Cinetica de Orden 0 Cinetica de Orden 1 Cinetica de Orden 2

Cineti
Tiempo DQO Tiempo Tiempo
(h) (mg/L) (h) LN(Ca/Cao) (h) 1/CA 0.005
0 500 0 0 0 0.002
2.6 450 2.6 -0.10536052 2.6 0.00222222 0.004

5.22 400 5.22 -0.22314355 5.22 0.0025

0.003
7.85 350 7.85 -0.35667494 7.85 0.00285714
10.51 300 10.51 -0.51082562 10.51 0.00333333
0.002
13.91 250 13.91 -0.69314718 13.91 0.004
15.91 200 15.91 -0.91629073 15.91 0.005 0.001
18.7 150 18.7 -1.2039728 18.7 0.00666667
21.61 100 21.61 -1.60943791 21.61 0.01 8.67361737988404E-19
0 5
24.8 50 24.8 -2.30258509 24.8 0.02
31.16 1 31.16 -6.2146081 31.16 1 -0.000999999999999999

Co 500 mg/L
Ca(t)

y=mx+b
K=m
k=-16,913
 Cinetica de Orden 2 Cinetica de Orden 1
0.005 0
f(x) = 0.0185264671580334 x − 0.160222344461308 0 5 10 15
f(x) = − 0.15428473510784 20 2
x + 0.850626378143
R² = 0.361864598742131 R² = 0.714537264983018
0.004 -1

-2
0.003

-3
0.002
-4
0.001
-5
8.67361737988404E-19
0 5 10 15 20 25 30 35 -6

-0.000999999999999999
-7

Cinetica de Orden 0
600

500
f(x) = − 16.9134126920242 x + 484.218668237684
R² = 0.987455536092176
400

300

200

100

0
0 5 10 15 20 25 30 35
 Cinetica de Orden 1
10 15
.15428473510784 20 25
x + 0.850626378143964 30 35
4537264983018
 Cinetica de Orden 0 Cinetica de Orden 1 Cinetica de Orden 2
Tiempo C Tiempo Tiempo
Cinetica
(d) (mol/L) (d) *-LN(Ca/Cao) (d) 1/CA 3.5
0 250 0 0 0 0.004 f(x) = 0.327297369031894 x + 0.79481
3 R² = 0.846842919361798
1 70 1 1.2729656758 1 0.01428571
2 42 2 1.7837912996 2 0.02380952 2.5
3 30 3 2.1202635362 3 0.03333333
2
4 23 4 2.3859667019 4 0.04347826
5 18 5 2.63108916 5 0.05555556 1.5
6 16 6 2.7488721956 6 0.0625
1
7 13 7 2.9565115604 7 0.07692308
8 12 8 3.0365542681 8 0.08333333 0.5

Cao 250 mg/L 0

0 1 2 3 4

y=mx+b
K=m
k=0,0101 L*dia/mol
 Cinetica de Orden 1 Cinetica de Orden 2
0.09
x) = 0.327297369031894 x + 0.794812123604476
² = 0.846842919361798 0.08 f(x) = 0.0100808099308099 x + 0.00381218228899389
R² = 0.997719588399684
0.07
0.06
0.05
0.04
0.03
0.02
0.01
0
1 2 3 4 5 6 7 8 9 0 1 2 3 4 5 6

