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pH [H+] [OH-] αCN(H) αNH3(H) [CN] [NH3]

0 1 1E-14 1584893193 1584893193 6.309573E-30 6.309573E-20


0.1 0.79432823 1.25893E-14 1258925413 1258925413 7.943282E-30 7.943282E-20
0.2 0.63095734 1.58489E-14 1000000001 1000000001 1E-29 1E-19
0.3 0.50118723 1.99526E-14 794328236 794328236 1.258925E-29 1.258925E-19
0.4 0.39810717 2.51189E-14 630957345 630957345 1.584893E-29 1.584893E-19
0.5 0.31622777 3.16228E-14 501187235 501187235 1.995262E-29 1.995262E-19
0.6 0.25118864 3.98107E-14 398107172 398107172 2.511886E-29 2.511886E-19
0.7 0.19952623 5.01187E-14 316227767 316227767 3.162278E-29 3.162278E-19
0.8 0.15848932 6.30957E-14 251188644 251188644 3.981072E-29 3.981072E-19
0.9 0.12589254 7.94328E-14 199526232 199526232 5.011872E-29 5.011872E-19
1 0.1 1E-13 158489320 158489320 6.309573E-29 6.309573E-19
1.1 0.07943282 1.25893E-13 125892542 125892542 7.943282E-29 7.943282E-19
1.2 0.06309573 1.58489E-13 100000001 100000001 1E-28 1E-18
1.3 0.05011872 1.99526E-13 79432824.5 79432824.5 1.258925E-28 1.258925E-18
1.4 0.03981072 2.51189E-13 63095735.4 63095735.4 1.584893E-28 1.584893E-18
1.5 0.03162278 3.16228E-13 50118724.4 50118724.4 1.995262E-28 1.995262E-18
1.6 0.02511886 3.98107E-13 39810718.1 39810718.1 2.511886E-28 2.511886E-18
1.7 0.01995262 5.01187E-13 31622777.6 31622777.6 3.162278E-28 3.162278E-18
1.8 0.01584893 6.30957E-13 25118865.3 25118865.3 3.981072E-28 3.981072E-18
1.9 0.01258925 7.94328E-13 19952624.1 19952624.1 5.011872E-28 5.011872E-18
2 0.01 1E-12 15848932.9 15848932.9 6.309573E-28 6.309573E-18
2.1 0.00794328 1.25893E-12 12589255.1 12589255.1 7.943282E-28 7.943282E-18
2.2 0.00630957 1.58489E-12 10000001 10000001 1E-27 1E-17
2.3 0.00501187 1.99526E-12 7943283.35 7943283.35 1.258925E-27 1.258925E-17
2.4 0.00398107 2.51189E-12 6309574.44 6309574.44 1.584893E-27 1.584893E-17
2.5 0.00316228 3.16228E-12 5011873.34 5011873.34 1.995262E-27 1.995262E-17
2.6 0.00251189 3.98107E-12 3981072.71 3981072.71 2.511886E-27 2.511886E-17
2.7 0.00199526 5.01187E-12 3162278.66 3162278.66 3.162277E-27 3.162277E-17
2.8 0.00158489 6.30957E-12 2511887.43 2511887.43 3.98107E-27 3.98107E-17
2.9 0.00125893 7.94328E-12 1995263.31 1995263.31 5.01187E-27 5.01187E-17
3 0.001 1E-11 1584894.19 1584894.19 6.309569E-27 6.309569E-17
3.1 0.00079433 1.25893E-11 1258926.41 1258926.41 7.943276E-27 7.943276E-17
3.2 0.00063096 1.58489E-11 1000001 1000001 9.99999E-27 9.99999E-17
3.3 0.00050119 1.99526E-11 794329.235 794329.235 1.258924E-26 1.258924E-16
3.4 0.00039811 2.51189E-11 630958.344 630958.344 1.584891E-26 1.584891E-16
3.5 0.00031623 3.16228E-11 501188.234 501188.234 1.995258E-26 1.995258E-16
3.6 0.00025119 3.98107E-11 398108.171 398108.171 2.51188E-26 2.51188E-16
3.7 0.00019953 5.01187E-11 316228.766 316228.766 3.162268E-26 3.162268E-16
3.8 0.00015849 6.30957E-11 251189.643 251189.643 3.981056E-26 3.981056E-16
3.9 0.00012589 7.94328E-11 199527.231 199527.231 5.011847E-26 5.011847E-16
4 0.0001 1E-10 158490.319 158490.319 6.309534E-26 6.309534E-16
4.1 7.94328E-05 1.25893E-10 125893.541 125893.541 7.943219E-26 7.943219E-16
4.2 6.30957E-05 1.58489E-10 100001 100001 9.9999E-26 9.9999E-16
4.3 5.01187E-05 1.99526E-10 79433.8235 79433.8235 1.25891E-25 1.25891E-15
4.4 3.98107E-05 2.51189E-10 63096.7344 63096.7344 1.584868E-25 1.584868E-15
4.5 3.16228E-05 3.16228E-10 50119.7234 50119.7234 1.995223E-25 1.995223E-15
4.6 2.51189E-05 3.98107E-10 39811.7171 39811.7171 2.511823E-25 2.511823E-15
4.7 1.99526E-05 5.01187E-10 31623.7766 31623.7766 3.162178E-25 3.162178E-15
4.8 1.58489E-05 6.30957E-10 25119.8643 25119.8643 3.980913E-25 3.980913E-15
4.9 1.25893E-05 7.94328E-10 19953.6231 19953.6231 5.011621E-25 5.011621E-15
5 0.00001 1E-09 15849.9319 15849.9319 6.309175E-25 6.309175E-15
5.1 7.94328E-06 1.25893E-09 12590.2541 12590.2541 7.942651E-25 7.942651E-15
5.2 6.30957E-06 1.58489E-09 10001 10001 9.999E-25 9.999E-15
5.3 5.01187E-06 1.99526E-09 7944.28235 7944.28235 1.258767E-24 1.258767E-14
5.4 3.98107E-06 2.51189E-09 6310.57344 6310.57344 1.584642E-24 1.584642E-14
5.5 3.16228E-06 3.16228E-09 5012.87234 5012.87234 1.994864E-24 1.994864E-14
5.6 2.51189E-06 3.98107E-09 3982.07171 3982.07171 2.511256E-24 2.511256E-14
5.7 1.99526E-06 5.01187E-09 3163.27766 3163.27766 3.161278E-24 3.161278E-14
5.8 1.58489E-06 6.30957E-09 2512.88643 2512.88643 3.979487E-24 3.979487E-14
5.9 1.25893E-06 7.94328E-09 1996.26231 1996.26231 5.009362E-24 5.009362E-14
6 0.000001 0.00000001 1585.89319 1585.89319 6.305595E-24 6.305595E-14
6.1 7.94328E-07 1.25893E-08 1259.92541 1259.92541 7.936978E-24 7.936978E-14
6.2 6.30957E-07 1.58489E-08 1001 1001 9.99001E-24 9.99001E-14
6.3 5.01187E-07 1.99526E-08 795.328235 795.328235 1.257343E-23 1.257343E-13
6.4 3.98107E-07 2.51189E-08 631.957344 631.957344 1.582385E-23 1.582385E-13
6.5 3.16228E-07 3.16228E-08 502.187234 502.187234 1.991289E-23 1.991289E-13
6.6 2.51189E-07 3.98107E-08 399.107171 399.107171 2.505593E-23 2.505593E-13
6.7 1.99526E-07 5.01187E-08 317.227766 317.227766 3.152309E-23 3.152309E-13
6.8 1.58489E-07 6.30957E-08 252.188643 252.188643 3.965286E-23 3.965286E-13
6.9 1.25893E-07 7.94328E-08 200.526231 200.526231 4.986879E-23 4.986879E-13
7 0.0000001 0.0000001 159.489319 159.489319 6.270012E-23 6.270012E-13
7.1 7.94328E-08 1.25893E-07 126.892541 126.892541 7.880684E-23 7.880684E-13
7.2 6.30957E-08 1.58489E-07 101 101 9.90099E-23 9.90099E-13
7.3 5.01187E-08 1.99526E-07 80.4328235 80.4328235 1.243274E-22 1.243274E-12
7.4 3.98107E-08 2.51189E-07 64.0957344 64.0957344 1.560166E-22 1.560166E-12
7.5 3.16228E-08 3.16228E-07 51.1187234 51.1187234 1.95623E-22 1.95623E-12
7.6 2.51189E-08 3.98107E-07 40.8107171 40.8107171 2.450337E-22 2.450337E-12
7.7 1.99526E-08 5.01187E-07 32.6227766 32.6227766 3.065343E-22 3.065343E-12
7.8 1.58489E-08 6.30957E-07 26.1188643 26.1188643 3.82865E-22 3.82865E-12
7.9 1.25893E-08 7.94328E-07 20.9526231 20.9526231 4.772672E-22 4.772672E-12
8 0.00000001 0.000001 16.8489319 16.8489319 5.935094E-22 5.935094E-12
8.1 7.94328E-09 1.25893E-06 13.5892541 13.5892541 7.358756E-22 7.358756E-12
8.2 6.30957E-09 1.58489E-06 11 11 9.090909E-22 9.090909E-12
8.3 5.01187E-09 1.99526E-06 8.94328235 8.94328235 1.118158E-21 1.118158E-11
8.4 3.98107E-09 2.51189E-06 7.30957344 7.30957344 1.368069E-21 1.368069E-11
8.5 3.16228E-09 3.16228E-06 6.01187234 6.01187234 1.663375E-21 1.663375E-11
8.6 2.51189E-09 3.98107E-06 4.98107171 4.98107171 2.0076E-21 2.0076E-11
8.7 1.99526E-09 5.01187E-06 4.16227766 4.16227766 2.402531E-21 2.402531E-11
8.8 1.58489E-09 6.30957E-06 3.51188643 3.51188643 2.847472E-21 2.847472E-11
8.9 1.25893E-09 7.94328E-06 2.99526231 2.99526231 3.338606E-21 3.338606E-11
9 1E-09 0.00001 2.58489319 2.58489319 3.868632E-21 3.868632E-11
9.1 7.94328E-10 1.25893E-05 2.25892541 2.25892541 4.426884E-21 4.426884E-11
9.2 6.30957E-10 1.58489E-05 2 2 5E-21 5E-11
9.3 5.01187E-10 1.99526E-05 1.79432823 1.79432823 5.573116E-21 5.573116E-11
9.4 3.98107E-10 2.51189E-05 1.63095734 1.63095734 6.131368E-21 6.131368E-11
9.5 3.16228E-10 3.16228E-05 1.50118723 1.50118723 6.661394E-21 6.661394E-11
9.6 2.51189E-10 3.98107E-05 1.39810717 1.39810717 7.152528E-21 7.152528E-11
9.7 1.99526E-10 5.01187E-05 1.31622777 1.31622777 7.597469E-21 7.597469E-11
9.8 1.58489E-10 6.30957E-05 1.25118864 1.25118864 7.9924E-21 7.9924E-11
9.9 1.25893E-10 7.94328E-05 1.19952623 1.19952623 8.336625E-21 8.336625E-11
10 1E-10 0.0001 1.15848932 1.15848932 8.631931E-21 8.631931E-11
10.1 7.94328E-11 0.00012589 1.12589254 1.12589254 8.881842E-21 8.881842E-11
10.2 6.30957E-11 0.00015849 1.1 1.1 9.090909E-21 9.090909E-11
10.3 5.01187E-11 0.00019953 1.07943282 1.07943282 9.264124E-21 9.264124E-11
10.4 3.98107E-11 0.00025119 1.06309573 1.06309573 9.406491E-21 9.406491E-11
10.5 3.16228E-11 0.00031623 1.05011872 1.05011872 9.522733E-21 9.522733E-11
10.6 2.51189E-11 0.00039811 1.03981072 1.03981072 9.617135E-21 9.617135E-11
10.7 1.99526E-11 0.00050119 1.03162278 1.03162278 9.693466E-21 9.693466E-11
10.8 1.58489E-11 0.00063096 1.02511886 1.02511886 9.754966E-21 9.754966E-11
10.9 1.25893E-11 0.00079433 1.01995262 1.01995262 9.804377E-21 9.804377E-11
11 1E-11 0.001 1.01584893 1.01584893 9.843983E-21 9.843983E-11
11.1 7.94328E-12 0.00125893 1.01258925 1.01258925 9.875673E-21 9.875673E-11
11.2 6.30957E-12 0.00158489 1.01 1.01 9.90099E-21 9.90099E-11
11.3 5.01187E-12 0.00199526 1.00794328 1.00794328 9.921193E-21 9.921193E-11
11.4 3.98107E-12 0.00251189 1.00630957 1.00630957 9.9373E-21 9.9373E-11
11.5 3.16228E-12 0.00316228 1.00501187 1.00501187 9.950131E-21 9.950131E-11
11.6 2.51189E-12 0.00398107 1.00398107 1.00398107 9.960347E-21 9.960347E-11
11.7 1.99526E-12 0.00501187 1.00316228 1.00316228 9.968477E-21 9.968477E-11
11.8 1.58489E-12 0.00630957 1.00251189 1.00251189 9.974944E-21 9.974944E-11
11.9 1.25893E-12 0.00794328 1.00199526 1.00199526 9.980087E-21 9.980087E-11
12 1E-12 0.01 1.00158489 1.00158489 9.984176E-21 9.984176E-11
12.1 7.94328E-13 0.01258925 1.00125893 1.00125893 9.987427E-21 9.987427E-11
12.2 6.30957E-13 0.01584893 1.001 1.001 9.99001E-21 9.99001E-11
12.3 5.01187E-13 0.01995262 1.00079433 1.00079433 9.992063E-21 9.992063E-11
12.4 3.98107E-13 0.02511886 1.00063096 1.00063096 9.993694E-21 9.993694E-11
12.5 3.16228E-13 0.03162278 1.00050119 1.00050119 9.994991E-21 9.994991E-11
12.6 2.51189E-13 0.03981072 1.00039811 1.00039811 9.996021E-21 9.996021E-11
12.7 1.99526E-13 0.05011872 1.00031623 1.00031623 9.996839E-21 9.996839E-11
12.8 1.58489E-13 0.06309573 1.00025119 1.00025119 9.997489E-21 9.997489E-11
12.9 1.25893E-13 0.07943282 1.00019953 1.00019953 9.998005E-21 9.998005E-11
13 1E-13 0.1 1.00015849 1.00015849 9.998415E-21 9.998415E-11
13.1 7.94328E-14 0.12589254 1.00012589 1.00012589 9.998741E-21 9.998741E-11
13.2 6.30957E-14 0.15848932 1.0001 1.0001 9.999E-21 9.999E-11
13.3 5.01187E-14 0.19952623 1.00007943 1.00007943 9.999206E-21 9.999206E-11
13.4 3.98107E-14 0.25118864 1.0000631 1.0000631 9.999369E-21 9.999369E-11
13.5 3.16228E-14 0.31622777 1.00005012 1.00005012 9.999499E-21 9.999499E-11
13.6 2.51189E-14 0.39810717 1.00003981 1.00003981 9.999602E-21 9.999602E-11
13.7 1.99526E-14 0.50118723 1.00003162 1.00003162 9.999684E-21 9.999684E-11
13.8 1.58489E-14 0.63095734 1.00002512 1.00002512 9.999749E-21 9.999749E-11
13.9 1.25893E-14 0.79432823 1.00001995 1.00001995 9.9998E-21 9.9998E-11
14 1E-14 1 1.00001585 1.00001585 9.999842E-21 9.999842E-11
αHg2+(OH-,NH3,CN-) αY4-(H+) αHgY2-(OH-,H+) Kf´ Ph logkf´
1.00010010004612 1.600774E+21 1259.92541179496 4965.596331 0 3.69597141
