SELF ASSESSMENT SPEED TEST-1 Time: 50 Min. 90 INSTRUCTIONS Q. 1 to Q.

30 have one or more than one correct alternative(s) and carry 3 marks each. There is NEGATIVE marking and 1 mark will be deducted for each wrong answer. 1. Which of the following is not a polymide fibre (A) Nylon-66 (B) Nylon-6 (C) Teflon (D) Terylene 2. Which one of the following pairs is correctly matched: (A) Sucrose : reducing sugar (B) Glucose : mutarotation (C) Fructose : aldose sugar (D) Sucrose : monosaccharide 3. Match List-I with List-II and select the correct answer using the codes given below the lists: List-I List-II (a-amino acids) COOH R in R CH NH 2 Max. Marks:

(a) Leucine (b) Phenylalanine (c) Tyrosine (d) Serine Codes: ( a ) ( b ) (A) 4.

(i) HO (ii) ( CH3 ) 2 (iii) CH 2OH (iv) C6 H5 CH 2

CH 2

(C) Which of the following will not give blue colour during the test for N in sodium extract NH 2
r (A) C6 H5 N 2 Cl

( c) ( d) ( ii ) ( i ) ( iv) ( iii) ( iv ) ( ii ) ( i) ( iii)

( a ) ( b ) ( c) ( d) (B) ( ii ) ( iv ) ( i ) ( iii) (D) ( iv ) ( ii ) ( iii) ( i)

(B) NH 2CONH 2

(C) NH 2 NH 2

(D) SO3H

5.

An electric current is passed through an aqueous solution (buffered at pH = 6.0) of alanine (pI = 6.0) and ariginine (pI = 10.2). he two amino acids can be separated because (A) alanine migrates to anode, and arginine to cathode
1

6.

7. 8.

9.

10.

11.

12.

(B) alanine migrates to cathode, and arginione to anode (C) alanine does not migrate, while arginine migrates to cathode (D) alanine does nor migrate, while arginine migrates to anode Glucose and fructose form identical osazones because: (A) they are monosaccharides (B) they are reducing sugars (C) they are epimers (D) their configurations differ only at C-1 and C-2 Which of the following is a natural polymer (A) Nylon (B) Teflon (C) PVC (D) Cellulose Glucose reacts with CH3OH to form (A) methyl glycoside (B) ethyl glycoside (C) methyl ester of gluconic acid (D) None of these 2, 4-Dinitro fluoro benzene is used in peptide chemistry because: (A) it has a characteristic colour (B) it undergoes nucleophilic substitution (C) it undergoes electrophilic substitution (D) it makes the amino acids insoluble in water and thus making them readily crystallisable Mullikan and Barkers test for the detection of the nitro group is based on (A) the reduction of nitrobenzene by hydrogen in the presence of a catalyst like Ni Pt (B) the conversion of nitrobenzene to azoxy benzene (C) the treatment of nitrobenzene with zinc dust in the neutral medium. (D) the reduction of nitrobenzene with iron fillings and sodium hydroxide. In the given reaction: H Glucose + 3C6H 5 NH NH2 Osazone + A + B (A) and (B) are: (A) C6 H5 NH 2 and NH3 (B) C6 H 5 NH 2 and NH 2OH (C) C6 H5 NH NHOH and NH3 (D) NH 2 OH and NHOH In solution D-glucose exist in how many isomeric forms? (A) Two (B) Sixteen (C) Three (D) Four

Question No. 13 & 14 (2 questions) These questions consist of two statements each, printed as assertion and reason, while answering these questions you are required to choose any one of the following responses. (A) If assertion is true but the reason is false. (B) If assertion is false but the reason is true. (C) If both assertion and reason are true and the reason is a correct explanation of assertion. (D) If both assertion and reason are true but reason is not a correct explanation of assertion. 13. Assertion: Reducing sugar give brick red ppt with Fehlings solution and show mutarotation Reason: During mutarotation, one pure anomer is converted into mixture of two anomers. 14. Assertion: A solution of sucrose in water is dextro rotatory but on hydrolysis in presence of H + , it becomes leavo rotatory. Reason: Inversion of sugar follows first order kinetics. 15. Teflon, Polystyrene and Neoprene are all (A) Addition polymers (B) Chain growth polymer
2

16. 17. 18.

