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Engineering
Volume 2, Issue 1 2006 Article 5
∗
Firat University, Elazig-Turkey, eakpinar@firat.edu.tr
†
Firat University, Elazig-Turkey, ybicer@firat.edu.tr
Copyright
2006
c The Berkeley Electronic Press. All rights reserved.
Mathematical Modeling and Experimental
Study on Thin Layer Drying of Strawberry
Ebru Kavak Akpinar and Yasar Bicer
Abstract
This paper presents mathematical modeling and the thin layer convective drying of straw-
berry. The experiments are conducted at drying air temperatures of 60, 75 and 85 deg.C in drying
air velocities of 0.5, 1 and 1.5 m/s in a convective cyclone type dryer. The data of sample mass,
temperature and velocity of the drying air were recorded continuously during each test. The ex-
perimental drying curves show only a falling drying rate period. The main factor in controlling
the drying rate was found to be the drying air temperature. Also, the experimental drying curves
obtained were fitted to eleven mathematical models. The Modified Page (I) drying model was
found to satisfactorily describe the drying curves of strawberry with a correlation coefficient (R)
of 0.98042, chi-square (2) of 0.0035 and root mean square error (RMSE) of 0.0588. The constants
and coefficients of this model could be explained by the effect of drying air temperature and ve-
locity with a correlation coefficient (R) of 0.998. The effective diffusivity coefficient of moisture
transfer varied from 4.528x10-10 to 9.631x10-10 m2/s over the temperature and velocity range in
this study.
1. INTRODUCTION
• to study the effect of temperature and velocity on air drying kinetics of the
strawberry samples in a cyclone type dryer,
• to fit the drying curves with eleven mathematical models,
• to calculate the diffusivity coefficients of the samples.
Figure 1 illustrates the schematic diagram of the cyclone type dryer. The
system was introduced in the literature (Akpinar et al., 2003a; Akpinar et al.,
2003; Akpinar et al., 2003b). Briefly, it consists of fan, resistance and heating
control systems, air-duct, drying chamber in cyclone type, and measurement
instruments. The heating system consisted of an electric 4000 W heater placed
inside the duct. The rectangular duct included air fan and resistance was
constructed from sheet iron in 1000 mm length, 200 mm width and 250 mm
height. The drying chamber was constructed from sheet iron in 600 mm
diameter and 800 mm height cylinder. In the measurements of temperatures, J
type iron-constantan thermocouples were used with a manually controlled 20-
channel automatic digital thermometer (ELIMKO, 6400, Turkey), with
reading accuracy of ±0.1 °C. A thermo hygrometer (EXTECH, 444731,
China) was used to measure humidity levels at various locations of the system.
A 0-15 m/s range anemometer (LUTRON, AM-4201, Taiwan) measured the
velocity of air passing through the system. Moisture loss was recorded at 20
minutes intervals during drying for determination of drying curves by a digital
balance (BEL, Mark 3100, Italy) in the measurement range of 0-3100 g and an
accuracy of ±0.01 g.
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Akpinar and Bicer: Thin Layer Drying of Strawberry
2.2. Procedure
The fresh strawberry samples were used in the experiments. Before drying
process, the strawberries were washed and divided as two pieces with a
mechanical cutter, separated from leaves. Strawberry samples were dried as
thin layer with the thickness of 5 mm at temperatures of 60, 75 and 85oC in the
velocity of drying air of 0.5, 1 and 1.5 m/s. Drying of strawberry samples
started with an initial moisture content around 89.6 % (wb) and continued until
no further changes in their mass were observed, e.g. to the final moisture
content of about 10% (wb), which was then taken as the equilibrium moisture
content in the later computations.
The strawberry samples were carefully and orderly placed as 450 each g as 5
mm-distance between each slice on the trays that is made of nylon so that the
airflow could pass across the trays. The initial and final moisture contents of
the strawberry samples were determined by drying duplicate samples in an
oven at 70 °C for 72 h. After dryer is reached at steady state conditions for
operation temperatures, the samples are put on the tray and dried there.
