For preparing for Physics chemistry mathematics and biology Please visit http://www.exams.qoney.com 1.

Freon used as refrigerant is:

Ans. (c) 2. Formic acid can be distinguished from acetic acid by: (a) NaHCO3 (b) Tollens reagent (c) NaOH (d) None of these Ans. (b) 3. Amongst the trihalides of nitrogen which one is the least basic? (a) NF3 (b) Nd3 (c) NBr3 (d) NI3 Ans. (a) 4. Aldol condensation is not given by: (a) CH3CHO (b) HCHO (c) CH3CH2CHO (d) CH3COCH3 Ans. (b) 5. Which pair is of isoelectronic species?

Ans. (b) 6. Glycerol on heating with KHSO4 gives: (a) Acrolein (b) Formic acid (c) Oxalic acid (d) Allyl alcohol Ans. (a) 7. Acetaldehyde reacts with chlorine to give: (a) CC14 (b) CHC13

For preparing for Physics chemistry mathematics and biology Please visit http://www.exams.qoney.com (c) CC13 COCH3 (d) CCI3CHO Ans. (d) 8. Hydrolysis of cyanoen gives: (a) Oxalic acid + NH3 (b) Oxalic acid (c) NH3 (d) None of these Ans. (a) 9. Which of the following compound shows optical isomerism?

Ans. () 10. Number of primary alcohols of the formula. C5H120 are: (a) 1 (b) 4 (c) 5 (d) 3 Ans. (b) 11. Which enzyme converts sucrose into ethanol? (a) Diastase (b) Invertase (c) Zymase (d) Both (b) and (c) Ans. (d) 12. Which acts as auto catalyst during titration of KMnO4 and oxalic acid in presence ofH2SO4? (a) H2S04 (b) KMnSO4 (c) Oxalic acid

For preparing for Physics chemistry mathematics and biology Please visit http://www.exams.qoney.com (d) MnSO4 Ans. (d)

13. shows Cannizaros reaction due to: (a) Carbon is bounded by 3 methyl groups (b) Absence of ct-hydrogen atom (c) Due to steric effect (d) None of the above Ans. (b) 14. When primary amines react with nifros acid, the gas evolved is (a) N2 (b) NH3 (c) CO2 (d) CO Ans. (a) 15. Which is a natural polymer? (a) Protein (b) PVC (c) PMMA (d) SBR Ans. (a) 16. The greater the charge on an ion, the greater its coagulating power is a statement of: (a) Tyndalls effect (b) Faradays law (c) Mosleys law (d) Hardy-Schuize law Ans. (d) 17. When ice melts into water, entropy: (a) Becomes zero (b) Decreases (c) Increases (d) Remain same Ans. (c) 18. If the solubility of PbI2 in its saturated solutions at 25C be 2 x 10-3 mol/L. Its solubility product is: (a) 4x10-9 (b) 8 x 10-12 (c) 6x10-9 (d) 32x10-9

For preparing for Physics chemistry mathematics and biology Please visit http://www.exams.qoney.com Ans. (d) 19. The ionisation potential of nitrogen is greater than oxygen due to: (a) Half-filled 2p-subshell (b) More electropositive (c) Less electropositive (d) None of the above Ans. (a) 20. A radioactive substance decays to 3/4 of its original value in 30 min. The half-life of the substance is: (a) 60 mm (b) 5 mm (c) 7.5 mm (d) 15 mm Ans. (d) 21. The Epsom salt is represented by the formula:

Ans. (d) 22. Cinnabar is: (a) HgS (b) PbS (c) SnO2 (d) PbCO3 Ans. (a) 23. Which of the following has least bond angle? (a) H20 (b) H2S (c) H2Se (d) H2Te Ans. (d) 24. Which molecule is linear in shape? (a) NH3 (b) CO2 (c) BF3 (d) H20 Ans. (b) 25. CaCN2 + C is called as:

For preparing for Physics chemistry mathematics and biology Please visit http://www.exams.qoney.com (a) Urea (b) Thomas slag (c) Nitrolim (d) Triple superphosphate Ans. (c) 26. Alcoholic solution of KOH is used for: (a) Dehydration (b) Dehydrogenation (c) Dehydrohalogenation (d) Dehalogenation Ans. (c) 27. [EDTA]4 is a: (a) Monodentate ligand (b) Bidentate ligand (c) Quadridentate ligand (d) Hexadentate ligand Ans. (d) 28. 2.76g of silver carbonate on being strongly heated yield a residue weighing: (a) 2.16g (b) 2.48g (c) 2.64 g (d) 2.32 g Ans. (a) 29. A cylinder of gas supplied by Bharat petroleum is assumed to contain 14 kg of butane. It is normal family requires 20,000 kJ of energy per day for cooking, butane gas per mol) in the cylinder last for days. (a) 15 days (b) 20 days (c) 32 days (d) 40 days Ans. (c) 30. After losing a number of and -particles 92U238 is changed to 82Pb206. The total number of -particles lost in this process is: (a) 10 (b) 5 (c) 8 (d) 32 Ans. (c) 31. Which type of bond is present in H2S molecule? (a) Ionic bond