Cinetica de Orden 0
300

250

200

150
f(x) = − 19.7833333333333 x + 131.8
100 R² = 0.504767995070433

50

0
0 1 2 3 4 5 6 7 8 9
inetica de Orden 2

99 x + 0.00381218228899389

3 4 5 6 7 8 9
h 0.1
Tiempo NH3 NO2 NO3
x y1 f(y1) y2 f(y2) y3 f(y3)
0 25 -15 0 15 0 0
0.1 26.5 -15.9 1.5 15.45 0 0.45
0.2 28.09 -16.854 3.045 15.9405 0.045 0.9135
0.3 29.7754 -17.86524 4.63905 16.473525 0.13635 1.391715
0.4 31.561924 -18.9371544 6.2864025 17.0512337 0.2755215 1.88592075
0.5 33.4556394 -20.0733837 7.99152587 17.6759259 0.46411358 2.39745776
0.6 35.4629778 -21.2777867 9.75911846 18.3500511 0.70385935 2.92773554
0.7 37.5907565 -22.5544539 11.5941236 19.0762168 0.9966329 3.47823707
0.8 39.8462019 -23.9077211 13.5017453 19.8571975 1.34445661 4.05052358
0.9 42.236974 -25.3421844 15.487465 20.6959449 1.74950897 4.6462395
1 44.7711924 -26.8627154 17.5570595 21.5955976 2.21413292 5.26711785
1.1 47.457464 -28.4744784 19.7166193 22.5594926 2.7408447 5.91498578
1.2 50.3049118 -30.1829471 21.9725685 23.5911765 3.33234328 6.59177055
1.3 53.3232065 -31.9939239 24.3316862 24.6944181 3.99152034 7.29950585
1.4 56.5225989 -33.9135593 26.801128 25.8732209 4.72147092 8.04033839
1.5 59.9139548 -35.9483729 29.3884501 27.1318379 5.52550476 8.81653502
1.6 63.5087921 -38.1052753 32.1016339 28.4747851 6.40715826 9.63049016
1.7 67.3193196 -40.3915918 34.9491124 29.9068581 7.37020728 10.4847337
1.8 71.3584788 -42.8150873 37.9397982 31.4331478 8.41868065 11.3819395
1.9 75.6399876 -45.3839925 41.083113 33.0590586 9.5568746 12.3249339
2 80.1783868 -48.1070321 44.3890188 34.7903264 10.789368 13.3167056
2.1 84.98909 -50.993454 47.8680515 36.6330386 12.1210385 14.3604154
2.2 90.0884354 -54.0530612 51.5313553 38.5936547 13.5570801 15.4594066
1.3 95.4937415 -57.2962449 55.3907208 40.6790287 15.1030208 16.6172162
2.4 101.223366 -60.7340196 59.4586237 42.8964325 16.7647424 17.8375871
2.5 107.296768 -64.3780608 63.7482669 45.2535807 18.5485011 19.1244801
2.6 113.734574 -68.2407444 68.273625 47.7586569 20.4609491 20.4820875
2.7 120.558649 -72.3351891 73.0494907 50.4203419 22.5091578 21.9148472
2.8 127.792167 -76.6753005 78.0915249 53.247843 24.7006426 23.4274575
2.9 135.459697 -81.2758185 83.4163092 56.2509257 27.0433883 25.0248927
3 143.587279 -86.1523676 89.0414017 59.4399471 29.5458776 26.7124205
3.1 152.202516 -91.3215096 94.9853964 62.8258907 32.2171196 28.4956189
3.2 161.334667 -96.8008002 101.267986 66.4204046 35.0666815 30.3803957
3.3 171.014747 -102.608848 107.910026 70.2358404 38.1047211 32.3730078
3.4 181.275632 -108.765379 114.93361 74.2852961 41.3420219 34.480083
3.5 192.15217 -115.291302 122.36214 78.58266 44.7900302 36.7086419
 23.5 -15
22.09 -14.1
20.7646 -13
19.518724 -12
18.3476006 -11
h 0.1
Tiempo NH3 NO2 NO3
x y1 f(y1) y2 f(y2) y3 f(y3)
0.1 45 -25.2 0 9.45 0 15.75
0.2 42.48 -23.7888 0.945 8.9208 1.575 14.868
0.3 40.10112 -22.4566272 1.83708 8.4212352 3.0618 14.035392
45
0.4 37.8554573 -21.1990561 2.67920352 7.94964603 4.4653392 13.24941
0.5 35.7355517 -20.0119089 3.47416812 7.50446585 5.7902802 12.5074431 40
