NaOH #de limones X peso X por limon ml de jugo x limon densidad de limon

Ct NaOH Co HCit Vo HCit pka1 pka2

0.0986 0.0345 5 3.15 4.77
ka1 ka2
0.000707945784384 1.698243652462E-05

V NaOH pH Φ H3O+ αH3Cit αH2Cit-

0.5 3.2 0.2858 0.000630957 0.464570246743737 0.52125639016609
1 3.6 0.57159 0.000251189 0.249138802446297 0.70216854833031
1.5 4 0.85739 0.0001 0.106845060991483 0.756405105111864
2 4.4 1.14319 3.981072E-05 0.036233408721091 0.644331246842406
2.5 4.75 1.42899 1.778279E-05 0.010795230744771 0.429765876727283
3 5.15 1.71478 7.079458E-06 0.001786800870283 0.178680087028333
3.5 5.5 2.00058 3.162278E-06 0.000257609430677 0.057671567795221
4 5.95 2.28638 1.122018E-06 1.53525001767E-05 0.009686772742627
4.1 6 2.34354 0.000001 1.10672966927E-05 0.007835046038102
4.2 6.1 2.4007 7.943282E-07 5.71989055303E-06 0.005097857821411
4.3 6.2 2.45786 6.309573E-07 2.93813395588E-06 0.003296640519712
4.4 6.3 2.51501 5.011872E-07 1.50179115183E-06 0.002121336386141
4.5 6.4 2.57217 3.981072E-07 7.64581053233E-07 0.00135963874427
4.6 6.45 2.62933 3.548134E-07 5.44871132219E-07 0.001087160836631
4.7 6.6 2.68649 2.511886E-07 1.9641913583E-07 0.000553584339798
4.8 6.7 2.74365 1.995262E-07 9.92268588912E-08 0.000352070181062
4.9 6.8 2.80081 1.584893E-07 5.00461828031E-08 0.000223548087079
5 7.05 2.85797 8.912509E-08 8.99528713244E-09 7.145210548751E-05
5.1 7.15 2.91513 7.079458E-08 4.52110232007E-09 4.521102320071E-05
5.2 7.7 2.97229 1.995262E-08 1.0201367643E-10 3.619581828232E-06
5.3 8.35 3.02945 4.466836E-09 1.14735963378E-12 1.818442472884E-07
5.4 9 3.08661 0.000000001 1.28805004461E-14 9.118695991606E-09
5.5 9.2 3.14377 6.309573E-10 3.23562036068E-15 3.630425755802E-09
5.6 9.5 3.20093 3.162278E-10 4.07360325787E-16 9.119661723527E-10
5.7 9.75 3.25809 1.778279E-10 7.24416007792E-17 2.883952071659E-10
5.8 9.85 3.31525 1.412538E-10 3.63070111595E-17 1.819661048433E-10
5.9 10 3.37241 1E-10 1.28822959926E-17 9.119967141161E-11
6 10.15 3.42957 7.079458E-11 4.57083177777E-18 4.570831777766E-11
6.1 10.25 3.48672 5.623413E-11 2.29084770025E-18 2.884006384398E-11
6.2 10.4 3.54388 3.981072E-11 8.12825504311E-19 1.445430858271E-11
6.3 10.6 3.60104 2.511886E-11 2.04173000141E-19 5.754376986214E-12
6.4 10.65 3.6582 2.238721E-11 1.44543475888E-19 4.570866047251E-12
6.5 10.85 3.71536 1.412538E-11 3.63077260443E-20 1.819696877544E-12
7 11.3 4.00116 5.011872E-12 1.62180883843E-21 2.290865874489E-13
7.5 11.5 4.28696 3.162278E-12 4.07380078278E-22 9.120103926725E-14
8 11.6 4.57275 2.511886E-12 2.04173715034E-22 5.754397134651E-14
8.5 11.7 4.85855 1.995262E-12 1.02329267605E-22 3.630779425683E-14
9 11.75 5.14435 1.778279E-12 7.24435760549E-23 2.884030708799E-14

Teorica V vs pH
14
12
10
8
Axis Title Column B
6
4
2
0
0 1 2 3 4 5 6 7 8 9 10
Axis Title
Vvire fenolftaleina Vpe tangentes

pka3 pkw V1er PE V2 PE V3PE

5.19 14 1.7494929 3.4989858012 5.2484787 14
ka3 kw c1 c2 c3
6.456542290347E-06 1E-14 0.02555748 0.0202965394 0.01683177 12

10
αHCit2- α Cit3- ∑α OH- fi2 Vcalc
0.014029797159013 0.000143565931 1 1.584893E-11 0.5314696 0.5
8
0.047472420138183 0.001220229085 1 3.981072E-11 0.79349508 1