1.00012605108856 6.389206E+20 1001.000000001 9883.9937194 0.1 3.99493246
1.00015874058099 2.551823E+20 795.328234725541 19661.964666 0.2 4.29362691
1.00019992443069 1.020032E+20 631.957344481778 39082.931165 0.3 4.59198713
1.00025181971634 4.081573E+19 502.187233629268 77611.979606 0.4 4.88992876
1.00031722791186 1.635328E+19 399.107170556009 153938.36553 0.5 5.18734687
1.00039969224735 6.562757E+18 317.22776602 304867.61692 0.6 5.4841113
1.00050369935121 2.639038E+18 252.188643154939 602644.50176 0.7 5.7800612
1.00063493870719 1.06389E+18 200.5262315019 1188498.8769 0.8 6.07499878
1.00080063817452 4.302311E+17 159.489319252421 2337126.3536 0.9 6.36868219
1.0010100004612 1.746545E+17 126.89254118736 4579498.7641 1 6.66081795
1.00127477492434 7.123854E+16 101.00000001 8934146.3086 1.1 6.95105306
1.00161001278773 2.922583E+16 80.4328234850174 17336754.758 1.2 7.23896781
1.00203507395225 1.20747E+16 64.0957344638683 33424890.613 1.3 7.52406999
1.00257498332445 5.031191E+15 51.1187233826799 63942897.446 1.4 7.80579231
1.00326227911862 2.117704E+15 40.8107170804686 121197739.33 1.5 8.08349452
1.00413956286086 9.020991E+14 32.6227766333066 227233620.81 1.6 8.35647259
1.00526306329091 3.896708E+14 26.1188643549065 420704018.78 1.7 8.62397666
1.00670768352535 1.710393E+14 20.9526231998075 767783943.09 1.8 8.88523903
1.00857424335519 7.644562E+13 16.8489319877069 1378833774 1.9 9.13951191
1.01100000461203 3.486034E+13 13.5892541973745 2432835999 2 9.38611283
1.0141741531166 1.624828E+13 11.0000001 4211849531 2.1 9.62447285
1.0183608256657 7.752009E+12 8.94328247313535 7147941190 2.2 9.85418097
1.02393370405744 3.789691E+12 7.30957360329125 11885472629 2.3 10.0750165
1.0314284493448 1.899374E+12 6.01187253579895 19362445414 2.4 10.2869602
1.04162279118622 9759674146264.98107195672361 30915553328 2.5 10.490177
1.05565966734082 5138607278204.16227797639614 48412969778 2.6 10.6849617
1.07523761079282 2769437573923.51188682961675 74412258318 2.7 10.8716445
1.10290648060349 1525601806982.99526281615611112319471698 2.8 11.0504551
1.14252859455548 85747690535 2.58489382341846166476600449 2.9 11.2213532
1.20000004612106 49076554343 2.2589262061224 242017470578 3 11.3838467
1.28438191848907 28542711774 2.000001 344223723308 3.1 11.5368408
1.40967803549589 16834103722 1.79432949364969477081157288 3.2 11.6785923
1.59763349407866 10048544663 1.63095892937339641006894626 3.3 11.8068627
1.8821461034925 6059626337 1.50118922888959830493546895 3.4 11.9193363
2.31622791188684 3685623400 1.39810968243993 1.033354E+12 3.5 12.014249
2.98300054667247 2257772405 1.3162309282945 1.233101E+12 3.6 12.0909986
4.01307389638515 1391310912 1.25119262422266 1.413913E+12 3.7 12.1504228
5.61202934121296 861586247.83 1.19953124336922 1.565283E+12 3.8 12.1945929
8.10390204626907 535720004.83 1.15849562881956 1.683691E+12 3.9 12.2262624
12.0000004619945 334230450.58 1.12590048446176 1.771221E+12 4 12.2482727
18.1078579186059 209117503.77 1.10001 1.832902E+12 4.1 12.2631392
27.7037582416695 131157658.16 1.07944541272655 1.874426E+12 4.2 12.2728683
42.805980296838 82438086.787 1.06311158337994 1.900844E+12 4.3 12.2789465
66.60762205059 51917033.669 1.05013867598588 1.916077E+12 4.4 12.2824129
104.162279143711 32756507.073 1.03983583591966 1.9229E+12 4.5 12.2839567
163.470392837804 20705630.984 1.03165439937829 1.923121E+12 4.6 12.2840067
257.20051789865 13113506.018 1.02515867503215 1.917787E+12 4.7 12.2828004
405.41674710771 8322706.8477 1.02000274187305 1.90737E+12 4.8 12.2804351
639.900630888834 5294724.5667 1.01591202765906 1.891909E+12 4.9 12.2769002
1011.00000540608 3377669.6725 1.01266868694141 1.871109E+12 5 12.272099
1598.48245396972 2161702.2261 1.0101 1.844423E+12 5.1 12.2658606
2528.73537390533 1388802.5366 1.00806917488842 1.811117E+12 5.2 12.2579465
4002.02434419535 896325.49704 1.00646806276405 1.770331E+12 5.3 12.2480545
6335.69233328943 581621.45521 1.00521139856777 1.721167E+12 5.4 12.2358229
10032.6228163023 379825.84619 1.00423226034869 1.662781E+12 5.5 12.2208352
15889.7427101417 249897.2066 1.00347850542619 1.594519E+12 5.6 12.2026298
25169.9831615664 165830.17589 1.00290999360206 1.516057E+12 5.7 12.1807155
39874.813018413 111119.70581 1.0024964495486 1.427556E+12 5.8 12.1545931
63176.1677062161 75270.214435 1.00221585053694 1.329795E+12 5.9 12.1237848
100101.000840421 51592.250268 1.00205325364652 1.224244E+12 6 12.0878679
158616.213430202 35810.498988 1.002 1.113037E+12 6.1 12.0465098
251348.135705508 25183.489559 1.00205325364652998847589972 6.2 11.9994992
398307.70318648 17946.27771 1.00221585053694884643268998 6.3 11.9467682
631209.545828273 12957.154723 1.0024964495486 773391937497 6.4 11.8883996
1000317.25303045 9473.3523081 1.00290999360206667760169561 6.5 11.8246205
1585292.34993356 7008.3858462 1.00347850542619569876445179 6.6 11.7557807
2512388.71897366 5241.1230124 1.00423226034869481197077509 6.7 11.682323
3981703.86269559 3957.6689916 1.00521139856777402484333146 6.8 11.604749
6310369.17150844 3014.1052883 1.00646806276405333877238056 6.9 11.5235868
10001001.7947867 2312.5059301 1.00806917488842275019808048 7 11.439364
15850193.4354924 1785.4273673 1.0101 225209972201 7.1 11.3525876
25120453.37129 1385.8219341 1.01266868694141183540739488 7.2 11.2637325
39812719.6281475 1080.4348187 1.01591202765906149016955071 7.3 11.1732357
63098259.9248462 845.44795809 1.02000274187305120641596801 7.4 11.0814971
100003188.397956 663.58062227 1.02515867503215 97472824049 7.5 10.9888835
158493351.438334 522.14010797 1.03165439937829 78656774093 7.6 10.8957361
251193756.025538 411.69655056 1.03983583591966 63442269780 7.7 10.8023787
398113680.655978 325.17111146 1.05013867598588 51183219046 7.8 10.7091276
630965686.873208 257.20054711 1.06311158337994 41333408473 7.9 10.6163012
1000010795.33258 203.68852501 1.07944541272655 33437163859 8 10.5242294
1584907367.61382 161.4845895 1.10001 27118250312 8.1 10.4332617
2511905443.72585 128.15147057 1.12590048446176 22068515732 8.2 10.3437731
3981097968.73979 101.79433023 1.15849562881956 18037151173 8.3 10.2561679
6309611153.93044 80.934011706 1.19953124336922 14821013430 8.4 10.1708779
10000056742.6532 64.411962715 1.25119262422266 12256181349 8.5 10.0883552
15849021855.0663 51.318249845 1.3162309282945 10210753464 8.6 10.0090578
25119014434.837 40.936609722 1.39810968243993 8578804587 8.7 9.93342678
39810979678.3369 32.702209488 1.50118922888959 7275376592 8.8 9.86185548
63096211989.0382 26.16898307 1.63095892937339 6232365167 8.9 9.79465289
100000894329.264 20.984245942 1.79432949364969 5395167644 9 9.73200494
158491030032.878 16.868884556 2.000001 4719969136 9.1 9.67393916
251191963918.976 13.601843376 2.25892620612241 4171560367 9.2 9.62029853
398113679654.217 11.007943284 2.58489382341846 3721597701 9.3 9.57072942
630970184924.001 8.9482942206 2.99526281615612 3347232207 9.4 9.52468584
1000025435093.13 7.312735723 3.51188682961675 3030048552 9.5 9.48144959
1584943709292.71 6.0138675988 4.16227797639616 2755265005 9.6 9.44016338
2511986932697.88 4.9823306311 4.98107195672363 2511151388 9.7 9.3998729
3981271862724.89 4.1630719885 6.01187253579897 2288621685 9.8 9.35957401
6309972346301.79 3.5123876188 7.30957360329126 2080952418 9.9 9.31826215
10000795328235.8 2.9955785428 8.94328247313537 1883569710 10 9.2749817
15850518076730.2 2.5850927187 11.0000001 1693842802 10.1 9.2288731
25122028177650.4 2.2590513043 13.5892541973745 1510827322 10.2 9.17921483
39817028624058 2.0000794328 16.8489319877069 1334923216 10.3 9.12545629
63108326214024.9 1.7943783534 20.9526231998076 1167448468 10.4 9.06723772
100025122026594 1.6309889673 26.1188643549065 1010169326 10.5 9.00439418
158539441950548 1.5012071863 32.6227766333067 864854327.11 10.6 8.93694296
251288648162833 1.3981197598 40.8107170804687 732920690.49 10.7 8.86505698
398306703094570 1.3162357093 51.11872338268 615217549.08 10.8 8.78902872
631355459594031 1.251193655 64.0957344638684 511953663 10.9 8.70923065
1.00079433823473E+015 1.1995293938 80.4328234850175 422744124.18 11 8.62607758
1586478098242840 1.1584913145 101.00000001 346732467.93 11.1 8.53999451
2515048725018694 1.1258938001 126.89254118736 282743261.86 11.2 8.45139226
3987381298932411 1.1000007943 159.489319252421 229430334.29 11.3 8.36065084
6322162724038749 1.0794333247 200.5262315019 185399987.59 11.4 8.2681097
1.00251188959379E+016 1.0630960507 252.188643154939 149301265.29 11.5 8.17406349
1.58990506877847E+016 1.0501189229 317.227766020002 119884079.91 11.6 8.07876151
2.52188643652146E+016 1.0398108429 399.107170556011 96030604.533 11.7 7.98240966
4.00102433499425E+016 1.031622856 502.187233629269 76766814.518 11.8 7.88517352
6.34938416980057E+016 1.0251189144 631.957344481779 61260694.199 11.9 7.78718191
1.00794328334724E+017 1.0199526548 795.328234725541 48812414.737 12 7.68853029
1.60074212564466E+017 1.0158489519 1001.000000001 38840388.611 12.1 7.58928357
2.54350920969617E+017 1.0125892667 1259.92541179497 30865847.159 12.2 7.4894782
4.04416744197827E+017 1.0100000079 1585.89319246175 24497593.796 12.3 7.38912343
6.43546598849325E+017 1.0079432874 1996.26231496938 19417866.548 12.4 7.28820151
1.02511886463132E+018 1.0063095766 2512.88643150998 15369758.018 12.5 7.18666703
1.63501191622196E+018 1.0050118743 3163.27766016871 12146333.436 12.6 7.0844452
2.61188643201078E+018 1.003981073 3982.07170553524 9581406.3964 12.7 6.98142926
4.18059793766283E+018 1.0031622785 5012.87233627294 7541835.3933 12.8 6.87747705
6.70768061614977E+018 1.0025118869 6310.5734448021 5921161.67 12.9 6.77240692
1.07943282357243E+019 1.0019952626 7944.28234724295 4634398.5835 13 6.66599338
1.74338251183313E+019 1.0015848934 10001.0000000001 3613790.5385 13.1 6.55796298
2.82811419768492E+019 1.0012589255 12590.2541179418 2805376.4909 13.2 6.44799115
4.61202905021471E+019 1.0010000001 15849.9319246112 2166213.6573 13.3 6.33570129
7.5684988568473E+019 1.0007943283 19953.6231496889 1662138.3908 13.4 6.22066718
1.25118864318258E+020 1.0006309574 25119.8643150959 1265961.6818 13.5 6.10242056
2.08608042612821E+020 1.0005011873 31623.776601684 956015.8156 13.6 5.98046508
3.51188643155971E+020 1.0003981072 39811.7170553499 714986.07628 13.7 5.85429758
5.97633402056696E+020 1.0003162278 50119.7233627274 528976.6337 13.8 5.72343649
1.02906451504163E+021 1.0002511886 63096.7344480195 386772.15844 13.9 5.5874552
1.79432823473428E+021 1.0001995262 79433.8234724283 279265.27164 14 5.44601693
𝒍𝒐𝒈𝑲𝒇 ′𝑯𝒈/𝒀 = 𝒇(𝒑𝑯)
13
12
11
10
9
8
7
logKf´

