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<#> Download this Document for Free <#> 1 SET 1 PAPER 2: STRUCTURE QUESTION 1. (a) bromine and phenol 1 (b) liquid 1 (c) Nickel 1 (d) 1 (e) ion 1 (f) (i) T1 1 (ii) Heat absorbed by the particles/molecules is used to overcome the attraction forces between the particles/molecules in solid naphthalene. 1 (iii) Become faster 1 8 2(a) ToC 1 (b) t2 1 (c) Heat energy released to the surroundings is balanced by the heat release as the particles attract one another to form a solid 1 (d) (i) molecules 1 (ii) P R 1+1 (e) (i) liquid and solid 1 (ii) Solid 1 (f) Sublimation 1 .9 3(a) Functional apparatus 1 Label 1 (b) 1 2 (c) 1. Label and unit of axes X and Y 1 2. Scale and size of graph 1 3. Transfer point 1 4. Correct and smooth curve

1 (d) (i) Melting point is shown on the graph at 80OC 1 (ii) Melting point is the temperature at which solid change to liquid 1 (e) Heat absorbed by the particles/molecules is used to overcome the attraction forces between the particles/molecules in solid naphthalene. 1 10 4(a) (b) (i) (ii) (c) (d) (i) (ii) (iii) (e) (f) A representation of a chemical substance using letters for atoms and subscripts for each type of atoms present in the substance. Hydrochloric acid // nitric acid // sulphuric acid Magnesium // zinc Correct formula of reactant and product Balance equation Example: Mg + HCl MgCl2 + H2 Flow the hydrogen gas into the combustion tube for a few minutes to remove air before heating metal oxide Number of mole of copper = 1.62 // 0.025 mol 64 Number of mole of oxygen = 0.40 // 0.025 mol 16 Number of mole of copper : Number of mole of oxygen 0.025 : 0.025 // 1 :1 CuO Iron oxide // Tin oxide // Lead(II) oxide // Silver oxide Burn metal M in oxygen 1 1 1 1 1 1 1 1 1 1 1 ...11 5 (a) (i) Magnesium // zinc Hydrochloric acid // nitric acid // sulphuric acid

1 1 (ii) Correct formula of reactant and product Balance equation Example: Zn + 2HCl ZnCl2 + H2 1 1 3 (b) (i) Empirical formula is MO2 1 1 1 1 (ii) Correct formula of reactant and product Balance equation Example: MO2 + 2H2 M + 2H2O 1 1 (c) Flow the hydrogen gas into the combustion tube for a few minutes to remove air before heating metal oxide // Allow flow of hydrogen gas into the combustion tube during cooling 1 (d) No. Magnesium is more reactive than hydrogen. 1 1 13 6(a) The chemical formula that shows the simplest ratio of the number of atoms of each type of elements in the compound 1 (b) (i) Mass of magnesium = (26.4-24.0)g =2.4 g Mass of oxygen = (28.0 26.4) g = 1.6 g 1 (ii) moles of magnesium atoms : moles of oxygen atoms 1.6 : 2.4 // 24 16 0.1 : 0.1 1 (iii) MgO. 1 (iv) Correct formula of reactant and product 1 Balance equation 1 Example: 2Mg + O2 2MgO (c) To allow oxygen to enter the crucible for complete combustion to occur. 1 (d) Functional apparatus 1 Label 1

(e) Collect the gas in a test tube.Place a burning wooden splinter at the mouth of the test tube. No pop sound. 1 ..10 Heat X oxide Dry hydrogen gas 4 7 (a) (i) 2.6 1 (ii) Period : 2 Group : 16 1 1 (b) (i) 9 1 (ii) 10 1 (iii) 1 (iv) 1. Element Q is more reactive than element R. 2. The size of atom Q is smaller tha atom R 3. The attraction forces between nucleus and valence electron of atom Q is stronger than atom R 4. it is easier for atom Q to receive valence electron compare to atom R. 1 1 1 1 (c) (i) Ionic bond 1 (d) (i) Has high melting and boiling point // Conduct electricity in aqueous solution and molten state // Soluble in water // insoluble in organic solvent 1 1+1 .14 8(a) 2.8.2 1 (b) (i) Ionic bond 1 (ii) 1. Atom X releases 2 electrons to form X2+ ion 2. achieve octet electron arrangement 1 1 (iii) Each ion drawn correctly

Number of electrons for ion X and ion Y are correct Charge of ions are correct 1 1 (iv) Has high melting and boiling point// Conduct electricity in aqueous solution and molten state // Soluble in water // insoluble in organic solvent 1 (c) (i) ZY2 1 (ii) 12 + 2(16) // 44 1 9 9 (a) Metal : P/Q/R/S/T Non-metal : V/U/W/X 1 1 (b) 2.8.5 1 (c) R 1 (d) Electronegativity increases from Q to U 1 1. The atomic size decreases from Q to U 2. The nuclei attraction forces between electrons and nucleus increases from Q to U 1 1 (e) Q+ 1 P 19 9 C Y X 2+ 24 7 (a) (i) 2.6 1 (ii) Period : 2 Group : 16 1 1 (b) (i) 9 1 (ii) 10 1 (iii) 1 (iv) 1. Element Q is more reactive than element R.

2. The size of atom Q is smaller tha atom R 3. The attraction forces between nucleus and valence electron of atom Q is stronger than atom R 4. it is easier for atom Q to receive valence electron compare to atom R. 1 1 1 1 (c) (i) Ionic bond 1 (d) (i) Has high melting and boiling point // Conduct electricity in aqueous solution and molten state // Soluble in water // insoluble in organic solvent 1 1+1 .14 8(a) 2.8.2 1 (b) (i) Ionic bond 1 (ii) 1. Atom X releases 2 electrons to form X2+ ion 2. achieve octet electron arrangement 1 1 (iii) Each ion drawn correctly Number of electrons for ion X and ion Y are correct Charge of ions are correct 1 1 (iv) Has high melting and boiling point// Conduct electricity in aqueous solution and molten state // Soluble in water // insoluble in organic solvent 1 (c) (i) ZY2 1 (ii) 12 + 2(16) // 44 1 9 9 (a) Metal : P/Q/R/S/T Non-metal : V/U/W/X 1 1 (b) 2.8.5 1 (c) R 1 (d) Electronegativity increases from Q to U 1 1. The atomic size decreases from Q to U

2. The nuclei attraction forces between electrons and nucleus increases from Q to U 1 1 (e) Q+ 1 P 19 9 C Y X 2+ 25 (f) X 1 Atom X has achieved octet electron arrangement 1 (g) Correct formula of reactant and product Balance equation Example: 2R + U2 2RU 1 1 (h) 1. form coloured ions 2. has more than one oxidation number 3. as catalyst 4. form complex ions [ any one] 1 ..13 10 (a) (i) seven / 7 1 (ii) 2.8.7 1 (b) (i)P+ 1 (ii) Q 1 (iii) PQ2 1 (c) Element U is not reactive // do not cause explosion 1 (d) 1 st mark: - showing the sharing of electrons and correct number of electrons in each shell 2 nd mark correct label and correct number of electron pairs being shared 1 1 (e) low melting point & boiling point // does not conduct electricity 1 TOTAL

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