066 4.2257214 0.0497923717
4.12 -1.0935 4.226217566 0.0494415193
4.13 -0.995923 4.226710241 0.0490939278
4.14 -0.898335 4.227199456 0.0487495597
4.15 -0.800735 4.227685243 0.048408378
4.16 -0.703123 4.228167634 0.0480703463
4.17 -0.605501 4.22864666 0.0477354287
4.18 -0.507866 4.229122353 0.0474035897
4.19 -0.410221 4.229594742 0.0470747942
4.2 -0.312565 4.230063858 0.0467490078
4.21 -0.214897 4.230529732 0.0464261964
4.22 -0.117219 4.230992392 0.0461063263
4.23 -0.01953 4.231451868 0.0457893646
4.24 0.0781704 4.231908189 0.0454752783
4.25 0.1758811 4.232361383 0.0451640354
4.26 0.2736026 4.232811479 0.0448556039
4.27 0.3713346 4.233258505 0.0445499524
4.28 0.4690771 4.233702487 0.04424705
4.29 0.5668301 4.234143455 0.0439468659
4.3 0.6645934 4.234581434 0.0436493702
4.31 0.762367 4.235016451 0.0433545329
4.32 0.8601508 4.235448533 0.0430623246
4.33 0.9579447 4.235877706 0.0427727164
4.34 1.0557488 4.236303996 0.0424856797
4.35 1.1535628 4.236727428 0.0422011862
4.36 1.2513868 4.237148028 0.0419192079
4.37 1.3492206 4.237565821 0.0416397174
4.38 1.4470643 4.237980831 0.0413626875
4.39 1.5449177 4.238393082 0.0410880915
4.4 1.6427808 4.2388026 0.0408159027
4.41 1.7406535 4.239209408 0.0405460952
4.42 1.8385357 4.23961353 0.040278643
4.43 1.9364274 4.240014989 0.0400135209

k xl xu xr f(Xl) f(Xu ) f(Xr )

0 4.23 4.24 4.235 -0.0195297048 0.0781703541 0.029318979
1 4.23 4.235 4.2325 -0.0195297048 0.0293189791 0.0048943
2 4.23 4.2325 4.23125 -0.0195297048 0.0048943002 -0.00731779
3 4.23125 4.2325 4.231875 -0.0073177866 0.0048943002 -0.00121176
4 4.231875 4.2325 4.2321875 -0.0012117643 0.0048943002 0.001841263
5 4.231875 4.2321875 4.23203125 -0.0012117643 0.0018412627 0.000314748
6 4.231875 4.23203125 4.231953125 -0.0012117643 0.0003147479 -0.00044851
7 4.2319531 4.23203125 4.231992188 -0.0004485085 0.0003147479 -6.68804E-05
8 4.2319922 4.23203125 4.232011719 -6.688039E-05 0.0003147479 0.000123934
9 4.2319922 4.232011719 4.232001953 -6.688039E-05 0.0001239337 2.852666E-05
10 4.2319922 4.232001953 4.23199707 -6.688039E-05 2.852666E-05 -1.91769E-05
11 4.2319971 4.232001953 4.231999512 -1.917687E-05 2.852666E-05 4.674899E-06
12 4.2319971 4.231999512 4.231998291 -1.917687E-05 4.674899E-06 -7.25098E-06
13 4.2319983 4.231999512 4.231998901 -7.250983E-06 4.674899E-06 -1.28804E-06
14 4.2319989 4.231999512 4.231999207 -1.288042E-06 4.674899E-06 1.693428E-06
15 4.2319989 4.231999207 4.231999054 -1.288042E-06 1.693428E-06 2.026932E-07
 16 4.2319989 4.231999054 4.231998978 -1.288042E-06 2.026932E-07 -5.42674E-07
17 4.231999 4.231999054 4.231999016 -5.426745E-07 2.026932E-07 -1.69991E-07
18 4.231999 4.231999054 4.231999035 -1.699906E-07 2.026932E-07 1.635128E-08
19 4.231999 4.231999035 4.231999025 -1.699906E-07 1.635128E-08 -7.68197E-08
20 4.231999 4.231999035 4.23199903 -7.681967E-08 1.635128E-08 -3.02342E-08
21 4.231999 4.231999035 4.231999032 -3.02342E-08 1.635128E-08 -6.94146E-09
22 4.231999 4.231999035 4.231999034 -6.941455E-09 1.635128E-08 4.704908E-09
23 4.231999 4.231999034 4.231999033 -6.941455E-09 4.704908E-09 -1.11828E-09
24 4.231999 4.231999034 4.231999033 -1.118281E-09 4.704908E-09 1.79331E-09
25 4.231999 4.231999033 4.231999033 -1.118281E-09 1.79331E-09 3.375149E-10
26 4.231999 4.231999033 4.231999033 -1.118281E-09 3.375149E-10 -3.90379E-10
27 4.231999 4.231999033 4.231999033 -3.903793E-10 3.375149E-10 -2.64322E-11
28 4.231999 4.231999033 4.231999033 -2.643219E-11 3.375149E-10 1.555307E-10
29 4.231999 4.231999033 4.231999033 -2.643219E-11 1.555307E-10 6.45457E-11
30 4.231999 4.231999033 4.231999033 -2.643219E-11 6.45457E-11 1.906386E-11
31 4.231999 4.231999033 4.231999033 -2.643219E-11 1.906386E-11 -3.68772E-12
32 4.231999 4.231999033 4.231999033 -3.687717E-12 1.906386E-11 7.680967E-12
33 4.231999 4.231999033 4.231999033 -3.687717E-12 7.680967E-12 2.003731E-12

