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OF COMBUSTION
TABLES 171-183.--HEATS
T A B L E 1 7 1 . 4 O M B U S T I O N C O N S T A N T S O F S O M E SUBSTANCES 62
Substance
Heat of combustion
Reciprocal of
density
m*/100kg
Formula
Spec. gravity
air = 1.000
....
Carbon .................. C
Hydrogen ............... Hz
Oxygen ................. 0 2
Carbon monoxide ........ co
1172.
73.7
84.4
P
Btu/ft*
kg cnl/mJ
275.0
7840.*
2445.
321.8
2860.
913.1
1641.
2385.
3105.
8120.
14,600
21,200
27,600
1513.2
2186.
2869.
13,450
19,400
25,500
3601.
4284.
4980.
32,000
38,100
44,300
.9 107
4.4208
1.1052
1S890
S961
1448.
5654.
768.0
1450.5
365.1
1.1898
5%.
12,870
50,300
6830.
12,900
3245.
2210.*
5300.
6:959x 10.'
1.1053
.%72
....
....
....
................
...............
................
-9740
1.4504
1.9336
8.7.6
56.3
42.2
................. CoHo
................. CiHR
.................. GHio
Miscellaneous gases
89.5
Acetylene ............... CZH,
18.4
Naphthalene ............. CwH,
73.7
Methyl alcohol ........... C H I O H
51.3
Ethyl alcohol ............ C,H,OH
136.5
Ammonia ................ NHa
....
Sulfur .................. S
68.5
Hydrogen sulfide ......... HZS
....
....
62
Shnidman, Louis (ed.), Gaseous fuels, p. 118, Amer. Gas Assoc., 1948.
Expressed in cal/g.
T A B L E 172.-FLAME
T E M P E R A T U R E S AS M E A S U R E D B Y V A R I O U S
METHODS *
Gas
Amy1 acetate
City gas
City gas
............................
............................
.................................
+ air ...........................
Bunsen ............................
.1420
Meker (center flame) ...............1700
Meker
Bunse
Blast
"
Temp "C
Burner
"
"
"
"
('
"
"
"
"
"
"
............................ ,1680
...............1760
..............................
..........................
..........................
..........................
..............................
..........................
..............................
..............................
..............................
..............................
.........................
.........................
..............................
..............................
.1985
.2005
.2015
,2045
.1970
.2275
1950
2000
.2800
.3500
180
TABLE 173.--HEATS
O F COMBUSTION
OF
SOME CARBON
COMPOUNDS
Given in kg calls at constant pressure per gram-molecular weight in vacuo . When reterred
to constant volume the values should be 0.58 kg calls smaller (at about 18C) for each condensed
gaseous molecule . Combustion products are CO,. liquid H,O. etc. Benzoic acid was adopted at
Lyons as a primary standard. its heat of combustion. 6324 g cal15per gram in air. 6319 in vacuo .
This is tacitly assumed as heat of isothermal combustion at 20.C . In absolute joules. 26.466 and
26.445 respectively The following ratios may be taken as standard : Naphthalene/benzoic acid =
1.5201 (air) ; benzoic acid/sucrose = 1.6028 (air) ; naphthalene/sucrose = 2.4364 (air) .
Molecular
weight
5s
86.11
100.13
114.14
142.18
226.27
282.34
70
84.10
26.02
40
47
78.05
128.06
50.5
85.0
ll'B.5
kg calls
per
I mol
283.4
990.6
1143.6
1304.2
1610.2
2559.1
3183.1
803.4
952.6
312.0
469
496.8
782.8
1231.4
168.7
106.8
89.2
70.3
(I)
..............
Carbon-tetrachloride
( v ) ..............
Ca:mn di-su!fide (I) .
154.0
37.3
Ally1 alcohol
Formaldehyde (p.)
Acetone (b) . .I.
Camphor (s) ........
Sucrose: cane (s)
milk (s)
anhd .....
malt ( 5 )
58.05
30.02
58
152.13
342.18
44.5
394.5
246.6
442.4
134.1
435.8
1411
1349.6
''
1350.8
Compound
Isobutane ( g )
n-Hexane
n-Heptane
n-Octane ...........
Decane
Hexadecane (s) .....
Eicosane ( 5 ) ........
