Tiempo, (h.

) [A],(M) Ln [A] 1/[A]

0 1.240 0.21511138 0.806451613
1 0.960 -0.04082199 1.041666667
2 0.775 -0.25489225 1.290322581
3 0.655 -0.42312004 1.526717557
4 0.560 -0.5798185 1.785714286
5 0.502 -0.68915516 1.992031873
6 0.442 -0.8164454 2.262443439
7 0.402 -0.91130319 2.487562189
8 0.365 -1.00785793 2.739726027
9 0.335 -1.09362475 2.985074627
10 0.310 -1.17118298 3.225806452

Respuestas
(A) Segundo Orden
(B) 0.242𝑀^(−1) ℎ^(−1)
(C) 3.3324 h.
(D) 7.5417 h.
 1.400
1.240
1.200
0.960
1.000
f(x) = − 0.0818545454545454 x + 1.00436363636364
0.775
R² = 0.859489666449547
0.800
[A], (M).

0.655
0.560
0.600 0.502
0.442 0.402
0.365 0.335
0.400 0.310

0.200

0.000
0 2 4 6 8 10 12
Tiempo, (h).

0.2151113796169
0.4
45
-
0.2 0.0408219945202
552 -
0 f(x)0.2548922496287
= − 0.132859754901302 x + 0.0485614287110971
2
9 -
0 R² = 0.964514249126117 4 6 8 10 12
-0.2 0.4231200433468
85 -
-0.4 0.5798184952529
-
Ln[A].

42
0.6891551592904
-
-0.6 08
0.8164453969044-
-
0.9113031903631
39
-0.8 16 -
1.0078579253996
-
1.0936247471570
5
-1 1.1711829815029
7
5
-1.2

-1.4
Tiempo, (h).

3.5 3.2258064516129
2.9850746268656
2.73972602739727
3 f(x) = 0.241973043558237 x + 0.803181810348432 6
2.4875621890547
R² = 0.999865741033036
3
2.2624434389140
2.5 1.99203187250993
1.78571428571426
2 9
1.5267175572519
1/[A]

1
1.2903225806451
1.51.04166666666666
0.8064516129032 7
126

0.5

0
0 2 4 6 8 10 12
Tiempo, (h).
0
0 2 4 6 8 10 12
Tiempo, (h).
 k
0.0141
0.0180
Respuestas
0.0238
(A) Segundo Orden
0.0308
(B)
0.0393
k=0.0141, a 298.15K
k=0.0180, a 303.15K
k=0.0238, a 308.15K
k=0.0308, a 313.15K Ecuación de Arrhe
0.0033540164346
k=0.0393, a 318.15K 8053
(C) 0.0016628J/mol 0.0032986970146
792
f(x) = − 0.000203628024550978
0.003245172805x
R² = 0.999397840744405 5189
0.0
Ln [k]

-4.4 -4.2 -4 -3.8 -3

1/T
 5189
0.0

Ln [k]
-4.4 -4.2 -4 -3.8 -3
1/T
 A 298.15K (25°C)
Tiempo,(min.) [A], (M) Ln [A]
0 0.750 -0.28768207245
15 0.648 -0.43386458263
30 0.562 -0.57625342909
45 0.514 -0.66553201353
60 0.460 -0.7765287895
75 0.414 -0.88188930516
90 0.385 -0.95451194469

A 303.15K (30°C)
Tiempo,(min.) [A], (M) Ln [A]
0 0.750 -0.28768207245
15 0.622 -0.47481518624
30 0.530 -0.63487827244
45 0.467 -0.76142602131
60 0.410 -0.89159811928
75 0.378 -0.97286108336
90 0.336 -1.09064411902

