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6
5
4
3
2
1
0
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14
pH
Condiciones experimentales
PNH3´ PCN-´
10 20
[NH3´] [CN´]
1E-10 mol/L 1E-20 mol/L
Cantidades iniciales
[Hg2+] [EDTA]
0.01 mol/L 0.01 mol/L
Hg2++Y4-⇌equilibrio
HgY2- principal
logKf kf
21.8 6.31E+21
equilibrios secundarios
HgY2-+ H+⇌HgHY- HgY2-+ OH-⇌HgOHY3-
logKf kf
3.1 1258.9254
Hg2++iOH-⇌Hg(OH)i2-i
i logβi
1 10
2 21
3 20.9
HjYj-4⇌H++ Hj-1Yj-5
j pKa j
4 2
3 2.7
2 6.2
1 10.3
NH4+⇌H++NH3
HCN⇌H++CN-
pKa pKa
9.2 9.2
Logβ1 Logβ1
9.2 9.2
β1 β1
1.585E+09 1.585E+09
ibrio principal
logBj βj ka
21.2 1.585E+21 0.01
19.2 1.585E+19 0.0019953
16.5 3.162E+16 6.3096E-07
10.3 1.995E+10 5.0119E-11
CN⇌H++CN-
pH [H+] [OH-] αCN(H) αNH3(H) [CN] [NH3] pH
0 1 1E-14 1584893193 1584893193 6.309573E-30 6.309573E-20 0
0.1 0.79432823 1.25893E-14 1258925413 1258925413 7.943282E-30 7.943282E-20 0.1
0.2 0.63095734 1.58489E-14 1000000001 1000000001 1E-29 1E-19 0.2
0.3 0.50118723 1.99526E-14 794328236 794328236 1.258925E-29 1.258925E-19 0.3
0.4 0.39810717 2.51189E-14 630957345 630957345 1.584893E-29 1.584893E-19 0.4
0.5 0.31622777 3.16228E-14 501187235 501187235 1.995262E-29 1.995262E-19 0.5
0.6 0.25118864 3.98107E-14 398107172 398107172 2.511886E-29 2.511886E-19 0.6
0.7 0.19952623 5.01187E-14 316227767 316227767 3.162278E-29 3.162278E-19 0.7
0.8 0.15848932 6.30957E-14 251188644 251188644 3.981072E-29 3.981072E-19 0.8
0.9 0.12589254 7.94328E-14 199526232 199526232 5.011872E-29 5.011872E-19 0.9
1 0.1 1E-13 158489320 158489320 6.309573E-29 6.309573E-19 1
1.1 0.07943282 1.25893E-13 125892542 125892542 7.943282E-29 7.943282E-19 1.1
1.2 0.06309573 1.58489E-13 100000001 100000001 1E-28 1E-18 1.2
1.3 0.05011872 1.99526E-13 79432824.5 79432824.5 1.258925E-28 1.258925E-18 1.3
1.4 0.03981072 2.51189E-13 63095735.4 63095735.4 1.584893E-28 1.584893E-18 1.4
1.5 0.03162278 3.16228E-13 50118724.4 50118724.4 1.995262E-28 1.995262E-18 1.5
1.6 0.02511886 3.98107E-13 39810718.1 39810718.1 2.511886E-28 2.511886E-18 1.6
1.7 0.01995262 5.01187E-13 31622777.6 31622777.6 3.162278E-28 3.162278E-18 1.7
1.8 0.01584893 6.30957E-13 25118865.3 25118865.3 3.981072E-28 3.981072E-18 1.8
1.9 0.01258925 7.94328E-13 19952624.1 19952624.1 5.011872E-28 5.011872E-18 1.9
2 0.01 1E-12 15848932.9 15848932.9 6.309573E-28 6.309573E-18 2
2.1 0.00794328 1.25893E-12 12589255.1 12589255.1 7.943282E-28 7.943282E-18 2.1
2.2 0.00630957 1.58489E-12 10000001 10000001 1E-27 1E-17 2.2
2.3 0.00501187 1.99526E-12 7943283.35 7943283.35 1.258925E-27 1.258925E-17 2.3
2.4 0.00398107 2.51189E-12 6309574.44 6309574.44 1.584893E-27 1.584893E-17 2.4
2.5 0.00316228 3.16228E-12 5011873.34 5011873.34 1.995262E-27 1.995262E-17 2.5
2.6 0.00251189 3.98107E-12 3981072.71 3981072.71 2.511886E-27 2.511886E-17 2.6
2.7 0.00199526 5.01187E-12 3162278.66 3162278.66 3.162277E-27 3.162277E-17 2.7
2.8 0.00158489 6.30957E-12 2511887.43 2511887.43 3.98107E-27 3.98107E-17 2.8
2.9 0.00125893 7.94328E-12 1995263.31 1995263.31 5.01187E-27 5.01187E-17 2.9
3 0.001 1E-11 1584894.19 1584894.19 6.309569E-27 6.309569E-17 3
3.1 0.00079433 1.25893E-11 1258926.41 1258926.41 7.943276E-27 7.943276E-17 3.1
3.2 0.00063096 1.58489E-11 1000001 1000001 9.99999E-27 9.99999E-17 3.2
3.3 0.00050119 1.99526E-11 794329.235 794329.235 1.258924E-26 1.258924E-16 3.3
3.4 0.00039811 2.51189E-11 630958.344 630958.344 1.584891E-26 1.584891E-16 3.4
3.5 0.00031623 3.16228E-11 501188.234 501188.234 1.995258E-26 1.995258E-16 3.5
3.6 0.00025119 3.98107E-11 398108.171 398108.171 2.51188E-26 2.51188E-16 3.6