6
5
4
3
2
1
0
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14
pH
Condiciones experimentales
PNH3´ PCN-´
10 20
[NH3´] [CN´]
1E-10 mol/L 1E-20 mol/L

Cantidades iniciales
[Hg2+] [EDTA]
0.01 mol/L 0.01 mol/L
Hg2++Y4-⇌equilibrio
HgY2- principal
logKf kf
21.8 6.31E+21

equilibrios secundarios
HgY2-+ H+⇌HgHY- HgY2-+ OH-⇌HgOHY3-
logKf kf
3.1 1258.9254

Hg2++iOH-⇌Hg(OH)i2-i
i logβi
1 10
2 21
3 20.9

HjYj-4⇌H++ Hj-1Yj-5
j pKa j
4 2
3 2.7
2 6.2
1 10.3

NH4+⇌H++NH3
HCN⇌H++CN-
pKa pKa
9.2 9.2
Logβ1 Logβ1
9.2 9.2
β1 β1
1.585E+09 1.585E+09
ibrio principal

HgY2-+ OH-⇌HgOHY3- Hg2++kNH3⇌Hg(NH3)k2+


logKf kf k logβk βk
4.9 79432.823 1 8.8 630957344.4802
2 17.5 3.16227766E+17
3 18.5 3.16227766E+18
4 19.4 2.51188643E+19
Hg2++mCN-⇌Hg(CN)m2-m
m logβm βm
βi 1 18 1E+018
1E+10 2 34.7 5.01187234E+34
1E+021 3 38.5 3.16227766E+38
7.943E+20 4 41.5 3.16227766E+41

logBj βj ka
21.2 1.585E+21 0.01
19.2 1.585E+19 0.0019953
16.5 3.162E+16 6.3096E-07
10.3 1.995E+10 5.0119E-11

