BENCENO -AIRE A 1ATM

BENCENO (A) CONSTANTES DE ANTOINE

PM[kg/kmol] 78.112 C1 C2 C3 C4
Tc[K] 562.05 83.107 -6486.2 -9.2194 6.98E-06
Pc[Mpa] 4.895 Tabla 2-8 Perry 8va Ed.
Tabla 2-141 Perry 8va Ed.
Psistema [kPa] 101.325 CONSTANTES DE ANTOINE
Teb[C] 80.1 C1 C2 C3 C4
Tfusion[C] 5.5 21.662 -692.39 -0.392 4.76E-03
Tabla 2-2 Perry 8va Edicion. Tabla 2-8 Perry 8va Ed.

AIRE(B)
PM[kg/kmol] 28.96
Tc[K] 132.45
Pc[Mpa] 3.774
CURVAS DE HUMEDAD
T[ºC] T[K] Pvap[kPa] 2% 5% 10% 20%
5.6 278.75 4.7824 0.0025485056 0.00638031 0.01279087 0.02570363
10.6 283.75 6.2382 0.0033252936 0.00832864 0.01670887 0.03362604
15.6 288.75 8.0484 0.004291736 0.01075501 0.02159613 0.04354088
20.6 293.75 10.2768 0.0054824201 0.01374797 0.0276368 0.05584581
25.6 298.75 12.9945 0.0069359729 0.01740708 0.03504029 0.07100299
30.6 303.75 16.2799 0.0086952287 0.0218437 0.04404409 0.08955049
35.6 308.75 20.2186 0.0108073873 0.02718184 0.05491711 0.11211698
40.6 313.75 24.9039 0.0133241691 0.03355909 0.06796379 0.13944116
45.6 318.75 30.4362 0.0163019728 0.04112779 0.08352925 0.17239738
50.6 323.75 36.9233 0.0198020444 0.05005635 0.10200577 0.21203022
55.6 328.75 44.4801 0.023890667 0.06053089 0.123841 0.25960134
60.6 333.75 53.2285 0.028639381 0.07275726 0.14954856 0.31665402
65.6 338.75 63.2970 0.0341252484 0.0869635 0.17972154 0.38510315
70.6 343.75 74.8207 0.0404311717 0.10340292 0.21505013 0.46736301
75.6 348.75 87.9411 0.0476462844 0.12235786 0.25634457 0.56653217

2.1

1.95

1.8

1.65

1.5
 1.8

1.65

1.5

1.35
Humedad Absoluta [kg de benceno/kg de aire]

1.2

1.05

0.9

0.75

0.6

0.45

0.3

0.15

0
5.5 15.5 25.5 35.5 45.5

T[C]
 Humedad de saturación:

𝐻_𝑆=(𝑀_𝐴 〖𝑃 _𝐴 〗 ^,)/(𝑀_𝐵 (𝑃− 〖𝑃 _𝐴 〗 ^,))

C5 Ecuación 19.3
2 Ecuación de Antoine.

𝐿𝑛 𝑃=𝐶1+𝐶2/𝑇+𝐶3𝐿𝑛𝑇+𝐶4𝑇^𝐶5

C5
1

URVAS DE HUMEDAD
30% 40% 50% 60% 70% 80% 90% 100%
0.03874004 0.05190187 0.06519095 0.07860913 0.0921583 0.10584038 0.11965735 0.13361121
0.05075544 0.06810109 0.0856671 0.1034577 0.12147723 0.13973014 0.15822099 0.17695445
0.06584277 0.08851057 0.11155338 0.13498057 0.15880185 0.18302724 0.20766711 0.23273219
0.084645 0.11405307 0.14408956 0.1747748 0.20613006 0.23817752 0.27094036 0.3044428
0.10792502 0.14584527 0.18480478 0.22484687 0.2660173 0.30836444 0.35193948 0.3967966
0.13659323 0.18525147 0.23560987 0.28775913 0.3417965 0.39782643 0.45596117 0.51632162
0.17174496 0.23395902 0.29893111 0.3668488 0.43791705 0.51236028 0.59042477 0.67238131
0.2147118 0.2940859 0.37790843 0.46656412 0.56048341 0.66014938 0.76610613 0.87896867
0.26713315 0.36833752 0.47669644 0.59299638 0.71814347 0.85318716 0.9993497 1.15806327
0.33105757 0.46023996 0.60093491 0.75475315 0.92362062 1.10985949 1.3162956 1.54640285
0.40908882 0.57449629 0.75850994 0.9644563 1.19650511 1.45995463 1.7616411 2.11054043
0.50460095 0.7175477 0.96083767 1.2414539 1.56870013 1.95525231 2.41883865 2.98503527
0.62206282 0.89848988 1.22514047 1.61706979 2.09601843 2.69458653 3.46398202 4.48950669
0.76754234 1.13063674 1.57874141 2.14566944 2.88590723 3.89326478 5.34416097 7.61422489
0.94951734 1.43433425 2.06782417 2.93075953 4.17536241 6.1267401 9.62564998 17.7225747