3.7 0.00019953 5.01187E-11 316228.766 316228.766 3.162268E-26 3.162268E-16 3.7
3.8 0.00015849 6.30957E-11 251189.643 251189.643 3.981056E-26 3.981056E-16 3.8
3.9 0.00012589 7.94328E-11 199527.231 199527.231 5.011847E-26 5.011847E-16 3.9
4 0.0001 1E-10 158490.319 158490.319 6.309534E-26 6.309534E-16 4
4.1 7.94328E-05 1.25893E-10 125893.541 125893.541 7.943219E-26 7.943219E-16 4.1
4.2 6.30957E-05 1.58489E-10 100001 100001 9.9999E-26 9.9999E-16 4.2
4.3 5.01187E-05 1.99526E-10 79433.8235 79433.8235 1.25891E-25 1.25891E-15 4.3
4.4 3.98107E-05 2.51189E-10 63096.7344 63096.7344 1.584868E-25 1.584868E-15 4.4
4.5 3.16228E-05 3.16228E-10 50119.7234 50119.7234 1.995223E-25 1.995223E-15 4.5
4.6 2.51189E-05 3.98107E-10 39811.7171 39811.7171 2.511823E-25 2.511823E-15 4.6
4.7 1.99526E-05 5.01187E-10 31623.7766 31623.7766 3.162178E-25 3.162178E-15 4.7
4.8 1.58489E-05 6.30957E-10 25119.8643 25119.8643 3.980913E-25 3.980913E-15 4.8
4.9 1.25893E-05 7.94328E-10 19953.6231 19953.6231 5.011621E-25 5.011621E-15 4.9
5 0.00001 1E-09 15849.9319 15849.9319 6.309175E-25 6.309175E-15 5
5.1 7.94328E-06 1.25893E-09 12590.2541 12590.2541 7.942651E-25 7.942651E-15 5.1
5.2 6.30957E-06 1.58489E-09 10001 10001 9.999E-25 9.999E-15 5.2
5.3 5.01187E-06 1.99526E-09 7944.28235 7944.28235 1.258767E-24 1.258767E-14 5.3
5.4 3.98107E-06 2.51189E-09 6310.57344 6310.57344 1.584642E-24 1.584642E-14 5.4
5.5 3.16228E-06 3.16228E-09 5012.87234 5012.87234 1.994864E-24 1.994864E-14 5.5
5.6 2.51189E-06 3.98107E-09 3982.07171 3982.07171 2.511256E-24 2.511256E-14 5.6
5.7 1.99526E-06 5.01187E-09 3163.27766 3163.27766 3.161278E-24 3.161278E-14 5.7
5.8 1.58489E-06 6.30957E-09 2512.88643 2512.88643 3.979487E-24 3.979487E-14 5.8
5.9 1.25893E-06 7.94328E-09 1996.26231 1996.26231 5.009362E-24 5.009362E-14 5.9
6 0.000001 0.00000001 1585.89319 1585.89319 6.305595E-24 6.305595E-14 6
6.1 7.94328E-07 1.25893E-08 1259.92541 1259.92541 7.936978E-24 7.936978E-14 6.1
6.2 6.30957E-07 1.58489E-08 1001 1001 9.99001E-24 9.99001E-14 6.2
6.3 5.01187E-07 1.99526E-08 795.328235 795.328235 1.257343E-23 1.257343E-13 6.3
6.4 3.98107E-07 2.51189E-08 631.957344 631.957344 1.582385E-23 1.582385E-13 6.4
6.5 3.16228E-07 3.16228E-08 502.187234 502.187234 1.991289E-23 1.991289E-13 6.5
6.6 2.51189E-07 3.98107E-08 399.107171 399.107171 2.505593E-23 2.505593E-13 6.6
6.7 1.99526E-07 5.01187E-08 317.227766 317.227766 3.152309E-23 3.152309E-13 6.7
6.8 1.58489E-07 6.30957E-08 252.188643 252.188643 3.965286E-23 3.965286E-13 6.8
6.9 1.25893E-07 7.94328E-08 200.526231 200.526231 4.986879E-23 4.986879E-13 6.9
7 0.0000001 0.0000001 159.489319 159.489319 6.270012E-23 6.270012E-13 7
7.1 7.94328E-08 1.25893E-07 126.892541 126.892541 7.880684E-23 7.880684E-13 7.1
7.2 6.30957E-08 1.58489E-07 101 101 9.90099E-23 9.90099E-13 7.2
7.3 5.01187E-08 1.99526E-07 80.4328235 80.4328235 1.243274E-22 1.243274E-12 7.3
7.4 3.98107E-08 2.51189E-07 64.0957344 64.0957344 1.560166E-22 1.560166E-12 7.4
7.5 3.16228E-08 3.16228E-07 51.1187234 51.1187234 1.95623E-22 1.95623E-12 7.5
7.6 2.51189E-08 3.98107E-07 40.8107171 40.8107171 2.450337E-22 2.450337E-12 7.6
7.7 1.99526E-08 5.01187E-07 32.6227766 32.6227766 3.065343E-22 3.065343E-12 7.7
7.8 1.58489E-08 6.30957E-07 26.1188643 26.1188643 3.82865E-22 3.82865E-12 7.8
7.9 1.25893E-08 7.94328E-07 20.9526231 20.9526231 4.772672E-22 4.772672E-12 7.9
8 0.00000001 0.000001 16.8489319 16.8489319 5.935094E-22 5.935094E-12 8
8.1 7.94328E-09 1.25893E-06 13.5892541 13.5892541 7.358756E-22 7.358756E-12 8.1
