1

Temperatura de burbuja
a)
no componente A B C Tisat xi
1 acetona 14.7171 2975.95 -34.5228 328.823696 0.175
2 metanol 16.59158 3643.31 -33.424 337.377399 0.825

P 100 Kpa MODELO MARGULES

P 1 bar
A12 0.58
A21 0.62

Tsup P1sup sat p2supsat α γ1 γ2 P2Nsat Tn Abs|Tn-Tsup|

335.880501 126.717257 94.2402928 1.34461867 1.49824025 1.01711099 83.9162092 332.99492 2.885580074
332.99492 115.178951 83.9162092 1.37254712 1.49824025 1.01711099 83.403705 332.844098 0.150822336
332.844098 114.599813 83.403705 1.37403744 1.49824025 1.01711099 83.3765326 332.83608 0.008018017
332.83608 114.56909 83.3765326 1.37411675 1.49824025 1.01711099 83.375087 332.835654 0.000426635
332.835654 114.567456 83.375087 1.37412097 1.49824025 1.01711099 83.3750101 332.835631 2.27021E-05
332.835631 114.567369 83.3750101 1.3741212 1.49824025 1.01711099 83.375006 332.83563 1.20803E-06
332.83563 114.567364 83.375006 1.37412121 1.49824025 1.01711099 83.3750058 332.83563 6.42818E-08
332.83608
114.56909 2.02412228
83.3765321

y1 0.30039104 171.652021
y2 0.6996263
 x y T Diagrama T-x1-y1 de acetona/metanol a 1 bar
0 0 337.37739
0.1 0.19463 334.4497 338
0.2 0.33048 332.3824 336
0.3 0.43287 330.8962
0.4 0.5158306 329.8133 334
0.5 0.5880569 329.02399 332

T
T-x
0.6 0.6557626 328.4803
0.7 0.724216 328.142411 330 T-y
0.8 0.798436 328.0303 328
0.9 0.8870933 328.2091
1 1 328.8236 326
0 0.2 0.4 0.6 0.8 1
x1-y1
 no componente Ai Bi Ci Psat T 332.83608 K
1 acetona 14.7171 2975.95 -34.5228 114.56909 A12 0.58
2 metanol 16.59158 3643.31 -33.424 83.3765321 A21 0.62

x1 x2 y1 y2 α 12 P y1 y2
0 1 1.78603843 1 2.45422533 83.3765321 0 1
0.05 0.95 1.69394478 1.00136093 2.32451441 89.0191869 0.10900668 0.89099332
0.1 0.9 1.61007377 1.00549504 2.20033839 93.8976894 0.19645285 0.80354715
0.15 0.85 1.53375657 1.01249745 2.08154657 98.1139112 0.26864859 0.73135141
0.2 0.8 1.4643918 1.02248915 1.96798694 101.756087 0.32975725 0.67024275
0.25 0.75 1.40143961 1.03561971 1.85950656 104.9002 0.38265337 0.61734663
0.3 0.7 1.34441638 1.05207037 1.755952 107.611153 0.42940315 0.57059685
0.35 0.65 1.29288997 1.07205782 1.65716973 109.943731 0.47154876 0.52845124
0.4 0.6 1.24647554 1.09583869 1.56300643 111.943365 0.51028506 0.48971494
0.45 0.55 1.20483183 1.12371482 1.4733094 113.646713 0.5465747 0.4534253
0.5 0.5 1.16765796 1.15603957 1.38792686 115.08204 0.5812267 0.4187733
0.55 0.45 1.13469058 1.19322533 1.30670822 116.269402 0.61495334 0.38504666
0.6 0.4 1.10570153 1.23575238 1.2295044 117.22063 0.64841428 0.35158572
0.65 0.35 1.08049579 1.28417951 1.15616809 117.939074 0.68225415 0.31774585
0.7 0.3 1.05890992 1.33915658 1.08655394 118.419111 0.71713798 0.28286202
0.75 0.25 1.04081077 1.40143961 1.02051884 118.645351 0.75378897 0.24621103
0.85 0.15 1.01468681 1.55158967 0.89862556 118.218907 0.83585599 0.16414401
0.9 0.1 1.0065413 1.64167982 0.84249392 117.474425 0.88348309 0.11651691
0.95 0.05 1.00164135 1.74357918 0.78939469 116.287959 0.93749414 0.06250586
1 0 1 1.85892804 0.73919846 114.56909 1 0
 Diagrama T-x-y de acetona(1)/metanol(2) a 332.86K
140