CN⇌H++CN-
pH [H+] [OH-] αCN(H) αNH3(H) [CN] [NH3] pH
0 1 1E-14 1584893193 1584893193 6.309573E-30 6.309573E-20 0
0.1 0.79432823 1.25893E-14 1258925413 1258925413 7.943282E-30 7.943282E-20 0.1
0.2 0.63095734 1.58489E-14 1000000001 1000000001 1E-29 1E-19 0.2
0.3 0.50118723 1.99526E-14 794328236 794328236 1.258925E-29 1.258925E-19 0.3
0.4 0.39810717 2.51189E-14 630957345 630957345 1.584893E-29 1.584893E-19 0.4
0.5 0.31622777 3.16228E-14 501187235 501187235 1.995262E-29 1.995262E-19 0.5
0.6 0.25118864 3.98107E-14 398107172 398107172 2.511886E-29 2.511886E-19 0.6
0.7 0.19952623 5.01187E-14 316227767 316227767 3.162278E-29 3.162278E-19 0.7
0.8 0.15848932 6.30957E-14 251188644 251188644 3.981072E-29 3.981072E-19 0.8
0.9 0.12589254 7.94328E-14 199526232 199526232 5.011872E-29 5.011872E-19 0.9
1 0.1 1E-13 158489320 158489320 6.309573E-29 6.309573E-19 1
1.1 0.07943282 1.25893E-13 125892542 125892542 7.943282E-29 7.943282E-19 1.1
1.2 0.06309573 1.58489E-13 100000001 100000001 1E-28 1E-18 1.2
1.3 0.05011872 1.99526E-13 79432824.5 79432824.5 1.258925E-28 1.258925E-18 1.3
1.4 0.03981072 2.51189E-13 63095735.4 63095735.4 1.584893E-28 1.584893E-18 1.4
1.5 0.03162278 3.16228E-13 50118724.4 50118724.4 1.995262E-28 1.995262E-18 1.5
1.6 0.02511886 3.98107E-13 39810718.1 39810718.1 2.511886E-28 2.511886E-18 1.6
1.7 0.01995262 5.01187E-13 31622777.6 31622777.6 3.162278E-28 3.162278E-18 1.7
1.8 0.01584893 6.30957E-13 25118865.3 25118865.3 3.981072E-28 3.981072E-18 1.8
1.9 0.01258925 7.94328E-13 19952624.1 19952624.1 5.011872E-28 5.011872E-18 1.9
2 0.01 1E-12 15848932.9 15848932.9 6.309573E-28 6.309573E-18 2
2.1 0.00794328 1.25893E-12 12589255.1 12589255.1 7.943282E-28 7.943282E-18 2.1
2.2 0.00630957 1.58489E-12 10000001 10000001 1E-27 1E-17 2.2
2.3 0.00501187 1.99526E-12 7943283.35 7943283.35 1.258925E-27 1.258925E-17 2.3
2.4 0.00398107 2.51189E-12 6309574.44 6309574.44 1.584893E-27 1.584893E-17 2.4
2.5 0.00316228 3.16228E-12 5011873.34 5011873.34 1.995262E-27 1.995262E-17 2.5
2.6 0.00251189 3.98107E-12 3981072.71 3981072.71 2.511886E-27 2.511886E-17 2.6
2.7 0.00199526 5.01187E-12 3162278.66 3162278.66 3.162277E-27 3.162277E-17 2.7
2.8 0.00158489 6.30957E-12 2511887.43 2511887.43 3.98107E-27 3.98107E-17 2.8
2.9 0.00125893 7.94328E-12 1995263.31 1995263.31 5.01187E-27 5.01187E-17 2.9
3 0.001 1E-11 1584894.19 1584894.19 6.309569E-27 6.309569E-17 3
3.1 0.00079433 1.25893E-11 1258926.41 1258926.41 7.943276E-27 7.943276E-17 3.1
3.2 0.00063096 1.58489E-11 1000001 1000001 9.99999E-27 9.99999E-17 3.2
3.3 0.00050119 1.99526E-11 794329.235 794329.235 1.258924E-26 1.258924E-16 3.3
3.4 0.00039811 2.51189E-11 630958.344 630958.344 1.584891E-26 1.584891E-16 3.4
3.5 0.00031623 3.16228E-11 501188.234 501188.234 1.995258E-26 1.995258E-16 3.5
3.6 0.00025119 3.98107E-11 398108.171 398108.171 2.51188E-26 2.51188E-16 3.6
3.7 0.00019953 5.01187E-11 316228.766 316228.766 3.162268E-26 3.162268E-16 3.7
3.8 0.00015849 6.30957E-11 251189.643 251189.643 3.981056E-26 3.981056E-16 3.8
3.9 0.00012589 7.94328E-11 199527.231 199527.231 5.011847E-26 5.011847E-16 3.9
4 0.0001 1E-10 158490.319 158490.319 6.309534E-26 6.309534E-16 4
4.1 7.94328E-05 1.25893E-10 125893.541 125893.541 7.943219E-26 7.943219E-16 4.1
4.2 6.30957E-05 1.58489E-10 100001 100001 9.9999E-26 9.9999E-16 4.2
4.3 5.01187E-05 1.99526E-10 79433.8235 79433.8235 1.25891E-25 1.25891E-15 4.3
4.4 3.98107E-05 2.51189E-10 63096.7344 63096.7344 1.584868E-25 1.584868E-15 4.4
4.5 3.16228E-05 3.16228E-10 50119.7234 50119.7234 1.995223E-25 1.995223E-15 4.5
4.6 2.51189E-05 3.98107E-10 39811.7171 39811.7171 2.511823E-25 2.511823E-15 4.6
4.7 1.99526E-05 5.01187E-10 31623.7766 31623.7766 3.162178E-25 3.162178E-15 4.7
4.8 1.58489E-05 6.30957E-10 25119.8643 25119.8643 3.980913E-25 3.980913E-15 4.8
4.9 1.25893E-05 7.94328E-10 19953.6231 19953.6231 5.011621E-25 5.011621E-15 4.9
5 0.00001 1E-09 15849.9319 15849.9319 6.309175E-25 6.309175E-15 5
5.1 7.94328E-06 1.25893E-09 12590.2541 12590.2541 7.942651E-25 7.942651E-15 5.1
5.2 6.30957E-06 1.58489E-09 10001 10001 9.999E-25 9.999E-15 5.2
5.3 5.01187E-06 1.99526E-09 7944.28235 7944.28235 1.258767E-24 1.258767E-14 5.3
5.4 3.98107E-06 2.51189E-09 6310.57344 6310.57344 1.584642E-24 1.584642E-14 5.4
5.5 3.16228E-06 3.16228E-09 5012.87234 5012.87234 1.994864E-24 1.994864E-14 5.5
5.6 2.51189E-06 3.98107E-09 3982.07171 3982.07171 2.511256E-24 2.511256E-14 5.6
5.7 1.99526E-06 5.01187E-09 3163.27766 3163.27766 3.161278E-24 3.161278E-14 5.7
5.8 1.58489E-06 6.30957E-09 2512.88643 2512.88643 3.979487E-24 3.979487E-14 5.8
5.9 1.25893E-06 7.94328E-09 1996.26231 1996.26231 5.009362E-24 5.009362E-14 5.9
6 0.000001 0.00000001 1585.89319 1585.89319 6.305595E-24 6.305595E-14 6
6.1 7.94328E-07 1.25893E-08 1259.92541 1259.92541 7.936978E-24 7.936978E-14 6.1
6.2 6.30957E-07 1.58489E-08 1001 1001 9.99001E-24 9.99001E-14 6.2
6.3 5.01187E-07 1.99526E-08 795.328235 795.328235 1.257343E-23 1.257343E-13 6.3
6.4 3.98107E-07 2.51189E-08 631.957344 631.957344 1.582385E-23 1.582385E-13 6.4
6.5 3.16228E-07 3.16228E-08 502.187234 502.187234 1.991289E-23 1.991289E-13 6.5
6.6 2.51189E-07 3.98107E-08 399.107171 399.107171 2.505593E-23 2.505593E-13 6.6
6.7 1.99526E-07 5.01187E-08 317.227766 317.227766 3.152309E-23 3.152309E-13 6.7
6.8 1.58489E-07 6.30957E-08 252.188643 252.188643 3.965286E-23 3.965286E-13 6.8
6.9 1.25893E-07 7.94328E-08 200.526231 200.526231 4.986879E-23 4.986879E-13 6.9
7 0.0000001 0.0000001 159.489319 159.489319 6.270012E-23 6.270012E-13 7
7.1 7.94328E-08 1.25893E-07 126.892541 126.892541 7.880684E-23 7.880684E-13 7.1
7.2 6.30957E-08 1.58489E-07 101 101 9.90099E-23 9.90099E-13 7.2
7.3 5.01187E-08 1.99526E-07 80.4328235 80.4328235 1.243274E-22 1.243274E-12 7.3
7.4 3.98107E-08 2.51189E-07 64.0957344 64.0957344 1.560166E-22 1.560166E-12 7.4
7.5 3.16228E-08 3.16228E-07 51.1187234 51.1187234 1.95623E-22 1.95623E-12 7.5
7.6 2.51189E-08 3.98107E-07 40.8107171 40.8107171 2.450337E-22 2.450337E-12 7.6
7.7 1.99526E-08 5.01187E-07 32.6227766 32.6227766 3.065343E-22 3.065343E-12 7.7
7.8 1.58489E-08 6.30957E-07 26.1188643 26.1188643 3.82865E-22 3.82865E-12 7.8
7.9 1.25893E-08 7.94328E-07 20.9526231 20.9526231 4.772672E-22 4.772672E-12 7.9
8 0.00000001 0.000001 16.8489319 16.8489319 5.935094E-22 5.935094E-12 8
8.1 7.94328E-09 1.25893E-06 13.5892541 13.5892541 7.358756E-22 7.358756E-12 8.1
8.2 6.30957E-09 1.58489E-06 11 11 9.090909E-22 9.090909E-12 8.2
8.3 5.01187E-09 1.99526E-06 8.94328235 8.94328235 1.118158E-21 1.118158E-11 8.3
8.4 3.98107E-09 2.51189E-06 7.30957344 7.30957344 1.368069E-21 1.368069E-11 8.4
8.5 3.16228E-09 3.16228E-06 6.01187234 6.01187234 1.663375E-21 1.663375E-11 8.5
8.6 2.51189E-09 3.98107E-06 4.98107171 4.98107171 2.0076E-21 2.0076E-11 8.6
8.7 1.99526E-09 5.01187E-06 4.16227766 4.16227766 2.402531E-21 2.402531E-11 8.7
8.8 1.58489E-09 6.30957E-06 3.51188643 3.51188643 2.847472E-21 2.847472E-11 8.8
8.9 1.25893E-09 7.94328E-06 2.99526231 2.99526231 3.338606E-21 3.338606E-11 8.9
9 1E-09 0.00001 2.58489319 2.58489319 3.868632E-21 3.868632E-11 9
9.1 7.94328E-10 1.25893E-05 2.25892541 2.25892541 4.426884E-21 4.426884E-11 9.1
9.2 6.30957E-10 1.58489E-05 2 2 5E-21 5E-11 9.2
9.3 5.01187E-10 1.99526E-05 1.79432823 1.79432823 5.573116E-21 5.573116E-11 9.3
9.4 3.98107E-10 2.51189E-05 1.63095734 1.63095734 6.131368E-21 6.131368E-11 9.4
9.5 3.16228E-10 3.16228E-05 1.50118723 1.50118723 6.661394E-21 6.661394E-11 9.5
9.6 2.51189E-10 3.98107E-05 1.39810717 1.39810717 7.152528E-21 7.152528E-11 9.6
9.7 1.99526E-10 5.01187E-05 1.31622777 1.31622777 7.597469E-21 7.597469E-11 9.7
9.8 1.58489E-10 6.30957E-05 1.25118864 1.25118864 7.9924E-21 7.9924E-11 9.8
9.9 1.25893E-10 7.94328E-05 1.19952623 1.19952623 8.336625E-21 8.336625E-11 9.9
10 1E-10 0.0001 1.15848932 1.15848932 8.631931E-21 8.631931E-11 10
10.1 7.94328E-11 0.00012589 1.12589254 1.12589254 8.881842E-21 8.881842E-11 10.1
10.2 6.30957E-11 0.00015849 1.1 1.1 9.090909E-21 9.090909E-11 10.2
10.3 5.01187E-11 0.00019953 1.07943282 1.07943282 9.264124E-21 9.264124E-11 10.3
10.4 3.98107E-11 0.00025119 1.06309573 1.06309573 9.406491E-21 9.406491E-11 10.4
10.5 3.16228E-11 0.00031623 1.05011872 1.05011872 9.522733E-21 9.522733E-11 10.5
10.6 2.51189E-11 0.00039811 1.03981072 1.03981072 9.617135E-21 9.617135E-11 10.6
10.7 1.99526E-11 0.00050119 1.03162278 1.03162278 9.693466E-21 9.693466E-11 10.7
10.8 1.58489E-11 0.00063096 1.02511886 1.02511886 9.754966E-21 9.754966E-11 10.8
10.9 1.25893E-11 0.00079433 1.01995262 1.01995262 9.804377E-21 9.804377E-11 10.9
11 1E-11 0.001 1.01584893 1.01584893 9.843983E-21 9.843983E-11 11
11.1 7.94328E-12 0.00125893 1.01258925 1.01258925 9.875673E-21 9.875673E-11 11.1
11.2 6.30957E-12 0.00158489 1.01 1.01 9.90099E-21 9.90099E-11 11.2
11.3 5.01187E-12 0.00199526 1.00794328 1.00794328 9.921193E-21 9.921193E-11 11.3