8.2 6.30957E-09 1.58489E-06 11 11 9.090909E-22 9.090909E-12 8.2
8.3 5.01187E-09 1.99526E-06 8.94328235 8.94328235 1.118158E-21 1.118158E-11 8.3
8.4 3.98107E-09 2.51189E-06 7.30957344 7.30957344 1.368069E-21 1.368069E-11 8.4
8.5 3.16228E-09 3.16228E-06 6.01187234 6.01187234 1.663375E-21 1.663375E-11 8.5
8.6 2.51189E-09 3.98107E-06 4.98107171 4.98107171 2.0076E-21 2.0076E-11 8.6
8.7 1.99526E-09 5.01187E-06 4.16227766 4.16227766 2.402531E-21 2.402531E-11 8.7
8.8 1.58489E-09 6.30957E-06 3.51188643 3.51188643 2.847472E-21 2.847472E-11 8.8
8.9 1.25893E-09 7.94328E-06 2.99526231 2.99526231 3.338606E-21 3.338606E-11 8.9
9 1E-09 0.00001 2.58489319 2.58489319 3.868632E-21 3.868632E-11 9
9.1 7.94328E-10 1.25893E-05 2.25892541 2.25892541 4.426884E-21 4.426884E-11 9.1
9.2 6.30957E-10 1.58489E-05 2 2 5E-21 5E-11 9.2
9.3 5.01187E-10 1.99526E-05 1.79432823 1.79432823 5.573116E-21 5.573116E-11 9.3
9.4 3.98107E-10 2.51189E-05 1.63095734 1.63095734 6.131368E-21 6.131368E-11 9.4
9.5 3.16228E-10 3.16228E-05 1.50118723 1.50118723 6.661394E-21 6.661394E-11 9.5
9.6 2.51189E-10 3.98107E-05 1.39810717 1.39810717 7.152528E-21 7.152528E-11 9.6
9.7 1.99526E-10 5.01187E-05 1.31622777 1.31622777 7.597469E-21 7.597469E-11 9.7
9.8 1.58489E-10 6.30957E-05 1.25118864 1.25118864 7.9924E-21 7.9924E-11 9.8
9.9 1.25893E-10 7.94328E-05 1.19952623 1.19952623 8.336625E-21 8.336625E-11 9.9
10 1E-10 0.0001 1.15848932 1.15848932 8.631931E-21 8.631931E-11 10
10.1 7.94328E-11 0.00012589 1.12589254 1.12589254 8.881842E-21 8.881842E-11 10.1
10.2 6.30957E-11 0.00015849 1.1 1.1 9.090909E-21 9.090909E-11 10.2
10.3 5.01187E-11 0.00019953 1.07943282 1.07943282 9.264124E-21 9.264124E-11 10.3
10.4 3.98107E-11 0.00025119 1.06309573 1.06309573 9.406491E-21 9.406491E-11 10.4
10.5 3.16228E-11 0.00031623 1.05011872 1.05011872 9.522733E-21 9.522733E-11 10.5
10.6 2.51189E-11 0.00039811 1.03981072 1.03981072 9.617135E-21 9.617135E-11 10.6
10.7 1.99526E-11 0.00050119 1.03162278 1.03162278 9.693466E-21 9.693466E-11 10.7
10.8 1.58489E-11 0.00063096 1.02511886 1.02511886 9.754966E-21 9.754966E-11 10.8
10.9 1.25893E-11 0.00079433 1.01995262 1.01995262 9.804377E-21 9.804377E-11 10.9
11 1E-11 0.001 1.01584893 1.01584893 9.843983E-21 9.843983E-11 11
11.1 7.94328E-12 0.00125893 1.01258925 1.01258925 9.875673E-21 9.875673E-11 11.1
11.2 6.30957E-12 0.00158489 1.01 1.01 9.90099E-21 9.90099E-11 11.2
11.3 5.01187E-12 0.00199526 1.00794328 1.00794328 9.921193E-21 9.921193E-11 11.3
11.4 3.98107E-12 0.00251189 1.00630957 1.00630957 9.9373E-21 9.9373E-11 11.4
11.5 3.16228E-12 0.00316228 1.00501187 1.00501187 9.950131E-21 9.950131E-11 11.5
11.6 2.51189E-12 0.00398107 1.00398107 1.00398107 9.960347E-21 9.960347E-11 11.6
11.7 1.99526E-12 0.00501187 1.00316228 1.00316228 9.968477E-21 9.968477E-11 11.7
11.8 1.58489E-12 0.00630957 1.00251189 1.00251189 9.974944E-21 9.974944E-11 11.8
11.9 1.25893E-12 0.00794328 1.00199526 1.00199526 9.980087E-21 9.980087E-11 11.9
12 1E-12 0.01 1.00158489 1.00158489 9.984176E-21 9.984176E-11 12
12.1 7.94328E-13 0.01258925 1.00125893 1.00125893 9.987427E-21 9.987427E-11 12.1
12.2 6.30957E-13 0.01584893 1.001 1.001 9.99001E-21 9.99001E-11 12.2
12.3 5.01187E-13 0.01995262 1.00079433 1.00079433 9.992063E-21 9.992063E-11 12.3
12.4 3.98107E-13 0.02511886 1.00063096 1.00063096 9.993694E-21 9.993694E-11 12.4
12.5 3.16228E-13 0.03162278 1.00050119 1.00050119 9.994991E-21 9.994991E-11 12.5
12.6 2.51189E-13 0.03981072 1.00039811 1.00039811 9.996021E-21 9.996021E-11 12.6
12.7 1.99526E-13 0.05011872 1.00031623 1.00031623 9.996839E-21 9.996839E-11 12.7