Amylene ...........
Hexylene
Acetylene (9) .......
Allylene (9)
Trimethylene (9)
Benzene ............
Naphthalene (s) .....
MethyLchloride ( g )
Methylene-chloride (v)
Chlorqform (1)
.......
...........
..........
.............
...........
........
....
...
(v) .......
Carbon-tetrachloride
.......
......
........
c,?
...
.....
....
.
Karasch.
yp.0
MolecFor .
ular
Compound
mula
weight
Starch .............
Glvcoaen ...........
CeiIuIGse
Formic a;jd
CH?02
46.02
60.03
......... C2H102
Acetic
74.05
C?HsOz
Propionic asjd
n.butyric
....... C.HaO
88.06
n-valeric
102.08
CaHiodi
Palmitic
256.26
(5)
CiaH3eOn
Stearic
(s)
C I L H ~ O Z 284.29
90.05
Lactic
(s) .... C-HROI
Aniline . . ........... CnH7O
60.05
60.05
Krea (s) ........... C H I N ~ O
162.13
Nicotine . ........... C,.H,,N.
52.0
Cyanogen (9)
C$..
.
Trinitrotolyne (s)
C T H K N ~ O227.06
~
60.06
w row1 ( I
...... CnHEO
74.08
n-puty~
116.13
11-heptyl
130.14
Octyl
242.27
Cetyl
"
(s) . .
156.16
Menthol (s)
94.05
Phenol (s) .........
150.11
Thymol ............
46
Dimethyl
e t I y (8)
60
Methylethyl
(v)
74.08
Diethyl
(V)
...........
.........
.......
..
.........
....
....
::
.......
...
......
.....
.....
.......
1351
....
Nat . Bur . Standards Journ . Res., vol . 2. p . 359.
T A B L E 174.-HEATS
..
gmol
4178.8
4186.8
4180.8
62.8
208.2
367.2
524.3
681.6
2391
2700
326.0
151.6
151.6
1427.7
260.0
826
482.0
639.4
1104.9
1262.0
2504.5
1508.8
732.2
1353.4
347.6
503.4
660.3
"
1929.
Substance
Asphalt .........
.. .
Butter .........................
Carbon : amorphous ............
9530
9200
8080
8100
7860
graphite ..............
7900
590
Copper (to CuO) ................
Dynamite. 7570 . . . . . . . . . .
1290
Egg. white of . . . . . . . . . . . . .
5700
Egg. yolk of . . . . . . . . . . . . . . . . . . .
8100
Fats. animal . . . . . . . . . . . . . . . . . . . 9500
Hemoglobin . . . . . . . . . . . . .
5900
Hydrogen . . . . . . . . . . . . . . .
33900
Iron (to Fe203). . . . . . . . . . . . . . . . 1582
Magnesium (to MgO) ........... 6080
Oils : cotton-seed ............... 9500
lard .....................
9300
olive .....................
9400
kg calls
per
Calories
Substance
Oils :
petroleum :
crude ......................
light .......................
heavy ......................
rape .........................
sperm ........................
Paraffin (to CO.. Ha0 I) .........
Paraffin (to CO.. Hz0 g ) .........
Pitch ..........................
Sulfur. rhombic .................
Sulfur. monoclinic ..............
Tallow .........................
Woods: beech. 13% H'O ........
birch. 1Wo H, 0 ........
oak. 13% H, 0 ..........
pine. 12% H, 0 .........
11500
10000
10200
9500
10000
11140
10340
8400
2200
2240
9500
4170
4210
3990
4420
T A B L E 175.-HEAT
181
P a r t 1.-Coals
Coal
38.81
33.38
22.71
15.54
11.44
3.42
2.7
3.26
2.07
2.76
3.33
1.92
1.14
25.48
27.44
34.78
33.03
33.93
34.36
14.5
14.57
9.81
2.48
3.27
1.58
.04
Part 2.-Peats
Vol.
Ash
Peats :
Franklin County, N. Y . . . 67.10 28.99 3.91
Sawyer County, W i s . . .. 56.54 27.92 15.54
.37
.29
.37
Part 3.-Liquid
Fuel
\
M
45.57
40.75
34.09
27.03
17.88
11.51
4.66
5.09
3.59
4.64
5.06
-
3526
3994
5115
5865
6088
7852
7845
8166
7612
6987
7417
7946
8006
6347
7189
9207
10557
10958
14134
14121
14699
13702
12577
13351
14300
14410
hydro- Fixed
carbon carbon
Woods :
Oak, dry ................
