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Clouds appear white because the light coming from the sun has to pass through the
water droplets and ice crystals or we can say that the seven colors of visible spectrum
(red, orange, yellow, green, and blue, indigo, violet) which when combines forms white
light and this process of combining isdone by water droplets or ice crystals present in
theclouds. On the whole we can say that light is reflected in many ways which combines
to give white color. Mainlyclouds at a high altitude appear white and at that height water
vapors are frozen and changed in ice crystals.
Many times cloud alsoappears dark in color it is mainly because of its altitude and
reflection of sunlight. Stormsclouds are thickestclouds. So when sunlight falls on them
from above they soak the light altogether and very negligible light reaches to our eyes
which give dark color to theclouds when we look at them from bottom but if we observe
the sameclouds from above they will be pure white.
Greyclouds are caused because of the shadow of higherclouds on the lowerclouds or
theclouds are sometimes so dense that they cast their own shadow on the base which
gives them grey color. Darkclouds not always cause rain. More the droplets formed in
theclouds more is the light absorbed in it. During sunsetclouds are orange or red because
blue color of sunlight is scattered and light has to pass through thick layer of atmosphere
and dust particles when sun is lowered in the west. Sometimes a cloudappears blue due to
the scattered blue light which makes the sky look blue.
The most unusual color is green. When reddish light falls on the cloud having large
amount of water droplets make them look green.
Clouds
What areclouds?
A cloud is a large collection of very tiny droplets of water or ice crystals.
The droplets are so small and light that they can float in the air.
Cloud Chart
Cloud Group Cloud Height Cloud Types
Cirrus
HighClouds = Cirrus Above 18,000 feet Cirrostratus
Cirrocumulus
Altostratus
MiddleClouds = Alto 6,500 feet to 18,000 feet
Altocumulus
Stratus
LowClouds = Stratus Up to 6,500 feet Stratocumulus
Nimbostratus
Cumulus
Clouds with Vertical Growth
Cumulonimbus
SpecialClouds Mammatus
Lenticular
Fog
Contrails
CirrusClouds
Cirruscloudsare the most common of the highclouds. They are composed of
ice and are thin, wispyclouds blown in high winds into long streamers.
Cirrusclouds are usually white and predict fair to pleasant weather. By
watching the movement of cirrusclouds you can tell from which direction
weather is approaching. When you see cirrusclouds, it usually indicates that
a change in the weather will occur within 24 hours.
StratusClouds
Stratuscloudsare uniform grayishclouds that often cover the entire sky.
They resemble fog thatdoesn't reach the ground. Light mist or drizzle
sometimes falls out of theseclouds.
Stratocumuluscloudsare low, puffy and gray. Most form in rows with blue sky
visible in between them. Rain rarely occurs with stratocumulusclouds,
however, they can turn into nimbostratusclouds.
CumulusClouds
Cumuluscloudsare white, puffyclouds that look like pieces of floating cotton.
Cumulusclouds are often called "fair-weatherclouds". The base of each cloud
is flat and the top of each cloud has rounded towers. When the top of the
cumulusclouds resemble the head of a cauliflower, it is called cumulus
congestus or towering cumulus. Theseclouds grow upward and they can
develop into giant cumulonimbusclouds, which are thunderstormclouds.
Cumulonimbuscloudsare thunderstormclouds. High winds can flatten the top
of the cloud into an anvil-like shape. Cumulonimbusclouds are associated with
heavy rain, snow, hail, lightning and even tornadoes. The anvil usually points in
the direction the storm is moving.
SpecialClouds
Mammatuscloudsare low hanging bulges that droop from cumulonimbusclouds.
Mammatusclouds are usually associated with severe weather.
Contrails are condensation trails left behind jet aircrafts. Contrails form
when hot humid air from jet exhaust mixes with environmental air of low
vapor pressure and low temperature. The mixing is a result of turbulence
generated by the engine exhaust.
Radiation
Laws
The average or bulk properties of electromagnetic radiation interacting with matter
are systematized in a simple set of rules called radiation laws. These laws apply when
the radiating body is what physicists call a blackbody radiator. Generally, blackbody
conditions apply when the radiator has very weak interaction with the surrounding
environment and can be considered to be in a state of equilibrium. Although stars
do not satisfy perfectly the conditions to be blackbody radiators, they do to a
sufficiently good approximation that it is useful to view stars as approximate
blackbody radiators.
The behavior is illustrated in the figure shown above. The Planck Law gives a
distribution that peaks at a certain wavelength, the peak shifts to shorter
wavelengths for higher temperatures, and the area under the curve grows rapidly
with increasing temperature.