11.4 3.98107E-12 0.00251189 1.00630957 1.00630957 9.9373E-21 9.9373E-11 11.4
11.5 3.16228E-12 0.00316228 1.00501187 1.00501187 9.950131E-21 9.950131E-11 11.5
11.6 2.51189E-12 0.00398107 1.00398107 1.00398107 9.960347E-21 9.960347E-11 11.6
11.7 1.99526E-12 0.00501187 1.00316228 1.00316228 9.968477E-21 9.968477E-11 11.7
11.8 1.58489E-12 0.00630957 1.00251189 1.00251189 9.974944E-21 9.974944E-11 11.8
11.9 1.25893E-12 0.00794328 1.00199526 1.00199526 9.980087E-21 9.980087E-11 11.9
12 1E-12 0.01 1.00158489 1.00158489 9.984176E-21 9.984176E-11 12
12.1 7.94328E-13 0.01258925 1.00125893 1.00125893 9.987427E-21 9.987427E-11 12.1
12.2 6.30957E-13 0.01584893 1.001 1.001 9.99001E-21 9.99001E-11 12.2
12.3 5.01187E-13 0.01995262 1.00079433 1.00079433 9.992063E-21 9.992063E-11 12.3
12.4 3.98107E-13 0.02511886 1.00063096 1.00063096 9.993694E-21 9.993694E-11 12.4
12.5 3.16228E-13 0.03162278 1.00050119 1.00050119 9.994991E-21 9.994991E-11 12.5
12.6 2.51189E-13 0.03981072 1.00039811 1.00039811 9.996021E-21 9.996021E-11 12.6
12.7 1.99526E-13 0.05011872 1.00031623 1.00031623 9.996839E-21 9.996839E-11 12.7
12.8 1.58489E-13 0.06309573 1.00025119 1.00025119 9.997489E-21 9.997489E-11 12.8
12.9 1.25893E-13 0.07943282 1.00019953 1.00019953 9.998005E-21 9.998005E-11 12.9
13 1E-13 0.1 1.00015849 1.00015849 9.998415E-21 9.998415E-11 13
13.1 7.94328E-14 0.12589254 1.00012589 1.00012589 9.998741E-21 9.998741E-11 13.1
13.2 6.30957E-14 0.15848932 1.0001 1.0001 9.999E-21 9.999E-11 13.2
13.3 5.01187E-14 0.19952623 1.00007943 1.00007943 9.999206E-21 9.999206E-11 13.3
13.4 3.98107E-14 0.25118864 1.0000631 1.0000631 9.999369E-21 9.999369E-11 13.4
13.5 3.16228E-14 0.31622777 1.00005012 1.00005012 9.999499E-21 9.999499E-11 13.5
13.6 2.51189E-14 0.39810717 1.00003981 1.00003981 9.999602E-21 9.999602E-11 13.6
13.7 1.99526E-14 0.50118723 1.00003162 1.00003162 9.999684E-21 9.999684E-11 13.7
13.8 1.58489E-14 0.63095734 1.00002512 1.00002512 9.999749E-21 9.999749E-11 13.8
13.9 1.25893E-14 0.79432823 1.00001995 1.00001995 9.9998E-21 9.9998E-11 13.9
14 1E-14 1 1.00001585 1.00001585 9.999842E-21 9.999842E-11 14
φHg2+ φHg(OH)+ φHg(OH)2 φHg(OH)3- φHg(CN)+ φHg(CN)2 φHg(CN)3-
0.99989991 9.999E-05 9.998999E-08 7.942487E-22 6.308942E-12 1.995063E-24 7.942487E-50
0.99987396 0.00012588 1.584693E-07 1.584693E-21 7.942281E-12 3.161879E-24 1.584693E-49
0.99984128 0.00015846 2.511488E-07 3.161776E-21 9.998413E-12 5.011077E-24 3.161776E-49
0.99980012 0.00019949 3.980276E-07 6.308312E-21 1.258674E-11 7.941695E-24 6.308312E-49
0.99974824 0.00025113 6.307985E-07 1.258608E-20 1.584494E-11 1.258608E-23 1.258608E-48
0.99968287 0.00031613 9.996829E-07 2.51109E-20 1.99463E-11 1.99463E-23 2.51109E-48
0.99960047 0.00039795 1.58426E-06 5.00987E-20 2.510883E-11 3.161014E-23 5.00987E-48
0.99949655 0.00050093 2.510622E-06 9.994966E-20 3.160686E-11 5.009349E-23 9.994965E-48
0.99936546 0.00063056 3.978546E-06 1.993996E-19 3.978546E-11 7.938242E-23 1.993996E-47
0.9992 0.00079369 6.304526E-06 3.977887E-19 5.007863E-11 1.257918E-22 3.977887E-47
0.99899102 0.00099899 9.98991E-06 7.935268E-19 6.303207E-11 1.993249E-22 7.935268E-47
0.99872685 0.00125732 1.582875E-05 1.582875E-18 7.933169E-11 3.158252E-22 1.582875E-46
0.99839258 0.00158235 2.507849E-05 3.157195E-18 9.983926E-11 5.003816E-22 3.157194E-46
0.99796906 0.00199121 3.972986E-05 6.296759E-18 1.256369E-10 7.92715E-22 6.296759E-46
0.99743163 0.00250543 6.293368E-05 1.255692E-17 1.580823E-10 1.255692E-21 1.255692E-45
0.99674833 0.00315199 9.967483E-05 2.503719E-17 1.988774E-10 1.988774E-21 2.503718E-45
0.9958775 0.00396466 0.0001578359 4.991211E-17 2.501531E-10 3.149241E-21 4.991211E-45
0.99476449 0.00498563 0.0002498735 9.947645E-17 3.145721E-10 4.985632E-21 9.947644E-45
0.99333701 0.00626753 0.0003954546 1.981968E-16 3.954546E-10 7.890356E-21 1.981968E-44
0.99149865 0.00787575 0.0006255934 3.947227E-16 4.969264E-10 1.248223E-20 3.947227E-44
0.98911968 0.0098912 0.0009891197 7.856857E-16 6.240923E-10 1.973553E-20 7.856855E-44
0.98602395 0.01241331 0.0015627426 1.562743E-15 7.832266E-10 3.118081E-20 1.562742E-43
0.98197022 0.01556318 0.0024665977 3.105262E-15 9.819701E-10 4.921508E-20 3.105262E-43
0.97662573 0.01948625 0.0038880171 6.162092E-15 1.229499E-09 7.757612E-20 6.162089E-43
0.9695292 0.02435347 0.0061173157 1.220565E-14 1.5366E-09 1.220565E-19 1.220564E-42
0.96004044 0.03035914 0.0096004044 2.411513E-14 1.915532E-09 1.915532E-19 2.411511E-42
0.94727499 0.0377117 0.0150132968 4.747621E-14 2.379447E-09 2.995545E-19 4.747618E-42
0.93002699 0.04661177 0.0233612218 9.30027E-14 2.941003E-09 4.661174E-19 9.300261E-42
0.90669519 0.0572086 0.0360961856 1.809095E-13 3.609617E-09 7.20213E-19 1.809093E-41
0.87525162 0.06952371 0.0552246436 3.484439E-13 4.386647E-09 1.101875E-18 3.484434E-41
0.8333333 0.08333333 0.0833333301 6.619402E-13 5.257974E-09 1.662716E-18 6.619389E-41
0.77858461 0.098018 0.1233973454 1.233973E-12 6.184513E-09 2.462097E-18 1.233971E-40
0.70938184 0.11242945 0.1781886621 2.243262E-12 7.093811E-09 3.555324E-18 2.243256E-40
0.62592579 0.12488861 0.2491855435 3.949325E-12 7.879929E-09 4.971893E-18 3.94931E-40
0.53130838 0.13345863 0.3352329255 6.688776E-12 8.420657E-09 6.688755E-18 6.688744E-40
0.43173644 0.13652705 0.4317364431 1.084473E-11 8.614257E-09 8.61424E-18 1.084466E-39
0.33523293 0.13345863 0.5313083815 1.680145E-11 8.420649E-09 1.060094E-17 1.680132E-39
0.24918554 0.12488861 0.6259257857 2.491855E-11 7.879914E-09 1.248878E-17 2.491832E-39
0.17818866 0.11242945 0.7093818409 3.555331E-11 7.09379E-09 1.415392E-17 3.555289E-39
0.12339735 0.098018 0.7785846138 4.912537E-11 6.184486E-09 1.553465E-17 4.912463E-39
0.08333333 0.08333333 0.8333333013 6.619402E-11 5.257944E-09 1.662698E-17 6.619276E-39
0.05522464 0.06952371 0.8752516171 8.752516E-11 4.386615E-09 1.746329E-17 8.752308E-39
0.03609619 0.0572086 0.906695189 1.141462E-10 3.609582E-09 1.809059E-17 1.141427E-38
0.02336122 0.04661177 0.9300269911 1.473993E-10 2.940967E-09 1.855601E-17 1.473938E-38
0.0150133 0.0377117 0.947274989 1.890062E-10 2.379409E-09 1.890002E-17 1.889972E-38
0.0096004 0.03035914 0.9600404371 2.411513E-10 1.915494E-09 1.915456E-17 2.411368E-38
0.00611732 0.02435347 0.9695292003 3.065921E-10 1.536562E-09 1.934368E-17 3.06569E-38
0.00388802 0.01948625 0.9766257285 3.888017E-10 1.22946E-09 1.948501E-17 3.887648E-38
0.0024666 0.01556318 0.9819702156 4.921509E-10 9.819311E-10 1.959132E-17 4.920922E-38
0.00156274 0.01241331 0.986023945 6.22139E-10 7.831874E-10 1.967179E-17 6.220455E-38
0.00098912 0.0098912 0.9891196782 7.856857E-10 6.24053E-10 1.973304E-17 7.85537E-38
0.00062559 0.00787575 0.9914986483 9.914986E-10 4.96887E-10 1.977986E-17 9.912624E-38
0.00039545 0.00626753 0.9933370085 1.250537E-09 3.95415E-10 1.981572E-17 1.250162E-37
0.00024987 0.00498563 0.99476449 1.576595E-09 3.145326E-10 1.984316E-17 1.576E-37
0.00015784 0.00396466 0.9958775005 1.987037E-09 2.501135E-10 1.986407E-17 1.986092E-37
9.96748E-05 0.00315199 0.9967483262 2.503719E-09 1.988378E-10 1.987981E-17 2.502221E-37
6.29337E-05 0.00250543 0.997431627 3.154156E-09 1.580426E-10 1.989138E-17 3.15178E-37
3.97299E-05 0.00199121 0.9979690552 3.972986E-09 1.255971E-10 1.989951E-17 3.96922E-37
2.50785E-05 0.00158235 0.9983925702 5.003816E-09 9.979953E-11 1.99047E-17 4.997845E-37
1.58288E-05 0.00125732 0.9987268418 6.30154E-09 7.929195E-11 1.990726E-17 6.292075E-37
9.98991E-06 0.00099899 0.9989910107 7.935268E-09 6.299233E-11 1.990736E-17 7.920266E-37
6.30453E-06 0.00079369 0.9991999924 9.992E-09 5.003888E-11 1.990503E-17 9.968227E-37
3.97855E-06 0.00063056 0.9993654516 1.258127E-08 3.974571E-11 1.990014E-17 1.25436E-36
2.51062E-06 0.00050093 0.9994965384 1.584095E-08 3.156712E-11 1.989246E-17 1.578128E-36
1.58426E-06 0.00039795 0.9996004475 1.994465E-08 2.50691E-11 1.988158E-17 1.985012E-36
9.99683E-07 0.00031613 0.9996828476 2.51109E-08 1.990658E-11 1.986694E-17 2.496119E-36
6.30798E-07 0.00025113 0.9997482121 3.161481E-08 1.580524E-11 1.984776E-17 3.137777E-36
3.98028E-07 0.00019949 0.9998000757 3.980276E-08 1.254706E-11 1.982306E-17 3.942753E-36
2.51149E-07 0.00015846 0.9998412345 5.011077E-08 9.958766E-12 1.979156E-17 4.951702E-36
1.58469E-07 0.00012588 0.9998739017 6.308778E-08 7.902674E-12 1.975163E-17 6.214864E-36
9.999E-08 9.999E-05 0.9998998306 7.942487E-08 6.269384E-12 1.970123E-17 7.794023E-36
6.30907E-08 7.94265E-05 0.9999204104 9.999204E-08 4.97198E-12 1.963782E-17 9.764661E-36
3.98082E-08 6.30917E-05 0.9999367425 1.258846E-07 3.941406E-12 1.955824E-17 1.221823E-35
2.51176E-08 5.01162E-05 0.9999497002 1.584813E-07 3.122805E-12 1.94586E-17 1.526435E-35
1.58483E-08 3.98091E-05 0.9999599755 1.995182E-07 2.472598E-12 1.933412E-17 1.903247E-35
9.99968E-09 3.16218E-05 0.999968117 2.511806E-07 1.956168E-12 1.917901E-17 2.367261E-35
