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Assessment Chapter 5 BLM 5-4

Chapter 5 Test

Goal Procedure

Demonstrate and assess your understanding of the concepts presented in Chapter 5. Answer the following questions directly on the page. Attach additional pages if necessary.
1. Write balanced thermochemical equations for the following word equations.

Questions

Include the heat term in the equation.

(a) In the neutralization of nitric acid solution with aqueous potassium hydroxide

to form potassium nitrate and water, 53.4 kJ/mol of heat are produced.

(b) When water evaporates, 44.0 kJ/mol of heat is absorbed.

(c) Graphite reacts in excess oxygen to form carbon dioxide, releasing 393.5 kJ

of heat for each mol of graphite that reacts.

2. Draw enthalpy diagrams for each equation you wrote in question 1.

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3. Consider the following equations:

(1) Fe2O3(s) + 3CO(g) o 2Fe(s) + 3CO2(g) (2) 3Fe2O3(s) + CO(g) o 2Fe3O4(s) + CO2(g) (3) Fe3O4(s) + CO(g) o 3FeO(s) + CO2(g)

Ho = 25 kJ Ho = 47 kJ Ho = +38 kJ

(a) Calculate H for the following reaction, using equations (1), (2), and (3).

FeO(s) + CO(g) o Fe(s) + CO2(g)

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(b) Using Hesss law, explain briefly why the method you used in part (a) works

to determine H for a target equation.

4. HNO3(aq)

Hqf = 207 kJ/mol Hqf = 925 kJ/mol Hqf = 875 kJ/mol Hqf = 285.8 kJ/mol

Mg(OH)2(s) Mg(NO3)2(aq) H2O(l)

(a) Given the Hqf values above, calculate Hqrxn for the equation below:

2HNO3(aq) + Mg(OH)2(s) o Mg(NO3)2(aq) + 2H2O(l)

(b) Is the reaction above exothermic or endothermic? How can you tell?

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5. Consider the following thermochemical equation.

C6H12O6(s) + 6O2(g) o 6CO2(g) + 6H2O(l)

Hqcomb = 2802 kJ

Calculate Hqf for C6H12O6(s), given the following information: Hqf CO2(g) = 393.5 kJ/mol Hqf H2O(l) = 285.8 kJ/mol

Copyright 2002 McGraw-Hill Ryerson Limited