PRACTICE TEST FOR IIT JEE 2011 Practice Test 1 PAPER 1 Time : 3 Hrs Maximum Marks : 240 Disclaimer:

r: IIT-JEE-2011 need not be exactly in this model.

CHMISTRY
(Q. Nos. 1-8) : Have only one correct option. You will be awarded 3 marks for correct answer and 1 mark (minus one mark) for wrong answer. (Q. Nos. 9 - 12) : Have one or more than one correct option. You will be awarded 4 marks for correct answer and 1 mark (minus one mark) for wrong answer. (Q. Nos. 13 - 18) : These Questions are Comprehension type, with only one correct option. You will be awarded 4 marks for correct answer and 1 marks for wrong answer. (Q. Nos. 19 - 20) : These Questions in column-1 are to be matched with the answers in the column-2. These may have one or more correct options. You will be awarded 8 marks for correct answer. There is no negative marking.

SECTION I
ONLY ONE OPTION CORRECT

1.

The standard electrode potential for the electrode MnO4-|MnO2 in solution (given E 0 MnO4 / Mn 2 + = 1.51 V, E 0 MnO2 / Mn 2+ = 1.23 V). A) 1.70 B) 0.28 C) 2.74 D) 2.46 Number of moles of acidified K2Cr2O7 that can be reduced by 1 mole of Sn2+ ions is A) 1/3 B) 3/2 C) 5/6 D) 6/5 The dissociation constants for acetic acid and HCN at 25o C are 1.5 10-5 and 4.5 10-10 respectively. The equilibrium constant for the given reaction is CN- + CH3COOH HCN + CH3COOA) 3 104 B) 3 105 C) 3 10-5 D) 3 10-4

2. 3.

4.

An organic compound (X) adds Br2 to give C5H8Br2O. It gives negative Tollens but positive with Phenyl hydrazine ozonolysis of (X) gives ethanal and C3H4O2 which readily loses CO to form acetaldehyde. The compound A is A) CH3CH2 COH2C CH B) CH3CH = CHCOCH3 C) CH3COCH2 CH = CH2 D) CH3CH2CH2 CH2 CHO The most reactive alcohol towards dehydration is A) CH3 CH CH2 NO2 B) CH3 CH CH2 CHO
OH OH

5.

C) CH3 CH CH2 CN
OH

D) CH3 CH CH2 C CH3

OH O OsO4

6.

Identify the incorrect reaction A)

C=C cold, dil KMnO4 CC OH OH

B)

C=C

CC OH OH

C)

C=C

HIO4

acids

D)

C=C y

SeO2

CC OH OH

7.

The reactive site among x, y, z in cyclo-hexane is z A) x B) y C) z

D) all

8.

2 gm of aluminium is treated separately with excess of dilute H2SO4 and excess of NaOH. The ratio of volumes of hydrogen evolved under similar conditions of pressure and temperature is A) 2 : 3 B) 1 : 1 C) 2 : 1 D) 1 : 2

SECTION II MORE THAN ONE OPTION CORRECT:

9.

Which of the following represent meso form?

H OH OH H OH H

A)

B)

OH H

C)

CH3 D) H

Br

H C C Br

CH3

CH3

10. 11.

Which among the following compounds are paramagnetic? A) KO2 B) K2O2 C) K2O

D) O2

Which of the following statements are true for H3BO3> A) It is mainly monobasic Lewis acid B) It does not act as proton donor but acts as an acid by accepting hydroxyl ions C) It has a layer structure in which BO3 units are joined by hydrogen bonds. D) It is obtained by treating borax with conc. H2SO4. Auto oxidation process is used for the extraction of A) Cu B) Hg C) Pb
SECTION III

12.

D) Al

Comprehension I R X + Mg ether RMgX . Grignard reagents may be prepared from 1o, 2o, 3o

halides as well as from vinyl and aryl halides. Vicinal dihalides and those halides which contain acidic tail do not form grignard reagent. 13. Which of the following halides is most reactive for the preparation of grignard reagent? A) 14.
F

B)

Cl

C)

Br

D)

Which of the following compounds can form grignard reagent on reaction with Mg/ether? A)
CH2 CH2 Br Br Br Mg/THF MgBr Br

B)

CH2 CH CH2 Cl O

C)

Br

D) HO

Br

15.
Br

product. Identify the product ________ B) C)

MgBr MgBr

A)

D)

Comprehension II The base catalysed reaction of 1, 2-diketone to a salt of 2-hydroxy carboxylic acid is known as benzilic acid rearrangement. The reaction is not applicable to 1, 2-diketones containing -methylene group because of competing aldol condensation.
O O OH O O Ph C C Ph OH OH Ph C COO Ph O O O O Ph C C Ph Ph C C OH Ph

16.

