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B'E./B.Tech.DEGREEEXAMINATION, MAy/ruNE 2007 . Fifth Semester ChemicalEngineering CH 1301- CHEMICAL ENGINEERINGTHERMODYNAMICS _ I (Regulation 2004) Time : Three hours
Answer ALL questions. PARTA-(fO 1' 2' x2=2}marks)

Maximum : 100 marks

3' 4' 5. 6'

write the expression for work done in a polytropic process. Give the qualitative difference between heat and other forms of energy

show that a Carnot engine has the maximum efficiency and that the efficiencv is independent of the working fluid. 7. B' write clausius-clapeyron equation and give its physical significance.

What are the limiting conditions that should be satisfied by the equation of state in general? \trtrat are the different meLhoclsby which the fugacity of pure gases can be deternined? 10. Ijefine Mach number. 9'

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state the clausius statement of the secondlaw of thermodynamics.

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Show that the law of conservationof energy is a consequence of the first law of thermodynamics

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Distinguish between state function and path function.

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PARTB-(5xL6=80marks) 11. (a) Explain the following

(i) (ii) (iii) (iv) (v) Isobaric and polyhopic process. Intensive and extensive properties. Closed system and open system. Reversible and Irreversible processes. Adiabatic and Isothermal process. (Or)

( 3) ( 3) ( 3) (4) ( 3)

(ii)

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A stationary mass of gas is compressedin a friction less way from 2 Kg/c;m2and 0.1 m3 to 6 Kglcmz and 0.02 m3. Find the work done (8) using adiabatic process.

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(b)

(i)

Derive the frrst law of thermodynamics for a steady state flow (8) process.

L2. (a)

(i) (ii)

Discuss II Law of thermodynamics.

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A solid weighing 150 grams at 200'c and with a heat capacity 0.3zu/KgK is dropped into ?50 gm of water at 25"C. The heat capacity of water is 4 KJ/Kg K. Calculate the change in entropy for water, solid and total entropy change. Comment on the results. (10)

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(6)

Or (4) G)

(b)

(i)

Explain the physical concept of entropy. How do you calculate the lost work in an irreversible process?

(ii) ' (iii)

Assume that 5000 kglhr of oil with a heat capacity of 3.2 KJlI{g K is to be cooled ftom. 220'c to 40"c using a large quantity of water which can be assumed to be at a constant temperature of 30"C' Determine the lost work in the process and thermodynamic (8) efficiency of the process.

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13. (a)

Derive the following:

:c,d,r.lr(*] (i) d,(r

y\ot)v

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(ii) d.H =cPdr.[u - ,(*']

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(5+6+5)

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(b) Prove the following:

(i)

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14. (a)

(i)

Define the following:

Under what conditions a real gas behavesideally.

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(ii)

Compressibility factor, Tliple point, Critical properties.

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aP) (iii) (#),=-'I av), (a'v\ lw),

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(G) (g) (7)

p'vr cp -c, =

(b)

(i)

(ii)

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(iii) Write a brief note on the importance of studying the PVT behavior
of fluids.

Show that Raoult's law is valid for componentA of a binary solution over the rErngeof composition for which Henry's law holds for componentB. (8) Gaseous nitrogen obeys the following relation at 100"C, z =r + (2.11 x 10r) P, where P is in atm. calculate the fugacity of nitrogen at 100'C and 100 atm. (8)

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15'

(a)

Air at 600 K and 2000 KPa enters a convergent -divergent nozzlewhose throat area is one half that of the d.ischarge of the divergent section. Assuming / = L. for air, determine the following. (i) The presstrre, temperature, velocity and density at the throat when the Mach number is 0.g at the throat. The critical pressure corresponding to the reservoir condition. Or (16)

(ii)

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What is the effect of 'clearance' on the work required and theoretical volumetric efficiency of a murti stage adiabatic compressor? (16)

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