SELF ASSESSMENT SPEED TEST-2 Max. Marks: 90 INSTRUCTIONS Q. 1 to Q.

30 have one or more than one correct alternative(s) and carry 3 marks each. There is NEGATIVE marking and 1 mark will be deducted for each wrong answer. 1. A compound with molecular formula C6 H14O 4 does not give litmus test and does not give colour with 2, 4DNP. It reacts with excess MeCOCl to give a compound whose vapour density is 117. Compound A contains how many hydroxy groups? (A) 1 (B) 2 (C) 3 (D) 4 2. When isopentane is subjected to monochlorination. What will be the number of monochlorinated product contain chiral carbon? (A) 2 (B) 3 (C) 4 (D) 5 3. The heat of hydrogenation of 1-hexene is 126 kJ mol. When a second double bond is introduced in the molecule, the heat of hydrogenation of the resulting compound is found to be 230kJmol1 . The resulting compound (diene) is (A) 1: 5 hexadiane (B) 1: 4 hexadiene (C) 1: 3 hexadiene (D) cannot predict from the given information Cl2 Br2 CH 3CH 2CH 3 A B 4. hv hv A and B are: Br
Cl

Time: 50 Min.

Br Cl

(A) CH3CH 2CH 2Cl and CH3CH CH 2 Cl (B) CH3CHCH3 and CH3 CHCH 2 Cl Cl Cl Cl (C) CH3CHCH 3 and CH 3CH CH 2 Br 5. (D) CH3CHCH3 and CH3 C CH 3

Br Which one of the following compounds gives acetone ( CH3 ) 2 C = O as one of the products of its ozonolysis? (C)
Br2 Pr oduct CCl 4

(A) (B) 6.

(D)

CH 3 Product obtained in the above reaction is (A) Diastereomers (C) Meso compound 7. Monomer used to prepare Orlon is: (A) CH 2 = CHCN (B) CH 2 = CH Cl NH 2 8.
conc.H 2SO 4 Br2 H 2 O ( X ) ( Y ) excess Product (Y) of above reaction is

(B) Enantiomer (D) Single pure enantiomer (C) CH 2 = CHF (D) CH 2 = CCl2

NH 2 Br SO3 H
5

NH 2 Br Br

Br

SO3H

(A)

(B)

NH 2
Br Br

NH 2 Br (D) Br SO3H Br

(C)
Br

OC2 H5
O

9.

+ is OC2 H5

AlCl3 Zn Hg HCl HF O [ X ] [ Y ] [ Z ] . The structure of H + H2 O

[ Z]

OC2 H 5 O (B)

(A) COCH 2 CH2 COOH OC2 H5 (C)

O

(D) none

10.

Select aromatic compounds: (III) O

O

(I) (II) (A) I, II and IV

CHO

N N

K (IV)

(B) I and II

(C) II and IV

(D) I, II, III and IV

11.
OH

CH 2 =CH PPh 3Br HO ( X ) ( Y )

Product (Y) of above reaction is (A) (B)

CH = CH CH 3

CH = CH CH 2 OH CH 3

(C)
OH

(D)

12.

CH 2
CHO
14

14

CHO
Zn Hg A HCl

Final major product of this reaction is (A) CH 3 CH 2 CH3 (C) CH 3 CH 2 CHO 13.
14

(B) CH 3 CH 2CH 3 (D) CH 3 CH 2 CHO

14

14

Compound A (molecular formula C3H8O ) is treated with acidified potassium dichromate to form a product B (molecular formula C3H 6 O ). B forms a shining silver mirror on warming with ammoniacal silver nitrate, B when treated with an aqueous solution of NH 2 NHCONH 2 and sodium acetae give a product C. Identify the structure of C. (A) CH 3CH 2CH = NNHCONH 2 (B) CH 3C = NHHCONH 2 CH 3 (C) CH 3C = NCONHNH 2 CH 3 (D) CH3CH 2CH = NCONHNH 2

14.

LiNH 2 ( ) MnO2 Bu C CH A B C D ( ii ) H 2O i PhCHO

Compound D of the above reaction is Bu (A) (B) COOH 15. (A) Iodoform 16.
O

Bu COPh

Bu (D) C Ph
O

(C)

H3O ( A ) + ( B ) formed can be distinguished by

(B) Fehling

(C) NaHSO 3

(D) 2, 4 DNP

Et C Me is prepared as one of the products by dry distillation of calcium salt of

O

which of the following acids: (A) Ethanoic acid and methanoic acid (C) Propanoic acid and ethanoic acid
7

(B) Propanoic acid and methanoic acid (D) None of these

17.