The product of the following reaction is

OH

CC O

OH O OH O

A)

C COO O OH

B)

CC H

C CH2 COOH

C)
O O CH3 OH

D) none of these
CC OH O2N C COO * O2N

17.

O 2N

P. Find P.
OH O * C C O

A)

B)
CH3 CH3

CH3

C) O2N
O

* CH C OH O

D) none of the above

18.
O

1. NaOH 2. H+/H2O OH OH OH OH

A)
COOH

B)

COOH

C)

COOH

D)
COOH

SECTION IV Match the following :

19.

Matrix Matching Column - I A. N2O B. NO C. NO2 D. N2O5 Matrix Matching Column - I A. [Co(en)2cl2] B. [Pt(NH3)2cl2] C. Ni(CO)4 D. [Fe)H2O)6]3+

Column II P. acidic oxide Q. neutral oxide R. paramagnetic S. mixed/acid anhydride T. ionic in solid state Column II P. octahedral complexes Q. square planar complexes R. tetrahedral complexes S. geometrical isomerism T. optical isomerism MATHEMATICS

20.

(Q. Nos. 21-28) : Have only one correct option. You will be awarded 3 marks for correct answer and 1 mark (minus one mark) for wrong answer. (Q. Nos. 29 - 32) : Have one or more than one correct option. You will be awarded 4 marks for correct answer and 1 mark (minus one mark) for wrong answer. (Q. Nos. 33 - 38) : These Questions are Comprehension type, with only one correct option. You will be awarded 4 marks for correct answer and 1 marks for wrong answer. (Q. Nos. 39 - 40) : These Questions in column-1 are to be matched with the answers in the column-2. These may have one or more correct options. You will be awarded 8 marks for correct answer. There is no negative marking.

SECTION I
ONLY ONE OPTION CORRECT

21. The asymptotes of a hyperbola are x2 + 4xy + y2 -2x +2y -2 = 0 and the hyperbola passes through (1,1). The eccentricity of the hyperbola is A) 2 / 3 B) 4/ 3 C) 2 D) 3/2

22.

( x 2)3 If the function f ( x) = sin( x 2) + a cos( x 2) ,where [ ] denotes greatest integer a function, is continuous and differentiable in (4, 6), then a belongs A) [8, 64] B) (0, 8] C) (64, ) D) (0, 64)

23.

If k = x (1 x ) 49 dx , then the value of 1 / k must be

0

A) 5520 24.

B) 2550

C) 2055

D) 5205

If f ( x + y ) = f ( x) f ( y ) x, y R and f (1) = 2 , then area enclosed by 3 x + 2 y 8 is (in

sq. units) A) f (4)

25. 1 1 1 f (6) C) f (6) D) f (5) 2 3 3 If the point (cos ,sin ) does not fall in that angle between the lines y = x 1 in which

B)

the origin lies then belongs to 3 B) , A) , 2 2 2 2

C) (0, )

3 D) , 2 2

26.

A point P lies inside the circles x 2 + y 2 4 = 0 and x 2 + y 2 8 x + 7 = 0 . The point P starts moving under the conditions that, it is at a fixed distance from any arbitrarily chosen fixed point in its region and its path encloses greatest possible area. The locus of P is A) 4 x 2 + 4 y 2 12 x + 1 = 0 B) 4 x 2 + 4 y 2 + 12 x 1 = 0 D) x 2 + y 2 3 x + 2 = 0 C) x 2 + y 2 3x 2 = 0 If 0 , 1 , 2 ,..... n 1 be the n , nth roots of unity, then value of A)

27.

(3 )
i =0 i

n 1

is equal to

n 3 1
n

B)

n 1 3n 1

C)

n +1 3n 1

D)

n+2 3n 1

28.

The curve in which the normal at any point (x, y) on it, and the line joining origin to that point, form an isosceles triangle with x-axis is A) a circle B) a parabola C) an ellipse D) hyperbola

SECTION II Multiple Choice Questions with ONE or MORE correct answers

29.