7500

7000
CURVA 2

CURVA 5
6500
CURVA 1

6000 CURVA 2

CURVA 3

5500 CURVA 4

CURVA 5
 CURVA 1

6000 CURVA 2

CURVA 3

5500 CURVA 4

CURVA 5
5000
CURVA 6

4500 CURVA 7

CURVA 8

4000 CURVA 9

CURVA 1
3500
CURVA 1

CURVA 2
3000

CURVA3

2500 CURVA4

CURVA 5
2000
CURVA 6

CURVA7
1500
CURVA8

1000 CURVA9

CURVA1
500
Entalpia

ENTALPI
0 SATURA
45.5 55.5 65.5 75.5 85.5

T[C]
 CURVAS DE SATURACIÓN ADIABÁTICA
saturación adiabática:

𝐶_𝑆 (𝑇−𝑇𝑠)+𝐻λ_𝑠=𝐻_𝑠 λ_𝑠

(𝐻_𝑠−𝐻)/(𝑇−𝑇_𝑆 )=𝐶_𝑆/𝜆_𝑠 =(𝐶_𝑝𝐵+𝐶_𝑝𝐴 𝐻)/𝜆_𝑠

La iteración se comprueba con:

𝐶_𝑆 (𝑇−𝑇𝑠)+λ_𝑠 (𝐻−𝐻_𝑆)=0

Capacidad calorífica del Perry:

𝐶_𝑃𝑙=𝐶1+𝐶2𝑇+𝐶3𝑇^2+𝐶4𝑇^3+𝐶5𝑇^4

Para el calor húmedo:

𝐶_𝑆=𝐶_𝐵+𝑌´𝐶_𝐴

Para el calor de vaporización:

𝜆_𝑠=𝐶1(1−T_r )^(𝐶2+𝐶3𝑇_𝑟+𝐶4𝑇_𝑟^2 )

𝑇_𝑟=𝑇/𝑇_𝑐

CURVA2
Tomando solo dos puntos

7500 CURVA3

7000
CURVA 2%
CURVA4
CURVA 5%
6500
CURVA 10%

6000 CURVA 20% CURVA5

CURVA 30%

5500 CURVA 40%

CURVA 50%
 CURVA 10%

6000 CURVA 20%

CURVA 30%

5500 CURVA 40%

CURVA6
CURVA 50%
5000
CURVA 60%

4500 CURVA 70% CURVA7

CURVA 80%

4000 CURVA 90%

CURVA8
CURVA 100%
3500
CURVA 1

CURVA 2 CURVA9
3000

CURVA3

2500 CURVA4
CURVA10
CURVA 5
2000
CURVA 6

CURVA7
1500
CURVA8

1000 CURVA9

CURVA10
500
Entalpia gas seco

ENTALPIA GAS
0 SATURADO
ACIÓN ADIABÁTICA
CONSTANTES DE CAPACIDAD CALORÍFICA
AIRE C1 C2
J/kmol*K -214460 9185.1
Tabla 2-153 Perry 8va Ed.
𝜆_𝑠
CONSTANTES DE CAPACIDAD CALORÍFICA
BENCENO C1 C2
J/kmol*K 162940 -344.94
Tabla 2-153 Perry 8va Ed.