12.8 1.58489E-13 0.06309573 1.00025119 1.00025119 9.997489E-21 9.997489E-11 12.8
12.9 1.25893E-13 0.07943282 1.00019953 1.00019953 9.998005E-21 9.998005E-11 12.9
13 1E-13 0.1 1.00015849 1.00015849 9.998415E-21 9.998415E-11 13
13.1 7.94328E-14 0.12589254 1.00012589 1.00012589 9.998741E-21 9.998741E-11 13.1
13.2 6.30957E-14 0.15848932 1.0001 1.0001 9.999E-21 9.999E-11 13.2
13.3 5.01187E-14 0.19952623 1.00007943 1.00007943 9.999206E-21 9.999206E-11 13.3
13.4 3.98107E-14 0.25118864 1.0000631 1.0000631 9.999369E-21 9.999369E-11 13.4
13.5 3.16228E-14 0.31622777 1.00005012 1.00005012 9.999499E-21 9.999499E-11 13.5
13.6 2.51189E-14 0.39810717 1.00003981 1.00003981 9.999602E-21 9.999602E-11 13.6
13.7 1.99526E-14 0.50118723 1.00003162 1.00003162 9.999684E-21 9.999684E-11 13.7
13.8 1.58489E-14 0.63095734 1.00002512 1.00002512 9.999749E-21 9.999749E-11 13.8
13.9 1.25893E-14 0.79432823 1.00001995 1.00001995 9.9998E-21 9.9998E-11 13.9
14 1E-14 1 1.00001585 1.00001585 9.999842E-21 9.999842E-11 14
φHg2+ φHg(OH)+ φHg(OH)2 φHg(OH)3- φHg(CN)+ φHg(CN)2 φHg(CN)3-
0.99989991 9.999E-05 9.998999E-08 7.942487E-22 6.308942E-12 1.995063E-24 7.942487E-50
0.99987396 0.00012588 1.584693E-07 1.584693E-21 7.942281E-12 3.161879E-24 1.584693E-49
0.99984128 0.00015846 2.511488E-07 3.161776E-21 9.998413E-12 5.011077E-24 3.161776E-49
0.99980012 0.00019949 3.980276E-07 6.308312E-21 1.258674E-11 7.941695E-24 6.308312E-49
0.99974824 0.00025113 6.307985E-07 1.258608E-20 1.584494E-11 1.258608E-23 1.258608E-48
0.99968287 0.00031613 9.996829E-07 2.51109E-20 1.99463E-11 1.99463E-23 2.51109E-48
0.99960047 0.00039795 1.58426E-06 5.00987E-20 2.510883E-11 3.161014E-23 5.00987E-48
0.99949655 0.00050093 2.510622E-06 9.994966E-20 3.160686E-11 5.009349E-23 9.994965E-48
0.99936546 0.00063056 3.978546E-06 1.993996E-19 3.978546E-11 7.938242E-23 1.993996E-47
0.9992 0.00079369 6.304526E-06 3.977887E-19 5.007863E-11 1.257918E-22 3.977887E-47
0.99899102 0.00099899 9.98991E-06 7.935268E-19 6.303207E-11 1.993249E-22 7.935268E-47
0.99872685 0.00125732 1.582875E-05 1.582875E-18 7.933169E-11 3.158252E-22 1.582875E-46
0.99839258 0.00158235 2.507849E-05 3.157195E-18 9.983926E-11 5.003816E-22 3.157194E-46
0.99796906 0.00199121 3.972986E-05 6.296759E-18 1.256369E-10 7.92715E-22 6.296759E-46
0.99743163 0.00250543 6.293368E-05 1.255692E-17 1.580823E-10 1.255692E-21 1.255692E-45
0.99674833 0.00315199 9.967483E-05 2.503719E-17 1.988774E-10 1.988774E-21 2.503718E-45
0.9958775 0.00396466 0.0001578359 4.991211E-17 2.501531E-10 3.149241E-21 4.991211E-45
0.99476449 0.00498563 0.0002498735 9.947645E-17 3.145721E-10 4.985632E-21 9.947644E-45
0.99333701 0.00626753 0.0003954546 1.981968E-16 3.954546E-10 7.890356E-21 1.981968E-44
0.99149865 0.00787575 0.0006255934 3.947227E-16 4.969264E-10 1.248223E-20 3.947227E-44
0.98911968 0.0098912 0.0009891197 7.856857E-16 6.240923E-10 1.973553E-20 7.856855E-44
0.98602395 0.01241331 0.0015627426 1.562743E-15 7.832266E-10 3.118081E-20 1.562742E-43
0.98197022 0.01556318 0.0024665977 3.105262E-15 9.819701E-10 4.921508E-20 3.105262E-43
0.97662573 0.01948625 0.0038880171 6.162092E-15 1.229499E-09 7.757612E-20 6.162089E-43
0.9695292 0.02435347 0.0061173157 1.220565E-14 1.5366E-09 1.220565E-19 1.220564E-42
0.96004044 0.03035914 0.0096004044 2.411513E-14 1.915532E-09 1.915532E-19 2.411511E-42
0.94727499 0.0377117 0.0150132968 4.747621E-14 2.379447E-09 2.995545E-19 4.747618E-42
0.93002699 0.04661177 0.0233612218 9.30027E-14 2.941003E-09 4.661174E-19 9.300261E-42
