FIITJEE

MOCK TEST

for XII
th
Board CBSE

CHEMISTRY



Time allowed: 3 hrs. Maximum Marks: 70



General Instructions:

(i) All questions are compulsory.

(ii) There is no overall choice. However, an internal choice has been provided in one question of two
marks, one question of three marks and three questions of five marks. You have to attempt only
one of the choices in such questions.

(iii) Question Nos. 1 to 8 is very short answer type questions of 1 mark each. Answer them in one
word or about one sentence each.

(iv) Question Nos. 9 to 18 are short answer type questions of 2 marks each. Answer them in about 30
words each.

(v) Question Nos. 19 to 27 are short answer type questions of 3 marks each. Answer them in about
40 words each.

(vi) Question Nos. 28 to 30 are long answer type questions of 5 marks each. Answer them in about
70 words each.

(vii) Use Log tables if necessary.

Mock Test (2009)XII
th
(CBSE) Chemistry (S)2

1. In the following pairs of halogen compounds, which would undergo
N
S 2 reaction faster?

CH
2
Cl and
Cl


2. Among the following compounds the strongest acid is
(A) CHCH (B) C
6
H
6

(C) C
2
H
6
(D) CH
3
OH

3. Mention a chemical property in which methanoic acid differs from acetic acid.

4. Give one example of anthraquinone dye.

5. What are the coordination numbers of each of the ions present in the cubic close packed structure of CaF
2

at ordinary temperature and pressure?

6. Consider the reaction ( ) ( ) ( )
2 5 2 2
2N O g 4NO g O g . + When a graph is plotted between rate of reaction
against the concentration of N
2
O
5
the following figure is obtained. What would be the order of reaction?
Conc. of (N
2
O
5
)
R
a
t
e


7. What type of hybrid orbitals are associated with
(i) Ni atom in [Ni(CN)
4
]
2
(ii) C atom in
2
3
CO



8. The standard reduction potential values of three metal cations X
a+
, Y
b+
and Z
c+
are +0.52, 3.03, 1.18 V
respectively. Arrange the corresponding metals in the order of their reducing power.

9. Describe the functions of antibiotics and antiseptics. Give one example of each.

10. What is the effect of increasing pH of a solution of potassium dichromate?

11. Name the alkyl halide and sodium alkoxide to synthesize ethyl tertbutylether.

12. On the basis of following
0
r
G A values at 1073 K:
( ) ( ) ( )
0 1
2 2 2 r
S s 2O g 2SO g ; G 544kJ mol ...(1)

+ A =
( ) ( ) ( )
0 1
2 r
2Zn s O g 2ZnO s ; G 480kJ mol ...(2)

+ A =
( ) ( ) ( )
0 1
2 r
2Zn s S s 2ZnS s ; G 293kJ mol ...(3)

+ A =
Show that the roasting of zinc sulphide to form oxide is a spontaneous process.

13. Write the chemical reaction for each to show that
(i) Tin (II) chloride is a reducing agent.
(ii) Chlorine gas can be obtained from bleaching powder.

14. Write structures of monomers used for getting the following polymers?
(i) Bakelite
(ii) Teflon
Mock Test (2009)XII
th
(CBSE) Chemistry (S)3
15. Give the structures and IUPAC names of product expected from the following reactions
(a) Hydroboration of but1ene
(b) Hydration of propene in presence of dilute sulphuric acid
OR
(a) You are given benzene, conc. H
2
SO
4
and NaOH. Write the equations for the preparation of phenol
using these reagents
(b) Convert propan -1-ol to 1- propoxypropane

16. Using the standard electrode potential predict if the reaction between Fe
+3
(aq)
and Br
-
(aq)
is feasible
Given
3+ 2+ -
2

Fe /Fe Br /Br
E = 0.77volt E = 1.09Volt

17. Draw simple Fischer projections of D-and L-glucose. Are these enantiomers?

18. What are biodegradable and nonbiodegradable detergents? What are the consequences of using latter class
of detergents?

