Академический Документы
Профессиональный Документы
Культура Документы
2500
2000
Actual Thickness
Regressed Thickness() = 57783.15*{Spin Speed(RPM)}-0.53
1500
1000
500
1.2
0.8
0.6
0.4
0.2
0
250 300 350 400 450 500 550 600 650 700
1.2
0.8
0.6
0.4
0.2
0 250 300 350 400 450 500 550 600 650 700
1.2
0.8
MEH-DOO-PPV(2) MEH-DOO-PPV(3)
0.6
0.4
0.2
0 250 300 350 400 450 500 550 600 650 700
arbitrary units
0.2
0.1 0 350 400 450 500 550 600 650 700
wave length
Photoluminescence (a.u.)
350
450
550
650
750
1.2
0.8
M3EHPPV(1)
Photoluminescence (a.u.)
0.6
M3EHPPV(2)
M3EHPPV(3)
0.4
0.2
1.2
0.8
MEH-DOO-PPV(1)
MEH-DOO-PPV(2)
Photoluminescence (a.u.)
0.6
MEH-DOO-PPV(3)
0.4
0.2
0
250 -0.2 350 450 550 650 750
Electroluminescence (a.u.)
2.5
1.5
0.5
Figure 3.* Electroluminescent response of all the PPVs juxtaposed on the same axes.
absorption (a.u.)
PCBM C60
450
500
wave length
12
10
Absorptance (a.u.)
MEHPPV(PCBM 20%)
1.2
Absorptance (a.u.)
0.8
0.6
0.4
0.2
0 250 300 350 400 450 500 550 600 650 700
wavelength (nm)
1 0.9 0.8
Absorptance (a.u.)
250
300
350
400
450
500
550
600
650
700
1
0.9 0.8
Photoluminescence (a.u.)
0.1
0 350 -0.1 400 450 500 550 600 650 700 750 800
1.4
1.2
0.8
0.6
0.4
0.2
1.2
Photoluminescence (a.u.)
0.8
0.6
0.4
0.2
0 250 -0.2 300 350 400 450 500 550 600 650
2 1.8
Electroluminescence (a.u.)
1.6 1.4 1.2 1 0.8 0.6 0.4 0.2 0 500 550 600 650 700
750
800
2.5
Electroluminescence (a.u.)
1.5
0.5
0
500 550 600 650 700 750 800
2.5
Electroluminescence (a.u.)
1.5
MEH-DOO-PPV 5% PCBM composite 10 % PCBM Composite 20% PCBM Composite 30% PCBM Composite
0.5
500
550
600
650
700
750
800
0.5
0.4
0.3
0.2
0.1
Voltage
-0.2
0.6
0.5
0.4
0.3
0.2
0.1
-0.1
Voltage (V)
-0.2
mA/cm2
0
-0.1
0.2
0.4
0.6
0.8
1.2
Voltage
0.6
0.5
0.4 0.3 0.2 0.1 0 0 -0.1
0.2
0.4
0.6
0.8
1.2
1.4
Voltage (V)
-0.2
0.6 0.5 0.4 0.3 0.2 0.1 0 0 -0.1 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
-0.2
Voltage
1.2
0.8
0.6
0.4
0.2
-0.2
Voltage (V)
n (refractive index)
1.8
0.6
0.5
0.4
0.3
0.2
0.1
2.2
Real Part of Refractive Index of MEHPPV and its composite with PCBM
1.8
1.6
1.4
1.2
450
500
550
600
650
700
750
800
850
Imaginary part of Refractive index for MEHPPV and its composite with PCBM
MEHPPV 5% PCBM 10% PCBM 20% PCBM 30% PCBM
500
550
600
650
700
750
800
850
Real part of Refractive index for M3EHPPV and its composite with PCBM
2.2
1.8
1.6
1.4
1.2 450 500 550 600 650 700 750 800 850
0.8
Imaginary part of Refractive index for M3EHPPV and its composite with PCBM
M3EHPPV 5% PCBM 10% PCBM 20% PCBM 30% PCBM
450
500
550
600
650
700
750
800
850
2.2
Real part of Refractive index for MEH-DOO-PPV and its composite with PCBM
2.1
1.9
1.8
1.7
1.6
1.5
1.4 400 450 500 550 600 650 700 750 800
0.4
Imaginary part of Refractive index for MEH-DOO-PPV and its composite with PCBM
MEH-DOO-PPV 5% PCBM 10% PCBM 20% PCBM 30% PCBM
0.35 0.3
0.25 0.2
0.15 0.1
0.05 0 400 450 500 550 600 650 700 750 800
0.0001
(cm2/Vs)
1E-05
E1/2 (V1/2/cm1/2)
10
Heat Flow
Endo
0 20 30 40 50 60 70 80 90 100
Temperature in (oC)
10
Heat Flow
Endo
3 20 30 40 50 60 70 80 90 100
Temperature in (oC)
10
9.5
8.5
Heat Flow
7.5
6.5
Endo
6 5.5
5 20 30 40 50 60 70 80 90 100
Temperature in (oC)
7 6
5 4 3 2 1
0
0 0.5 1 1.5 2 2.5 3
Bias (V)
Bias (V)
7 6
5 4
3
2 1 0
0.5
1.5
2.5
3.5
Bias (V)
Capacitance as a function of frequency for MEHPPV and its 1.60E-09 composites with PCBM
1.40E-09 1.20E-09
Capacitance (F)
1.00E-09
8.00E-10
6.00E-10 4.00E-10 2.00E-10 0.00E+00
5
Log 10 Frequency
Capacitance as a function of frequency for M3EHPPV and its 1.80E-09 composites with PCBM
1.60E-09 1.40E-09
Capacitance (F)
6.00E-10
4.00E-10 2.00E-10 0.00E+00
Log 10 Frequency
Capacitance as a function of frequency for MEH-DOO-PPV 2.00E-09 and its composites with PCBM
1.80E-09 1.60E-09
Capacitance (F)
1.40E-09 1.20E-09
1.00E-09
8.00E-10 6.00E-10 4.00E-10 2.00E-10 0.00E+00
Log 10 Frequency
200
400
600
800
1000
1200
1400
1600
800 700
600 500 400 300 200 100 0 0 -100 200 400 600 800 1000 1200 1400 1600 M3EHPPV 5% PCBM 10% PCBM 20% PCBM 30% PCBM
200
400
600
800
1000
1200
1400
1600
1.4
1.2
Intensity (a.u.)
0.8
0.6
0.4
0.2
0 0 5 10 15 20 25 30 35
2 theta
Intensity (a.u.)
2 theta
Intensity (a.u.)
500
400
300 200 100 0 0 5 10 15
PCBM peaks
20
25
30
35
40
2 theta
800
Intensity (a.u.)
500
PCBM peaks
2 theta
Intensity (a.u.)
2 theta
800
600
Intensity (a.u.)
500
400
300
200
100
0 0 5 10 15 20 25 30 35
2 theta
Intensity (a.u.)
500
400 300
200 100 0 0 5 10 15 20 25 30 35 40
2 theta
600
500
Intensity (a.u.)
400
300
200
100
0 0 5 10 15 20 25 30 35 40
2 theta