0.90669519 0.0572086 0.0360961856 1.809095E-13 3.609617E-09 7.20213E-19 1.809093E-41
0.87525162 0.06952371 0.0552246436 3.484439E-13 4.386647E-09 1.101875E-18 3.484434E-41
0.8333333 0.08333333 0.0833333301 6.619402E-13 5.257974E-09 1.662716E-18 6.619389E-41
0.77858461 0.098018 0.1233973454 1.233973E-12 6.184513E-09 2.462097E-18 1.233971E-40
0.70938184 0.11242945 0.1781886621 2.243262E-12 7.093811E-09 3.555324E-18 2.243256E-40
0.62592579 0.12488861 0.2491855435 3.949325E-12 7.879929E-09 4.971893E-18 3.94931E-40
0.53130838 0.13345863 0.3352329255 6.688776E-12 8.420657E-09 6.688755E-18 6.688744E-40
0.43173644 0.13652705 0.4317364431 1.084473E-11 8.614257E-09 8.61424E-18 1.084466E-39
0.33523293 0.13345863 0.5313083815 1.680145E-11 8.420649E-09 1.060094E-17 1.680132E-39
0.24918554 0.12488861 0.6259257857 2.491855E-11 7.879914E-09 1.248878E-17 2.491832E-39
0.17818866 0.11242945 0.7093818409 3.555331E-11 7.09379E-09 1.415392E-17 3.555289E-39
0.12339735 0.098018 0.7785846138 4.912537E-11 6.184486E-09 1.553465E-17 4.912463E-39
0.08333333 0.08333333 0.8333333013 6.619402E-11 5.257944E-09 1.662698E-17 6.619276E-39
0.05522464 0.06952371 0.8752516171 8.752516E-11 4.386615E-09 1.746329E-17 8.752308E-39
0.03609619 0.0572086 0.906695189 1.141462E-10 3.609582E-09 1.809059E-17 1.141427E-38
0.02336122 0.04661177 0.9300269911 1.473993E-10 2.940967E-09 1.855601E-17 1.473938E-38
0.0150133 0.0377117 0.947274989 1.890062E-10 2.379409E-09 1.890002E-17 1.889972E-38
0.0096004 0.03035914 0.9600404371 2.411513E-10 1.915494E-09 1.915456E-17 2.411368E-38
0.00611732 0.02435347 0.9695292003 3.065921E-10 1.536562E-09 1.934368E-17 3.06569E-38
0.00388802 0.01948625 0.9766257285 3.888017E-10 1.22946E-09 1.948501E-17 3.887648E-38
0.0024666 0.01556318 0.9819702156 4.921509E-10 9.819311E-10 1.959132E-17 4.920922E-38
0.00156274 0.01241331 0.986023945 6.22139E-10 7.831874E-10 1.967179E-17 6.220455E-38
0.00098912 0.0098912 0.9891196782 7.856857E-10 6.24053E-10 1.973304E-17 7.85537E-38
0.00062559 0.00787575 0.9914986483 9.914986E-10 4.96887E-10 1.977986E-17 9.912624E-38
0.00039545 0.00626753 0.9933370085 1.250537E-09 3.95415E-10 1.981572E-17 1.250162E-37
0.00024987 0.00498563 0.99476449 1.576595E-09 3.145326E-10 1.984316E-17 1.576E-37
0.00015784 0.00396466 0.9958775005 1.987037E-09 2.501135E-10 1.986407E-17 1.986092E-37
9.96748E-05 0.00315199 0.9967483262 2.503719E-09 1.988378E-10 1.987981E-17 2.502221E-37
6.29337E-05 0.00250543 0.997431627 3.154156E-09 1.580426E-10 1.989138E-17 3.15178E-37
3.97299E-05 0.00199121 0.9979690552 3.972986E-09 1.255971E-10 1.989951E-17 3.96922E-37
2.50785E-05 0.00158235 0.9983925702 5.003816E-09 9.979953E-11 1.99047E-17 4.997845E-37
1.58288E-05 0.00125732 0.9987268418 6.30154E-09 7.929195E-11 1.990726E-17 6.292075E-37
9.98991E-06 0.00099899 0.9989910107 7.935268E-09 6.299233E-11 1.990736E-17 7.920266E-37
6.30453E-06 0.00079369 0.9991999924 9.992E-09 5.003888E-11 1.990503E-17 9.968227E-37
3.97855E-06 0.00063056 0.9993654516 1.258127E-08 3.974571E-11 1.990014E-17 1.25436E-36
2.51062E-06 0.00050093 0.9994965384 1.584095E-08 3.156712E-11 1.989246E-17 1.578128E-36
1.58426E-06 0.00039795 0.9996004475 1.994465E-08 2.50691E-11 1.988158E-17 1.985012E-36
9.99683E-07 0.00031613 0.9996828476 2.51109E-08 1.990658E-11 1.986694E-17 2.496119E-36
6.30798E-07 0.00025113 0.9997482121 3.161481E-08 1.580524E-11 1.984776E-17 3.137777E-36
3.98028E-07 0.00019949 0.9998000757 3.980276E-08 1.254706E-11 1.982306E-17 3.942753E-36
2.51149E-07 0.00015846 0.9998412345 5.011077E-08 9.958766E-12 1.979156E-17 4.951702E-36
