[A]= Concetración, o factor de análisis

t= tiempo
K=constante de proporcionalidad
Con catalizadores
 Modelo matematico
para entender las
reacciones quimicas

Ecuacion de la recta
 A

Tiempo(días) 10°C
0 100
4 97.6
7 93.9
11 80
18 75
21 71
25 65
28 60
32 55
[A]0= 101.16
K -1.4586
R2 0.9809
Promedio R2 0.96

lnA

Tiempo(días) 10°C
0 4.6051702
4 4.5808775
7 4.5422304
11 4.3820266
18 4.3174881
21 4.2626799
25 4.1743873
28 4.0943446
32 4.0073332
ln[A]0= 4.6385
K 0.019
R2 0.9818
Promedio R2 0.98

1/A

Tiempo(días) 10°C
0 0.01
 4 0.010245901639
7 0.010649627263
11 0.0125
18 0.013333333333
21 0.014084507042
25 0.015384615385
28 0.016666666667
32 0.018181818182
1/[A]0= 0.0093
K 0.9686
R2 0.9686
Promedio R2 0.97
A A [A] o ln [A] o 1/[A] (donde
A=Concentración o factor
15°C 20°C final)
100 100
90 91.03
75 79.36
65.16 53.18 K=Constante
48.51 35.51
41.13 31.68
30 29
29 25.1
25 21.3
95.466 94.025
-2.43 2.0632
0.9737 0.9229
Orden 0
120

100
f(x) = − 1.45861050328228 x + 101.161903719912
lnA lnA f(x)
f(x)===0.980896227624045
R² −− 2.43421991247265
2.6031772428884 x x++94.024875273523
95.4662341356674
R²
R² == 0.973703047936046
0.922902457732013
15°C 20°C 80

4.6051702 4.6051702
Axis Title

60
4.4998097 4.5111891
4.3174881 4.3739945
40
4.1768458 3.9736824
3.8817700 3.5698143
20
3.7167378 3.4556856
3.4011974 3.3672958
0
3.3672958 3.2228678 0 5 10 15 20 25 30
3.2188758 3.0587071
Axis Title
4.6502 4.6286
0.0457 0.0515
0.9906 0.9778

1/A 1/A Orden 1

15°C 20°C 5.0000000
4.5000000 0.0456631087369693
f(x) = − 0.0190391980925758 4.6502227
0.051499123378165 x x++4.62858653
4.6384734
0.01 0.01 R² = 0.990624618164206
0.981793260031743
0.977763345229141
4.0000000
3.5000000
3.0000000
s Title

2.5000000
 Orden 1
5.0000000
4.5000000 0.0456631087369693
f(x) = − 0.0190391980925758 4.6502227
0.051499123378165 x x++4.62858653
4.6384734
0.990624618164206
R² = 0.981793260031743
0.977763345229141
4.0000000
0.0111111111111111 0.010985389432055
0.0133333333333333 0.012600806451613 3.5000000

0.0153468385512584 0.018804061677322 3.0000000

Axis Title
0.020614306328592 0.028161081385525 2.5000000
0.024313153415998 0.031565656565657 2.0000000
0.0333333333333333 0.03448275862069
1.5000000
0.0344827586206897 0.039840637450199
1.0000000
0.04 0.046948356807512
0.0068 0.00067 0.5000000

0.001 0.0012 0.0000000

0 5 10 15 20 25 30
0.9532 0.9817
Axis Title

Orden 2
0.05
0.045
0.04 f(x) = 0.00118421904048904 x + 0.0067214187
R² = 0.981713621117762
0.035 f(x) = 0.000966478112086848 x + 0.006825447
0.03 R² = 0.953191940453772
Axis Title 0.025
0.02
0.015 f(x) = 0.000254307260050222 x + 0.009324178
0.01 R² = 0.968571685218461
0.005
0
0 5 10 15 20 25
Axis Title
 [A]0 Ó ln [A]0 Ó 1/[A]o
(donde A=Concentración o
factor inicial)

t=Tiempo/Fecha de vencimiento
K=Constante

Orden 0

861050328228 x + 101.161903719912
421991247265
6227624045 x x++94.024875273523
31772428884 95.4662341356674
3047936046
2457732013
Column E
Linear (Column E)
Column F
Linear (Column F)
Column G
Linear (Column G)

10 15 20 25 30 35

Axis Title

Orden 1

0.0456631087369693
x) = − 0.0190391980925758 4.6502227122447
0.051499123378165 x x++4.62858653702774
4.63847340330435
² = 0.990624618164206
0.981793260031743
0.977763345229141

Column E
Linear (Column E)
Column F
 Orden 1

0.0456631087369693
x) = − 0.0190391980925758 4.6502227122447
0.051499123378165 x x++4.62858653702774
4.63847340330435
0.990624618164206
² = 0.981793260031743
0.977763345229141

Column E
Linear (Column E)
Column F
Linear (Column F)
Column G
Linear (Column G)

5 10 15 20 25 30 35
Axis Title

Orden 2

= 0.00118421904048904 x + 0.00672141871990819
0.981713621117762
= 0.000966478112086848 x + 0.00682544781440402 Column E
0.953191940453772 Linear (Column E)
Column F
Linear (Column F)
Column G
= 0.000254307260050222 x + 0.00932417883819386
0.968571685218461 Linear (Column G)

5 10 15 20 25 30 35
Axis Title
 T (°C) K(Constante) T (Kelvin)

10
15
20

Qué tiempo durará nuestro tomate si este se mantiene a una temperatura de 5°C

T=5°C

LnK= +
LnK=
K
1

[A]/Limite permisible
[A]o/Estado Inicial
K
t/Fecha de vencimiento= Ln[ ]-Ln[ ]
(menos)K

t dias
 1/T(Kelvin Ln K (constante)

Ea/R
Ln A
LnK
1/T

ntiene a una temperatura de 5°C