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Calendar Description: Thermodynamic activity in solid and liquid systems: Gibbs energy of solutions; binary phase diagrams, equilibrium constant; reaction equilibria in gases; Ellingham diagrams. Three lectures, one tutorial; second term Prerequisite: CHEM 1A03 or 1E03; and MATLS 2B03 Antirequisite: MATLS 2B06 Lecture Hours: Tuesday, Thursday and Friday at 11:30-12:20 T13/125; Tutorial Hours: Thursday 9:30-10:20 in BSB-106
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Energy
0
Eaf A B
Ear
Reaction Coordinate
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k=A Ae
Ea RT
How is reaction rate constant, k, related to the free energy of reaction, Grx?
Review of Building Blocks from Materials 2B03 (Chap 5 4 & 5 5) 5.4 5.5)
Gibbs Free Energy, G, is the most important function for examining change of state in a reaction:
Applies at constant pressure (isobaric) Many processes operate at atmospheric pressure Others are controlled to operate at a constant pressure
G = H TS G = H TS
The later equation applies for a reaction at constant T Criterion for equilibrium for isobaric isothermal reaction is:
dG = 0 G = 0
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