Ratanbai Walbai Municipal Junior Science College

Brihanmumbai Mahanagarpalikas Managed & Run by

IIT ians PACE Education Pvt. Ltd.

R.R.T ROAD, OPP SARASWAT BANK, MULUND (W), MUMBAI-80.TeL:-25901499

STD: - XII - 23/12/11

Time: 2 Hrs Marks: 40

Date: CHEMISTRY PAPER II

Note:
1. 2. 3. 4.

All questions are compulsory All question carry equal marks Give balanced equations and draw diagrams, wherever necessary Figures to the right hand side indicate marks.

Q.1. Select and write the most appropriate answer from the given alternatives for each sub-questions:
[08 M] 1. Which of the following is used as an antiseptic a. Bleaching power b. Thymol c. Tincture iodine d. Chloroform 2. In esterification reaction, conc.H2SO4 act as a. Dehydrating agent b. Hydrating agent c. Catalyst d. Sulphonating agent 3. Which of the following amines give yellow oily liquid with nitrous acid a. Ethyl amine b. Methyl amine c. Diethyl amine d. Triethyl amine 4. Ethanol and phenol are distinguished from each other , by the action of a. Neutral ferrous chloride b. Neutral ferric chloride c. Ferric hydroxide d. Ferrous hydroxide 5. Which of the following statements is correct about SN2 mechanism? a. Two step reaction b. Complete inversion of configuration c. Formation by polar solvent d. Favoured by polar solvent 6. A + B Dryether Complex H2O/H+ Ethyl methyl ketone. In above reaction , A and B are a. Formonitril, Propyl magnesium bromide b. Ethyl cyanide, Ethyl magnesium bromide c. Hydrogen cyanide, Ethyl magnesium bromide

d. Acetonitrile, Ethyl magnesium bromide. 7. Colour of tripositive ion of lanthanides series elements are due to a. Lanthanide contraction b. Their catalytic properties c. Number of unpaired electrons in 4f orbitals. d. Uniform +3 oxidation state 8. Which of the following is NOT true about Glucose? a. It is monosaccharide b. It is polyhydroxide aldehyde c. It is polyhydroxy ketone d. It contains six carbon atoms.

Q.2.(A) Attempt any ONE:

1. How will you convert glucose into a. Gluconic acid b. Saccharic acid

[ 02 M]

2. What are antibiotics ? What is the difference between bactericidal and bacteriostatic antibiotics?

(B) Attempt any ONE:

1. Why does the basicity of hydroxides of lanthanide series elements decrease with increase in atomic number? 2. State and explain Markownikoff,s Rule with a suitable example.

[02 M]

(C) Answer the following:

2. What is the action of ammonia on a. Acetaldehyde b. Formaldehyde

1. From methyl magnesium iodide , how are the ethanol and propan-2-ol are prepared?

[04 M]

Q.3.(A) Answer any ONE:

1. What are synthetic fibres/ How is terylene prepared? 2. Define asymmetric carbon atom and explain optical activity of 2-chlorobutane

[ 03 M]

(B) Answer any ONE:

1. What is the action of the following on phenol? a. Bromine in CS2 b. Conc.HNO3 in presence of Conc. H2SO4 c. Conc. H2SO4at room temperature 2. How will you prepare ethanal from 1,1-dichloroethane?What is the reaction of acetaldehyde with a. Ammonical silver nitrate b. Fehlings solution

[03 M]

(C ) Answer the following:

1. How will you prepare diethyl ether by continuous etherification process?

[02 M] [04 M]

Q.4. (A) Answer the following:

Explain the terms:

1. Heterolytic fission 2. Electromeric effect

(B) Answer any ONE :

1. How will you bring about following conversions? a. Acetic acid to acetyl chloride b. Methyl cyanide to acetic acid c. Acetyl chloride to ethyl acetate d. Ethyl iodide to ethyl acetate

[04 M]

2. What are amine ? What is the action of acetyl chloride on ethanamine, N-ethyl ethanamine and N,N-Dimethyl ethanamine?

1. What are ethers/ Classify proteins on the basis of hydrolysis products and give examples. 2. How will you prepare trichloromethane (Chloroform) from ethanol?

Q.5.(A) Attempt any ONE:

[04 M]

(B) Attempt any TWO:

1. What is the action of following on 2-methyl propan-2-ol? a. 20% H2SO4 at 360 K b. NaBr and Conc.H2SO4 2. Write a note on cannizzaros reaction. 3. Write the outer observed electronic configuration of : a. Gadolinium(64) b. Ytterbium (70)

[04 M]