ANNEXTURE

Annexure
Annexure
RUN NO-1:
Date: 12.01.09
CODITION:
Weight of LAB:119.76 gm, Weight of H2SO4:249.65 gm, Avg
temp:61.520c
LAB and H2SO4 is taken same time at room temp.then it is heated up,
the temp. is maintained at 600c. After 30 min sample is taken as per the
following table A.1.
Table A.1
Sl No
1
2
Time
0
30
Tem
p
32
80
Wt
LABSA
0
0.341
Vol
CBC
0
0.6
45
80
0.353
3.9
4
5
60
75
70
70
0.359
0.035
3.9
3.9
90
60
0.355
3.9
105
60
0.297
3.4
120
60
0.37
4.3
135
60
0.364
4.2
10
150
62
0.345
3.9
11
165
62.5
0.323
3.7
12
180
62
0.47
5.3
13
195
62
0.315
3.6
14
210
52
0.385
4.4
15
225
63
0.298
3.4
16
17
240
255
64
56
0.487
0.588
5.6
6.7
63
%LABS
A
0
11.261
70.7082
2
69.5264
6
70
70.3098
6
73.2659
9
74.3783
8
73.8461
5
72.3478
3
73.3126
9
72.1702
1
73.1428
6
73.1428
6
73.0201
3
73.5934
3
72.9251
Annexure
18
270
62
0.324
3.7
19
285
61
0.508
5.9
20
300
64
0.505
5.8
21
315
57
0.534
6.2
22
330
52
0.58
6.7
23
345
63
0.527
6.3
24
360
62
0.53
6.32
7
73.0864
2
74.3307
1
73.5049
5
74.3071
2
73.9310
3
76.5085
4
76.3169
8
Plot A.1
%LABSA
Kinetic Data At Avg Temp. 61.52083 Deg C

90
80
70
60
50
40
30
20
10
0
Series1
100
200
300
400
Time (min)
RUN NO- 2:
Date: 06.02.09
CONDITION:
Weight of LAB: 60.47 gm, Weight of H2SO4:125.16 gm, Avg temp: 56.180
c
LAB and H2SO4 is taken same time at room tempter then it is heated up,
the reaction temp. is maintained at 550c. After 30 min sample is taken
as per the following table A.2.
Table A.2
Sl.
No
1
2
3
4
Time
0
30
35
40
Tem
p
35
55
58
56
Wt
LABSA
0
0.54
0.56
0.3
64
Vol
CBC
0
6.3
6
4
%LABS
A
0
74.666
74.45
74.53
Annexure
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
45
50
55
70
85
100
115
130
145
160
175
190
205
220
235
250
265
280
53
56
55
57
60
59
58
59
56
59
58
60
54
60
54
59
57
58
0.32
0.31
0.49
0.24
0.57
0.56
0.28
0.3
0.28
0.23
0.25
0.21
0.3
0.3
0.36
0.33
0.44
0.53
5
3.8
1
2.9
6.8
4.8
3.8
3.9
3.9
3
3.5
2.1
3.3
3.8
4.5
4.6
4.6
4.5
74.62
75
75.23
77.333
78.325
78.42
78.52
78.635
78.665
79.23
79.53
79.265
80
81.2654
81.9528
82.235
83.2356
85.3216
Plot A.2
%LABSA
Kinetic Deta At Temp. 56.18182 Deg C