6.30941E-09 2.51182E-05 0.9999745592 3.162197E-07 1.546019E-12 1.898631E-17 2.935393E-35
3.98099E-09 1.99522E-05 0.9999796457 3.980991E-07 1.22031E-12 1.874776E-17 3.626005E-35
2.51185E-09 1.58487E-05 0.9999836476 5.01179E-07 9.616978E-13 1.845374E-17 4.457897E-35
1.58487E-09 1.25891E-05 0.9999867784 6.30949E-07 7.564076E-13 1.809329E-17 5.448526E-35
9.99989E-10 9.99989E-06 0.9999892048 7.943197E-07 5.93503E-13 1.76543E-17 6.611168E-35
6.30952E-10 7.94321E-06 0.9999910562 9.999911E-07 4.643019E-13 1.712399E-17 7.950771E-35
3.98104E-10 6.30953E-06 0.9999924312 1.258916E-06 3.619129E-13 1.648965E-17 9.458421E-35
2.51187E-10 5.01184E-06 0.999993403 1.584883E-06 2.808667E-13 1.573995E-17 1.110469E-34
1.58488E-10 3.98105E-06 0.9999940235 1.99525E-06 2.16823E-13 1.486666E-17 1.28328E-34
9.99994E-11 3.16226E-06 0.9999943258 2.511872E-06 1.663366E-13 1.386686E-17 1.455353E-34
6.30954E-11 2.51187E-06 0.9999943258 3.16226E-06 1.266703E-13 1.274536E-17 1.614467E-34
3.98105E-11 1.99525E-06 0.9999940237 3.981048E-06 9.56459E-14 1.151689E-17 1.745839E-34
2.51187E-11 1.58488E-06 0.9999934033 5.011839E-06 7.15248E-14 1.020743E-17 1.8339E-34
1.58488E-11 1.25892E-06 0.9999924315 6.309526E-06 5.291293E-14 8.853745E-18 1.865057E-34
9.99991E-12 9.99991E-07 0.9999910568 7.943211E-06 3.868597E-14 7.500857E-18 1.830916E-34
6.30951E-12 7.9432E-07 0.9999892058 9.999892E-06 2.793145E-14 6.197143E-18 1.73097E-34
3.98102E-12 6.30949E-07 0.99998678 1.258909E-05 1.99051E-14 4.98809E-18 1.573636E-34
2.51185E-12 5.01179E-07 0.9999836501 1.584867E-05 1.399881E-14 3.910111E-18 1.374951E-34
1.58486E-12 3.98099E-07 0.9999796497 1.995222E-05 9.717366E-15 2.986111E-18 1.155216E-34
9.99975E-13 3.1622E-07 0.9999745656 2.511823E-05 6.661225E-15 2.22392E-18 9.347261E-35
6.30937E-13 2.51181E-07 0.9999681271 3.162177E-05 4.512796E-15 1.617727E-18 7.300704E-35
3.98091E-13 1.99518E-07 0.9999599914 3.980912E-05 3.024486E-15 1.15165E-18 5.520641E-35
2.51176E-13 1.58481E-07 0.9999497253 5.01162E-05 2.007499E-15 8.041417E-19 4.055177E-35
1.58479E-13 1.25885E-07 0.9999367824 6.309175E-05 1.321182E-15 5.520178E-19 2.903644E-35
9.9992E-14 9.9992E-08 0.9999204735 7.942651E-05 8.631245E-16 3.734061E-19 2.033712E-35
6.30894E-14 7.94249E-08 0.9998999306 9.998999E-05 5.603503E-16 2.49438E-19 1.397867E-35
3.98057E-14 6.30878E-08 0.9998740602 0.0001258767 3.6187E-16 1.648769E-19 9.457302E-36
2.51149E-14 5.01108E-08 0.9998414857 0.0001584642 2.326674E-16 1.080289E-19 6.314577E-36
1.58458E-14 3.98028E-08 0.9998004738 0.0001994864 1.490531E-16 7.026978E-20 4.170578E-36
9.99749E-15 3.16148E-08 0.9997488428 0.0002511256 9.520341E-17 4.543747E-20 2.730082E-36
6.30758E-15 2.51109E-08 0.9996838471 0.0003161278 6.066084E-17 2.923843E-20 1.774189E-36
3.97949E-15 1.99447E-08 0.9996020313 0.0003979487 3.857502E-17 1.874068E-20 1.14621E-36
2.51063E-15 1.5841E-08 0.999499048 0.0005009362 2.449109E-17 1.197385E-20 7.369868E-37
1.58389E-15 1.25813E-08 0.9993694279 0.0006305595 1.552909E-17 7.63073E-21 4.720479E-37
9.99206E-16 9.99206E-09 0.9992062922 0.0007936978 9.83617E-18 4.85285E-21 3.01417E-37
6.30327E-16 7.93535E-09 0.9990009911 0.000999001 6.224903E-18 3.081054E-21 1.919844E-37
3.97607E-16 6.30164E-09 0.9987426512 0.0012573425 3.936699E-18 1.953488E-21 1.220364E-37
2.50791E-16 5.00394E-09 0.9984176097 0.0015823853 2.488148E-18 1.2372E-21 7.744688E-38
1.58174E-16 3.97314E-09 0.9980087069 0.0019912892 1.57182E-18 7.828366E-22 4.908395E-38
9.97494E-17 3.15435E-09 0.9974944042 0.0025055927 9.9252E-19 4.949577E-22 3.107398E-38
6.28968E-17 2.50397E-09 0.9968476883 0.0031523092 6.264743E-19 3.127359E-22 1.965406E-38
3.96529E-17 1.98735E-09 0.9960347124 0.0039652856 3.952786E-19 1.974841E-22 1.242112E-38
2.49936E-17 1.57699E-09 0.9950131197 0.0049868787 2.493098E-19 1.246378E-22 7.844409E-39
1.57496E-17 1.25103E-09 0.9937299864 0.0062700123 1.57182E-19 7.862073E-23 4.950754E-39
9.92119E-18 9.92119E-10 0.9921193152 0.0078806838 9.905494E-20 4.956651E-23 3.122487E-39
6.2471E-18 7.86464E-10 0.9900990091 0.0099009901 6.239248E-20 3.1231E-23 1.968065E-39
3.93158E-18 6.23113E-10 0.9875672641 0.0124327352 3.927648E-20 1.966521E-23 1.239551E-39
2.4727E-18 4.93368E-10 0.9843983373 0.0156016622 2.470734E-20 1.237318E-23 7.80075E-40
1.55389E-18 3.90319E-10 0.9804376957 0.0195623039 1.552909E-20 7.778075E-24 4.904539E-40
9.75497E-19 3.08479E-10 0.9754966321 0.0245033675 9.75008E-21 4.884168E-24 3.080158E-40
6.11616E-19 2.43489E-10 0.9693465697 0.03065343 6.113729E-21 3.062904E-24 1.931793E-40
3.82865E-19 1.91887E-10 0.9617134959 0.0382865039 3.82744E-21 1.917658E-24 1.209578E-40
2.392E-19 1.50925E-10 0.9522732788 0.047726721 2.391402E-21 1.198239E-24 7.558478E-41
1.49083E-19 1.18421E-10 0.9406490568 0.0593509431 1.490531E-21 7.46886E-25 4.711592E-41
9.26412E-20 9.26412E-11 0.9264124438 0.0735875561 9.262656E-22 4.641589E-25 2.928181E-41
5.73598E-20 7.22117E-11 0.909090909 0.0909090909 5.735254E-22 2.874074E-25 1.81319E-41
3.53593E-20 5.60406E-11 0.8881842302 0.1118157698 3.535572E-22 1.771806E-25 1.117822E-41
2.16824E-20 4.32621E-11 0.8631931114 0.1368068886 2.168071E-22 1.086523E-25 6.854953E-42
1.32127E-20 3.31887E-11 0.8336624692 0.1663375308 1.321183E-22 6.621181E-26 4.177419E-42
7.9924E-21 2.52742E-11 0.7992399911 0.2007600089 7.991999E-23 4.005287E-26 2.527039E-42
4.79368E-21 1.9084E-11 0.7597469266 0.2402530733 4.793488E-23 2.402339E-26 1.515713E-42
2.84747E-21 1.42712E-11 0.715252751 0.2847472489 2.847382E-23 1.427027E-26 9.003644E-43
1.67327E-21 1.05576E-11 0.6661394246 0.3338605754 1.673225E-23 8.385777E-27 5.290935E-43
9.71756E-22 7.71894E-12 0.6131368201 0.3868631798 9.71737E-24 4.870125E-27 3.07278E-43
5.57312E-22 5.57312E-12 0.5573116338 0.4426883662 5.573028E-24 2.793086E-27 1.76229E-43
φHg(CN)4-2 φHg(NH3)2+ φHg(NH3)22+ φHg(NH3)32+ φHg(NH3)42+ ∑φ
5.011371E-76 3.980673E-11 1.2587994E-21 7.9424873E-40 3.98067E-58 1
1.258767E-75 5.011241E-11 1.9950108E-21 1.5846934E-39 9.99874E-58 1
3.161776E-75 6.308572E-11 3.1617758E-21 3.1617757E-39 2.51149E-57 1
7.941695E-75 7.941695E-11 5.0108705E-21 6.3083122E-39 6.30831E-57 1
1.99476E-74 9.997482E-11 7.9412826E-21 1.2586085E-38 1.58449E-56 1
5.010283E-74 1.258526E-10 1.2585262E-20 2.5110898E-38 3.97981E-56 1
1.258422E-73 1.58426E-10 1.9944651E-20 5.0098699E-38 9.996E-56 1
3.160686E-73 1.994258E-10 3.1606856E-20 9.9949654E-38 2.51062E-55 1
7.938242E-73 2.510293E-10 5.0086921E-20 1.9939962E-37 6.30557E-55 1
1.993666E-72 3.159748E-10 7.9369277E-20 3.9778868E-37 1.58363E-54 1
5.006815E-72 3.977055E-10 1.2576552E-19 7.9352676E-37 3.97705E-54 1
1.257323E-71 5.005491E-10 1.992722E-19 1.5828753E-36 9.98727E-54 1
3.157194E-71 6.299431E-10 3.1571945E-19 3.1571944E-36 2.50785E-53 1
7.92715E-71 7.92715E-10 5.0016934E-19 6.2967588E-36 6.29676E-53 1
1.990138E-70 9.974316E-10 7.9228808E-19 1.255692E-35 1.58082E-52 1
4.995575E-70 1.254832E-09 1.2548318E-18 2.5037185E-35 3.96813E-52 1
1.253735E-69 1.578359E-09 1.9870368E-18 4.9912105E-35 9.95877E-52 1
3.145721E-69 1.984816E-09 3.1457213E-18 9.947644E-35 2.49874E-51 1
7.890355E-69 2.49515E-09 4.9784779E-18 1.9819677E-34 6.26753E-51 1
1.978299E-68 3.135394E-09 7.8757529E-18 3.9472266E-34 1.57142E-50 1
4.95734E-68 3.937756E-09 1.2452277E-17 7.8568554E-34 3.93776E-50 1
1.24133E-67 4.941826E-09 1.9673761E-17 1.5627423E-33 9.86024E-50 1
3.105261E-67 6.195813E-09 3.1052619E-17 3.1052615E-33 2.4666E-49 1
7.75761E-67 7.757613E-09 4.8947222E-17 6.1620894E-33 6.16209E-49 1
1.934464E-66 9.69529E-09 7.7012417E-17 1.2205644E-32 1.5366E-48 1
4.811596E-66 1.208619E-08 1.2086188E-16 2.4115111E-32 3.82199E-48 1
1.192547E-65 1.501329E-08 1.8900611E-16 4.7476177E-32 9.47274E-48 1
2.941E-65 1.855647E-08 2.9410017E-16 9.3002611E-32 2.33612E-47 1
7.202124E-65 2.277514E-08 4.5442369E-16 1.8090926E-31 5.72085E-47 1
1.746353E-64 2.767787E-08 6.9523638E-16 3.4844342E-31 1.38718E-46 1
4.17655E-64 3.317558E-08 1.0491031E-15 6.6193892E-31 3.31755E-46 1
9.801768E-64 3.902164E-08 1.5534781E-15 1.2339705E-30 7.78582E-46 1
2.243253E-63 4.475892E-08 2.2432579E-15 2.2432556E-30 1.78188E-45 1
4.97188E-63 4.971899E-08 3.1370522E-15 3.9493098E-30 3.9493E-45 1
1.060093E-62 5.313075E-08 4.2203191E-15 6.6887444E-30 8.42062E-45 1
2.163791E-62 5.435229E-08 5.4352181E-15 1.0844664E-29 1.71876E-44 1
4.22029E-62 5.31307E-08 6.6887426E-15 1.680132E-29 3.3523E-44 1
7.879839E-62 4.97189E-08 7.8798889E-15 2.4918318E-29 6.25918E-44 1
1
1.41538E-61 4.475879E-08 8.9305172E-15 3.5552888E-29 1.12428E-43 1
2.462051E-61 3.902147E-08 9.8017013E-15 4.9124629E-29 1.95568E-43 1
0.9
4.176455E-61 3.317539E-08 1.0490912E-14 6.6192764E-29 3.31748E-43 1
6.95215E-61 2.767767E-08 1.101859E-14 8.7523076E-29 5.52229E-43 1
0.8
1.141416E-60 2.277493E-08 1.1414388E-14 1.1414274E-28 9.06659E-43 1
0.7