19. Calculate the standard free energy change G

A for the reaction,

( ) ( ) ( )
2 2
1
CO g O g CO g ; H 282.8 kJ
2

+ A =
Given: Standard entropies of CO
2
, CO and O
2
are 213.6, 197.6 and 205 JK
1
mol
1
respectively. Predict
whether the reaction is feasible or not at standard state.
OR
Aluminium crystallizes in an cubic close packed structure. Its metallic radius is 125 pm.
(a) What is the length of the side of the unit cell?
(b) How many unit cell are there in 1.00 cm
3
of aluminium?

20. What happens when (give only ionic equation)
(a) potassium manganate is treated with ozone
(b) sodium thiosulphate is treated with acidified K
2
Cr
2
O
7

(c) potassium iodide is treated with acidified potassium dichromate solution

21. In the cubic crystal CsCl (d = 3.97 g/cm
3
) the eight corners are occupied by Cl

with a Cs
+
at the centre and
vice versa. Calculate the distance between the neighbouring Cs
+
and Cl

ions. What is the radius ratio of the

two ions? (Atomic weight of Cs = 132.9 and Cl = 35.46)

22. Describe the following
(a) Transesterification
(b) Cross aldol condensation
(c) Hoffmann bromamide reaction

23. Distinguish physisorption from chemisorption.

24. Draw figures to show splitting of degenerate d-orbitals in an octahedral and in a tetrahedral crystal field.

25. The molar freezing point depression constant of benzene (C
6
H
6
) us 4.90 Kkg mol
1
. Selenium exists as a
polymer of the type
x
Se . When 3.26 g of selenium is dissolved in 226 g of benzene, the observed freezing
point was 0.112
o
C lower than for pure benzene. Deduce the molecular formula of selenium.
(At. mass of Se = 78.8 g mol
1
).

26. How would you convert?
(a) Chlorobenzne to phenol
(b) Phenol to 4-bromophenol
(c) Phenol to 2-acetoxybenzoic acid (Aspirin)

Mock Test (2009)XII
th
(CBSE) Chemistry (S)4

27. Write short notes on
(i) Brownian movement
(ii) Hardy and Schultz rule

28. An organic compound (A) with molecular formula C
9
H
10
O forms orange red precipitate on heating with
iodine in presence of sodium hydroxide. It does not reduce Tollens reagent or Fehling solution, nor it
decolourises bromine water or Baeyers reagent. On drastic oxidation with chromic acid, it gives a
carboxylic acid (B) having molecular formula C
7
H
6
O
2
. Identify the compounds (A) and (B) explain the
reaction involved.
OR
(a) Write the general formula for nitroalkanes and for alkyl nitrites.
(b) How are nitroalkanes prepared alkanes?
(c) What happens when:
(i) Nitroethane is treated with lithium aluminium hydride.
(ii) Nitrobenzene is reduced with hydrogen using copper oxide as catalyst.
(d) Write two uses of nitroalkanes, one each in the laboratory and in the industry.

29. (a) Calculate the value of Avogadro constant from the following data:
Density of NaCl = 2.165 g cm
3

Distance between Na
+
and Cl

in NaCl = 281 pm
(b) The enthalpy of vapourisation of benzene is 30.8 kJmol
1
at its boiling point (80.1
o
C). Calculate the
entropy change in going from (i) liquid to vapour (ii) vapour to liquid at 80.1
o
C.
OR
(a) Use molecular orbital theory to explain why the Be
2
molecule does not exist.
(b) 2 gm of CH
3
COOH dissolved in 25 gm of benzene shows a depression in freezing point equal to 1.62
K. Molar depression constant for benzene is 4.9 K Kgmol
1
. What is the percentage association of acid
if it forms double molecules (dimer) in solution?

30. Account for the following
(a) (i) Fluorine is the strongest oxidant amongst the halogens?
(ii) Among the noble gases, only Xenon is known to form true chemical compounds
(b) Describe the preparation of ClO
2
, HOCl, XeF
4
.
OR
(a) Account for the following
(i) Phosphinic acid behave as monoprotic acid
(ii)
2
6
SiF

is known but
2
6
SiCl

is not.
(b) Arrange the following in the order of property indicated for each set:
(i) HOCl,
2
HClO ,
3
HClO
4
HClO (increasing acid strength)
(ii)
2 2 2 2
F , Cl , Br , I (increasing bond energy)
(iii)
3 3 3 3 3
NH , PH , AsH ,SbH , BiH (increasing basic strength)