120

100

80
P

60 P-x

40 P-y

20

0
0 0.2 0.4 0.6 0.8 1
x-y
Temperatura de burbuja
a)
no componente A B C Tisat xi
1 acetona 14.7171 2975.95 -34.5228 328.823696 0.175 MODELO DE VAN LAAR
2 metanol 16.59158 3643.31 -33.424 337.377399 0.825

P 100 Kpa
P 1 bar
A12 0.58
A21 0.62

Tsup P1sup sat p2supsat α γ1 γ2 P2Nsat Tn Abs|Tn-Tsup|

335.880501 126.717257 94.2402928 1.34461867 1.49754898 1.59248716 60.01725256 324.959983 10.92051766
324.959983 87.4135453 60.0172526 1.45647362 1.49754898 1.59248716 58.97959938 324.553689 0.406293885
324.553689 86.1677835 58.9795994 1.46097607 1.49754898 1.59248716 58.93858186 324.537506 0.016183463
324.537506 86.11846 58.9385819 1.46115596 1.49754898 1.59248716 58.93694428 324.536859 0.000646303
324.536859 86.1164907 58.9369443 1.46116314 1.49754898 1.59248716 58.93687887 324.536833 2.58134E-05
324.536833 86.1164121 58.9368789 1.46116343 1.49754898 1.59248716 58.93687626 324.536832 1.031E-06
324.536832 86.1164089 58.9368763 1.46116344 1.49754898 1.59248716 58.93687616 324.536832 4.11783E-08

y1 0.22569157
y2 0.77433621
 x y T
0 0 322.4285
0.1 0.135503 323.8987
0.2 0.25361052 324.7051
0.3 0.35629 325.2689
0.4 0.448206 325.70049
0.5 0.53382 326.240073
0.6 0.61694 326.719538
0.7 0.70081129 327.192216
0.8 0.78868 327.65513
0.9 0.88511613 328.143467
1 1 328.823695
 Diagrama T-x1-y1 de acetona/metanol a 1 bar
330
329
328
327
326
T

T-x1
325
T-y
324
323
322
0 0.2 0.4 0.6 0.8 1
x1-y1
 no componente Ai Bi Ci Psat T 324.5368 K
1 acetona 14.7171 2975.95 -34.5228 86.1163102 A12 0.58
2 metanol 16.59158 3643.31 -33.424 58.9367941 A21 0.62

x1 x2 y1 y2 α 12 P y1 y2
0 1 1.78603843 1.85892804 1.40387075 109.559259 0 1
0.05 0.95 1.78603843 1.85892804 1.40387075 111.771648 0.06880414 0.93119586
0.1 0.9 1.78603843 1.85892804 1.40387075 113.984037 0.13493735 0.86506265
0.15 0.85 1.78603843 1.85892804 1.40387075 116.196426 0.1985522 0.8014478
0.2 0.8 1.78603843 1.85892804 1.40387075 118.408815 0.25978985 0.74021015
0.25 0.75 1.78603843 1.85892804 1.40387075 120.621204 0.3187811 0.6812189
0.3 0.7 1.78603843 1.85892804 1.40387075 122.833593 0.37564733 0.62435267
0.35 0.65 1.78603843 1.85892804 1.40387075 125.045982 0.43050135 0.56949865
0.4 0.6 1.78603843 1.85892804 1.40387075 127.258371 0.48344808 0.51655192
0.45 0.55 1.78603843 1.85892804 1.40387075 129.47076 0.53458532 0.46541468
0.5 0.5 1.78603843 1.85892804 1.40387075 131.683149 0.58400426 0.41599574
0.55 0.45 1.78603843 1.85892804 1.40387075 133.895538 0.63179007 0.36820993
0.6 0.4 1.78603843 1.85892804 1.40387075 136.107927 0.6780224 0.3219776
0.65 0.35 1.78603843 1.85892804 1.40387075 138.320316 0.72277579 0.27722421
0.7 0.3 1.78603843 1.85892804 1.40387075 140.532705 0.76612008 0.23387992
0.75 0.25 1.78603843 1.85892804 1.40387075 142.745094 0.8081208 0.1918792
0.85 0.15 1.78603843 1.85892804 1.40387075 147.169872 0.88833388 0.11166612
0.9 0.1 1.78603843 1.85892804 1.40387075 149.382261 0.92665845 0.07334155
0.95 0.05 1.78603843 1.85892804 1.40387075 151.59465 0.9638644 0.0361356
1 0 1.78603843 1.85892804 1.40387075 153.807039 1 0
 Diagrama T-x-y de acetona(1)/metanol(2) a 332.86K
160

150

140

130
P

P-x1
120 P-y1
110

100
0 0.2 0.4 0.6 0.8 1
x-y