1.58469E-07 0.00012588 0.9998739017 6.308778E-08 7.902674E-12 1.975163E-17 6.214864E-36
9.999E-08 9.999E-05 0.9998998306 7.942487E-08 6.269384E-12 1.970123E-17 7.794023E-36
6.30907E-08 7.94265E-05 0.9999204104 9.999204E-08 4.97198E-12 1.963782E-17 9.764661E-36
3.98082E-08 6.30917E-05 0.9999367425 1.258846E-07 3.941406E-12 1.955824E-17 1.221823E-35
2.51176E-08 5.01162E-05 0.9999497002 1.584813E-07 3.122805E-12 1.94586E-17 1.526435E-35
1.58483E-08 3.98091E-05 0.9999599755 1.995182E-07 2.472598E-12 1.933412E-17 1.903247E-35
9.99968E-09 3.16218E-05 0.999968117 2.511806E-07 1.956168E-12 1.917901E-17 2.367261E-35
6.30941E-09 2.51182E-05 0.9999745592 3.162197E-07 1.546019E-12 1.898631E-17 2.935393E-35
3.98099E-09 1.99522E-05 0.9999796457 3.980991E-07 1.22031E-12 1.874776E-17 3.626005E-35
2.51185E-09 1.58487E-05 0.9999836476 5.01179E-07 9.616978E-13 1.845374E-17 4.457897E-35
1.58487E-09 1.25891E-05 0.9999867784 6.30949E-07 7.564076E-13 1.809329E-17 5.448526E-35
9.99989E-10 9.99989E-06 0.9999892048 7.943197E-07 5.93503E-13 1.76543E-17 6.611168E-35
6.30952E-10 7.94321E-06 0.9999910562 9.999911E-07 4.643019E-13 1.712399E-17 7.950771E-35
3.98104E-10 6.30953E-06 0.9999924312 1.258916E-06 3.619129E-13 1.648965E-17 9.458421E-35
2.51187E-10 5.01184E-06 0.999993403 1.584883E-06 2.808667E-13 1.573995E-17 1.110469E-34
1.58488E-10 3.98105E-06 0.9999940235 1.99525E-06 2.16823E-13 1.486666E-17 1.28328E-34
9.99994E-11 3.16226E-06 0.9999943258 2.511872E-06 1.663366E-13 1.386686E-17 1.455353E-34
6.30954E-11 2.51187E-06 0.9999943258 3.16226E-06 1.266703E-13 1.274536E-17 1.614467E-34
3.98105E-11 1.99525E-06 0.9999940237 3.981048E-06 9.56459E-14 1.151689E-17 1.745839E-34
2.51187E-11 1.58488E-06 0.9999934033 5.011839E-06 7.15248E-14 1.020743E-17 1.8339E-34
1.58488E-11 1.25892E-06 0.9999924315 6.309526E-06 5.291293E-14 8.853745E-18 1.865057E-34
9.99991E-12 9.99991E-07 0.9999910568 7.943211E-06 3.868597E-14 7.500857E-18 1.830916E-34
6.30951E-12 7.9432E-07 0.9999892058 9.999892E-06 2.793145E-14 6.197143E-18 1.73097E-34
3.98102E-12 6.30949E-07 0.99998678 1.258909E-05 1.99051E-14 4.98809E-18 1.573636E-34
2.51185E-12 5.01179E-07 0.9999836501 1.584867E-05 1.399881E-14 3.910111E-18 1.374951E-34
1.58486E-12 3.98099E-07 0.9999796497 1.995222E-05 9.717366E-15 2.986111E-18 1.155216E-34
9.99975E-13 3.1622E-07 0.9999745656 2.511823E-05 6.661225E-15 2.22392E-18 9.347261E-35
6.30937E-13 2.51181E-07 0.9999681271 3.162177E-05 4.512796E-15 1.617727E-18 7.300704E-35
3.98091E-13 1.99518E-07 0.9999599914 3.980912E-05 3.024486E-15 1.15165E-18 5.520641E-35
2.51176E-13 1.58481E-07 0.9999497253 5.01162E-05 2.007499E-15 8.041417E-19 4.055177E-35
1.58479E-13 1.25885E-07 0.9999367824 6.309175E-05 1.321182E-15 5.520178E-19 2.903644E-35
9.9992E-14 9.9992E-08 0.9999204735 7.942651E-05 8.631245E-16 3.734061E-19 2.033712E-35
6.30894E-14 7.94249E-08 0.9998999306 9.998999E-05 5.603503E-16 2.49438E-19 1.397867E-35
3.98057E-14 6.30878E-08 0.9998740602 0.0001258767 3.6187E-16 1.648769E-19 9.457302E-36
2.51149E-14 5.01108E-08 0.9998414857 0.0001584642 2.326674E-16 1.080289E-19 6.314577E-36
1.58458E-14 3.98028E-08 0.9998004738 0.0001994864 1.490531E-16 7.026978E-20 4.170578E-36
9.99749E-15 3.16148E-08 0.9997488428 0.0002511256 9.520341E-17 4.543747E-20 2.730082E-36
6.30758E-15 2.51109E-08 0.9996838471 0.0003161278 6.066084E-17 2.923843E-20 1.774189E-36
3.97949E-15 1.99447E-08 0.9996020313 0.0003979487 3.857502E-17 1.874068E-20 1.14621E-36
2.51063E-15 1.5841E-08 0.999499048 0.0005009362 2.449109E-17 1.197385E-20 7.369868E-37