A 308.15K (35°C)
Tiempo,(min.) [A], (M) Ln [A]
0 0.750 -0.28768207245
15 0.590 -0.52763274208
30 0.490 -0.71334988788
45 0.410 -0.89159811928
60 0.365 -1.0078579254
75 0.315 -1.15518264016
Temperatura (K) Ln (k) 1/T 90 0.290 -1.237874356
298.15 -4.26158048 0.003354016
303.15 -4.01738352 0.003298697
308.15 -3.7380697 0.003245173 A 313.15K (40°C)
313.15 -3.48024059 0.003193358 Tiempo,(min.) [A], (M) Ln [A]
318.15 -3.23653076 0.003143171 0 0.750 -0.28768207245
15 0.556 -0.58698698473
30 0.440 -0.82098055207
Ecuación de Arrhenius 45 0.365 -1.0078579254
0.0033540164346 60 0.315 -1.15518264016
8053 0.0034
0.0032986970146 0.00335 75 0.275 -1.29098418132
792
f(x) = − 0.000203628024550978 x + 0.00248393756317667
0.0032451728054 0.0033 90 0.243 -1.41469383564
R² = 0.999397840744405 5189
0.0031933578157 0.00325
4325
0.0031431714600
0.0032
0314 A 318.15K (45°C)
0.00315
0.0031
Tiempo,(min.) [A], (M) Ln [A]
0.00305
0.003
-4.4 -4.2 -4 -3.8 -3.6 -3.4 -3.2 -3
1/T
 5189
0.0031933578157 0.00325
4325
0.0031431714600
0.0032
0314
0.00315
0.0031
0.00305
0 0.750 -0.28768207245
0.003
15 0.520 -0.65392646741
-4.4 -4.2 -4 -3.8 -3.6 -3.4 -3.2 -3 30 0.400 -0.91629073187
1/T 45 0.324 -1.12701176319
60 0.270 -1.30933331998
75 0.235 -1.44816976484
90 0.205 -1.58474529984
C)
1/[A] A 298.15K
1.333333333 0.750
0.800
1.543209877 0.700 0.648
f(x) = − 0.00396428571428572 x + 0.711678571428572
1.779359431 0.600 0.562
R² = 0.962089063059612 0.514
1.945525292 0.500 0.460
0.414 0.385
2.173913043

[A], (M)
0.400
2.415458937 0.300
2.597402597 0.200
0.100
0.000
C) 0 10 20 30 40 50 60 70 80 90 100
1/[A] Tiempo, (min.)
1.333333333
1.607717042
1.886792453
2.141327623 A 303.15K
2.43902439 0.750
0.800
2.645502646 0.700 0.622
2.976190476 f(x) = − 0.0044047619047619 x + 0.697214285714286
0.600 0.530
R² = 0.945732501254529
0.467
0.500 0.410
0.378
[A], (M)

0.400 0.336
C) 0.300
1/[A] 0.200
1.333333333
0.100
1.694915254
0.000
2.040816327 0 10 20 30 40 50 60 70 80 90 100
2.43902439 Tiempo, (min.)
2.739726027
3.174603175
3.448275862
A 308.15K
0.750
0.800
C) 0.700
0.590
1/[A] 0.600 f(x) = − 0.00489285714285714 x + 0.67875
R² = 0.92338850745616
0.490
1.333333333 0.500 0.410
1.798561151
[A], (M)

0.365
0.400 0.315
2.272727273 0.290
0.300
2.739726027 0.200
3.174603175 0.100
3.636363636 0.000
4.115226337 0 10 20 30 40 50 60 70 80 90 100
Tiempo, (min.)

C)
1/[A]
A 313.15K
0.750
0.800
0.700
0.600 0.556
f(x) = − 0.00525714285714286 x + 0.657142857142857
1.333333333 A 313.15K
1.923076923 0.750
0.800
2.5 0.700
3.086419753 0.600 0.556
f(x) = − 0.00525714285714286 x + 0.657142857142857
3.703703704 R² = 0.896594339789199
0.500 0.440
4.255319149

[A], (M)
0.365
0.400 0.315
4.87804878 0.300
0.275
0.243
0.200
0.100
0.000
0 10 20 30 40 50 60 70 80 90 100
Tiempo, (min.)

A 318.15K
0.750
0.800
0.700
0.600 0.520
f(x) = − 0.00555952380952381 x + 0.636464285714286
0.500 R² = 0.871204059144836
0.400
[A], (M)

0.400 0.324
0.270
0.300 0.235 0.205
0.200
0.100
0.000
0 10 20 30 40 50 60 70 80 90 100
Tiempo, (min.)
 A 298.15K
0- 3
0
0.2876820724517 10 20 30 40 50 60 70 80 90 100
-0.281 - 2.5
0.4338645826298
62 -
-0.4 f(x) = − 0.00737336767188616
0.5762534290884
x − 0.321950188629013
- 2
R² = 0.989682987064498 46 0.6655320135269 - 1.3333333
0.385
1.5 3
Ln [A]

1/[A]
-0.6 72 0.7765287894989
-
96 0.8818893051568 -
23 0.9545119446943 1
-0.8
53
0.5
-1
0
90 100 -1.2 0
Tiempo, (min.)

A 303.15K
0- 3.5
0
0.2876820724517 10 20 30 40 50 60 70 80 90 100
-0.281 3
-
0.4748151862429 2.5
58 -
-0.4 f(x) = − 0.00871832804949632 x − 0.338233076931125
0.6348782724359
R² = 0.985390909132245 - 2
1.3333333
7 0.7614260213132
Ln [A]

1/[A]
0.336 -0.6
4 - 1.5 3
0.8915981192837 -
-0.8 84 0.9728610833625 - 1
49 1.0906441190189
-1 3 0.5
0
90 100 -1.2 0
Tiempo, (min.)