During the experiments, ambient temperature and relative humidity, inlet
and outlet temperatures of drying air in the duct and dryer chamber were
recorded. In the calculations, the dry basis values were used. Figure 2 shows
the process flow diagram of drying, pursued in this work for strawberry
samples.
Thin layer drying models that describe the drying phenomenon of agricultural
materials mainly fall into three categories, namely theoretical, semi-theoretical
and empirical (Midilli et al., 2002; Panchariya et al., 2002). The first takes into
account only internal resistance to moisture transfer while the other two
consider only external resistance to moisture transfer between product and air
(Bruce, 1985; Parti, 1993; Ozdemir and Devres, 1999). The most widely
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Akpinar and Bicer: Thin Layer Drying of Strawberry
investigated theoretical drying model has been Fick’s second law of diffusion.
Drying of many food products such as rice (Ece and Cihan, 1993) and
hazelnut (Demirtas et al., 1998) has been successfully predicted using Fick’s
second law. Semi-theoretical models offer a compromise between theory and
ease of use (Fortes and Okos, 1981). Simplifying general series solution of
second law Fick’s or modification of simplified models generally derives
semi-theoretical models. But they are only valid within the temperature,
relative humidity, and airflow velocity and moisture content range for which
they were developed. They require small time compared to theoretical thin
layer models and do not need assumptions of geometry of a typical food, its
mass diffusivity and conductivity (Parry, 1985). Among semi theoretical thin
layer drying models, the Newton model, Page model, the modified Page model
(I and II), the Henderson and Pabis model, the logarithmic model, the two-
term model, the two-term exponential, the diffusion approach model, and the
Verma et al. model are used widely. Empirical models derive a direct
relationship between average moisture content and drying time. They neglect
fundamentals of the drying process and their parameters have no physical
meaning. Therefore they cannot give clear accurate view of the important
processes occurring during drying although they may describe the drying
curve for the conditions of the experiments (Ozdemir and Devres, 1999).
Among them, the Wang and Singh model has been found application in the
literature.
Moisture ratios of strawberry samples (MR) during the thin layer drying
experiments were calculated by using the following equation (Akpinar et al.,
2003).
W − We
MR = t (1)
Wi − We
For mathematical modeling, the thin layer drying equations in Table 2 were
tested to select the best model for describing the drying curve equation of
strawberry samples during drying process by the convective cyclone type
dryer. The regression analysis was performed using Statistica computer
program. The correlation coefficient (R) was primary criterion for selecting the
best equation to describe the drying curve equation. In addition to R, the
reduced χ2 as the mean square of the deviations between the experimental and
calculated values for the models and root mean square error
analysis (RMSE) were used to determine the goodness of the fit. The higher
the values of the R, and lowest values of the χ2 and RMSE, the better the
goodness of the fit (Yaldiz and Ertekin, 2001; Akpinar et al., 2003a; Akpinar
et al., 2003; Akpinar et al., 2003; Gunhan et al., 2005; Doymaz et al., 2004;
Sacilik and Elicin, 2005). These can be calculated as:
∑ (MR )
n
− MR pre,i
2
exp ,i
i =1
χ2 = (2)
N−n
1/ 2
⎡1 N 2⎤
RMSE = ⎢ ∑ (MR pre,i − MR exp,i ) ⎥ (3)
⎣ N i =1 ⎦
The strawberries of 8.61 g water/g dry matter average initial moisture content
were dried to 0.10 g water/g dry matter using different air temperatures (60, 75
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Akpinar and Bicer: Thin Layer Drying of Strawberry
and 85 oC) and different air velocities (0.5, 1 and 1.5 ms-1). Figure 3 presents
the variations of moisture content with drying time based on drying air
temperatures and at drying air velocities. The times to reach 0.10 g water/g dry
matter moisture content from the initial moisture content at the various drying
air temperature and velocity of the strawberry samples were found to be
between 12000 and 33600 seconds.