Constantes para el calor de vaporización

BENCENO C1 C2
J/kmol 4.53E+07 0.39053
Tabla 2-150 Perry 8va Ed.

CURVA1 Tas supuesta[ºC] Tas sup.[K]

6 279.15
12 282.043069
20 285.661642
35 290.465499
44 297.543764
60 308.888833

Tas supuesta[ºC] Tas sup.[K] P_benceno* [kPa] CpA[J/kg K] CpB[J/kg K] H_R

12 285.15 6.70676 1717.4220128 118265.112319839 100%
50 316.8306 28.20561 1786.4218643 182275.689098776 2%

Tas supuesta[ºC] Tas sup.[K] P_benceno* [kPa] CpA[J/kg K] CpB[J/kg K] H_R

20 293.15 9.985025 1732.7707 132686.419487463 100%
55 332.078284456083 50.163114 1827.4690 220066.027388931 2%

Tas supuesta[ºC] Tas sup.[K] P_benceno* [kPa] CpA[J/kg K] CpB[J/kg K] H_R

25 298.15 12.640013 1743.0757 142280.210330488 100%
60 342.094760588484 70.836116 1857.2055 247567.665409061 2%

Tas supuesta[ºC] Tas sup.[K] P_benceno* [kPa] CpA[J/kg K] CpB[J/kg K] H_R

30 303.15 15.852874 1753.9283 152333.452679038 100%
 65 352.550887749446 99.073372 1890.5921 278650.361527606 2%

Tas supuesta[ºC] Tas sup.[K] P_benceno* [kPa] CpA[J/kg K] CpB[J/kg K] H_R

35 308.15 19.708454 1765.3287 162856.924157422 100%
66 363.531046399652 137.512430 1928.2301 314007.474235946 2%

Tas supuesta[ºC] Tas sup.[K] P_benceno* [kPa] CpA[J/kg K] CpB[J/kg K] H_R

40 313.15 24.298996 1777.2767 173861.402389949 100%
68 375.157996138374 189.885160 1970.9644 354605.984957415 2%

Tas supuesta[ºC] Tas sup.[K] P_benceno* [kPa] CpA[J/kg K] CpB[J/kg K] H_R

42 315.15 26.363070 1782.2092 178400.289761966 100%
70 380.027625803213 215.885269 1989.7425 372606.625919347 2%

Tas supuesta[ºC] Tas sup.[K] P_benceno* [kPa] CpA[J/kg K] CpB[J/kg K] H_R

50 323.15 36.090712 1802.8158 197356.489614673 100%
71 401.161321384144 361.496766 2077.2569 457845.587057982 2%

Tas supuesta[ºC] Tas sup.[K] P_benceno* [kPa] CpA[J/kg K] CpB[J/kg K] H_R

55 328.15 43.512848 1816.4069 209868.653855488 100%
75 416.226827608344 503.508328 2145.6167 525995.234110118 2%
DAD CALORÍFICA
C3 C4 C5
-106.12 4.16E-01 0

DAD CALORÍFICA
C3 C4 C5
0.85562 0.00E+00 0

de vaporización
C3 C4 C5
0 0.00E+00 0

P_benceno* [CpA[J/kg K] CpB[J/kg K] H_R λ_s[J/kmol] H_sat C_s[J/kg] %ERROR

4.88718 1706.83 108176.348 100% 34682116 0.13668807
5.70441 1711.84 112964.547 80% 34543170.5 0.1272088 113182.308 -1.7986E-08
6.88516 1718.36 119153.903 60% 34368143.9 0.11464251 119350.9 -4.2492E-09
8.76240 1727.46 127721.312 40% 34133614.9 0.09664392 127888.261 6.75209E-09
12.28999 1741.80 141092.728 20% 33783393.4 0.06705783 141209.529 0
20.33819 1767.06 164452.471 2% 33209935.9 0.01087156 164471.682 1.0943E-08

λ_s[J/kmol] H_sat C_s[J/kg] %ERROR Tas[ºC]

34392975.9 0.19118636 12.0000
32799121.3 0.01510055 182302.665 -5.4203E-07 43.6806

λ_s[J/kmol] H_sat C_s[J/kg] %ERROR Tas[ºC]