For preparing for Physics chemistry mathematics and biology Please visit http://www.exams.qoney.com (b) Covalent bond (c) Co-ordinate bond (d) All of the above Ans. (b) 32. A non-ideal solution was prepared by mixing 30 mL chloroform and 50 mL acetone. The volume of mixture will be: (a) >80mL (b) <80mL (c) =80mL (d) 80mL Ans. (b) 33. For the reaction A + B C, it found that doubling the concentration of A increases the rate by 4 times, and doubling the concentration of B doubles the reaction rate. What is the overall order of the reaction? (a) 4 (b) 3/2 (c) 3 (d) 1 Ans. (c) 34. Na and Mg crystallize in bcc and fcc type crystals respectively, then the number of atoms of Na and Mg present in the unit cell of their respective crystal is: (a) 4 and 2 (b) 9 and 14 (c) 14 and 9 (d) 2 and 4 Ans. (d) 35. The pH of 0.1M solution of the following salts increases in the order:

Ans. (d) 36. The compound in which cation is isoelectronic with anion is: (a) NaCl (b) CsF (c) Nal (d) K2S Ans. (d) 37. Which process of purification is represented by the following scheme?

For preparing for Physics chemistry mathematics and biology Please visit http://www.exams.qoney.com (a) Cupellation (b) Poling (c) Electrolytic refining (d) Van-Arkel process Ans. (d) 38. Bredig arc method cannot be used to prepare colloidal solution of which of the following? (a) Pt (b) Fe (c) Ag (d) Au Ans. (b) 39. In alkaline medium CIO2 oxidize H202 in O2 and reduced itself in Cl- then how many moles of H202 will oxidize by one mole of ClO2? (a) 1.0 (b) 1.5 (c) 2.5 (d) 3.5 Ans. (c) 40. For the electrochemical cell, From this data one can deduce that: and

Ans. (b) 41. Potassium is kept in: (a) Alcohol (c) Kerosene (b) Water (d) Liquid ammonia Ans. (c) 42. Which of the following is not obtained by direct reaction of constituent elements? (a) XeF2 (b) XeF4 (c) Xe03 (d) XeF6 Ans. (c) 43. The reagent which forms crystalline osazone derivative when reacted with glucose is

For preparing for Physics chemistry mathematics and biology Please visit http://www.exams.qoney.com (a) Fehling solution (b) Phenyl hydrazine (c) Benedict solution (d) Hydroxylamine Ans. (b) 44. The volume of a gas decreases from 500 cc to 300 cc when a sample gas is compressed by an average pressure of 0.6 atm. During this process 10 J of heat is liberated. The change in internal energy is: (a) 2.16J (b) 12.156J (c) 2.16J (d) 101.3J Ans. (c) 45. Benzaldehyde condenses with N, N-dimethylaniline in presence of anhydrous ZnCl2 to give: (a) Michlers ketone (b) azo-dye (c) Malachite green (d) Buffer yellow Ans. (c) 46. Which of the following cannot be used in Friedel-Crafts reaction? (a) FeC13 (b) FeBr2 (c) A1C13 (d) NaC1 Ans. (d) 47. A gaseous hypothetical chemical equation is carried out in a closed vessel. The concentration of B is found to increase by 5 x 10-3 mol L-1 in 10s. The rate of appearance of B is:

Ans. (a) 48. Which of the following collative properties can provide molar mass of proteins (or polymers or colloids) with greater precision? (a) Relative lowering of vapour pressure (b) Elevation in boiling point (c) Depression in freezing point (d) Osmotic pressure Ans. (d)

For preparing for Physics chemistry mathematics and biology Please visit http://www.exams.qoney.com 49. In compound X, all the bond angles are exactly 10928, X is: (a) Chloromethane (b) Iodoform (c) Carbon tetrachloride (d) Chloroform Ans. (c) 50. Glass is: (a) Super cooled liquid (b) Crystalline solid (c) Amorphous solid (d) Liquid crystal Ans. (a)