A 308.15K
0- 4
0.2876820724517
0 10 20 30 40 50 60 70 80 90 100
-0.281 3.5
-
0.5276327420823 3
-0.4 f(x) = − 0.0104766302007618
72 - x − 0.360148461430457
0.7133498878774 2.5
R² = 0.978532040034925 -
-0.6 65
Ln [A]

1/[A]

0.8915981192837 - 2
1.3333333
0.290 3
-0.8 84 1.0078579253996 1.5
5 - -
-1 1.2378743560016 1
1.1551826401565
2 0.5
-1.2
0
90 100 -1.4 0
Tiempo, (min.)

A 313.15K
-
0
0.2876820724517 4.5
0 10 20 30 40 50 60 70 80 90 100
-0.281 -
4
0.5869869847315 3.5
-0.4
 A 313.15K
-
0
0.2876820724517 4.5
0 10 20 30 40 50 60 70 80 90 100
-0.281 -
4
0.5869869847315 3.5
-0.4
55 -
f(x) = − 0.0121981708829146 x − 0.388849194806911 3
0.8209805520698
-0.6 R² = 0.97272061865123
3 - 2.5
Ln [A]

1/[A]
-0.8 1.0078579253996 1.3333333
5 2
0.243 - - 3
-1 1.1551826401565
1.2909841813155 - 1.5
-1.2 7 1.4146938356415 1
9 0.5
-1.4
0
90 100 -1.6 0
Tiempo, (min.)

A 318.15K
-
0
0.2876820724517 6
0 10 20 30 40 50 60 70 80 90 100
-0.281 - 5
-0.4 0.6539264674066 f
64 -
f(x) = − 0.0139826639646383 x − 0.417517181532402 4 R
-0.6 R² = 0.967224551156846
0.9162907318741
55 -
-0.8
Ln [A]

1/[A]
1.1270117631898 - 3
-1 1 1.3093333199837 -
0.205 6 1.4481697648379 - 2
-1.2
8 1.5847452998437
-1.4 3 1
-1.6
0
90 100 -1.8 0
Tiempo, (min.)
 A 298.15K
3 2.4154589371980
2.5974025974026
2.1739130434782 7
2.5 f(x) = 0.0141220464914066 1.9455252918287 6
x + 1.33425112365659
1.7793594306049 9
R² = 0.998678942919619
2 1.5432098765432 8
1.3333333333333 1
1.5 3
1/[A]

0.5

0
0 10 20 30 40 50 60 70 80 90 100
Tiempo, (min.)

A 303.15K
3.5 2.9761904761904
2.6455026455026 8
3 5
2.4390243902439
f(x) = 0.0179913680318789 2.1413276231263
x + 1.33751529042652
2.5 R² = 0.998669502006982
1.8867924528301 4
1.6077170418006 9
2
1.3333333333333 4
1/[A]

1.5 3
1
0.5
0
0 10 20 30 40 50 60 70 80 90 100
Tiempo, (min.)

A 308.15K
4 3.4482758620689
3.1746031746031 7
3.5 2.7397260273972 7
f(x) = 0.0238169360185841 x + 1.33833707465151
6
3 R² = 0.998491865530769
2.4390243902439
2.0408163265306
2.5
1.6949152542372 1
9
1/[A]

2
1.3333333333333
3
1.5
1
0.5
0
0 10 20 30 40 50 60 70 80 90 100
Tiempo, (min.)

A 313.15K
4.1152263374485
4.5 3.6363636363636 6
4 3.1746031746031 4
f(x) = 0.0307694282971204 x + 1.33973871705135
3.5 R² = 0.999887342933514 2.7397260273972 7
 A 313.15K
4.1152263374485
4.5 3.6363636363636 6
4 3.1746031746031 4
f(x) = 0.0307694282971204 x + 1.33973871705135
3.5 R² = 0.999887342933514 2.7397260273972 7
3 2.2727272727272 6
2.5 1.7985611510791 7
1/[A]

1.3333333333333
2 4
3
1.5
1
0.5
0
0 10 20 30 40 50 60 70 80 90 100
Tiempo, (min.)

A 318.15K
6

5
f(x) = 0.0392912726116324 x + 1.32902153856574
4 R² = 0.999887132557386
1/[A]

0
0 10 20 30 40 50 60 70 80 90 100
Tiempo, (min.)