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PhilipSmith , p , USDOL USDOL OSHA,HealthResponseTeam, SaltLakeCity,UT PittsburghConferencePaper#180 20P PittsburghConferencePaper#180 March2011 March 2011
TypesofSamples yp f p
BTEX ChlorinatedHC(TCA,TCE,PERC,MeCl2) Chlorinated HC (TCA TCE PERC MeCl2 ) GasolineHCs Solvents
=============================== Columnsselected ThickfilmMSCap(0.53mm)&aGasPro Columnsselected PLOT(0.32mm) 0.32mm) =============================== Pesticides&PCBs notconsideredhere Pesticides&PCBs Betterwithshort(5 ( ) p y Betterwithshort(510M)thinfilmcapillarycolumn
ComparisonofPLOT&ThickFilm Columns l
Compare PLOT to Thick Film columns for ComparePLOTtoThickFilmcolumnsfor speedforC1C6anes &enes speedforC1C6anes &enes What are the advantages/disadvantages of Whataretheadvantages/disadvantagesof each? A Anyadvantagesofresistivelyheated d f i i l h d columns? Heatup/cooldown?Powerutilized? Heatup/cooldown?Powerutilized? g g p y Advantagese.g comparisonofsensitiviity Advantagese.g comparisonofsensitiviity
GC312
PortableGC PortableGC Portable GC312 Features Batteryoperated Batteryoperated 8hours Has external charger or Hasexternalchargeror powerfromcarbattery Carriergassupply Carriergassupply >25 hours hours 1or2Detectors PID FID TCD Far UV FPD (S PID,FID,TCD,FarUV,FPD(S orP) TemperatureProgramming TemperatureProgramming NEW
GCSchematic GC Schematic
Focus is on the column/oven Small or no oven (direct heating of column) provides rapid temperature p g programming and faster analyses g y
ResistivelyHeatedColumnorLow MassOven
ComparisonofOvenCoolDown times
120
Cooldowntimes(Agilent)resistive(blue)&Lowmass(red)ovens
100
80 Oven nTemperatureC
60 Series1 Series2 40
20
DifferencesBetweenTFCapandPLOTfor C1C6 HC
Main differences are for C1C3HC MaindifferencesareforC1C3 HC C1
SeparationofCH4 &C2H6 betteronPLOT SeparationofC2H6 &C2H4 better on PLOT Separation of C &C betteronPLOT SeparationofC3H8 &C3H6 betteronPLOT El ti ElutionofC4 t C6 HC muchshorteronTFC f C toC HC HC h h t TFC
ComparisonofPLOTtoWideBoreThick FilmCapsensitivity il ii i
WCOTSensitivityThickFilm7ux0.53mmx7.5M;15cc&35C;PID0.2ccinj.X100 Compound Run PH C2H425ppm Avg pp H2S25ppm Avg g 3306 cts/ppm 1453cts/ppm /pp
Gaspro Sensitivity30Mx0.32mm;5cc&35C:PID 0.2ccinj.X100 C2H425ppm Avg. 1519 cts/ppm H2S25ppm Avg. 1739cts/ppm
SUMMARY
Thethickfilmcapscanprovidefasteranalyseswithexcellentseparations forawidevarietyofHC&solventsthanPLOTcolumns Thesensitivityforthethickfilmcolumnforgases(C2H4&H2S)issimilarto thePLOT AResistivelyheatedcolumncanprovidefasteranalysesthanasmallGC ovenbecauseofitslowmass Ifweprogramfrom30Cto100C,thetotaltimefortheRHCis10min., whereas,asmalloven(fancooled)willtake>20mintorunthisprogram. ThesetwodetectorsFUV&PIDcanprovidesubppmorppbdetectionof CH4,TCAtothexylenes ordecane inair,waterorsoil(headspaceforthe lattertwo) Ifweuseathickfilm30Mx0.32mmcolumnthatisresistivelyheated,we candomostanalysesin1012minandnearlydoublethevolumeof samplesdoneinanormalworkday.