90
80
70
60
50
40
30
20
10
0
Series1
100
200
300
Time (min)
RUN NO- 3:
Date: 20.02.09
CONDITION:
Weight of LAB: 120 gm, Weight of H2SO4:125 gm, Avg temp: 58.930 c
LAB is heated upto 400c then 125 gm H2SO4 is added. The reaction start
at 2.00 pm. After 30 min sample is collected as per following table A.3.
Table A.3
Sl
no.
Time
HH:MI
N
Tem
p
65
Wt.
Labs
a
Vol
CBC
%
LABS
A
Annexure
2.00
40
30
2.30
61
0.62
2.9
40
2.40
57
0.6
3.7
4
5
50
60
2.50
3.00
54
57
0.6
0.6
3.8
5.4
70
3.10
60
0.53
3.1
80
3.20
61
0.53
3.8
8
9
10
11
12
90
100
110
120
130
3.30
3.40
3.50
4.00
4.10
59
60
60
59
60
0.33
0.37
0.39
0.37
0.36
2.3
3.3
3.1
2.7
2.8
13
140
4.20
59.5
0.41
3.3
14
150
4.30
59
0.45
3.5
15
16
17
18
19
20
21
22
160
170
180
200
210
220
230
240
4.40
4.50
5.00
5.20
5.30
5.40
5.50
6.00
71
62
59
60
58
61
60
59
0.43
0.52
0.32
0.32
0.32
0.36
0.33
0.34
3.2
3.9
2.5
2.5
2.6
2.7
2.5
4.2
0
29.93
5
39.46
7
40.53
3
41.8
37.43
3
46.00
7
44.60
6
48.2
50.87
46.7
49.77
51.51
21
49.77
7
47.62
8
48
50
50
52
48
48.48
52.3
Plot-A.3
Kinetic Data at Avg Temp 58.93 deg C
60
% LABSA
50
40
30
Series1
20
10
0
0
50
100
150
time (min)
RUN NO- 4:
66
200
250
300
Annexure
Date: 21.02.09
Weight of LAB: 93.33 gm, Weight of H2SO4: 200 gm, Avg temp: 59.790 c
LAB is heated upto 400c then 200 gm H2SO4 is added. The reaction
starts at 4.00 pm. After 30 min sample is collected as per following
table A.4
Table A.4
Ti
me
(mi
n)
0
10
20
30
40
50
60
80
100
120
140
160
180
200
220
240
260
280
310
340
370
HH:MI
N
4
4.10
4.20
4.30
4.40
4.50
5.00
5.20
5.40
6.00
6.20
6.40
7.00
7.20
7.40
8.00
8.20
8.40
9.10
9.40
10.10
Tem
p
50
56
69
58
63
62
57
58
70
58
63
59
61
55
66
60
58.5
63
53
63
53
Wt.
LABS
A
Vol
CBC
0.51
0.57
0.41
0.42
0.54
0.33
0.32
0.36
0.38
0.5
0.5
0.39
0.67
0.42
0.33
0.41
0.53
0.34
0.36
0.37
0.7
3.4
2.7
2.9
3.7
2.4
2.3
2.6
2.5
3.5
3.8
2.9
5.3
2.9
2.2
2.9
3.8
2.3
2.6
3
%
LABSA
0
8.7843
38.1754
42.1463
44.1904
43.8518
46.5454
46
46.2222
42.1052
44.8
48.64
47.5897
50.6268
44.1905
42.6667
45.2682
45.8867
43.2941
46.2222
51.8918
Plot-A. 4
Kinetic Deta At Avg Temp. 59.785 DegC
60
50
%LABSA
Sl
No
.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
40
30
Series1
20
10
0
0
100
200
Time (min)
67
300
400
Annexure
RUN NO- 5:
Date: 21.02.09
Weight of LAB: 93 gm, Weight of H2SO4: 200 gm, Avg temp: 54.550 c,
table A.5
Table A.5
Sl
No
.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
Tim
e
(mi
n)
0
10
20
30
40
50
60
80
100
120
140
160
180
200
220
240
270
300
330
360
HH:MI
N
4
4.1
4.2
4.3
4.4
4.5
5
5.2
5.4
6
6.2
6.4
7
7.2
7.4
8
8.3
9
9.3
10
Tem
p
50
50
66
60
53
51
53
53.5
53.5
55
54
55
54
55.5
53
56
55
53
55
55
Wt.
LABSA
Vol
CBC
0.6
0.55
0.53
0.53
0.63
0.56
0.52
0.51
0.64
0.49
0.64
0.55
0.42
0.29
0.63
0.7
0.83
0.72
0.36
0.8
2.3
2.8
3.5
4.3
3.8
3.9
3.7
5
3.6
5.2
4
3.1
2.1
4.7
5
5.9
5
2.6
Plot-A.5
68
%
LABSA
0.0000
8.5333
26.7636
33.8113
42.2642
43.6825
43.4286
48.0000
46.4314
50.0000
47.0204
52.0000
46.5455
47.2381
46.3448
47.7460
45.7143
45.4940
44.4444
46.2222
Annexure
Kinetic Deta At Avg Temp. 54.252 Deg C

