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2505
1982
18
i9
4\
0 OMe
23
2506
0.281 4(6)
0.199 O(6)
0.346 2(9)
0.760 3(9)
0.409 2(11)
0.935 8(6)
1.020 6(6)
1.023 l(8)
0.255 l(39)
0.413 3(8)
0.393 0(9)
0.389 6(10)
0.674 3(10)
0.580 O(8)
0.776 7(8)
0.830 8(9)
0.868 8(8)
0.669 2(8)
0.602 6(7)
0.727 9(8)
0.804 8(9)
0.929 0(9)
1.126 7(10)
1.177 l(12)
0.874 l(10)
0.938 9(8)
0.666 7(16)
0.379 8(9)
0.486 9(8)
0.194 6(12)
-0.026 3(12)
0.767 Q(18)
0.613
0.264
0.397
0.706
0.899
0.763
0.716
0.966
0.971
0.726
0.606
0.844
0.681
1.208
1.309
0.738
0.383
0.263
0.376
0.369
0.446
0.638
-0.095
-0.013
-0.102
0.916
0.692
0.694
Y/ b
0.479 6(3)
0.642 l(3)
0.366 2(4)
0.961 l(4)
0.961 3(4)
0.406 9(3)
0.674 6(3)
0.039 6(3)
0.131 2(20)
0.542 7(6)
0.684 2(5)
0.718 6(5)
0.771 8(5)
0.728 O(4)
0.779 3(5)
0.719 9(5)
0.687 9(6)
0.627 4(4)
0.690 6(4)
0.400 8(6)
0.333 6(6)
0.227 6(6)
0.221 l(6)
0.109 3(6)
0.114 9(6)
0.626 O(6)
0.904 2(6)
0.770 3(6)
0.626 7(6)
0.425 9(7)
0.387 3(7)
1.079 3(6)
0.654
0.746
0.742
0.744
0.768
0.864
0.736
0.766
0.678
0.677
0.367
0.403
0.308
0.290
0.078
0.090
0.743
0.738
0.869
0.486
0.610
0.485
0.360
0.318
0.462
1.109
1.113
1.111
B
4c
0.369 5( 1)
0.288 2(1)
0.279 6(2)
0.326 9(1)
0.323 9(2)
0.478 2(1)
0.607 8(1)
0.430 6(1)
0.271 l(7) 14.0 (11)
0.353 l(2)
0.306 3(2)
0.304 6(2)
0.329 6(2)
0.378 6(2)
0.401 2(2)
0.444 6(2)
0.437 7(1)
0.419 6(1)
0.376 6(1)
0.409 3(2)
0.449 4(2)
0.439 O(2)
0.417 6(2)
0.414 O(2)
0.446 6(2)
0.477 6(2)
0.326 9(2)
0.402 2(2)
0.464 8(2)
0.279 O(2)
0.268 2(2)
0.324 8(2)
0.289
4.6
0.318
5.0
0.274
6.0
0.316
4.0
0.381
4.0
0.406
4.0
0.465
4.0
0.455
4.0
0.415
3.6
0.367
3.0
0.397
4.0
0.387
4.0
0.467
4.0
0.407
6.0
0.401
7.0
0.460
6.0
0.433
6.0
0.388
6.0
0.402
6.0
0.443
4.0
0.462
4.0
0.481
4.0
0.296
8.0
0.247
8.0
0.264
8.0
0.326
12.0
0.362
12.0
0.299
12.0
1982
TABLE2
Bond lengths (A) in salvinorin (1)
(standard deviations in parentheses)
1.213(6)
1.437(7)
1.348(9)
1.186(9)
1.343(11)
1.455(8)
1.195( 11)
1.468(6)
1.362(7)
1.199 (6)
1.368(8)
1.357(8)
1.518(7)
1.604(7)
1.624(8)
1.531(8)
1.682(7)
C (4)-C( 18)
c(5)-C(6)
C(5)-C ( 10)
C(5)-C( 19)
C(6)-C(7)
C(7)-C(8)
C(8)--C(9)