The Wien Law gives the wavelength of the peak of the radiation distribution, while
the Stefan-Boltzmann Law gives the total energy being emitted at all wavelengths by
the blackbody (which is the area under the Planck Law curve). Thus, the Wien Law
explains the shift of the peak to shorter wavelengths as the temperature increases,
while the Stefan-Boltzmann Law explains the growth in the height of the curve as
the temperature increases. Notice that this growth is very abrupt, since it varies as
the fourth power of the temperature.
The following figure illustrates the Wien law in action for three different stars of
quite different surface temperature. The strong shift of the spectrum to shorter
wavelengths with increasing temperatures is apparent in this illustration.
For convenience in plotting these distributions have been normalized to unity at the
respective peaks; by the Stefan-Boltzmann Law, the area under the peak for the hot
star Spica is in reality 2094 times the area under the peak for the cool star Antares.
Here are three Java applets illustrating some important properties of blackbody
radiation.
RADIATION
Radiation is energy that comes from a source and travels through some material or through
space. Light, heat and sound are types of radiation. The kind of radiation discussed in this
presentation is called ionizing radiation because it can produce charged particles (ions) in matter.
Ionizing radiation is produced by unstable atoms. Unstable atoms differ from stable atoms
because they have an excess of energy or mass or both.
Unstable atoms are said to be radioactive. In order to reach stability, these atoms give off, or
emit, the excess energy or mass. These emissions are called radiation. The kinds of radiation are
electromagnetic (like light) and particulate (i.e., mass given off with the energy of motion).
Gamma radiation and X-rays are examples of electromagnetic radiation. Beta and alpha radiation
are examples of particulate radiation. Ionizing radiation can also be produced by devices such as
X-ray machines.
A scale heightis a term often used in scientific contexts for a distance over which a
quantity decreases by a factor of e (the base of natural logarithms). It is usually denoted
by the capital letter H.
For planetary atmospheres, it is the vertical distance upwards, over which the pressure of
theatmosphere decreases by a factor of e.The scale height remains constant for a
particular temperature. It can be calculated by:-
where:
• k = Boltzmann constant = 1.38 x 10−23 J·K−1
• T = mean planetary surface temperaturein kelvins
• M = mean molecular mass of dry air (units kg)
• g = acceleration due to gravity on planetary surface (m/s²)
The pressure at the Earth's surface (or at higher levels) is a result of the weight of the
overlyingatmosphere [force per unit area]. If at a height of ztheatmosphere has density ρ
and pressure P, then moving upwards at aninfinitesimally small height dz will decrease
the pressure by amount dP, equal to the weight of a layer ofatmosphere of thickness dz.
Thus:
where g is used to denote the acceleration due to gravity. For small dz it is possible to
assume gto be constant; the minus signindicates that as the heightincreases the pressure
decreases. Therefore using the equation of state for an ideal gas of mean molecular mass
M at temperature T, the density can be expressed as such:
which can then beincorporated with the equation for H given above to give:
which will not change unless the temperature does.Integrating the above and assuming
where P0 is the pressure at height z = 0 (pressure at sea level) the pressure at height z can
be written as:
In the Earth'satmosphere, the pressure at sea level P0 averages about 1.01×105Pa, the
mean molecular mass of dry air is 28.964 u and hence 28.964 × 1.660×10−27 =
4.808×10−26 kg, and g= 9.81 m/s². As a function of temperature the scale height of the
Earth'satmosphere is therefore 1.38/(4.808×9.81)×103= 29.26 m/deg. This yields the
following scale heights for representative air temperatures.
T = 290 K, H = 8500 m
T = 273 K, H = 8000 m
T = 260 K, H = 7610 m
T = 210 K, H = 6000 m
These figures should be compared with the temperature and density of the
Earth'satmosphere plotted at NRLMSISE-00, which shows the air density dropping from
1200 g/m3 at sea level to 0.53 = .125 g/m3at 70 km, a factor of 9600,indicating an average
scale height of 70/ln(9600) = 7.64 km, consistent with theindicated average air
temperature over that range of close to 260 K.
Note:
inertial force
An apparent force that appears to affect bodies within a non-inertial
frame, but is absent from the point of view of an inertial frame.
Centrifugal forces and Coriolis forces, both observed in rotating
systems, are inertial forces. Inertial forces are proportional to the
body's mass.
The shape of the cluster is a part of a sphere with the base attached
to the insoluble surface. The angle θ between the embryo surface and
the substrate surface is called the contact angle. The critical radius in
heterogeneous nucleation is the same as in homogeneous nucleation,
as it only depends on the vapor super saturation.
Diamond and Graphite
Graphite and diamond are two of the most interesting minerals. They are identical
chemically—both are composed of carbon (C), but physically, they are very different.
Minerals which have the same chemistry but different crystal structures are called
polymorphs.