Birch, dry ..............
Pine, dry ...............
c:
Btu
Sul- HydroNitro- Oxy- Calories per
fur
gen Carbon gen
gen
perg
pound
.15
.29
-
57.17
51.00
6.02 50.16
6.06 48.88
6.20 50.31
8316
8588
9153
fuels *
Gravity API t
...................... 68
Motor gasoline .........................
58
Kerosene ..............................
42
Domestic fuel oil ........................
32
Diesel fuel oil ..........................
28
Medium industrial fuel oil. ............... 18
Heavy industrial fuel oil ................ 11
Petroleum ether ........................
.68$
Aviation gasoline
5.93
4.71
.82$
20,420
120,700
20,120
125,800
19,810
134,700
19,450
19,350
141,200
143,100
18,930
149,400
18,590
153,900
22,000
12,2209
11,600
6,4501
(continued)
T A B L E 175.-HEAT
Substance
Natural gas
.......................
OF V A R I O U S F U E L S
**
Spec. gravity
Air = 1.000
.60- 1.29
8040-17. 400
20.950
20. 600
26. 350
26. I00
1965
2015
.
2005
.
........................
Oil gas ............................
Coal gas ...........................
1.16
4590.
37
4535.
2000
47
4320.
1980
.......................
86
1182.
1655
...........................
57
2330.
Butane-air
Producer gas
Blue gas
Part 5.-Gross
Density
Area
Density
Area
Btu/lb
......... 898
CaVg
19.370
10.760
California
............863
18.800
10.490
Ohio
Japan
20. 670
11.480
Oklahoma
. . . . . . .886
19.420
10.790
Poland
20.010
11.120
Pennsylvania
19.780
10.990
18.920
10.510
Texas
. . . . .828
. . . ........943
18.950
10.520
19.420
10.790
Argentina
. . . . . . .989
18.540
10.300
18.180
10.100
Patagonia
........948
18.970
10.540
18.360
10.200
20"/4"C
Borneo
India
...........925
.......... 299
Rumania .........936
Canada ..........855
Mexico ..........966
Trinidad .........941
20"/4"C Btu/lb
CaVg
. . . . . . . .960
18.590
10.330
........... 338
19.710
10.950
P a r t 6.-Sugars
Sugar
kg cal/mol
8-d-Levulose
................
671.70
a-d-Galactose
................
666.76
a-d-Glucose
8-Maltose monohydrate
a-Lactose monohydrate
......
a-Monopalmitin
............. 2788.30
Ascorbic acid ................ 560.60
a-D-Glucose pentaacetate ..... 1718.62
1360.50
1349.00
8-D-Glucose pentaacetate
.......... 666.73
............. 2778.78
@-Monopalmitin
....... 1354.66
....................
1 Prepared
kg cal/mol
................. 669.58
a-d-Glucose hydrate
.................. 1345.47
B-Lactose
Sucrose
Sugar
................... 670.30
I-Sorbose
.....
1722.63
T A B L E 176.-NONFLAMMABLE
LIQUIDS
183
FOR CRYOSTATS
Liquid ..........
CClr
CHCla
4" CzH5Br
32
39*
No.40
Freezing point .... "C
-23
-63
-81
-119
-139
-145
-150+
Compositions : * No. 4 ; CCI,, 49.4% ; CHCL, 50.6%.
No. 32; CHCls, 19.7%; CzHaBr, 44.9%; C2HzCL, 13.8% ; CZHCIS,
21.6%.
No. 39; CHCL, 14.5%; CzH5Br, 33.4%; CZHZCIZ, 10.4%; CzHC13,
16.4% ; CH,CL, 25.3%.
No. 40 ; CHCls, 17.9% ; CzH,Cl, 9.3% ; CzHaBr,40.7% ; CzH2CIz,12.5% ;
CzHCla, 19.6%.
Viscositiesin
centipoises:
2.25
3.03
2.57
2.88
2.89
4.57
3.69
3.89
3.86
7.4
5.6
5.9
.........