C(8)-C (17)
c(9)-c ( 10)
c(9)-c ( 11)
C(9)-C( 20)
C( 11)-C( 12)
C( 12)-C ( 13)
C( 13)-C (14)
C(13)-C( 16)
C(14)-C(15)
C(21)-C(22)
TABLE3
Bond angles (") in salvinorin (1)
(standard deviations in parentheses)
C(2)-0(2)-C(2 1)
C(18)-0 (4)-C( 23)
C(12)-O( 6)-C( 17)
C (16)-0 (8)-C (16)
O(1)-C( 1)-C(2)
o(l)-c(l)-c(lo)
c(2)-C( 1)-c(10)
O(2)-C( 2)-C( 1)
O(2)-C(2)-C( 3)
c(l)-C(2)-C (3)
C ( W C(3)-c (4)
C(3)-c (4)-C (5)
C(3)-C(4)-C(18)
C( 5)-C (4)-C ( 18)
c(4)-c (6)-C(6)
C (4)-C (6)-C (10)
C(4)-C( 6)-C (19)
c (6)-C (5)-C ( 10)
C(6)-C( 6)-C( 19)
c( 10)-c (5)-C ( 19)
C(5)-C (6)-C( 7)
C (6)-C( 7)-C (8)
C(7)-C (8)-C (9)
C(7)-C (8)+ (17)
C(9)-C (8)-C (17)
C(8)-C( 9)-C( 10)
C(8)-C(9)-C( 11)
C(8)-C (9)-C(20)
c( 10)-c (9)-c (11)
c( 10)-c (9)-c (20)
C(11)-c(9)-C( 20)
c 1)-c( 10)-c ( 5 )
c( 1)-c(10)-c (9)
c(5)-C (10)-c (9)
C(9)-C( 11)-C( 12)
O(6)-C( 12)-C( 11)
O(6)-C( 12)-C( 13)
c( 11)-C( 12)-C( 13)
C(12)-C( 13)-C( 14)
C(12)-C( 13)-C( 16)
C( 14)-C ( 13 ) s( 16)
c(13)-C( 14)-c (15)
O(8)-C (16)-C (14)
0(8)-C( 16)-C ( 13)
0(6)-C ( 17)-0 (7)
O(6)-C( 17)-C( 8)
O(7)-C (17)-C( 8)
0(4)-C ( 18)-0 ( 5 )
0(4)-C ( 18)-C (4)
0(5)-C(18)-C(4)
O(2)-C( 2 1)-O( 3)
O(2)-C( 2 1)-C(22)
O(3)-C(2 1)-C( 22)
115.1(6)
115.2(7)
123.9(4)
105.5(6)
121.1(5)
124.7 (4)
114.1(4)
109.7(4)
107.8(4)
110.3(4)
111.3(5)
111.9(4)
109.3( 5 )
112.7(4)
109.2(4)
106.1(4)
109.3(4)
108.6(4)
109.7(4)
113.8(4)
114.3(4)
109.9 (4)
112.9(4)
112.9(4)
111.3(4)
107.0(4)
104.8(4)
109.8(4)
108.9(4)
115.7(4)
110.1 (4)
107.7(4)
115.3(4)
116.6(4)
113.1(4)
112.9(4)
106.4 (4)
113.8(4)
128.2(6)
127.2(6)
104.5( 5 )
108.0(6)
110.6(6)
111.4(5)
117.O(6)
118.4(4)
124.4 (5)
123.8(6)
111.4(7)
124.8(8)
123.1(7)
110.5(6)
126.3(7)
1.507(8)
1.541(7)
1.566(7)
1.544(7)
1.531(8)
1.622(7)
1.648(7)
1.600(7)
1.648(6)
1.534(7)
1.544(7)
1.528(7)
1.473(8)
1.417(8)
1.340(8)
1.313(9)
1.504(11)
2507
1982
-56.5(6)
5 1.3(6)
- 55.9 (6)
60.1 (5)
-- 61.1(5)
62.3(5)
- 50.0(5)
56.1(6)
- 59.7(5)
57.0(5)
- 53.2(5)
50.2(5)
-59.3(5)
61.1(5)
- 41.2(6)
18.9(6)
- 19.3(7)
40.5(6)
- 1.7(7)
1.9(8)
- 1.3(7)
0.1(6)
1.0(6)
- 60.8(6)
123.3(5)
--111.8(6)
64.1 (7)
REFERENCES
1
2508
0 Copyright
1982