In a ABC , 2 cos
A) B =

a+c ( A C) = then 2 a 2 + c 2 ac B) B = C C) A, B, C are in A.P D) B + C = A

30.

A line L passing through the focus of the parabola y 2 = 4( x 1) intersects the parabola in two distinct points. If m be the slope of the line L, then A) m (1,1) B) m ( , 1) [0, ) C) m R D) m R {0} 16 If the tangent at the point 4 cos , sin to the ellipse 16 x 2 + 11 y 2 = 256 is also a 11 2 2 tangent to the circle x + y 2 x = 15 , then is A) / 3 B) 2 / 3 C) / 3 D) 5 / 3 If P , P2 , P3 denote the distances of the plane 2 x 3 y + 4 z + 2 = 0 from the planes 1 2 x 3 y + 4 z + 6 = 0 , 4 x 6 y + 8 z + 3 = 0 and 2 x 3 y + 4 z 6 = 0 respectively, then A) P + 8P2 P3 = 0 1 B) P3 = 16 P2 C) 8P2 = P 1 D) P + 2 P2 + 3P3 = 29 1

31.

32.

SECTION III

Comprehension - 1 A player tosses a coin and scores one point for every head and two points for every tail that turns up. He plays on until his score reaches or passes n. If Pn denotes the probability of getting a score of exactly n. Answer the following questions. 1 33. Value of Pn + Pn 1 is 2 A) 0 B) 1/2 C) 1 D) 7/11 34. Value of Pn for n 1 A) 35.
1 (1) n 2 + n 3 2

B)

1 (1) n 3 + n 4 3

C)

1 (1) n 4 + n 5 2

D)

1 (1) n 3 + n 6 5

Value of P3 is A) 1/2

B) 5/8

C) 1/3

D) 1/6

Comprehension 2 Given the function (y-2x)3 = 27x2,representing a curve C. 36. 37. The number of non differentiable points of the function is A) 0 B) 1 C) 2 D) 3

The equation of the parabola symmetric about y-axis and passing through the stationary points of the given curve C is A) (y-1)2 = x2 + 1 B) (y+1)2 = x2 + 1 C) (y-1)2 = x2 1 D) y = x2 2 , in square units is x +1
2

38. The area bounded by this parabola and the curve y = A)

2
3

B) -

2 3

C)
SECTION IV

D) -

3 2

Match the following :

39. A. Column I The edges of a parallelopiped are of unit length and are parallel to non-coplanar unit vector a, b, c such that a .b = b.c = c.a = 1 , then, the volume of the parallelepiped
2

Column II 1/2

in cubic units is B. If f and g are differentiable on [0,1] such that f (0) = 2, g (0) = 0, f (1) = 6 and g (1) = 2, then for c (0,1), g ( c ) is f ( c ) The eccentricity of the ellipse x2+12y2 -6x-48y+9 = 0 is E and the latus rectum of the parabola x2-6x-12y+9 = 0 is L.If the radius of the circle through the intersection of these two conic is R then the value of LE2 / 2R is The Binomial expansions of, (1+mx)10 for integral values of m between 10 and 10 are written down, one on each paper. These 21 papers are kept in a box, shuffled and 2 papers are taken at random. The probability that in at least one of the papers, the coefficients of x4 and x6 are equal is:

1 2

C.

R 19/70

D.

11/15

40. Column I
(1 + x )
21 31

Column II
(1 + x )
22 32

(1 + x )

23

A.

(1 + x ) The coefficient of x in (1 + x ) (1 + x )41 (1 + x ) 42

(1 + x )33 is (1 + x ) 43

P.

B.

C.

x 3 x 3 , where [ ] denotes greatest integer lim x 3 3 3 function, is If A and B are square matrices of order 3 such that A = 1, B = -3 then 3AB is equals to If a, b, c are positive integers such that a + b + c 8 , then the no.of possible values of the ordered triplets (a, b, c) is.

Q.

56

R.

81

D.

S.