5.6
13.7
10
10.2
29.3
22.3
22.5
81
85
71
242 1480
170 631
Because of volatility and oxidation of some, these liquids should be kept in well-stoppered bottles
when not in use.
T A B L E 177.-DATA
ON EXPLOSIVES
Calculated
temperatire
Val. gas
Explosive
per g in
cma
=V
Calories
per
g=Q
280
741
923
871
888
817
877
738
1652
931
1242
1031
1349
810
Gunpowder ...............................
Nitrodvcerine
............................
-u
Nitrocellulose, 13% Nz. ....................
Cordite, Mk.I. (NG, 57; NC, 38; Vaseline, 5).
Cordite, MD (NG, 30; NC, 65 ; Vaseline, 5). .
Ballistite (NG. 50: NC. 50: Stabilizer., 5).
...
,
Picric acid (Lyddite). ......................
d
Coeffi- Coefficient
cient
GP
= QV
- 1
t 1000
207
1224
859
1082
915
1102
710
1
6
4.3
5.2
4.4
5.3
3.4
Q/C
C, sp. ht.
gases
- .24
2240" C
6880
3876
5175
4225
5621
3375
Shattering power of explosive = vol. gas per g x cals/g x V, x density where V, is the velocity of
detonation.
Trinitrotoluene: V, = 7000 m/sec. Shattering effect = .87 picric acid.
trinitrotoluene, T N T ) : V, = 4500 m/sec.
Amatol (ammonium nitrate
Ammonal (ammonium nitrate, T N T , Al) : 1578 cal/g; 682 cma gas; V, = 4000 m/sec.
Sabulite (ammonium nitrate, 78, T N T 8, Ca silicide 14) : about same as ammonal.
T A B L E 178.-TIME
Temperature
Time
"C
180
190
200
220
sec
sec
sec
sec
sec
n
195
130
60
165
100
340
n
n
130
67
60
240
n
45
90
21
56
50
150
600
190
170
870
160
n
n
-
n
-
590
23
25
9
18
30
60
480
-
Ignition temperature
"C t
"C t
440
(300
300
590
450
900
184
TABLE 179.-CHEMICAL
kg/cm*
m/sec
m/sec
In.
In.
88.4
79.7
14.5
25
..........
8235
227*
4688
.358
24.63
12
1.25
789.4
4817
374t
458*
469.4z 925.
54.32
- 154.4
126.9
4.1 1I
760.5
5912
301*
3008
.471
27.79
explosive ; ammonium
.97
nitrate class
4 103.9
65.1
15.4
992.8
7300
279*
34386 .483
25.68
89.8
27.5
75.5
610.6
6597
434*
2479
17.49
86.1 Over
56.0 1000
33.0
powder
(D) Permissible
......
.338
25
1000
800
Chemical analyses
............. .23
............. 83.10
............. .46
............. 2.61
.............
17.74
10.89
1.89
2.54
2.64
6.53
.....................
2.34
(E) Moisture
8 Cartridges
$ R a t e of burning.
T A B L E 180.-THERMOCHEMISTRY.
185
C H E M I C A L ENERGY DATA
The total heat generated in a chemical reaction is independent of the steps from initial to final
state . Heats of formation may therefore be calculated from steps chemically impracticable .
Chemical symbols now represent the chemical energy in a gram-molecule or mol(e); treat reaction equations like algebraic equations : CO + 0 = CO. 68 k g cal ; subtract C 2 0 = C o t
97 kg ca!. then C 0 = CO 29 kg cal . W e may substitute the negative values of the formation heats in an energy equation and solve MgCL 2 Na = 2 NaCl Mg x kg cal ; - 151 =
- 196 + x ; x = 45 kg cat . Heats of formation of organic compounds can be found from the
heats of combustion since burned to H, 0 and COz. When changes are at constant volume. energy
of external work is negligible ; also generally for solid or liquid changes in volume . When a gas
forms a solid or liquid at constant pressure. or vice versa. it must be allowed for . For N mols of
gas formed (disappearing) at T K O the energy of the substance is decreased (increased) by
0.002.N.T~ kg cal Hz 0 = HzO 67.5 kg cal at 18C at constant volume; 1(2 HZ 0, 2 HZO = 135.0 0.002 x 3 x 291 = 136.7) = 68.4 kg cal .