En la iteracion 11 se cumple la tolerancia asociada 1E-5 y asi la respuesta es la siguiente

V(L/mol) 4.2319995

k x f(x) f´(x) |f(x)|

0 4.23 -0.0195297 9.769467056 0.0195297048
1 4.2319991 2.157321E-07 9.769682839 2.1573208E-07
2 4.231999 0 9.769682837 0
3 4.231999 0 9.769682837 0
4 4.231999 0 9.769682837 0
5 4.231999 0 9.769682837 0
6 4.231999 0 9.769682837 0

En la iteración 1 se cumple la tolerancia de 1E-05, asi la respúesta es la siguiente,

V(L/mol) 4.2319991
 k x g(x) f(x) |f(x)|
0 4.23 4.231908189 -0.0195297 0.0195297048
1 4.2319082 4.231994908 -0.00088752 0.0008875182
2 4.2319949 4.231998846 -4.0306E-05 4.0305992E-05
3 4.2319988 4.231999025 -1.83041E-06 1.8304119E-06
4 4.231999 4.231999033 -8.31242E-08 8.3124199E-08
5 4.231999 4.231999033 -3.77491E-09 3.7749075E-09
6 4.231999 4.231999033 -1.71433E-10 1.7143265E-10
7 4.231999 4.231999033 -7.78755E-12 7.7875484E-12
8 4.231999 4.231999033 -3.48166E-13 3.4816594E-13
9 4.231999 4.231999033 0 0
10 4.231999 4.231999033 0 0
11 4.231999 4.231999033 0 0
12 4.231999 4.231999033 0 0
13 4.231999 4.231999033 0 0
14 4.231999 4.231999033 0 0
15 4.231999 4.231999033 0 0
16 4.231999 4.231999033 0 0
17 4.231999 4.231999033 0 0
18 4.231999 4.231999033 0 0

En la iteracion 3 se cumple la tolerancia de 1E-05, asi la respuesta es la siguiente,

V(L/mol) 4.231999
Sustancia Tc (K) Pc (kPa)
Azano 405.65 11280

2.5 f(x) vs x
2

1.5

0.5

0
3.95 4 4.05 4.1 4.15 4.2 4.25
-0.5

-1

-1.5

-2

-2.5

XAprox 4.235
 f(Xaprox) 0.02931898

P(atm) 10
a(atm L2/mol2) 4.19911036
b(L/mol K) 0.03737666
R(atm L/mol K) 0.08206
T(K) 523.15
f(xl)f(xr) lf(xr)l Tc(K) 405.65
-0.000572591 0.029318979 Pc(atm) 111.324944
-9.558424E-05 0.0048943
0.0001429142 0.007317787
8.8674324E-06 0.001211764
-2.231176E-06 0.001841263
-3.814003E-07 0.000314748
5.434866E-07 0.000448509
2.9996426E-08 6.688039E-05
-8.288737E-09 0.000123934
-1.907875E-09 2.852666E-05
1.2825563E-09 1.917687E-05
-8.964991E-11 4.674899E-06
1.3905113E-10 7.250983E-06
9.3395718E-12 1.288042E-06
-2.181207E-12 1.693428E-06
-2.610774E-13 2.026932E-07
6.9898756E-13 5.426745E-07
9.224958E-14 1.699906E-07
-2.779564E-15 1.635128E-08
1.3058626E-14 7.681967E-08
2.3225812E-15 3.02342E-08
2.0986933E-16 6.941455E-09
-3.265891E-17 4.704908E-09
7.7624948E-18 1.118281E-09
-2.005424E-18 1.79331E-09
-3.774364E-19 3.375149E-10
4.3655357E-19 3.903793E-10
1.0318579E-20 2.643219E-11
-4.111017E-21 1.555307E-10
-1.706084E-21 6.45457E-11
-5.038996E-22 1.906386E-11
9.747443E-23 3.687717E-12
-2.832523E-23 7.680967E-12
-7.389191E-24 2.003731E-12

P(atm) 10
a(atm L2/mol2) 4.19911036
b(L/mol K) 0.03737666
R(atm L/mol K) 0.08206
T(K) 523.15
Tc(K) 405.65
Pc(atm) 111.324944
 P(atm) 10
a(atm L2/mol2) 4.19911036
b(L/mol K) 0.03737666
R(atm L/mol K) 0.08206
T(K) 523.15
Tc(K) 405.65
Pc(atm) 111.324944
 f(x) vs x

1 4.15 4.2 4.25 4.3 4.35 4.4 4.45