JMS 2 PAPER - 2

PAPER-2
Maximum Marks: 80

Question paper format and Marking scheme: 1. In Section I (Total Marks: 24), for each question you will be awarded 3 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks if no bubble is darkened. In all other cases, minus one (1) mark will be awarded. 2. In Section II (Total Marks: 16), for each question you will be awarded 4 marks if you darken ALL the bubble(s) corresponding to the correct answer(s) ONLY and zero marks other wise. There are no negative marks in this section. 3. In Section III (Total Marks: 24), for each question you will be awarded 4 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks otherwise There are no negative marks in this section. 4. In Section IV (Total Marks: 16), for each question you will be awarded 2 marks for each row in which you have darken ALL the bubble(s) corresponding to the correct answer(s) ONLY and zero marks otherwise. Thus each question in this section carries a maximum of 8 Marks. There are no negative marks in this section.

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JMS 2 PAPER - 2

SECTION I (Total Marks : 24) (Single Correct Answer Type)

This Section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct. 1. Choose the incorrect statement. (A) C6H6 is more reactive than C6D6 towards nitration (B) C6D6 is more reactive than C6T6 towards sulphonation (C) C6H6 is more reactive than C6D6 towards sulphonation (D) C6D6 and C6H6 have equal reactively towards nitration Octane, C8H18 a constituent of gasoline burns according to the equation. 1 C8H18 (l) + 12 O2 (g) 8 CO2(g) + 9 H2O(l) 2 0.257 g of C8H18 was burnt in the presence of excess O2 in a bomb calorimeter. The heat capacity of the calorimeter was 1.726 x 103 J/oC. The temperature of the calorimeter and 1.2 x 103 g of water rose from 21.22oC to 23.05oC. The heat of combustion per mole of octane is A) - 6266.9 KJ mole1 B) - 5476.9 KJ mole1 C) - 5269.9 KJ mole1 D) - 4572.9 KJ mole1

2.

3. Which of the following set of reagents is the most appropriate to perform the above conversion (A)HIO ; OH ; ZnHg/conc HCl
4

(B) Cold, alkaline KMnO4; Pb(OAC)4, OH; Li/Liq. NH3 (C) O , (CH ) S; OH; Li/Liq NH
3 3 2 3

(D) KMnO4, H+; OH; ; NH2 NH2, OH , 150oC 4. The height of a HCP unit cell is 5.715 0A. Volume of the unit cell in A0 ? A) 91 B) 182 C) 273 D) 82.5
3

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JMS 2 PAPER - 2
5. Identify A in the following scheme.
A(C 7 H14O) 2 o alcohol
H+,

B (C 7 H12 )

O 3 / Zn , CH 3COOH 6 oxo hep tan al

CH 3
OH

(A)

(B)

HO
CH 3

CH 3 CH 3

CH 3

OH

(C)

OH

(D)

CH 3

6.

Calculate the cell emf in mV for pt, H2 (1 atm) / HCl (0.01 M) / AgCl (s) / Ag (s) at 298 K if G 0 values at 25 0C are -109.56 KJ mole-1 for AgCl and -130.79 KJ mole-1 for f

(H

+ Cl ) aq.

(A) 456

(B) 654

(C) 546

(D) 564

7.

Match the following. Column-I

(a) (b) (c) (d) H2S2O2 H2S2O3 H2S2O4 H2S2O7 (P) (Q) (R) (S)

Column-II SOS linkage Diprotic S = S linkage S S linkage

A) a-R,S; b-P,S; c-Q; d-P,R B) a-Q,R; b-Q,R; c-Q,S; d-P,Q C) a-P,Q; b-P,Q; c-P,S; d-R,S D) a-Q,R; b-P,S; c-Q,R; d-P,S

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JMS 2 PAPER - 2
8. For the reaction, A Products
1 1 1 k= t a x a
1

