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ethene ethanol Y
(a) Write a chemical equation for the reaction between ethene and bromine.
(ii) Draw a labelled diagram of the laboratory set-up for the conversion of ethanol to Y.
(c) Ethanol can be detected in the breath of a drunken driver. Suggest ONE chemical test to show the presence of
ethanol in his breath and state the observable change produced by the test. (7 marks)
[modified 1995-CE-7b]
2. The relative molecular mass of an alkanol X is 60.0. X contains 60% of carbon by mass.
(a) Calculate the number of moles of carbon in one mole of X and hence deduce the molecular formula of X.
(b) Draw ONE possible structure of X and give its systematic name. (5 marks)
[1996-CE-2]
3. The photograph below shows a gas burner with a can of fuel. The can contains 250 g of liquefied butane.
(b) (i) Write the chemical equation for the complete combustion of butane.
(ii) Suggest a chemical test for EACH of the products formed when butane is completely burnt in air.
(iii) Calculate the volume of the gaseous product formed, measured at room temperature and pressure, if all
(Molar volume of gas at room temperature and pressure = 24.0 dm3) (9 marks)
[1997-CE-9a]
4. The teacher used ethanol solution) to carry out the following experiment on a redox reaction:
(ii) Explain, in terms of oxidation number, whether potassium dichromate was oxidized or reduced.
(iii) Give the structural formula of the product formed from ethanol in the reaction.
(ii) Excessive drinking of alcoholic beverages may cause health problems. (7 marks)
[1999-CE-6b]
5. Cracking of naphtha gives alkane X (relative molecular mass 44), alkene Y (relative molecular mass 42) and other
products.
(a) What is the meaning of the term ‘cracking’?
(e) Suggest an advantage and a disadvantage of using plastic wastes as an energy source.
(10 marks)
[1999-CE-9b]
(a) The candle wax is a petroleum product. What type of compounds is mainly present in the wax?
(b) (i) In which of the following states does wax act as the fuel in a burning candle?
Solid, liquid, vapour
(ii) State the conditions required for the combustion of wax.
(c) Explain why it is hazardous to add cold water to a tray containing molten wax at a high temperature.
(6 marks)
[2001-CE-1]
7. Using alkenes as an example, describe the characteristics of members of a homologous series . (9 marks)
[2002-CE-5]
8. Ethyl ethanoate is an ester. It can be prepared by heating a mixture of ethanoic acid and ethanol under reflux in the
presence of a catalyst.
Chemistry HKCEE Past Paper Fossil Fuels and Carbon Compounds 4
(a) What is the catalyst used in the preparation?
(b) Draw a labelled diagram of the set-up used for heating the mixture under reflux.
(v) Which ONE of following hazard warning labels should be displayed on a bottle of ethyl ethanoate?
(d) Draw the structure of another ester which has the same molecular formula as ethyl ethanoate, and give its
[2002-CE-6c]
(a) The coal used in the power station contains 1.5% of sulphur by the mass. Calculate the volume of sulphur
dioxide released, measured at room temperature and pressure, when 1.0 kg of the coal is burnt.
(You may assume that all the sulphur in coal is converted to sulphur dioxide upon burning.)
(b) State ONE environmental problem associated with the emission of sulphur dioxide into the atmosphere.
(c) Suggest ONE measure to reduce the emission of sulphur dioxide from the power station.
(d) Particulates are also present in the flue gas generated in the power station.
(i) State ONE environmental problem associated with the discharge of particulates into the atmosphere.
(ii) Suggest ONE way to remove particulates from the flue gas.
(Relative atomic masses : O = 16.0, S = 32.0; molar volume of gas at room temperature and pressure = 24 dm3)
(7 marks)
Chemistry HKCEE Past Paper Fossil Fuels and Carbon Compounds 5
[2002-CE]
10. Organic wastes can be used as an alternative energy source. Under suitable conditions, the wastes can be digested
by bacteria to give a gaseous mixture containing a high proportion of methane. Methane can be used as fuel.
(a) Suggest ONE organic waste that can be used for this purpose.
(b) Write the chemical equation for the complete combustion of methane.
(c) Suggest ONE advantage of using organic wastes as an alternative energy source.
(d) Suggest ONE reason why organic wastes are not yet widely used as an energy source.
(4 marks)
[2003-CE]
11. A policeman suspected a car driver to have drunk an excessive amount of alcoholic drinks, and used a dichromate
breathalyser to conduct a test on the driver’s breath. The result was positive.
(a) State the principle underlying the test of ethanol using a dichromate breathalyser.
(b) The driver claimed that he had just rinsed his mouth using ethanol-containing mouthwash. Without using other
instruments, suggest how the policeman could check whether the driver’s claim was valid or not. Explain your
answer. (4 marks)
Chemistry HKCEE Past Paper Fossil Fuels and Carbon Compounds 6
[2004-CE-8c]
12. An ester can be prepared by heating an alkanol with an alkanoic acid under reflux in the presence of concentrated
sulphuric acid.