60.0000
%LABSA
50.0000
40.0000
30.0000
Series1
20.0000
10.0000
0.0000
0
100
200
300
400
Time (min)
RUN NO- 6:
Date: 22.03.09
Weight of LAB: 119.189 gm, Weight of H2SO4: 250.123 gm, Avg temp:
62.520c, LAB is heated upto 400c then 250.123 gm H2SO4 is added. The
reaction starts at 2.00 pm. After 30 min sample is collected as per
following table A.6
Table A.6
SL
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
Time(mi
n)
0
5
10
15
20
25
30
35
40
45
50
60
70
80
90
100
110
120
130
140
150
220
HH:MI
N
2
2.5
2.1
2.15
2.2
2.3
2.35
2.4
2.45
2.5
2.55
3.05
3.15
3.25
3.35
3.45
3.55
4.05
4.15
4.25
4.35
5.05
Tem
p
0
43
52.5
64.5
65
64
64.1
64.1
64.1
65
64.5
63.8
64.5
65
64
63.5
64.5
64
64.2
63.5
65.5
62.5
69
Wt.
LABS
A
0
0.62
0.63
0.68
0.56
0.51
0.54
0.58
0.69
0.52
0.54
0.46
0.64
0.54
0.75
0.52
0.47
0.45
0.53
0.57
0.47
0.47
vol
CBC
0
0.1
0.7
3
3
3.4
3.8
4.2
5.1
3.7
3.9
3.5
4.9
4
5.7
3.9
3.5
3.5
4.1
4.3
3.6
3.5
%
LABS
A
0.00
1.03
7.11
28.24
34.29
42.67
45.04
46.34
47.30
45.54
46.22
47.70
49.00
47.41
48.64
48.00
47.66
49.78
49.51
48.28
49.02
47.66
Annexure
23
24
25
26
240
260
280
300
5.25
5.45
6.05
6.25
61.2
63
62
61
0.45
0.37
0.45
0.47
3.3
2.8
3.4
3.5
46.93
48.43
47.70
47.66
Plot-A.6
Kinetic Data at Avg. Temp 62.5 deg C

60.00
% LABSA
50.00
40.00
Series1
30.00
20.00
10.00
0.00
0
100
200
300
400
Time (min.)
RUN NO- 7:
Date: 22.03.09
Weight of LAB: 119.76 gm, Weight of H2SO4: 249.647 gm, Avg temp:
57.820c
LAB is heated upto 400c then H2SO4 is added drop wise at a constant
flow rate. The reaction start at 2.00 pm. After 30 min sample is
collected as per following table A.7.
Table A.7
SL
No.
Time(mi
n)
HH:MI
N
Tem
p
Wt.
LABS
A
vol
CBC
35
2.5
42
0.61
0.1
10
2.1
43
0.64
0.2
15
2.15
60
0.7
2.2
20
2.2
66.5
0.54
2.6
25
2.3
65.5
0.54
3.2
30
2.35
63.5
0.54
3.9
35
2.4
61
0.53
3.8
70
%
LABS
A
0.000
0
1.049
2
2.000
0
20.11
43
30.81
48
37.92
59
46.22
22
45.88
68
Annexure
40
2.45
58.5
0.5
3.8
10
45
2.5
56
0.671
11
50
2.55
54
0.644
4.8
12
60
3.05
54
0.44
3.3
13
70.4
3.15
60
0.467
3.5
14
80
3.25
53.5
0.46
3.4
15
90
3.35
60
0.4
2.9
16
100
3.45
59
0.45
3.3
17
110
3.55
59.5
0.45
3.5
18
120
4.05
59
0.439
3.4
19
130
4.15
58
0.465
3.6
20
140
4.25
60
0.467
3.6
21
150
4.35
60
0.483
3.7
22
165
5.05
59
0.390
23
180
5.25
60
Plot-A. 7
0.360
2.9
48.64
00
47.69
96
47.69
98
48.00
00
47.99
98
47.30
43
46.40
00
46.93
33
49.77
78
49.60
00
49.59
99
49.29
95
48.99
97
49.23
08
51.60
00