PHYSICS
(Q. Nos. 41-48) : Have only one correct option. You will be awarded 3 marks for correct answer and 1 mark (minus one mark) for wrong answer. (Q. Nos. 49 - 52) : Have one or more than one correct option. You will be awarded 4 marks for correct answer and 1 mark (minus one mark) for wrong answer. (Q. Nos. 53 - 58) : These Questions are Comprehension type, with only one correct option. You will be awarded 4 marks for correct answer and 1 marks for wrong answer. (Q. Nos. 59 - 60) : These Questions in column-1 are to be matched with the answers in the column-2. These may have one or more correct options. You will be awarded 8 marks for correct answer. There is no negative marking.

SECTION I
ONLY ONE OPTION CORRECT

41.

A battery of emf 0 = 5V and internal resistance 5 is connected across a long uniform wire. AB of length 1 m and resistance per unit length 5m1 . Two cells of emf 2V and 1V and both having internal resistances 2 are connected as shown in the figure. The distance of null point P from end A of rod is: A) 1m C)
1 m 5 1 B) m 2

5v

1v

2v

D) not possible

42.

In a Young double slit experiment, two films of thickness t1 and t2 having refractive, indices 1 and 2 are placed in from of slits A and B respectively. If 1t1 = 2t2 the central maximum will : A) not shift C) shift towards B if t1 < t2 B) shift towards A it t1 < t2 D) shift towards A if t1 > t2

43.

A uniform chain of length L and mass M is suspend with two rigid supports as shown in figure, tension in the chain at the lowest point P is : A) Mg/2 B) 3 Mg/2 C)
2 Mg

45o

45o

D) Mg / 2

44.

In the circuit shown in figure, the switch S was initially at position 1. After sufficiently long time, the switch S was thrown from position 1 to position 2. The voltage drop across the resistor at that instant is : A) zero B) E
E C) LC R

C R L E S 2 1

D) None of these

45.

Two identical strings fixed at both ends are stretched at tensions TA and TB. A tuning fork is used to set them in vibration. A vibrates in its fundamental mode and B in its second overtone mode. A) TA = 2TB B) TA = 9TB C) 2TA = TB D)TA = 4TB A conical pendulum consists of a simple pendulum moving in a horizontal circle as shown. C is the pivot, O the centre of the circle in which the pendulum bob moves and the constant angular velocity of the bob. If L is the angular momentum about point C, then :
r C) only magnitude of L is constant r

46.

A) L is constant

B) only direction of L is constant D) None of these

47.

A metal rod PQ of length L is released from rest such that it rotates in vertical plane about a fixed axis passing through end P and perpendicular the plane of rotation. A uniform magnetic field B exists perpendicular to the plane of rotation. The potential difference between the ends P and Q when the rod becomes vertical is : A) l
3/ 2

3 gB 2 4

B) l

3/ 2

3 gB 2 2

C) l 3 / 2 3 gB 2

D) zero

48.

When an ideal diatomic gas is heated at constant pressure, the fraction of the heat energy supplied which increases the internal energy of the gas is : A) 2/5 B) 3/5 C) 3/7 D) 5/7

SECTION II MORE THAN ONE OPTION CORRECT

49.

Let [ 0 ] denote the dimensional formula of the permittivity of the vacuum and [ 0 ] that of the permeability of the vacuum. If M = mass, L = length, T = time and I = electric current : A) [ 0 ] = M 1 L3 T 2 I C) [ 0 ] = MLT 2 I 2 B) [ 0 ] = M 1 L3 T 4 I 2 D) [ 0 ] = ML2 T 1 I

50.

One mole of ideal monoatomic gas is taken through process AB given by P = V 2 (where and are positive constant) on P-V diagram. Which of the following is the correct statement regarding the given process ?
A) Temperature is maximum at V = 3

B V V

3 C) Rate of increase of temperature of gas with volume is maximum at A

B) Temperature is minimum at V =

D) Rate of increase of temperature of gas with volume is maximum at V =

51.