34001452.3 0.2948543 20.0000
31987042.3 0.02697358 220115.321 0 58.9283

λ_s[J/kmol] H_sat C_s[J/kg] %ERROR Tas[ºC]

33753133.5 0.3844294 25.0000
31435559.2 0.03824745 247638.699 1.67638E-08 68.9448

λ_s[J/kmol] H_sat C_s[J/kg] %ERROR Tas[ºC]

33501930.3 0.50026797 30.0000
30843286.7 0.05379805 278752.072 -2.11783E-06 79.4009

λ_s[J/kmol] H_sat C_s[J/kg] %ERROR Tas[ºC]

33247752.7 0.65131871 35.0000
30201601.8 0.07525328 314152.58 0 90.3810

λ_s[J/kmol] H_sat C_s[J/kg] %ERROR Tas[ºC]

32990505.8 0.85088364 40.0000
29498076.4 0.10503016 354812.996 -3.66569E-06 102.0080

λ_s[J/kmol] H_sat C_s[J/kg] %ERROR Tas[ºC]

32886725.5 0.94858101 42.0000
29195498.8 0.12005156 372845.498 -9.76771E-06 106.8776

λ_s[J/kmol] H_sat C_s[J/kg] %ERROR Tas[ºC]

32466399.2 1.49224019 50.0000
27821706.8 0.20724629 458276.091 -3.17842E-05 128.0113

λ_s[J/kmol] H_sat C_s[J/kg] %ERROR Tas[ºC]

32199323.3 2.03010069 55.0000
26773709.8 0.29764595 526633.868 -1.98334E-05 143.0768
 LINEAS DE ENTALPIA

Entalpía de gas saturado:

𝐻^′=𝐶_𝑠 (𝑇𝑔−𝑇𝑜)+𝐻_𝑠 λ_𝑠

Entalpía de gas seco:

𝐻^′=𝐶_𝑝𝐵 (𝑇𝑔−𝑇_𝑜 )

T [°C] T [K] T med [K] Cp A [J/Kg*K]

5.6 278.75 275.95 1701.5043
10.6 283.75 278.45 1705.6463
15.6 288.75 280.95 1709.9252
20.6 293.75 283.45 1714.3410
25.6 298.75 285.95 1718.8938
30.6 303.75 288.45 1723.5835
35.6 308.75 290.95 1728.4101
40.6 313.75 293.45 1733.3736
45.6 318.75 295.95 1738.4740
50.6 323.75 298.45 1743.7114
55.6 328.75 300.95 1749.0857
Tas [ºC] 60.6 333.75 303.45 1754.5969
6 65.6 338.75 305.95 1760.2451
8.8931 70.6 343.75 308.45 1766.0301
12.5116 75.6 348.75 310.95 1771.9521
17.3155
24.3938
35.7388
 Tref[K] 273.15
ʎ_0 [J/Kg] 142.560428471696

Se utilizó la
Treferencia= 273 K
Y los Cp se
calcularon a una
temperatura media.

Cp B [J/Kg*K] C_s[J/kg] Haire seco [kJ/Kg] Haire saturado [kJ/Kg]

103043.269013646 103270.61 288.521153238209 289.1768
107038.9376681 107340.76 567.306369640932 568.9313
111138.853238991 111536.81 866.88305526413 870.0203
115344.362929357 115866.28 1188.04693817238 1193.4661
119656.813942237 120338.87 1531.60721846063 1540.3940
124077.553480669 124967.48 1898.38656825424 1912.0760
128607.928747693 129770.08 2289.22113170893 2310.0033
133249.286946346 134772.87 2704.96052501082 2736.0145
138002.975279668 140016.24 3146.46783637643 3192.5353
142870.340950697 145566.82 3614.61962605263 3683.0610
147852.731162472 151544.25 4110.30592631671 4213.2310
152951.493118031 158189.03 4634.43024147634 4793.5531
158167.974020414 166070.61 5187.90954786957 5447.7559
163503.521072658 176950.47 5771.67429386483 6247.4371
168959.481477803 200363.03 6386.66839986096 7576.2492