0.6
0.9

0.8

1.855554E-60 1.855624E-08 1.1708051E-14 1.4739378E-28 1.47392E-42 1 0.7


2.995357E-60 1.501306E-08 1.1925108E-14 1.8899722E-28 2.3793E-42 1
4.811216E-60 1.208595E-08 1.2085711E-14 2.4113682E-28 3.82168E-42 1 0.6
7.70047E-60 9.695048E-09 1.2205036E-14 3.0656895E-28 6.1167E-42 1
1.229343E-59 7.757369E-09 1.2294212E-14 3.8876482E-28 9.76502E-42 1 0.5

φ
1.958976E-59 6.195567E-09 1.2361288E-14 4.9209216E-28 1.55607E-41 1
3.117456E-59 4.941578E-09 1.2412062E-14 6.2204552E-28 2.47628E-41 1 0.4
4.956091E-59 3.937508E-09 1.2450708E-14 7.8553699E-28 3.93676E-41 1
7.873252E-59 3.135145E-09 1.2480246E-14 9.9126241E-28 6.25395E-41 1 0.3
1.250037E-58 2.4949E-09 1.2502871E-14 1.2501621E-27 9.9294E-41 1
1.983817E-58 1.984566E-09 1.252019E-14 1.5760002E-27 1.5758E-40 1 0.2