A graph between (ax) and time t is of the type

p (a x )
(A)
1

p (a x ) 1

t
(a x ) 1 p

(B)

t
p (a x )
1

(C)

(D) SECTION II (Total Marks : 16)

(Multiple Correct Answer(s) Type)

This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONE OR MORE may be correct. 9. When a mxiture of NaCl and K2Cr2O7 is heated with conc. H2SO4. A) A deep red vapour is evolved B) The vapour when passed into NaOH solution gives a yellow solution of Na2CrO4 C) Deep red vapour is of chromyl chloride D) Chlorine gas is evolved 4NH 3 +5O 2 4NO+6H 2 O ; if reaction starts with 3mole of NH3 and X mole of O2 (obtained by complete decomposition of 5 lit H2O2 solution of 11.2 volume strength), then choose the correct option (A) Oxygen is limiting reagent (B) 2 mole of NO is formed after complete reaction (C) Normality of H2O2 solution is 2 (D) % strength of H2O2 solution is 3.4 Which of the following polymers do not have ester linkage (A) Nylon (B) Bakelite (C) Teflon Phosphine is obtained, when A) Red P is heated with NaOH C) Ca3 P2 reacts with water (D) Terylene

10.

11.

12.

B) White P is heated with NaOH D) Phosphorus trioxide is treated with hot water Page 4

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JMS 2 PAPER - 2
SECTION-III (Total Marks : 24) (Integer Answer Type) This section contains 6 questions. The answer to each of the questions is a single-digit integer, ranging from 0 to 9. The bubble corresponding to the correct answer is to be darkened in the ORS. 13.
heat 3B2 H 6 + 6NH3 3X 2Y + 12H 2 .In the anionic part of the intermediate X, the covalency of the central atom is

14.

3 atoms of hydrogen are excited from ground state to n = 4,then maximum number of different radiations,when all H atoms come at ground state finally is The number of organic products obtained when but-1-ene reacts with Cl2 in CH3OH medium containing LiBr is Air contains O2 and N2 in the ratio of 1 : 4. The ratio of their solubilities in terms of mole fractions at atmospheric pressure and room temperature is Z x 10-1. Z is (Given, Henrys constant for O2 = 3.3 107 torr, for N2 = 6.6 107 torr) n-Butylethanoate when heated to high temperature produces a hydrocarbon. The number of carbon atoms in the hydrocarbon is The approximate change in pH when a 0.1M solution of CH3COOH in water at 25 0C is diluted to a final concentration of 0.01 M is Z x 10 -1 ( K a = 1.85 105 , log1.36 = 0.1335, log 4.3 = 0.6335)

15.

16.

17.

18.

SECTION-IV (Total Marks : 16) (Matrix-Match Type) This section contains 2 questions. Each question has four statements (A, B, C and D) given in Column I and five statements (p, q, r, s and t) in Column II. Any given statement in Column I can have correct matching with ONE or MORE statement(s) given in Column II. For example, if for a given question, statement B matches with the statements given q and r, then for the particular question, against statement B, darken the bubbles corresponding to q and r in the ORS. 19. Match the following. (A) (B) (C) (D)

-decay

Column-I (P) (Q) (R) (S) (T)

-decay
Positron emission K-electron capture

Column-II Results in increase of n/p ratio Results in decrease of atomic number by 1 Accompanied by emission of a neutrino Results in production of Xrays Does not affect mass number Page 5

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JMS 2 PAPER - 2
20. Match the reactions in column I with appropriate types of steps/reactive intermediate involved in these reactions as given in column II. Column-I (A) (P) Column-II Product formation through intramolecular reaction Reaction has carbanion intermediate Product is keto ester Aldol product is not formed in given condition

(B) (C)

O || OH Ph C H
O C2H5O || CH3 C O C2H5 C2H5 OH
O || C OC H 2 5

(Q) (R)

(D)

(S)

O
O C2H5

C2H5ONa+ C2H5OH

(T)

Product is aldol

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