1.58389E-15 1.25813E-08 0.9993694279 0.0006305595 1.552909E-17 7.63073E-21 4.720479E-37
9.99206E-16 9.99206E-09 0.9992062922 0.0007936978 9.83617E-18 4.85285E-21 3.01417E-37
6.30327E-16 7.93535E-09 0.9990009911 0.000999001 6.224903E-18 3.081054E-21 1.919844E-37
3.97607E-16 6.30164E-09 0.9987426512 0.0012573425 3.936699E-18 1.953488E-21 1.220364E-37
2.50791E-16 5.00394E-09 0.9984176097 0.0015823853 2.488148E-18 1.2372E-21 7.744688E-38
1.58174E-16 3.97314E-09 0.9980087069 0.0019912892 1.57182E-18 7.828366E-22 4.908395E-38
9.97494E-17 3.15435E-09 0.9974944042 0.0025055927 9.9252E-19 4.949577E-22 3.107398E-38
6.28968E-17 2.50397E-09 0.9968476883 0.0031523092 6.264743E-19 3.127359E-22 1.965406E-38
3.96529E-17 1.98735E-09 0.9960347124 0.0039652856 3.952786E-19 1.974841E-22 1.242112E-38
2.49936E-17 1.57699E-09 0.9950131197 0.0049868787 2.493098E-19 1.246378E-22 7.844409E-39
1.57496E-17 1.25103E-09 0.9937299864 0.0062700123 1.57182E-19 7.862073E-23 4.950754E-39
9.92119E-18 9.92119E-10 0.9921193152 0.0078806838 9.905494E-20 4.956651E-23 3.122487E-39
6.2471E-18 7.86464E-10 0.9900990091 0.0099009901 6.239248E-20 3.1231E-23 1.968065E-39
3.93158E-18 6.23113E-10 0.9875672641 0.0124327352 3.927648E-20 1.966521E-23 1.239551E-39
2.4727E-18 4.93368E-10 0.9843983373 0.0156016622 2.470734E-20 1.237318E-23 7.80075E-40
1.55389E-18 3.90319E-10 0.9804376957 0.0195623039 1.552909E-20 7.778075E-24 4.904539E-40
9.75497E-19 3.08479E-10 0.9754966321 0.0245033675 9.75008E-21 4.884168E-24 3.080158E-40
6.11616E-19 2.43489E-10 0.9693465697 0.03065343 6.113729E-21 3.062904E-24 1.931793E-40
3.82865E-19 1.91887E-10 0.9617134959 0.0382865039 3.82744E-21 1.917658E-24 1.209578E-40
2.392E-19 1.50925E-10 0.9522732788 0.047726721 2.391402E-21 1.198239E-24 7.558478E-41
1.49083E-19 1.18421E-10 0.9406490568 0.0593509431 1.490531E-21 7.46886E-25 4.711592E-41
9.26412E-20 9.26412E-11 0.9264124438 0.0735875561 9.262656E-22 4.641589E-25 2.928181E-41
5.73598E-20 7.22117E-11 0.909090909 0.0909090909 5.735254E-22 2.874074E-25 1.81319E-41
3.53593E-20 5.60406E-11 0.8881842302 0.1118157698 3.535572E-22 1.771806E-25 1.117822E-41
2.16824E-20 4.32621E-11 0.8631931114 0.1368068886 2.168071E-22 1.086523E-25 6.854953E-42
1.32127E-20 3.31887E-11 0.8336624692 0.1663375308 1.321183E-22 6.621181E-26 4.177419E-42
7.9924E-21 2.52742E-11 0.7992399911 0.2007600089 7.991999E-23 4.005287E-26 2.527039E-42
4.79368E-21 1.9084E-11 0.7597469266 0.2402530733 4.793488E-23 2.402339E-26 1.515713E-42
2.84747E-21 1.42712E-11 0.715252751 0.2847472489 2.847382E-23 1.427027E-26 9.003644E-43
1.67327E-21 1.05576E-11 0.6661394246 0.3338605754 1.673225E-23 8.385777E-27 5.290935E-43
9.71756E-22 7.71894E-12 0.6131368201 0.3868631798 9.71737E-24 4.870125E-27 3.07278E-43
5.57312E-22 5.57312E-12 0.5573116338 0.4426883662 5.573028E-24 2.793086E-27 1.76229E-43
φHg(CN)4-2 φHg(NH3)2+ φHg(NH3)22+ φHg(NH3)32+ φHg(NH3)42+ ∑φ
5.011371E-76 3.980673E-11 1.2587994E-21 7.9424873E-40 3.98067E-58 1
1.258767E-75 5.011241E-11 1.9950108E-21 1.5846934E-39 9.99874E-58 1
3.161776E-75 6.308572E-11 3.1617758E-21 3.1617757E-39 2.51149E-57 1
7.941695E-75 7.941695E-11 5.0108705E-21 6.3083122E-39 6.30831E-57 1
1.99476E-74 9.997482E-11 7.9412826E-21 1.2586085E-38 1.58449E-56 1
5.010283E-74 1.258526E-10 1.2585262E-20 2.5110898E-38 3.97981E-56 1
1.258422E-73 1.58426E-10 1.9944651E-20 5.0098699E-38 9.996E-56 1
3.160686E-73 1.994258E-10 3.1606856E-20 9.9949654E-38 2.51062E-55 1
7.938242E-73 2.510293E-10 5.0086921E-20 1.9939962E-37 6.30557E-55 1
1.993666E-72 3.159748E-10 7.9369277E-20 3.9778868E-37 1.58363E-54 1