The heat of solution is the heat. + or
liberated by the solution of 1 mol of substance in so
much water that the addition of more water will produce no additional heat effects . Aq signifies
this amount of water; HzO. one mot ; N H + Aq = N H 4 0 H . A q 8 kg cal .
Part 1.-Heats
-.
At ordinary temperatures
Compound
Heat of
formation
Compound
Heat of
formation
Compound
Compound
Heat of
formation
am = amorphous:
s = solid; y = yellow (gold) .
Heats of formation not from elements but as indicated
(contintled)
SMITHSONIAN PHYSICAL TABLES
Heat of
formation
186
T A B L E 180.-TH
P a rt 2.-Heats
and - signs indicate signs of ions and the number of these signs the valency. For the ionization of each gram-molecule of an element divide the numbers in the table by the valency, e. g.,
9.00 g AI = 9.00 g AI'
40.3 kg cal. When a solution is of such dilution that further dilution does not increase its conductivity, then the heats of formation of substances in such solutions
may be found as follows : FeCI2Aq= 22.2 2 X 39.1 = 100.4 kg cal. CuSOaAq = - 15.8
214.0 = 198.2 kg cal.
+++ +
Ag
A1
Co+
Ca+
Cd+
Cu+
+
+
+
+
+ 16.0
+108.8
50.2
4.0
+625.0
++ +
+ +
SSrn +
+ +++
$11;:
TI +
+ 1.7
Zn+ +
+ 35.0
- 9.3
0.0
- 19.8
61.8
62.8
+
+
+ 32.7
+ + 37.5
+ 57.3
Mn
Pb+
Rb+
F
He++ + +
Hg
K+
Li
NH4+
NH40
Na+
+121.0
+170.0
+133.?
18.4
- 16.0
- 15.87
22.2
++
cu
Fe+
- 25.3
ASOi--BrBr0,CO,-C1CIOCIOaclo4~~~~~
I-
T A B L E 18l.-lGNl1TlON
+
+
10,-
+
+
szoa--
+215.0
28.2
11.2
+160.8
39.1
26.0
23.4
38.7
+163.0
+143.9
+229.6
+304.8
1.2
+ 27.0
48.9
13.1
+
55.8
+ 46.5
+ 54.4
1 0 4 -
OHPo,---
+298.0
+1386
+2782
+260.8
+151.0
+214.0
- 35.6
+119.6
+144.8
- 34.8
77.0
98.4
- 12.6
SzOe-S,Oe--
+
-
SOa- -
SO,--
+
+
+
+
T E M P E R A T U R E S O F GASEOUS M I X T U R E S
Ignition temperature taken as temperature necessary for hot body immersed in gas to
cause ignition; slow combination may take place at lower temperatures. Gases were
mixed with air. Practically same temperatures as with 0,.
Benzene and air.. ............. 1062" C
Coal gas and air.. ............. 878
CO and air ....................
931
T A B L E 182.-HEATS
O F N E U T R A L I Z A T I O N IN K I L O G R A M C A L O R I E S
The heat generated by the neutralization of an acid by a base is equal, for each gram-molecule
of water formed, to 13.7 kg cal plus the heat produced by the amount of un-ionized salt formed,
plus the sum of the heats produced in the completion of the ionizations of the acid and the base.
Base
KOH.aq .........
NaOH.aq ........
N H 4 0 H . a q .......
f Ca(OH)z.aq . . . . .
1 Zn(OHI2.aq .....
3 Cu(OH),.aq .....
HC1.aq
HNOa,aq
H2S04.aq
HCN%q
CH3COOH-aq
HnCOraq
13.7
13.7
12.4
14.0
9.9
7.5
13.8
13.7
12.5
13.9
9.9
7.5
15.7
15.7
14.5
15.6
11.7
9.2
2.9
2.9
1.3
3.2
8.1
13.3
13.3
12.0
13.4
8.9
6.2
10.1
10.2
8.
9.5
5.5
T A B L E 183.-HEATS
O F D I L U T I O N O F H,SO,
9.42
3
11.14
5
13.11
19
16.26
49
16.68
99
16.86
199
17.06
399
1599
17.86
17.31