When you look at graphite and diamond, it is hard to imagine that they are identical
chemically, for they are so different physically. Graphite is opaque and metallic- to
earthy-looking, while diamonds are transparent and brilliant. (See examples on display.)
The reason for the differences in hardness and other physical properties can be explained
with the molecular models below. In graphite, the individual carbon atoms link up to
form sheets of carbon atoms. Each sheet of carbon atoms is translated (offset) by one-half
of a unit such that alternate sheets are in the same position. Within each sheet every
carbon atom is bonded to three adjacent carbon atoms that lie at the apices of equilateral
triangles. This produces hexagonal rings of carbon atoms. Each carbon atom has four
valence electrons available to participate in the formation of chemical bonds. Three of
these electrons are used in forming strong covalent bonds with the adjacent atoms in the
sheet. Covalent bonds are a type of chemical bond in which electrons are shared between
atoms. The fourth electron is free to wander over the surface of the sheet making graphite
an electrical conductor. The spacing between the sheets of carbon atoms is greater than
the diameter of the individual atoms. Weak bonding forces called van der Waals forces
hold the sheets together. Because these forces are weak, the sheets can easily slide past
each other. The sliding of these sheets gives graphite its softness for writing and its
lubricating properties.
In diamonds, each carbon atom is strongly bonded to four adjacent carbon atoms located
at the apices of a tetrahedron (a three-sided pyramid). The four valence electrons of each
carbon atom participate in the formation of very strong covalent bonds. These bonds have
the same strength in all directions. This gives diamonds their great hardness. Since there
are no free electrons to wander through the structure, diamonds are excellent insulators.
The brilliance and "fire" of cut diamonds is due to a very high index of refraction (2.42)
and the strong dispersion of light; properties which are related to the structure of
diamonds.
Derivation of Lamkbert’s law for the attenuation of solar
radiation by the atmosphere.
The derivation is quite simple in concept. There are many details, so think of this first
paragraph as a conceptual overview. Divide the absorbing sample into thin slices that are
perpendicular to the beam of light. The light that emerges from a slice is slightly less
intense than the light that entered because some of the photons have run into molecules in
the sample and did not make it to the other side. For most cases where measurements of
absorption are needed, a vast majority of the light entering the slice leaves without being
absorbed. Because the physical description of the problem is in terms of differences---
intensity before and after light passes through the slice---we can easily write an ordinary
differential equation model for absorption. The difference in intensity due to the slice of
absorbing material dI is reduced; leaving the slice, it is a fraction β of the light entering
the slice I. The thickness of the slice is dz, which scales the amount of absorption (thin
slice does not absorb much light but a thick slice absorbs a lot). In symbols, dI = βIdz,
or dI / dz = βI. This conceptual overview uses β to describe how much light is
absorbed. All we can say about the value of this constant is that it will be different for
each material. Also, its values should be constrained between -1 and 0. The following
paragraphs cover the meaning of this constant and the whole derivation in much greater
detail.
Assume that particles may be described as having an absorption cross section (i.e. area),
σ, perpendicular to the path of light through a solution, such that a photon of light is
absorbed if it strikes the particle, and is transmitted if it does not.
Define z as an axis parallel to the direction that photons of light are moving, and A and dz
as the area and thickness (along the z axis) of a 3-dimensional slab of space through
which light is passing. We assume that dz is sufficiently small that one particle in the slab
cannot obscure another particle in the slab when viewed along the z direction. The
concentration of particles in the slab is represented by N.
It follows that the fraction of photons absorbed when passing through this slab is equal to
the total opaque area of the particles in the slab, σAN dz, divided by the area of the slab A,
which yields σN dz. Expressing the number of photons absorbed by the slab as dIz, and
the total number of photons incident on the slab as Iz, the fraction of photons absorbed by
the slab is given by
Note that because there are fewer photons which pass through the slab than are incident
on it, dIz is actually negative (It is proportional in magnitude to the number of photons
absorbed).
The solution to this simple differential equation is obtained by integrating both sides to
obtain Iz as a function of z
The difference of intensity for a slab of real thickness ℓ is I0 at z = 0, and Il at z = ℓ. Using
the previous equation, the difference in intensity can be written as,
and
The derivation assumes that every absorbing particle behaves independently with respect
to the light and is not affected by other particles. Error is introduced when particles are
lying along the same optical path such that some particles are in the shadow of others.
This occurs in highly concentrated solutions. In practice, when large absorption values
are measured, dilution is required to achieve accurate results. Measurements of
absorption in the range of I1 / I0 = 0.1 to 1 are less affected by shadowing than other
sources of random error. In this range, the ODE model developed above is a good
approximation; measurements of absorption in this range are linearly related to
concentration. At higher absorbances, concentrations will be underestimated due to this
shadow effect unless one employs a more sophisticated model that describes the non-
linear relationship between absorption and concentration