60.0000
%LABSA
50.0000
40.0000
30.0000
Series1
20.0000
10.0000
0.0000
0
50
100
Time (min)
RUN NO- 8:
Date: 26.03.09
71
150
200
Annexure
Weight of LAB: 93.34 gm

Weight of H2SO4: 200 gm
Avg temp: 57.810c
flow rate. The reaction starts at 2.00 pm. After 30 min sample is
collected as per following table A.8
Table- A.8
HH:MI
N
Tem
p
Wt.
LABS
A
vol
CBC
0.00
SL
No.
Time(mi
n)
2.05
42
0.61
0.1
10
2.1
43
0.64
0.2
15
2.15
60
0.70
2.2
20
2.2
66.5
0.54
2.6
25
2.25
65.5
0.54
3.2
30
2.3
63.5
0.54
3.9
35
2.35
61
0.53
3.8
40
2.4
58.5
0.50
3.8
10
45
2.45
56
0.69
5.1
11
50
2.5
54
0.65
4.9
12
60
54
0.44
3.3
13
70
3.1
60
0.47
3.5
14
80
3.2
53.5
0.44
3.4
15
90
3.4
60
0.37
2.9
16
100
3.5
59
0.43
3.3
17
18
110
120.5
59.5
59
0.45
0.42
3.5
3.4
4
4.15
72
%
LABS
A
0.000
0
1.049
2
2.000
0
20.11
43
30.81
48
37.92
59
46.22
22
45.88
68
48.64
00
47.39
99
48.39
99
48.00
00
47.69
99
49.62
17
50.34
99
49.61
91
49.77
78
51.80
Annexure
19
130
4.3
58
0.44
3.6
20
140
4.4
60
0.46
3.7
21
150
4.5
0.45
3.7
22
165
5.05
0.37
23
180
0.34
2.9
60
59
5.2
60
Plot-A.8
95
52.29
98
51.20
00
52.29
99
52.60
00
54.58
82
% LABSA
Kinetic Data at Avg temp 57.8 deg C

60.0000
50.0000
40.0000
30.0000
20.0000
10.0000
0.0000
Series1
50
100
150
200
time (min.)
RUN NO- 9:
Date: 02.04.09
Weight of LAB:93.3 gm, Weight of H2SO4: 200 gm, Avg temp: 56.840c
LAB is heated upto 400c then 200 gm H2SO4 is added. The reaction start
at 5.25 pm. After 30 min sample is collected as per following table A.9.
Table A.9
Sl
No.
Time(mi
n)
HH:MI
N
Tem
p
Wt.
LABSA
Vol
CBC
1.00
5.25
0.00
0.00
0.00
2.00
5.30
45.00
1.15
0.10
3.00
10
5.35
47.00
0.64
0.10
4.00
15
5.40
49.50
0.50
0.20
5.00
20
5.45
54.00
0.59
0.50
6.00
25
5.50
58.00
0.49
0.60
73
%
LABS
A
0.000
0
0.556
5
1.000
0
2.560
0
5.423
7
7.836
7
Annexure
7.00
30
5.55
60.00
0.54
1.00
8.00
40
6.05
59.00
0.45
2.00
9.00
50
6.15
59.00
0.52
2.70
10.00
60
6.25
59.00
0.62
3.30
11.00
70
6.35
61.00
0.67
3.70
12.00
80
6.45
60.00
0.38
2.20
13.00
100
7.05
59.00
0.47
2.90
14.00
120
7.25
61.00
0.60
3.80
15.00
140
7.45
58.00
0.40
2.60
16.00
160
8.05
60.00
0.39
2.60
17.00
180
8.25
60.00
0.54
3.60
11.85
19
28.40
00
33.23
08
33.99
96
35.30
00
36.79
98
39.48
94
40.53
33
41.60
00
42.40
07
42.66
67
Plot- A.9
45.0000
% LABSA
40.0000
35.0000
30.0000
25.0000
Series1
20.0000
15.0000
10.0000
5.0000
0.0000
0
50
100
150
200
Time(min.)
RUN NO- 10:

Date: 03.04.09
Weight of LAB: 93.34 gm, Weight of H2SO4: 200 gm, Avg temp:56.840c
74
Annexure
table A.10.
Table A.10
Tem
p
Wt.
LABS
A
vol
CBC
2.00
0.00
0.00
0.00
5.00
2.05
43.00
0.77
0.10
3.00
10.00
2.10
51.00
0.76
0.70
4.00
15.00
2.15
65.00
0.64
2.50
5.00
20.00
2.20
69.00
0.56
3.10
6.00
25.00
2.25
62.50
0.73
5.50
7.00
30.00
2.30
60.00
0.66
5.10
8.00
35.00
2.35
58.00
0.68
5.40
9.00
40.00
2.40
55.00
0.77
6.00
10.00
45.00
2.45
54.50
0.49
3.90
11.00
50.00
2.50
54.00
0.45
3.60
12.00
60.00
3.00
54.00
0.52
4.20
13.00
75.00
3.15
54.00
0.47
3.80
14.00
90.00
3.30
55.50
0.52
4.20
15.00
105.00
3.45
54.00
0.36
3.00
16.00
120.00
4.00
55.00
0.34
2.90
17.00
135.00
4.15
53.50
0.35
3.00
18.00
150.00
4.30
54.00
0.41
3.60
19.00
165.00
4.45
54.00
0.36
3.20
Sl
No.
Time(mi
n)
1.00
0.00
2.00
HH:MI
N
75
%
LABS
A
0.000
0
0.831
2
5.894
7
25.00
00
35.42
86
48.21
92
49.45
45
50.82
35
49.87
01
50.93
88
51.20
00
51.69
23
51.74
47
52.16
90
53.15
73
54.15
61
54.15
57
56.15
22
56.91
57
Annexure
20.00
180.00
5.00
57.50
0.36
3.20
21.00
195.00
5.15
56.00
0.54
4.90
22.00
210.00
5.30
53.00
0.54
4.90
23.00
225.00
5.45
52.50
0.45
4.20
24.00
240.00
6.00
54.00
0.56
5.20
25.00
255.00
6.15
51.50
0.43
4.00
26.00
270.00
6.30
54.00
0.56
5.30
27.00
285.00
6.45
55.00
0.49
4.60
28.00
300.00
7.00
54.00
0.63
5.90
29.00
315.00
7.15
55.00
0.49
4.70
30.00
330.00
7.30
56.00
0.51
4.90
31.00
345.00
7.45
53.00
0.54
5.10
32.00
360.00
8.00
50.00
0.52
5.10
57.46
30
57.80
04
58.13
60
59.38
45
59.39
30
60.19
41
60.69
33
60.36
75
60.34
37
61.21
73
61.49
02
61.00
00
62.76
92
Plot- A.10
Kinetic data at Avg Temp 55 deg C
% LABSA
80.0000
60.0000
40.0000
Series1
20.0000
0.0000
0.00
100.00
200.00
Time(min)
RUN NO- 11:
76
300.00
400.00
Annexure
Date: 07.04.09
Weight of LAB: 120 gm, Weight of H2SO4: 301 gm, Avg temp:57.140c
LAB is heated upto 400c then 200 gm H2SO4 is added drop wise at a
constant flow rate. The reaction starts at 3.55 pm. After 30 min sample
is collected as per following table A.11.
Table A.11
Sl
No.
Time(mi
n)
HH:MI
N
Tem
p
Wt.
LABS
A
Vol
CBC
3.55
37
30
4.25
61
0.86
0.3
40
4.35
60
0.4
50
4.45
59
0.86
0.4267
14
60
4.55
63
0.55
1.3
70
5.05
60
0.57
2.2
80
5.15
60
0.52
2.4
90
5.25
59
0.57
2.9
100
5.35
59
2.4
10
110
5.45
58
0.46
0.5919
07
11
120
5.55
55
2.6
12
130
6.05
55
0.47
0.5318
05
13
140
6.15
57
0.53
2.8
14
150
6.25
57
0.5
2.6
15
165
6.4
57
0.62
3.3
16
180
6.55
58
0.512
2.8
17
195
7.1
57
0.59
3.2
18
19
200
220
7.25
7.45
56
55
0.58
0.44
3.2
2.5
77
0.4
3.2
2.9
%
LABS
A
0.000
0
2.232
6
2.976
7
5.999
3
15.12
73
24.70
18
29.53
85
32.56
14
33.39
13
34.60
00
35.40
43
34.90
00
33.81
13
33.28
00
34.06
45
35.00
00
34.71
19
35.31
03
36.36
Annexure
20
240
8.05
60
21
260
8.25
57
0.52
0.4032
9
3
2.3
36
36.92
31
36.49
98
Plot-A.11
Kinetic data at Avg temp 57.14 deg C
% LABSA
40.0000
30.0000
Series1
20.0000
10.0000
0.0000
0
50
100
150
200
250
300
time (min)
RUN NO- 12:

