Dados Problema Tc Zc Pc Vc

x1 0.2 Água 647.3 0.229 220.48 5.589615E-05

x2 0.35 etanol 516.2 0.24 63.83 0.0001613669
x3 0.45 N-propanol 536.7 0.254 51.68 0.0002193072
T (K) 318.15

Parâmetros Coef de atividade

0.9044179632 ɣ1 0.999865197 2.717915 A12
9.98447E-07 ɣ2 0.118411083 1.125707 A21
0.5672875285 ɣ3 0.134380984 1.143829 A13
1.0907697474 A23
7.411309E-06 R (cal/ mol K) 1.98721 A31
0.5898154284 R (m³ bar/ K mol) 0.00008314 A32
 Tr Vl
0.49150316700139 4.512117E-05
0.616330879504068 0.0001379993
0.592789267747345 0.0001869869

calculos intermediarios
cte exp Aij
-1.21836032833396 0.2957146445 0.9044179632 DECHEMA
-12.6991681186699 3.053665E-06 9.98447E-07 a12 770.285
-1.98857581393154 0.1368902439 0.5672875285 a21 8028.806
-0.216906526319579 0.8050052126 1.0907697474 a13 1257.239
-10.3908167096016 3.071324E-05 7.411309E-06 a23 137.135
-0.224155460655253 0.799190882 0.5898154284 a31 6569.395
a32 -141.718
Componente Nome Grupo
H20 H20 7
CH3 1
𝐸𝑡𝑂𝐻 CH2 1
OH 5
CH3 1
𝑛−𝑃𝑟𝑜𝑝𝑎𝑛𝑜𝑙 CH2 1
OH 5

ri qi
Água 0.92 1.4
etanol 2.5755 2.588
n-propanol 3.2499 3.128

Parâmetros amn
m/n 1 5
1 0 986.5
5 156.4 0
7 300 -229.1

amn valor
a1,1 0
a1,5 986.5
a1,7 1318
a5,1 156.4
a 5,5 0
a 5,7 353.5
a 7,1 300
a 7,5 -229.1
a 7,7 0

Fração Sub Molécula

X1² 0.3333333333333
X1³ 0.25
X2² 0.3333333333333
X2³ 0.5
X14² 0.3333333333333
X14³ 0.25
X16¹ 1

Vk¹ lnГk
H20 (1) 1 0.6841986112

GRUPOS Vk¹
1 1
2 1
EtOH (2) 14 1
 GRUPOS Vk¹
1 1
2 2
n-pentanol (3) 14 1

lnɣi ɣi
H20 0.8016737981528 2.2292691541
EtOH 0.011520927069 1.0115875486
n-pentanol 0.047763977411 1.0489230566
Subgrupo 𝑣𝑖 R Q Dados Problema
16 1 0.92 1.4 x1 0.2
1 1 0.9011 0.848 x2 0.35
2 1 0.6744 0.54 x3 0.45
14 1 1 1.2 T (K) 318.15
1 1 0.9011 0.848 z 10
2 2 0.6744 0.54
14 1 1 1.2

ɵi li ln ɣ𝑖𝑐
0.072217 0.107966 -2.32 0.117475 1.124654
0.353794 0.349271 -1.638 0.001017 1.001018
0.573989 0.542762 -1.6404 -0.007236 0.99279

7
1318 somatorio inf
353.5 0.694585
0

Ѱ valor Fração Sub mist Fração Area sup mist Coef ativid m
Ѱ1,1 1 X1 0.262295 Ѳ1 0.261587 Г1
Ѱ1,5 0.045016 X2 0.409836 Ѳ2 0.260276 Г2
Ѱ1,7 0.01588 X14 0.262295 Ѳ14 0.37017 Г14
Ѱ5,1 0.611652 X16 0.065574 Ѳ16 0.107966 Г16
Ѱ5,5 1
Ѱ5,7 0.329193
Ѱ7,1 0.389477 Soma 1 soma 2
Ѱ7,5 2.05464 Г1¹ 0.848 0.848 1
Ѱ7,7 1 Г2¹ 0.54 0.54 1
Г14¹ 1.2 1.2 1
Fração AS molécula Г16¹ 1.4 1.4 1
Ѳ1² 0.327666 Г1² 0.4253918172 1.198535 0.696893
Ѳ1³ 0.2711 Г2² 0.2708862987 1.198535 0.696893
Ѳ2² 0.208655 Г14² 0.4406548468 1.717806 1.350593
Ѳ2³ 0.368852 Г1³ 0.3094852679 1.150618 0.785659
Ѳ14² 0.463679 Г2³ 0.1970778829 1.150618 0.785659
Ѳ14³ 0.360048 Г14³ 0.6762901385 1.944547 1.380971
Ѳ16¹ 1

lnГki Sub Multip ln ɣr

1.4 -0.715801 0.684199 0.684199

lnГk lnГki Sub Mult

0.458531 0.425392 0.033139 0.033139
0.291989 0.270886 0.021103 0.021103 ln ɣr
0.396916 0.440655 -0.043739 -0.043739 0.010504
 Soma 0.010504

lnГk lnГki Sub Mult

0.458531 0.309485 0.149046 0.149046
0.291989 0.197078 0.094911 0.189823 ln ɣr
0.396916 0.67629 -0.279374 -0.279374 0.055
Soma 0.059495
matorio inf

Coef ativid mist

0.458531 1.581749
0.291989 1.339089
0.396916 1.487231
0.684199 1.982183

div 1,2 0.819931

div 2,2 0.819931
div 3,2 0.487822

div 1,3 0.860176

div 2,3 0.860176
div 3,3 0.388856