SULIT 4541/1 Chemistry Mac 2012 1jam UJIAN PENILAIAN 1 TINGKATAN 5 ______________________________________________

4541/1

KIMIA Kertas 1 Satu jam

JANGAN BUKA KERTAS SOALAN INI HINGGA DIBERITAHU 1. 2. 3. 4. Kertas soalan ini 1 bahagian soalan. Jawab semua soalan Bagi setiap soalan, jawab pada ruangan yang disediakan Anda dibenarkan menggunakan kalkulator saintifik yang tidak boleh diprogramkan.

Prepared by,

Checked by,

........................................ (NAZREEN BT NASHRUDDIN)

......................................... (PN. ROBEATON ADON)

Answer all question Section A :Choose the correct answer in the space provided 1. Which of the following is an organic compound? A. Carbon dioxide B. Ethanol C. Calcium carbonate D. Potassium cyanide 2. A hydrocarbon is an organic compound consisting of A. Carbon and hydrogen B. Carbon and oxygen only C. Carbon, hydrogen and oxygen only D. Carbon, hydrogen, oxygen and nitrogen only 3. Which of the following statements is not true about hydrocarbons A. Contains only the carbon and hydrogen B. Obtained from the fractional distillation of petroleum C. Produces carbon dioxide and water when burned D. All exist as gas because of low boiling point 4. The following information shows four different types of hydrocarbon Methane Ethane I. II. III. Propane Butane

All the compounds exist as gases at room temperature The melting point increases from methane to butane The number of molecules per one mole of compound increases from methane to butane IV. Each subsequent member differs by CH2 A. II and IV only B. I, II and III only C. I, II and IV only D. II, III and IV only

5. The reaction between compound X and bromine gas to produce 2-bromo-2methylpropane is shown in the equation below H X + Br2 Br H

H C C C H + HBr

H CH3 H Which of the following is the molecular formula of compound X? A. CH3CH2CH3 B. CH3CHCH2 C. CH3C(CH3)CH2 D. CH3CH(CH3)CH3 6. Methane reacts with chlorine gas as shown in the following equation : CH4 + Cl2 CH3Cl + HCl In this reaction, methane undergoes A. Oxidation B. Reduction C. Substitution D. Addition 7. In the homologous series alkane, the number of carbon atoms increases down the group. Which of the following is true about the properties of the members of this series at room conditions? I. More reactive II. Molecular mass increases III. Melting and boiling point increases IV. Density increases A. B. C. D. I, II and III only I, II and IV only II, III and IV only I, II, III and IV

8. Which of the following equations represents complete combustion of ethane? A. C2H6 + 3 O2 2C + 3H2O 2 B. 2C2H6 + 7O2 4CO2 + 6H2O C. 2C2H6 + 5O2 4CO2 + 6H2O D. C2H6 + 3O2 CO + CO2 + 3H2O

9. Which of the following comparisons on alkanes and alkenes is not true?

Alkanes A Insoluble in water B Do not decolourize brown coloured bromine water C React with chlorine by substitution D Have a general formula CnH2n+2 Alkenes Soluble in water Decolourize brown coloured bromine water React with chlorine by addition Have a general formula CnH2n

10. What type of reaction occurs when the product from the dehydration of ethanol, reacts with hydrogen in the presence of a catalyst? A. Addition B. Oxidation C. Polymerisation D. Substitution 11. What is the IUPAC name for the hydrocarbon with the structural formula as shown below? H H H

HCC=CCH H H HCH H A. B. C. D. 2,3-dimethylpentane 2-methylbut-2-ene 3-methyl-but-2-ene 2-methylpent-2-ene

12. Which of the following are isomers? I. 2-methylpentane II. 3-methylpentane III. 2,2-dimethylbutane IV. 2,3-dimethylbutane A. B. C. D. I and II only I and III only I, II and III only I, II, III and IV

13. Diagram 1 below shows the stuctural formula of pentene H H H H H

HC=CCCCH H H H

Diagram 1 How many isomers can pentene have? A. 4 B. 5 C. 6 D. 7 14. Isomers are A. Compound with the same molecular formula and the same structural formula B. Compound with the same molecular formula but different structural formula C. Compound with the same structural formula but different molecular formula D. Compound with the different structural formula and different molecular formula 15. Diagram 2 shows the apparatus set up to prepare a carbon compound

The carbon compound that is produced A. Burns with a sooty flame B. Does not dissolve in water C. Has a double bond in its structural formula D. Decolourises acidified potassium manganate(VII) solution 16. What is the functional group for 2-methylbutan-1-ol? A. Carboxylate B. Diol C. Hydroxide D. Hydroxyl

17. A mixture of grape juice and yeast is kept at 35C for three days. What are the products formed? A. Ethanol and water B. Ethanoic acid and oxygen C. Ethanol and carbon dioxide D. Starch and carbon dioxide 18. Compound X has the following properties :
Complete combustion produces carbon dioxide gas and water Very miscible in water Can be prepared from alkene

What is the molecular formula of compound X? A. C2H6 B. C2H5OH C. HCOOCH3 D. CH3COOH 19. Which of the following is the physical property of ethanol? A. Fruity smell B. Low boiling point C. Insoluble in water D. Turns lime water milky 20. The following flow chart shows the conversion of ethanol to ethene and ethanol to ethanoic acid Ethene Process I Process II Ethanol Ethanoic acid

What are Process I and Process II? Process I A. B. C. D. Oxidation Dehydration Fermentation Esterification Process II Esterification Oxidation Dehydration Fermentation

Section B : Answer all the question given 1. In diagram below, X and Y are the structures of two hydrocarbon molecules that have the same number of hydrogen and carbon atoms

H H H

H HCH H H

HC=CCCH H H

HC=CCH H X a) i ) Y What are X and Y known as? _________________________________________________________ (2 marks) Name each of hydrocarbons X and Y X : ______________________________________________________ Y : ______________________________________________________ (2 marks) Name another hydrocarbon that has the same molecular formula as X and Y but with different structural formula _________________________________________________________ (1 mark) Draw the structural formula of the hydrocarbon named in (a)(iii)

ii)

iii)

iv)

(1 mark)

b) X will react with steam(water) to form an alcohol under the following conditions : Temperature : 300C Pressure : 60 atmosphere Catalyst : Phosporic acid i) Name the alcohol ________________________________________________________ (1 mark) Name the reaction involved in this process ________________________________________________________ (1 mark) Write a balanced equation to represent the reaction

ii)

iii)

(2 marks) 2. Table 1 shows the molecular formula and boiling points for three compounds, which are members of a homologous series
Compound P Q R Molecular formula C2H5OH C3H7OH C4H9OH Boiling point (C) 78 97 118

Table 1 a) i ) Name the homologous series for these compounds ________________________________________________________________ (1 mark) ii) Write the general formula for this homologous series ________________________________________________________________ (1 mark) b) Explain why the boiling point for the members of this homologous series increases when the number of carbon atoms per molecule increases _____________________________________________________________________ _____________________________________________________________________ _____________________________________________________________________ (3 marks)

3. Alkene is an unsaturated hydrocarbon a) What is meant by unsaturated hydrocarbon ? __________________________________________________________________ (2 marks) b) Write the chemical equation for the complete combustion of propene __________________________________________________________________ (1 mark) c) Draw the structural formula of one isomer of butene and name the isomer

(2 marks)

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