Which one of the following compounds is the best candidate for being prepared by an efficient mixed aldol addition reaction?
OH
O O

(A)

CCH 2 CH(B) CH 3
O

CCHCH 3 CH 2 OH
O O

(C)

CH 2CCHCH3 HO C CH 3

(D)

CCH 2CCH3

18. (A) P giving +ve iodoform test & ve test with Fehling solution. (B) P giving ve iodoform test & +ve test with NaHCO 3 solution. (C) P give +ve Lucas test & ve test with NaHCO 3 solution. (D) P give +ve test with NaHCO 3 & cerric ammonium nitrate solution. 19. Correct order of reactivity of following acid derivatives is MeCON 3 MeCOCl MeCOOCOMe
I II III

CH 3 aq.H 2SO4 MeCH ( CN ) CO Me P

(A) I > II > III NO 2

(B) II > I > III

(C) I > III > II

(D) II > III > I

20.

(S) :

C=N OH

PCl5 O 2 N

C NH
O

OMe

OMe (E): Migratory aptitude of

OMe group is greater than migratory aptitude of

group during cation rearrangements. NO 2 In question below a statement S and an explanation E is given. Choose the correct answers from the codes A, B, C, D given for each question. (A) S is correct but E is wrong. (B) S is wrong but E is correct. (C) Both S and E are correct and E is correct explanation of S. (D) Both S and E are correct but E is not correct explanation of S. Find the reagent used to bring about following conversions. H H O OH O
8

21.

OH

(A) ClCOCH 2 CH 2COCl (C) CH 3COCl I 22. Me Et H SH (A) Me Et H H D (B) Me Et I H H D H D

KSH

(B) CH 3COOCOCH3 (D) ClCO COCl

H (C) HS Et H Me D (D) H Et

SH Me D H

23. The reaction of 4-bromobenzylchloride with sodium cyanide in ethanol leads to (A) 4-bromobenzylcyanide (B) 4-cyanobenzlychloride (C) 4-cyanobenzyl cyanide (D) 4-bromo-2-cyanobenzyl chloride 24. In a compound M ( CO ) 3 NC C=C C2 H 5 NC the number of sigma and pi bonds respectively are (A) 19, 11 (B) 19, 5 (C) 13, 11 25. How many stereoisomers are possible for the adjacent compound
NO2 CHBrMe

(D) 7, 3

CH = CH Me I

26.

(A) 2 (B) 4 (C) 6 The values of the following are given below NO2 NO 2 This is because of

(D) 8

( II ) ( I) (A) Steric inhibition of resonance

9

3.9 ( D )

3.39 ( D )

27. (A)

(B) Me shows hyperconjugation effect whereas NO 2 shows R effect in structure II which oppose with each other (C) + I effect of four Me groups nullify I effect of NO 2 group. (D) % of acinitro form of IInd structure is less w.r.t. % of acinitro form Ist structure Alanine (2-amino propanoic acid) exists asat pH 10 CH 3 CH COO (B) NH 2 (C) CH 3 CH COOH NH 2

CH3 CH COOH

NH 2

(D) CH 3 CH COO

NH 3

28.

( I)

( II )

( III )
(D) II > III > I

Correct order of stability of these carbocations is: (A) I > II > III (B) I > III > II (C) II > I > III 29. Column I (reactants) Cl (A) PhCH 3 H 2O OH
( 4)2 (B) CH 3 CH = CH 2 + CO + H2
CO CO Hg (C) CH CH + H 2O PdCl 2 ,CuCl 2 (D) H 2C = CH 2 + O2 H 2O
2+

Column II (product) (p) CH 3CHO (q) PhCHO (r) CH 3CH 2CH 2CHO

30. Column I (organic compounds oxidised by HIO 4 ) HIO4 (A) CH 3CH 2CH CH CH 2 CH3
OH OH
HIO4 (B) PhCH 2CH CH CH 3

Column II (product of HIO 4 oxidation) (p) 2H 2C = O + HCOOH (q) 2CH 3CH 2CH = O (r) 2H 2C = O

OH OH
HIO 4 (C) CH 2 CH 2

OH

OH (s) PhCH 2CH = O + CH 3CH = O

HIO4 (D) CH 2 CH 2 CH2

OH

OH

OH

10

ANSWER KEY 1. 7. 13. 19. 20. B 2. C 3. C 4. B 5. D A 8. C 9. D 10. B 11. B A 14. D 15. A 16. C 17. B A (This order is only for nucleophilic attack) B 21. D 22. D 23. A 24. A 27. A 28. D 29. A-Q B-R C-P D-P 30. A-Q B-S C-R D-P 6. A 12. BD 18. A 25. D

26. A

11