Date: 08.04.09
Weight of LAB: 100 gm, Weight of H2SO4: 214.28 gm, Avg temp: 55.730c
flow rate. The reaction starts at 1.56 pm. After 30 min sample is
collected as per following table A.12.
Table A.12
Sl
No.
Time(mi
n)
HH:MI
N
Tem
p
Wt.
LABS
A
vol
CBC
1.56
37
30
2.26
55
0.83
0.1
35
2.31
54
0.65
0.2
40
2.36
55
0.69
0.3
45
2.41
55
0.62
0.5
6
7
50
55
2.46
2.51
57
57
0.51
0.67
0.8
1.2
78
%
LABS
A
0.000
0
0.771
1
1.969
2
2.782
6
5.161
3
10.03
92
11.46
Annexure
60
2.56
56
0.57
1.1
65
3.01
57
0.56
1.2
10
70
3.06
56
0.67
1.6
11
75
3.11
55
0.55
1.8
12
80
3.16
57
0.53
1.9
13
85
3.21
59
0.54
2.1
14
90
3.26
59
0.47
1.9
15
100
3.36
57
0.45
1.9
16
120
3.56
59
0.48
2.1
17
140
4.16
56
0.48
2.2
18
160
4.36
59
0.5
2.3
19
180
4.56
59
2.2
20
210
5.2
55
0.48
0.4842
11
21
240
5.56
55
0.56
2.8
22
270
6.26
58
0.53
2.7
23
300
6.56
55
0.55
2.9
2.3
27
12.35
09
13.71
43
15.28
36
20.94
55
22.94
34
24.88
89
25.87
23
27.02
22
28.00
00
29.33
33
29.44
00
29.33
33
30.40
00
32.00
00
32.60
38
33.74
55
Plot-A.12
KineticDataat AvgTemp56.8degC
45.0000
% LABSA
40.0000
35.0000
30.0000
25.0000
Series1
20.0000
15.0000
10.0000
5.0000
0.0000
0
50
100
Time(min.)
79
150
200

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Annexure

Kinetic Data At Avg Temp. 61.52083 Deg C

Kinetic Deta At Temp. 56.18182 Deg C

Kinetic Deta At Avg Temp. 54.252 Deg C

Kinetic Data at Avg. Temp 62.5 deg C

Kinetic Data at Avg Temp 57.8 deg C

Weight of LAB: 93.34 gm

Kinetic Data at Avg temp 57.8 deg C

RUN NO- 10:

RUN NO- 11:

RUN NO- 12:

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