3.147245E-58 1.578109E-09 1.2533382E-14 1.9860924E-27 2.49995E-40 1


0.1
4.99159E-58 1.254581E-09 1.2543312E-14 2.5022205E-27 3.96496E-40 1
7.914925E-58 9.971811E-10 1.2550614E-14 3.1517801E-27 6.28705E-40 1
0
1.254781E-57 7.924644E-10 1.2555744E-14 3.9692196E-27 9.96708E-40 1 0 1
1.988886E-57 6.296924E-10 1.2559016E-14 4.9978447E-27 1.57983E-39 1
3.151928E-57 5.002984E-10 1.2560632E-14 6.2920751E-27 2.50367E-39 1
4.994199E-57 3.974547E-10 1.2560696E-14 7.9202661E-27 3.96703E-39 1
7.91176E-57 3.15724E-10 1.2559222E-14 9.9682269E-27 6.28453E-39 1
1.253107E-56 2.507785E-10 1.2556141E-14 1.2543597E-26 9.95378E-39 1
1.984247E-56 1.99175E-10 1.2551294E-14 1.5781275E-26 1.57614E-38 1
3.141054E-56 1.581753E-10 1.2544429E-14 1.985012E-26 2.49503E-38 1
4.970494E-56 1.25602E-10 1.253519E-14 2.4961187E-26 3.9482E-38 1
7.86199E-56 9.972433E-11 1.2523092E-14 3.1377768E-26 6.245E-38 1
1.242878E-55 7.91666E-11 1.2507508E-14 3.9427531E-26 9.87253E-38 1
1.963491E-55 6.283556E-11 1.2487629E-14 4.9517016E-26 1.55966E-37 1
3.099278E-55 4.98625E-11 1.2462433E-14 6.2148644E-26 2.46184E-37 1
4.886862E-55 3.955714E-11 1.2430634E-14 7.794023E-26 3.88177E-37 1
7.69522E-55 3.137107E-11 1.2390626E-14 9.7646605E-26 6.11253E-37 1
1.209726E-54 2.486859E-11 1.2340415E-14 1.2218233E-25 9.6092E-37 1
1.897776E-54 1.970357E-11 1.2277545E-14 1.5264346E-25 1.50746E-36 1
2.969382E-54 1.560104E-11 1.2199004E-14 1.9032473E-25 2.35866E-36 1
4.630908E-54 1.234259E-11 1.2101136E-14 2.3672611E-25 3.67846E-36 1
7.192702E-54 9.754718E-12 1.197955E-14 2.9353931E-25 5.71337E-36 1
1.111495E-53 7.699637E-12 1.1829035E-14 3.626005E-25 8.82892E-36 1
1.706773E-53 6.067903E-12 1.1643521E-14 4.457897E-25 1.35574E-35 1
2.600403E-53 4.772609E-12 1.1416092E-14 5.4485263E-25 2.06557E-35 1
3.92379E-53 3.744751E-12 1.1139112E-14 6.6111679E-25 3.11678E-35 1
5.850778E-53 2.929547E-12 1.0804505E-14 7.9507712E-25 4.64744E-35 1
8.598565E-53 2.283516E-12 1.0404263E-14 9.4584214E-25 6.83008E-35 1
1.241679E-52 1.772149E-12 9.9312348E-15 1.1104687E-24 9.86301E-35 1
1.755615E-52 1.368061E-12 9.3802267E-15 1.2832796E-24 1.39453E-34 1
2.420798E-52 1.049513E-12 8.7493953E-15 1.4553528E-24 1.92291E-34 1
3.241204E-52 7.992355E-13 8.0417756E-15 1.6144669E-24 2.57458E-34 1
4.194433E-52 6.034848E-13 7.2666678E-15 1.7458393E-24 3.33176E-34 1
5.221981E-52 4.51291E-13 6.4404499E-15 1.8339004E-24 4.14797E-34 1
6.22669E-52 3.33858E-13 5.5863352E-15 1.8650571E-24 4.94604E-34 1
7.083138E-52 2.44092E-13 4.7327211E-15 1.8309155E-24 5.62634E-34 1
7.662805E-52 1.762355E-13 3.910133E-15 1.7309704E-24 6.08678E-34 1
7.86818E-52 1.255927E-13 3.1472719E-15 1.573636E-24 6.24992E-34 1
7.662762E-52 8.83265E-14 2.4671134E-15 1.374951E-24 6.08675E-34 1
7.083057E-52 6.131243E-14 1.8841087E-15 1.1552164E-24 5.62627E-34 1
6.226579E-52 4.202949E-14 1.4031989E-15 9.3472609E-25 4.94595E-34 1
5.221849E-52 2.847382E-14 1.0207167E-15 7.3007045E-25 4.14786E-34 1
4.19429E-52 1.908322E-14 7.2664205E-16 5.5206407E-25 3.33164E-34 1
3.241059E-52 1.266646E-14 5.073791E-16 4.0551767E-25 2.57446E-34 1
2.420659E-52 8.336098E-15 3.4829966E-16 2.9036435E-25 1.9228E-34 1
1.755486E-52 5.445947E-15 2.3560331E-16 2.0337116E-25 1.39443E-34 1
1.241563E-52 3.535571E-15 1.5738475E-16 1.3978665E-25 9.86209E-35 1
8.597547E-53 2.283246E-15 1.0403032E-16 9.4573018E-26 6.82927E-35 1
5.849903E-53 1.468032E-15 6.8161621E-17 6.3145774E-26 4.64674E-35 1
3.92305E-53 9.404614E-16 4.4337233E-17 4.1705776E-26 3.11619E-35 1
2.599784E-53 6.006929E-16 2.8669103E-17 2.7300821E-26 2.06508E-35 1
1.706261E-53 3.82744E-16 1.8448204E-17 1.7741887E-26 1.35533E-35 1
1.111075E-53 2.433919E-16 1.1824568E-17 1.1462105E-26 8.82558E-36 1
7.189281E-54 1.545283E-16 7.5549907E-18 7.369868E-27 5.71065E-36 1
4.628135E-54 9.798195E-17 4.8146649E-18 4.7204789E-27 3.67626E-36 1
2.967144E-54 6.206204E-17 3.0619416E-18 3.0141702E-27 2.35689E-36 1
1.895975E-54 3.927648E-17 1.9440136E-18 1.9198442E-27 1.50603E-36 1
1.208281E-54 2.483889E-17 1.2325679E-18 1.2203642E-27 9.59772E-37 1
7.683655E-55 1.569915E-17 7.8062066E-19 7.7446884E-28 6.10334E-37 1
4.877619E-55 9.917512E-18 4.939365E-19 4.9083951E-28 3.87443E-37 1
3.091902E-55 6.262378E-18 3.122972E-19 3.1073981E-28 2.45598E-37 1
1.957612E-55 3.952786E-18 1.9732302E-19 1.9654058E-28 1.55499E-37 1
1.238197E-55 2.494039E-18 1.2460403E-19 1.2421124E-28 9.83535E-38 1
7.824754E-56 1.573038E-18 7.864113E-20 7.8444087E-29 6.21542E-38 1
4.940896E-56 9.917512E-19 4.9606326E-20 4.9507545E-29 3.92469E-38 1
3.117546E-56 6.249944E-19 3.1274356E-20 3.1224868E-29 2.47635E-38 1
1.96559E-56 3.936699E-19 1.9705426E-20 1.9680649E-29 1.56132E-38 1
1.238313E-56 2.478179E-19 1.2407907E-20 1.2395512E-29 9.83627E-39 1
7.794559E-57 1.558928E-19 7.8069465E-21 7.8007501E-30 6.19144E-39 1
4.901446E-57 9.798195E-20 4.9076336E-21 4.904539E-30 3.89336E-39 1
3.078615E-57 6.151884E-20 3.0817014E-21 3.0801577E-30 2.44543E-39 1
1.931024E-57 3.857503E-20 1.9325616E-21 1.9317926E-30 1.53387E-39 1
1.209195E-57 2.414951E-20 1.2099602E-21 1.2095777E-30 9.60498E-40 1
7.55658E-58 1.508872E-20 7.5603769E-22 7.5584783E-31 6.0024E-40 1
4.710652E-58 9.404614E-21 4.7125323E-22 4.7115922E-31 3.7418E-40 1
2.927717E-58 5.844341E-21 2.928645E-22 2.9281809E-31 2.32557E-40 1
1.812962E-58 3.618701E-21 1.8134182E-22 1.8131899E-31 1.44009E-40 1
1.117711E-58 2.230795E-21 1.1179341E-22 1.1178223E-31 8.87829E-41 1
6.854408E-59 1.36796E-21 6.8554975E-23 6.8549529E-32 5.44465E-41 1
4.177156E-59 8.336099E-22 4.1776827E-23 4.1774191E-32 3.31803E-41 1
2.526912E-59 5.042611E-22 2.5271654E-23 2.5270388E-32 2.0072E-41 1
1.515653E-59 3.024487E-22 1.5157737E-23 1.5157134E-32 1.20393E-41 1
9.00336E-60 1.796577E-22 9.0039292E-24 9.0036445E-33 7.15162E-42 1
5.290802E-60 1.055733E-22 5.2910677E-24 5.2909348E-33 4.20263E-42 1
3.072718E-60 6.131246E-23 3.0728408E-24 3.0727795E-33 2.44075E-42 1
1.762262E-60 3.516343E-23 1.7623183E-24 1.7622903E-33 1.39981E-42 1
Hg2++Y4-⇌HgY2- equilibrio principal
logKf kf
21.8 6.309573444802E+21

equilibrios secundarios
HgY2-+ H+⇌HgHY- HgY2-+ OH-⇌HgOHY3-
logKf kf logKf kf
3.1 1258.92541179417 4.9 79432.8234724282

Hg2++iOH-⇌Hg(OH)i2-i
i logβi βi
1 10 10000000000
2 21 1E+021
3 20.9 7.94328234724279E+020

HjYj-4⇌H++ Hj-1Yj-5
j pKa j= logβj βj
4 2 100
3 2.7 501.187233627272
2 6.2 1584893.19246111
1 10.3 19952623149.6888

NH4+⇌H++NH3 HCN⇌H++CN-
pKa pKa
9.2 9.2
Logβ1 Logβ1
9.2 9.2
β1 β1
1584893192.46112 1584893192.46112

Diagrama de abundancia relativa


1

0.9

0.8

0.7

0.6
0.9

0.8

0.7

0.6

0.5
φ

0.4

0.3

0.2

0.1

0
0 1 2 3 4 5 6 7 8 9 10 11

pH

φHg2+ φHg(OH)+ φHg(OH)2 φHg(OH)3- φHg(CN)+ φHg(CN)2


φHg(CN)3- φHg(CN)4-2 φHg(NH3)2+ φHg(NH3)22+ φHg(NH3)32+ φHg(NH3)42

Condiciones experimentales
PNH3´ PCN-´
10 20
[NH3´] [CN´]
1E-10 mol/L 1E-20 mol/L
Hg2++kNH3⇌Hg(NH3)k2+
k logβk βk
1 8.8 630957344
2 17.5 3.1623E+17
3 18.5 3.1623E+18
4 19.4 2.5119E+19
Hg2++mCN-⇌Hg(CN)m2-m
m logβm βm
1 18 1E+018
2 34.7 5.0119E+34
3 38.5 3.1623E+38
4 41.5 3.1623E+41
10 11 12 13 14

CN)+ φHg(CN)2
NH3)32+ φHg(NH3)42+

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