pH
0.128456016844588 0.008293817052 1 1E-10 1.03530033 1.5
6
0.274858513226864 0.04457683121 1 2.511886E-10 1.32662489 2
0.410423225999557 0.149015666528 1 5.623413E-10 1.69714391 2.5
4
0.428623674736832 0.390909437365 1 1.412538E-09 2.20845059 3
0.309714656525565 0.632356166249 1 3.162278E-09 2.57407781 3.5
2
0.146615238456484 0.843682636301 1 8.912509E-09 2.83393289 4
0.133058172009522 0.859095714656 1 0.00000001 2.85120984 4.1
0
0.108990267598502 0.88590615469 1 1.258925E-08 2.8807742 4.2 0
0.088730226948413 0.907970194398 1 1.584893E-08 2.90464985 4.3
0.07188024376494 0.925996918058 1 1.995262E-08 2.92385863 4.4
0.057999404127464 0.940640192547 1 2.511886E-08 2.93926821 4.5
0.052034789160616 0.946877505132 1 2.818383E-08 2.94577979 4.6
0.037426894758079 0.962019324483 1 3.981072E-08 2.96145922 4.7
0.02996603232186 0.96968179827 1 5.011872E-08 2.9693252 4.8 14
0.023953609095444 0.975822792771 1 6.309573E-08 2.97559638 4.9
0.013614918022221 0.986313620877 1 1.122018E-07 2.98624282 5
12
0.010845369075642 0.98910941538 1 1.412538E-07 2.98906624 5.1
0.003080763776394 0.99691561654 1 5.011872E-07 2.99692595 5.2
0.00069135254601 0.999308465609 1 2.238721E-06 2.99937304 5.3 10
0.000154857675865 0.999845133205 1 0.00001 3.00013495 5.4
9.771417274814E-05 0.999902282197 1 1.584893E-05 3.00036166 5.5 8
4.897548317675E-05 0.999951023605 1 3.162278E-05 3.00086764 5.6 pH
2.754152846876E-05 0.999972458183 1 5.623413E-05 3.00160252 5.7
6
2.187713761589E-05 0.99997812268 1 7.079458E-05 3.00203028 5.8
1.548792630814E-05 0.999984511982 1 0.0001 3.00288335 5.9
1.096466173581E-05 0.999989035293 1 0.0001412538 3.00408392 6 4
8.709560042213E-06 0.999991290411 1 0.0001778279 3.00514664 6.1
6.165911999821E-06 0.999993834074 1 0.0002511886 3.00727649 6.2 2
3.890436314367E-06 0.999996109558 1 0.0003981072 3.01154004 6.3
3.467356481907E-06 0.999996532639 1 0.0004466836 3.01294967 6.4
2.187756837655E-06 0.999997812241 1 0.0007079458 3.02053252 6.5 0
0
7.762465140694E-07 0.999999223753 1 0.0019952623 3.05794854 7
4.897785794852E-07 0.999999510221 1 0.0031622777 3.09195051 7.5
3.890449936382E-07 0.999999610955 1 0.0039810717 3.11585422 8
 3.090294477521E-07 0.999999690971 1 0.0050118723 3.1460031 8.5
2.754227944761E-07 0.999999724577 1 0.0056234133 3.163919 9

Column B

0
 Experimental Φ vs pH
14

12

10

8
pH

0
0 1 2 3 4 5 6
Φ

Experimental V vs pH
14

12

10

8
Column B
pH

0
0 1 2 3 4 5 6 7 8 9 10
vol NaOH
 Column B

10
pkw pka1 pka2 pKa3 Co Ct Vo V
V NaOH pH vol prom 1ra derivada vol prom prom 2da dericada
0.5 3.2
1 3.6 1.25 0.8
1.5 4 1.75 0.8 1.5 1.776357E-15 7
2 4.4 2.25 0.7 2 -0.2
2.5 4.75 2.75 0.8 2.5 0.2 6
3 5.15 3.25 0.7 3 -0.2
5
3.5 5.5 3.75 0.9 3.5 0.4
4 5.95 4.05 0.5 3.9 -0.8

1ra derivada
4
4.1 6 4.15 1 4.1 1
4.2 6.1 4.25 1 4.2 1.776357E-13 3
4.3 6.2 4.35 1 4.3 -1.77636E-13
4.4 6.3 4.45 1 4.4 1.776357E-13 2
4.5 6.4 4.55 0.5 4.5 -5
1
4.6 6.45 4.65 1.5 4.6 10
4.7 6.6 4.75 1 4.7 -5
0
4.8 6.7 4.85 1 4.8 -1.77636E-13 0 1
4.9 6.8 4.95 2.5 4.9 15
5 7.05 5.05 1 5 -15
5.1 7.15 5.15 5.5 5.1 45
5.2 7.7 5.25 6.5 5.2 10
5.3 8.35 5.35 6.5 5.3 -4.88498E-13
5.4 9 5.45 2 5.4 -45
5.5 9.2 5.55 3 5.5 10
5.6 9.5 5.65 2.5 5.6 -5 50
5.7 9.75 5.75 1 5.7 -15 40
5.8 9.85 5.85 1.5 5.8 5
30
5.9 10 5.95 1.5 5.9 1.332268E-13
6 10.15 6.05 1 6 -5 20
2da derivada

6.1 10.25 6.15 1.5 6.1 5 10

6.2 10.4 6.25 2 6.2 5 0
1 2
6.3 10.6 6.35 0.5 6.3 -15
-10
6.4 10.65 6.45 2 6.4 15
-20
6.5 10.85 6.75 0.9 6.6 -11
7 11.3 7.25 0.4 7 -5 -30
7.5 11.5 7.75 0.2 7.5 -0.4 -40
8 11.6 8.25 0.2 8 0
-50
8.5 11.7 8.75 0.1 8.5 -0.2
9 11.75 4.5 1.30555556 6.625 2.4111111111
 primera derivada
7

0
0 1 2 3 4 5 6 7 8 9 10
volumen promedio

segunda derivada

2 3 4 5 6 7 8 9

volumen promedio promedio

9