The ground state and first excited state energies of hydrogen atom are 13.6 eV and 3.4 eV respectively. If potential energy in ground state is taken to be zero, then : A) potential energy in the first excited state would be 20.4 eV B) total energy in the first excited state would be 23.8 eV C) kinetic energy in the first excited state would be 3.4 eV D) total energy in the ground state would be 13.6 eV Which of the following statements is correct about the refraction of light from a plane surface when light ray goes from denser to rarer medium [C is critical angle] A) The maximum angle of deviation during refraction is C , it will be at angle of
2

52.

incidence C B) The maximum angle of deviation for all angle of incidences is 2C , when angle of incidence is slightly greater than C C) If angle of incidence is less than C then deviation increases if angle of incidence is also increased D) If angle of incidence is greater than C then angle of deviation decreases if angle of incidence is increased
SECTION III

Paragraph for Q.53 - 55 We have two radioactive nuclei A and B. Both convert into a stable nucleus C. Nucleus A converts into C after emitting tow -particles and three -particles. Nucleus B converts to C after emitting one -articles and five -particles. At time t = 0, nuclei of A are 4 N0 and that of B are N0. Half-life of A (into the conversion of C) is 1 minute and that of B is 2 minutes. Initially numbers of nuclei of C are zero. 53. If atomic numbers and mass numbers of A and B are Z1, Z2, A1 and A2 respectively. Then : A) Z1 Z 2 = 6 B) A1 A2 = 4 C) Both (A) and (B) are correct 54. D) Both (A) and (B) are wrong
9 N0 2 5N0 2

What are number of nuclei of C, when number of nuclei of A and B are equal ? A) 2 N0 B) 3 N0 C) D)

55.

At what time are rate of disintegrations of A and B are equal : A) 4 minutes B) 6 minutes C) 8 minutes

D) 2 minutes
v0 + C L 2v0 + 3C S

Paragraph for Q.56 58 : Two capacitors of capacitance C and 3C are charged to potential difference V0 and 2V0 respectively and connected to an inductor of inductance L as shown in the figure. Initially current in the inductor is zero. Now the switch S is closed. 56 The maximum current in the inductor is : A) 57.
3V0 2 3C L 3C L 3C L

B) V0

C) 2V0

D) V0

C L

Potential difference across capacitor of capacitance C when the current in the circuit is maximum : A)
V0 4

B)

3V0 4

(C)

5V0 4

D) None of these

58.

Potential difference across capacitor of capacitance 3C when the current in the circuit is maximum : A)
V0 4

B)

3V0 4

C)

5V0 4

D) None of these

SECTION IV Match the following : 59.

A uniform solid cube is floating in a liquid as shown in the figure with part x inside the liquid. Some changes in the parameters are mentioned in column-II. Assuming no other changes, match the following.

Column I A) B) C) D)
60.

Column II P) Q) R) S) If density of the liquid decreases. If height of the cube is increased keeping base area and density same. If the whole system is accelerated upward. If the cube is replaced by another cube of same size but lesser density.

x will Increase x will Decrease x will same. Remain

The cube may sink.

The variation of a physical quantity P with the space coordinates x or y is graphically represented in column I as A, B, C and D. The statements in column II are labeled p, q, r, s and t. Each graph in column I can have correct matching with one or more statements(s) in column II [Q is in Coulomb and a is in metre]
Column I
P

Column II
y

A)

+a

P)

a
+Q O

+a

Q x

Variation of potential along x-axis.

B)

+a

Q)

a
+Q O

+a +Q x

Variation of electric field along x-axis.

z + + + + O + y

C)

+a

R)

Variation of electric field along y-axis

Due to uniformly charged ring of radius a in ( x z ) plane.

P y

D)

+a

S)

a
+Q O

+a +Q x

Variation of electric potential along y

axis.

TEST - I - PAPER 1 IIT-JEE - KEY :

CHEMISTRY : 1. A, 2. A, 3. D, 4. B, 5. A, 6. D, 7. B 8. B, 9. AD, 10. AD, 11. ABCD, 12. ABC 13. D, 14. C, 15. B, 16. A, 17. B, 18. C, 19. A Q, B QR, C PRS, D PST; 20. A PST, B QS, C R, D P MATHEMATICS : 21. C, 22. C, 23. B, 24. C, 25. B, 26. D, 27. A, 28. D, 29. AC, 30. D, 31. ACD, 32. ABCD 33. C, 34. A, 35. B, 36. B, 37. D, 38. B, 39. A Q, B P, C S, D R, 40. A S, B P, C R, D Q. PHYSICS : 41. D, 42. B, 43. A, 44. B, 45. B. 46. C, 47. A, 48. D, 49. BC, 50. AC, 51. ABCD, 52. ABCD, 53. B, 54. C, 55. B, 56. A, 57. C, 58. C, 59. A PQ, B S, C R, D PQ, 60. A PQ, B NO MATCH, C R, D S