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.
< L O
UL- VWXZMgO ap\cdnoqKr
stubt#-!Mg(C4H7O
)
2
(H2O. $.VWX
U/9012ZMg
2 +
34&Mg
2 +
sp
3
5#6. =
#-!e<^_.=>#\?#@&8 1k>?
^_ MgO. ;\PQD&R 2 786. 23 (
Compounds !O H !C H !C = H !as COO ( ) !s COO ( ) !C O
L-threonic acid 3 366. 2 2 928. 739. 204. 092. 7
3. 0.
Zinc L-threonate 3 37. 8 2 93. 6 9. 8 48. 2 30. 28. 2 044. 8
Calcium L-threonate 3 30. 0 2 86. 6 606. 440. 376. 0 3. 024. 3
Magnesium L-threonate 3 40. 2 82. 4 67. 400. 9 303. 3 24. 6 074. 2
Mg
@
C4H7O
A
2
(H2O
60 1~ 96 1~ 49 1
94. 22% @94. 3% A
Mg
@
C4H7O
A
49 1~ 80 1~ 38 1
4. 9%
2
!4. 6% "
Mg
!
OAc
"
2. 7%
2
!2. 90% "
38 1~ 2 1~ 8 1
MgO
! B CDE%)*+,-
+2 L- VWXvJKLMN\I#89.
$PQLMR!!Hm
"
dB298. K ?0. MPa f&
f="CLMa\Rf
Mg
:
(C4H7O
)
2
(H2O(s + 7O )
2
(g)
MgO
=
(s + 8CO )
2
(g + 8H )
2O( ) ( l 3)
!!Hm
"
Z> (4) /Db 3 249. 99 . 46 kJ ( ) (
mol
!!Hm
"
= !E + !nRT (4)
I<<#$(u/ (3)&{Hess #EFO;\PQ
D&R:
!f Hm
"
= [!f, MgO( s ) Hm
"
+ 8 !f&CO2
@gAHm
"
+
8 !f&H2O@lAHm
"
] "c Hm
"
()
_F&!f, MgO( s ) Hm
"
= 60. 0 0. 30 kJ ( ) (mol
,
!f&CO2
@gAHm
"
= 393. 0. 3 kJ ( ) (mol
,
!f&H2O@lAHm
"
= 28. 83 0. 04 kJ ( ) (mol
7 [ ]
.
89Ob$PQD&R 2 786. 23 . 84 kJ ( ) (
# &%
V! %& !"#$]^_a%89LM
Table 2 The experimental results of constant-volume combustion energy for the magnesium L-threonate
Calibrated heat of Calibrated heat Calibrated Combustion energy
No. m ' g combustion wire of acid ! T K of sample
qc J qN J ! E (J(g
. 002 36 . 70 . 38 0. 80 7 0 408. 6
2 . 04 30 2. 60 . 6 0. 606 0 420. 00
3 0. 993 2 2. 60 . 33 0. 7 7 0 4. 38
4 0. 996 7 0. 80 . 3 0. 76 4 0 39.
. 024 2 2. 60 . 0 0. 92 3 0 39. 72
6 . 03 84 2. 60 . 44 0. 87 0 43. 26
Mean . 040 7. 34 4. 67
)
996
Acta Phys. -Chim. Sin. ( Wuli Huaue Xuebao% !""! Vol. 8
Received: February 0, 2002; Revised: May 6, 2002. Correspondent: Gao Sheng-Li E-mail: gaoshli@nwu. edu. cn ( ) .
!
The Project Sup-
ported by NSFC 207036 and NSF of Shaanxi Province 99H03 ( ) ( )
. 84 kJ ) (mol
. _GHU3$Di?a{=>#
\B]IJ.
)/5/2/70/-
Sun XD, Yin XC, Zhu SR, Lin HK, Chen RD. Chem. J. Chin.
Univ. , #CC$D #C(6 : 849 ) [KLM&NLO&PQR, STQ, A
RU. 1i$,#$$%( Gaodeng Xueiao Huaue Xuebao),
#CC$D #C(6 : 849
2 Braon G.
) ]
J. Am. Chem. Soc., #C<"D E!F 367
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40
4 Glattfeld J W E, Lee E C. J. Am. Chem. Soc., #CB"D H!F 34
Sun XD, Yin XC, Zhu SR, Lin HK, Chen RD. J. Inorg.
Chem. , #CC$D #B( : 09 ) [KLM, NLO, PQR, STQ,
ARU. KL#$$%( Wuji Huaue Xuebao), #CC$D #B()
09
:
6 Yu K, Wang ZW, Kou FP. CN Patent, 200 366 A, 998-
2-02
]
[a V&WX[&YZh. .4C3, 200, 366 A,
998-2- 02
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02
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_D. :;.\:V-!. =T<=8$ab9cd&
989: 379
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]
J. Appl. Chem. , !""#D #$(9 : 76 )
[Agh&efg&123. a{#$( Yingyong Huaue ),
!""#D #$(9 : 76
0 Chen S P, Ju Z F, Li H Y, Gao S L.
) ]
Chem. Pap. , !""#D EE
(4 : 239
Gao S L, Chen S P, Yang X W, Hu R Z, Shi Q Z.
)
Chinese
Journal of Chemistry, !""#D #C : 037
2 Yang XF, Yang XW, Sun LZ.
( )
Chem. J. Chin. Univ. , #C$HD
GF 363 [h}r&hij&Kkl. 1i$,#$$%
( Gaodeng Xueiao Huaue Xuebao), #C$HD GF 363
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Univ. Press, 94: 382
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979: 29
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]
J. Chem. Thermodyn., #CG$D #"F 903
Synthei and Standard Enthalpy of Formation of Magneium L-Threonate
!
Gao Sheng-Li Yang Xu-Wu Chen San-Ping Ju Zhan-Feng
Shaani Key Laboratory of Physico-Inorganic Chemistry, Department of Chemistry, Northwest University, Xi' an 710069 ( )
IJ-12301 The white powder of magnesium L-threonate was obtained by extracting with alcohol the concen-
trated solution obtained from the reaction between L-threonic acid solution prepared by double decomposition
reaction of calcium L-threonate with oxalic acid and superfluous magnesium oxide at 80 1. The composition of
the new compound was determined by chemical and elemental analyses and its formula fits Mg(C4H7O
)
2
(H2O,
the IR spectra indicated that Mg
2 +
in the compound coordinates to oxygen atom of the carboxyl group, while th
proton of the carboxyl group is dissociated, it was assumed that the coordination number of Mg
e
2 +
was 4 . The
results of TG-DTG showed that the compound had fairish stability, the intermediate and final product of the
thermal decomposition of the compound are Mg(C4H7O
)
2, Mg CH (
3COO)
2 and MgO, respectively. The con-
stant volume combustion energy of the compound, !c E, was determined as 0 407. 34 4. 67 kJ ( ) (mol
by
a precise rotating-bomb calorimeter at 298. K, its standard enthalpies of combustion, !!Hm
"
, and standard
enthalpies of formation, "f Hm
"
, were calculated as 3 249. 49 . 46 kJ ( ) (mol
and 2 786. 23 . 84
kJ
( )
(mol
, respectively.
K/LM428-F Magnesium L-threonate, Synthesis, Thermal analysis, Standard enthalpies of formation
997 No. 123iL- VWXv\uT}PQD&R