5.006815E-72 3.977055E-10 1.2576552E-19 7.9352676E-37 3.97705E-54 1
1.257323E-71 5.005491E-10 1.992722E-19 1.5828753E-36 9.98727E-54 1
3.157194E-71 6.299431E-10 3.1571945E-19 3.1571944E-36 2.50785E-53 1
7.92715E-71 7.92715E-10 5.0016934E-19 6.2967588E-36 6.29676E-53 1
1.990138E-70 9.974316E-10 7.9228808E-19 1.255692E-35 1.58082E-52 1
4.995575E-70 1.254832E-09 1.2548318E-18 2.5037185E-35 3.96813E-52 1
1.253735E-69 1.578359E-09 1.9870368E-18 4.9912105E-35 9.95877E-52 1
3.145721E-69 1.984816E-09 3.1457213E-18 9.947644E-35 2.49874E-51 1
7.890355E-69 2.49515E-09 4.9784779E-18 1.9819677E-34 6.26753E-51 1
1.978299E-68 3.135394E-09 7.8757529E-18 3.9472266E-34 1.57142E-50 1
4.95734E-68 3.937756E-09 1.2452277E-17 7.8568554E-34 3.93776E-50 1
1.24133E-67 4.941826E-09 1.9673761E-17 1.5627423E-33 9.86024E-50 1
3.105261E-67 6.195813E-09 3.1052619E-17 3.1052615E-33 2.4666E-49 1
7.75761E-67 7.757613E-09 4.8947222E-17 6.1620894E-33 6.16209E-49 1
1.934464E-66 9.69529E-09 7.7012417E-17 1.2205644E-32 1.5366E-48 1
4.811596E-66 1.208619E-08 1.2086188E-16 2.4115111E-32 3.82199E-48 1
1.192547E-65 1.501329E-08 1.8900611E-16 4.7476177E-32 9.47274E-48 1
2.941E-65 1.855647E-08 2.9410017E-16 9.3002611E-32 2.33612E-47 1
7.202124E-65 2.277514E-08 4.5442369E-16 1.8090926E-31 5.72085E-47 1
1.746353E-64 2.767787E-08 6.9523638E-16 3.4844342E-31 1.38718E-46 1
4.17655E-64 3.317558E-08 1.0491031E-15 6.6193892E-31 3.31755E-46 1
9.801768E-64 3.902164E-08 1.5534781E-15 1.2339705E-30 7.78582E-46 1
2.243253E-63 4.475892E-08 2.2432579E-15 2.2432556E-30 1.78188E-45 1
4.97188E-63 4.971899E-08 3.1370522E-15 3.9493098E-30 3.9493E-45 1
1.060093E-62 5.313075E-08 4.2203191E-15 6.6887444E-30 8.42062E-45 1
2.163791E-62 5.435229E-08 5.4352181E-15 1.0844664E-29 1.71876E-44 1
4.22029E-62 5.31307E-08 6.6887426E-15 1.680132E-29 3.3523E-44 1
7.879839E-62 4.97189E-08 7.8798889E-15 2.4918318E-29 6.25918E-44 1
1
1.41538E-61 4.475879E-08 8.9305172E-15 3.5552888E-29 1.12428E-43 1
2.462051E-61 3.902147E-08 9.8017013E-15 4.9124629E-29 1.95568E-43 1
0.9
4.176455E-61 3.317539E-08 1.0490912E-14 6.6192764E-29 3.31748E-43 1
6.95215E-61 2.767767E-08 1.101859E-14 8.7523076E-29 5.52229E-43 1
0.8
1.141416E-60 2.277493E-08 1.1414388E-14 1.1414274E-28 9.06659E-43 1
0.7
0.6
0.9
0.8
φ
1.958976E-59 6.195567E-09 1.2361288E-14 4.9209216E-28 1.55607E-41 1
3.117456E-59 4.941578E-09 1.2412062E-14 6.2204552E-28 2.47628E-41 1 0.4
4.956091E-59 3.937508E-09 1.2450708E-14 7.8553699E-28 3.93676E-41 1
7.873252E-59 3.135145E-09 1.2480246E-14 9.9126241E-28 6.25395E-41 1 0.3
1.250037E-58 2.4949E-09 1.2502871E-14 1.2501621E-27 9.9294E-41 1
1.983817E-58 1.984566E-09 1.252019E-14 1.5760002E-27 1.5758E-40 1 0.2
equilibrios secundarios
HgY2-+ H+⇌HgHY- HgY2-+ OH-⇌HgOHY3-
logKf kf logKf kf
3.1 1258.92541179417 4.9 79432.8234724282
Hg2++iOH-⇌Hg(OH)i2-i
i logβi βi
1 10 10000000000
2 21 1E+021
3 20.9 7.94328234724279E+020
HjYj-4⇌H++ Hj-1Yj-5
j pKa j= logβj βj
4 2 100
3 2.7 501.187233627272
2 6.2 1584893.19246111
1 10.3 19952623149.6888
NH4+⇌H++NH3 HCN⇌H++CN-
pKa pKa
9.2 9.2
Logβ1 Logβ1
9.2 9.2
β1 β1
1584893192.46112 1584893192.46112
0.9
0.8
0.7
0.6
0.9
0.8
0.7
0.6
0.5
φ
0.4
0.3
0.2
0.1
0
0 1 2 3 4 5 6 7 8 9 10 11
pH
Condiciones experimentales
PNH3´ PCN-´
10 20
[NH3´] [CN´]
1E-10 mol/L 1E-20 mol/L
Hg2++kNH3⇌Hg(NH3)k2+
k logβk βk
1 8.8 630957344
2 17.5 3.1623E+17
3 18.5 3.1623E+18
4 19.4 2.5119E+19
Hg2++mCN-⇌Hg(CN)m2-m
m logβm βm
1 18 1E+018
2 34.7 5.0119E+34
3 38.5 3.1623E+38
4 41.5 3.1623E+41
10 11 12 13 14
CN)+ φHg(CN)2
NH3)32+ φHg(NH3)42+