19. 20. 21.

22.

23. 24.

(C) Condensation polymer (D) Step growth polymer Which of the following pairs can be distinguished by Fehlings solution? (A) Glucose and fructose (B) Glucose and sucrose (C) Methanal and ethanal (D) Hydroxy propanone and benzaldehyde Which of the following is monosaccharide (A) Galactose (B) Sucrose (C) Glycogen (D) Cellulose pKa1 = 2.34 and the ammonium ion at In an amino acid, the carboxylic group ionises at pKa 2 = 9.60. The isoelectric point of the amino acid is (A) 5.97 (B) 2.34 (C) 9.60 (D) 6.97 Lysine is which type of amino acid: (A) -Amino acid (B) Acidic (C) Basic (D) Neutral On hydrolysis, which of the following carbohydrate give glucose only. (A) Sucrose (B) Lactose (C) Maltose (D) Raffinose An organic compound contains C, H, N, S and Cl. For the detection of chlorine, the sodium extract of the compound is first heated with a few drops of concentrated HNO3 and then AgNO 3 is added to get a white ppt of AgCl. The digestion with HNO3 before the addition of AgNO 3 is (A) to prevent the formation of NO 2 . (B) to create a common ion effect. (C) to convert CN and S2 to volatite HCN and H 2S, or else they will interfere with the test forming AgCN or Ag 2S (D) to prevent the hydrolysis of NaCN and Na 2S. Consider the following statements regarding the methyl glucosides obtained by the reaction of D-glucose with methanol in the presence of dry HCl gas (i) These are methyl ester of hemiacetal of glucose formed by intramolecular reaction. (ii) There are enantiomers (iii) These are inomers (iv) In one of these, all the substituents are equiatorial Which of the above statements are corrects (A) i and iii (B) ii and iv (C) ii, iii and iv (D) i, iii and iv a-Amino acids can be identified by: (A) Baeyer reagent (B) Ninhydrin (C) Tollens reagents (D) NaSO 3H Match List- I with List- II and select the correct answer using the codes given below the lists: List-I List-II (a) -D and b-D glucose (i) Enantiomers (b) D-glucose and D-galactose (ii) Anomers (c) Erthythose and threose (iii) Epimers (d) D-glyceraldehyde and L-glyceraldehyde (iv) Diastereomers ( a ) ( b ) ( c) ( d) Codes: ( a ) ( b ) ( c ) ( d ) (A) (C) Which amino acid is achiral? (A) Alamine (B) Valine (C) Proline (D) Glycine If specific rotation of glucose solution is 52 and fructose solution is 92 then what will be specific rotation of invert sugar?
3

( iii ) ( ii ) ( i) ( iv) ( iii ) ( ii ) ( iv) ( i)

(B) ( ii )

( iii ) ( iv) ( i) (D) ( ii ) ( iii ) ( i) ( iv)

25. 26.

27. 28.

(A) 20 (B) +20 (C) 72 Which of the following compounds reduces Tollens reagents? (A) Glucose (B) Sucrose (C) Methanal The given structure of -amino acid will exist at which pH? COOH
H3 N C H R (A) 7 (B) 14 In the given polypeptide: Arg Try Ile Asn Gly C-terminus amino acid is (A) Gly (B) Arg Which one of the following on reduction sorbitol and mannitol? (A) Glucose (B) Xylose

(D) +72 (D) Formic acid

(C) 2.1

(D) 12

29.

30.

(C) Try (D) Asn with NaBH 4 gives equimolar mixture of (C) Fructose (D) Mannose

ANSWER KEY 1. 7. 13. 19. 25. CD D A C D 2. 8. 14. 20. 26. B A B C A

H

3. 9. 15. 21. 27.

B B AB C ACD
OH H OH OH

4. 10. 16. 22. 28.

ACD C BD D C

5. 11. 17. 23. 29.

C A A B A
HO

6. 12. 18. 24. 30.

D C A B C
H H OH OH

CH 2OH

CH 2OH HO H H

Sorbitol

HO H H

Mannitol

CH 2OH

CH 2OH