1 Given the following values, estimate the change in enthalpy for the following

reaction :
C-C = 347 kJ/mol O=O = 495 kJ/mol O-H = 467 kJ/mol
C-H = 413 kJ/mol O=C = 799 kJ/mol

2881 kJ/mol
-2881 kJ/mol
1235 kJ/mol
-1235 kJ/mol

2 Given the following values, estimate the change in enthalpy for the following
reaction :
N=N = 941 kJ/mol N-H = 391 kJ/mol
H-H = 432 kJ/mol

Reaction : 3 H2 + N2 --> 2 NH3

-2345 kJ/mol
-1091 kJ/mol
-562 kJ/mol
-109 kJ/mol
567 kJ/mol
3 Use the following information to estimate the value of Hfº for MgCl2.(Mg(g) + Cl2(g)
--> MgCl2(s))
Lattice energy = -2326 kJ/mol
first ionization energy for Mg = 735 kJ/mol
second ionization energy for Mg = 1445 kJ/mol
electron affinity for Cl = -349 kJ/mol
bond energy of Cl2 = 239 kJ/mol
enthalpy of sublimation for Mg = 150. kJ/mol
-155 kJ/mol
-322 kJ/mol
-455 kJ/mol
-693 kJ/mol

4 Use the following information to estimate the value of Hfº for MgO.(2Mg(g) + O2(g)
--> 2 MgO(s))
lattice energy of MgO = -3795 kJ/mol
first ionization energy for Mg = 735 kJ/mol
second ionization energy for Mg = 1445 kJ/mol
O(g) +e- --> O- = -141 kJ/mol
O-(g) + e- --> O2- = 878 kJ/mol
bond energy for O2 = 495 kJ/mol
enthalpy of sublimation for Mg = 150. kJ/mol
-1321 kJ/mol
-1120 kJ/mol
 -961 kJ/mol
-766 kJ/mol

5 Calculate the lattice energy of CaCl2 from the following data :

enthalpy of sublimation of Ca = 121 kJ/mol
enthalpy of formation of CaCl2 = -795 kJ/mol
first ionization energy for Ca = 595.5 kJ/mol
second ionization energy of Ca = 1145 kJ/mol
electron affinity of Cl = -349 kJ/mol
bond energy of Cl2 = 239 kJ/mol
-1595 kJ/mol
-2198 kJ/mol
-1431 kJ/mol
-1879 kJ/mol

6 Based on Lewis structures which of the following could not exist?

CH4
C2H2
C4H8
CH3Cl2

7 How many of the following molecules have triple bonds?

N2, PN, HCN, NO3-, NO2
1
2
3
4
5
8 Which of the following molecules is nonpolar? (choose 2)
BCl3
NH3
CCl4
H2O
HCl
9 Which of the following molecules is nonpolar? (choose 2)
PI3
OClF
CH3Cl
CO2
SF6
10 Which of the following molecules has the most polar bonds, but is not a polar
molecule?
SiBr4
CO2
NF3
 SiF4
O3
11 Which of the following is the correct Lewis structure for SO2?

12 Which of the following molecules could not exist?

SF6
XeF6
XeF4
BF4
BF3
13 Which of the following molecules do not obey the octet rule? (choose 2)
CCl4
BF3
SF6
SF4
XeF2
14 What is the formal charge on the carbon atom in the carbonate ion?
0
+1
-1
+2
-2
15 What is the formal charge on the iodine atom in the iodate ion(IO3-)?
0
-1
+1
-2
+2
16 Based on formal charge on the nitrogen atom, which of the following would be the
preferred Lewis structure of NO2?