(a) Draw a labelled diagram to show the set-up used in heating the reaction mixture under reflux.
(b) Suggest ONE reason why it is necessary to heat the mixture under reflux. (3 marks)
[2004-CE-9b]
13. Both ethane and ethene are hydrocarbons. Compare the chemical reactions of these two hydrocarbons with
14. Both pentane (C5H12) and octane (C8H18) are members of the same homologous series.
(a) Using pentane and octane as examples, illustrate TWO characteristics of the members of a homologous
series. (4 marks)
(b) Which compound, pentane or octane, will burn with a more sooty flame? Explain your answer. (2 marks)
(c) Draw TWO structures which have the same molecular formula C5H12. (2 marks)
[2005-CE-5]
Ans:
1. (a) CH2=CH2 + Br2 CH2BrCH2Br 1
(b) (i) Ethanoic acid 1
(ii) Diagram of heating under reflux
Chemistry HKCEE Past Paper Fossil Fuels and Carbon Compounds 7
If more than 1 diagram is drawn, only the first diagram will be marked.) 3
deduct 1 mark for worng reagents/ incomplete indication of reagents
deduct 1 mark for closed / open system
deduct 1 mark for wrong / no indication of direction of water flow
deduct 1 mark for no indication of heat (max mark deducted =3)
(c) pass the breath into acidified potassium dichromate solution. 1
The colour of the solution will change from orange to green. 1
4. (a) (i) acidified potassium dichromate solution changes from orange to green 1
(ii) O.N. of Cr in Cr2O72- is +6 / VI
O.N. of Cr in Cr3+ is +3 / III 1
Cr2O72- is reduced because O.N. of Cr decreases 1
Chemistry HKCEE Past Paper Fossil Fuels and Carbon Compounds 8
(iii) CH3CO2H or structural formula 1
(also accept structural formula of ethanal, CH2CHO)
(b) (i) drinking a small quantity of wine can reduce the proneness to heart attack. 1
(Also accept causing thinning of blood.)
(ii) Excessive drinking can cause brain damage/ depression/ hepatitis/ cirrhosis of the liver / stomach ulcer/
cancer of mouth, throat and gullet. 1
5. (a) Breaking down of large hydrocarbon (molecules) to small hydrocarbon (molecules) by heat with the help of a
catalyst 1
or Breaking down of heavy petroleum fractions(long chain carbon compounds) into light petroleum fractions
(short chain carbon compounds) (1)
(Accept equivalent answers.)
(b) Treat compounds with bromine in 1,1,1-trichloroethane/ bromine water. 1
Y can cause the bromine solution to change from brown/ orange to colourless rapidly 1
Or Treat compounds with acidified KMnO4 (1)
Only Y can cause the KMnO4 solution to change from purple to colourless (1)
(Do NOT accept combustion.)
(c) General formula of alkene is CnH2n 1
12n + 2n = 42 (1)
n=3
Y is C3H6 1
(d) (i) 1
CH3 H
C C
CH3CH=CH2
n H H
(ii) Apply heat to Z to the shape of a cup in a mould and allow it to cool. 1
(e) Advantage: to reduce the consumption of non-renewable energy sources / fossil fuels 1
(also accept reduction of solid waste for landfill.)
Disadvantage: Burning plastic wastes produces air pollutants / toxic gases 1
or, the cost to the remove the pollutants produced by burning plastic wastes is high. (1)
The steam produced causes the molten candle wax to splash out. The hot wax may cause burning of skin. 1
Or, The steam produced causes the wax to form tiny drops of wax which can easily catch fire / burn violently.
(1)
7. Chemical knowledge (6 marks)
Notes: The chemical knowledge covers three different areas (see below). Award a maximum of 2 for each area.
Chemistry HKCEE Past Paper Fossil Fuels and Carbon Compounds 9
(Award 2 marks for characteristic related to structure / formula; 2 marks for physical property; 2 marks for chemical
property.)
Members of a homologous series can be represented by the same general formula 1
General formula of alkenes: CnH2n 1
Or, Successive members of a homologou series differ in their structure by one CH2 unit (1)
Formulae: ethane (C2H4), propene (C3H6) etc. (1)
Or, Members of a homologou series have the same functional group (1)
Functional group of alkenes: C=C
(1)
Or, Alkenes possess the C=C functionality
(1)
Structures of alkenes: ethane (CH2=CH2); propene (CH3CH=CH2)
(1)
Their physical properties change gradually from one member to the next 1
(with no. of carbon atoms)
The melting point / boiling point of alkene increases with increase in relative molecular mass/ 1
The volatility / flammabitity of alkenes decreases with increase in relative molecular mass (1)
(1 mark for the diagram; 1 mark for direction of water flow in the condenser)
(0 mark for wrong set-up, closed systems)
(c) flammable / C 1
(d) Any ONE of the following: 1+1