0.6 33.7343608 -18.891242 4.22461471 7.08421576 7.04102451 11.8070263
0.7 31.8452366 -17.8333325 4.93303628 6.68749968 8.22172714 11.1458328 35
0.8 30.0619033 -16.8346659 5.60178625 6.3129997 9.33631042 10.5216662
0.9 28.3784367 -15.8919246 6.23308622 5.95947172 10.388477 9.93245286 30
1 26.7892443 -15.0019768 6.82903339 5.6257413 11.3817223 9.3762355
25
1.1 25.2890466 -14.1618661 7.39160752 5.31069979 12.3193459 8.85116631
1.2 23.87286 -13.3688016 7.9226775 5.0133006 13.2044625 8.355501
20
1.3 22.5359798 -12.6201487 8.42400756 4.73255577 14.0400126 7.88759294
1.4 21.273965 -11.9134204 8.89726314 4.46753264 14.8287719 7.44588774 15
1.5 20.0826229 -11.2462688 9.3440164 4.21735081 15.5733607 7.02891802
1.6 18.957996 -10.6164778 9.76575148 3.98117917 16.2762525 6.63529861 10
1.7 17.8963483 -10.021955 10.1638694 3.75823314 16.9397823 6.26372189
1.8 16.8941528 -9.46072555 10.5396927 3.54777208 17.5661545 5.91295347 5
0 0.5
1.9 15.9480802 -8.93092492 10.8944699 3.34909684 18.1574499 5.58182807
2 15.0549877 -8.43079312 11.2293796 3.16154742 18.7156327 5.2692457
2.1 14.2119084 -7.95866871 11.5455343 2.98450076 19.2425572 4.97416794
2.2 13.4160415 -7.51298326 11.8439844 2.81736872 19.739974 4.69561454
2.3 12.6647432 -7.0922562 12.1257213 2.65959607 20.2095355 4.43266012
2.4 11.9555176 -6.69508985 12.3916809 2.51065869 20.6528015 4.18443116
2.5 11.2860086 -6.32016482 12.6427468 2.37006181 21.0712446 3.95010301
2.6 10.6539921 -5.96623559 12.879753 2.23733835 21.4662549 3.72889724
2.7 10.0573686 -5.63212639 13.1034868 2.1120474 21.8391446 3.520079
2.8 9.49415592 -5.31672732 13.3146915 1.99377274 22.1911525 3.32295457
2.9 8.96248319 -5.01899059 13.5140688 1.88212147 22.523448 3.13686912
3 8.46058413 -4.73792711 13.702281 1.77672267 22.8371349 2.96120445
3.1 7.98679142 -4.4726032 13.8799532 1.6772262 23.1332554 2.795377
3.2 7.5395311 -4.22213742 14.0476758 1.58330153 23.4127931 2.63883589
3.3 7.11731736 -3.98569772 14.206006 1.49463665 23.6766767 2.49106108
3.4 6.71874759 -3.76249865 14.3554697 1.41093699 23.9257828 2.35156166
3.5 6.34249772 -3.55179872 14.4965634 1.33192452 24.1609389 2.2198742
3.6 5.98731785 -3.352898 14.6297558 1.25733675 24.3829263 2.09556125
3.7 5.65202805 -3.16513571 14.7554895 1.18692589 24.5924825 1.97820982
3.8 5.33551448 -2.98788811 14.8741821 1.12045804 24.7903035 1.86743007
3.9 5.03672567 -2.82056637 14.9862279 1.05771239 24.9770465 1.76285398
4 4.75466903 -2.66261466 15.0919991 0.9984805 25.1533319 1.66413416
4.1 4.48840757 -2.51350824 15.1918472 0.94256559 25.3197453 1.57094265
4.2 4.23705674 -2.37275178 15.2861037 0.88978192 25.4768395 1.48296986
4.3 3.99978156 -2.23987768 15.3750819 0.83995413 25.6251365 1.39992355
4.4 3.7757938 -2.11444453 15.4590773 0.7929167 25.7651289 1.32152783
4.5 3.56434934 -1.99603563 15.538369 0.74851336 25.8972817 1.24752227
4.6 3.36474578 -1.88425764 15.6132203 0.70659661 26.0220339 1.17766102
 K1 0.35
K2 0.21

45 Gráfico de NH3,NO2 Y NO3 30

NH3
40 NO2
25
NO3
35

20
30

25 15

20
10

15

5
10

5 0
0 0.5 1 1.5 2 2.5 3 3.5 4 4.5 5
 30
NH3
NO2
25
NO3

20

15

10

0
4.5 5