Moisture content (g water/g dry matter)
10
V=1.5 m/s, T=85 C
9 V=1 m/s, T=85 C
8 V=0.5 m/s, T=85 C
7 V=1.5 m/s, T=75 C
V=1m/s, T=75 C
6 V=0.5m/s, T=75 C
5 V=1.5 m/s, T=60 C
V=1 m/s, T=60 C
4 V=0.5 m/s, T=60 C
3
2
1
0
0 4800 9600 14400 19200 24000 28800 33600 38400
Drying time
Figure 3. Variation of moisture content with drying time of strawberry samples at
different temperatures and velocities
0.0025
0.0005
0
0 4800 9600 14400 19200 24000 28800 33600 38400
Drying time
Figure 4. Variation of drying rate with drying time of strawberry samples at different
temperatures and velocities
0.0025
Drying rate (g water/g dry matter.s)
0.0005
0
0 1 2 3 4 5 6 7 8 9 10
Moisture content (g water/g dry matter)
In order to normalise the drying curves, the data involving dry basis moisture
content versus time were transformed to a dimensionless parameter called as
moisture ratio versus time (Figure 6). The moisture content data at the
different drying air temperatures and velocities were converted to the most
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Akpinar and Bicer: Thin Layer Drying of Strawberry
1.2
V=1.5 m/s, T=85 C
1 V=1 m/s, T=85 C
V=0.5 m/s, T=85 C
(Wt-We)/(Wi-We) V=1.5 m/s, T=75 C
0.8 V=1m/s, T=75 C
V=0.5m/s, T=75 C
0.6 V=1.5 m/s, T=60 C
V=1 m/s, T=60 C
0.4 V=0.5 m/s, T=60 C
0.2
0
0 4800 9600 14400 19200 24000 28800 33600 38400
Drying time
useful moisture ratio expression and then curve fitting computations with the
drying time were carried on the 11 drying models evaluated by the previous
workers. The results of statistical analyses undertaken on these models are
given in Table 3. The models were evaluated based on R, χ2and RMSE
(Ertekin and Yaldiz, 2004; Gunhan et al., 2005). These curve fitting criteria
for the there models were shown in Table 1. The Modified Page (I) model was
the best descriptive model as shown in Table 3. Generally, R, χ2 and RMSE
values were varied between 0.61718-0.98042, 0.0034993-0.0562449 and
k=-0.00008781+0.0000035*T+0.000036*V
n=0.796264+0.004795*T-0.047211*V
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Experimental values
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Akpinar and Bicer: Thin Layer Drying of Strawberry
dW d2W
=D 2 (4)
dt dr
Wt − We 8 ∞
1 ⎡ − (2n + 1)2 π 2 Dt ⎤
MR = =
Wi − We π 2
∑
n =1 (2n + 1)
2
exp ⎢
4L2
⎥ (5)
⎣ ⎦
For sufficiently long drying times, only the 1st term of n=1 in Equation (5) can
be used with small error.
Effective moisture diffusivity was calculated by Eq. (5), using slopes derived
from the linear regression of ln (MR) vs time data shown Figure 8. It is noticed
that the drying curves have a concave form when the curves of ln (MR)-time
are analysed (Akpinar et al., 2003a; Akpinar et al., 2003; Akpinar et al.,
2003b).
V=1.5 m/s, T=85 C V=1 m/s, T=85 C V=0.5 m/s, T=85 C
V=1.5 m/s, T=75 C V=1m/s, T=75 C V=0.5m/s, T=75 C
V=1.5 m/s, T=60 C V=1 m/s, T=60 C V=0.5 m/s, T=60 C
1
0
-1 0 4800 9600 14400 19200 24000 28800 33600 38400
(In( /8)*MR)
-2
-3
-4
2
-5
-6
-7
-8
Drying time
12
10
8
Dx10 (m /s)
2
6
10
4
T=85 C
2 T=75 C
T=60 C
0
0.4 0.6 0.8 1 1.2 1.4 1.6
Figure 9. Variation of the diffusion coefficient with the velocity at the different
temperatures
4. CONCLUSIONS
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Akpinar and Bicer: Thin Layer Drying of Strawberry
ACKNOWLEDGMENT
NOMENCLATURE
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