1. A sample of unknown metal was found to have a mass of 4.78 grams and volume o f 1.77 milliliters. a.

What is the density of the unknown metal?

b. What is the specific heat of the unknown metal if the addition of 1,200 J of heat causes an increase in the temperature of the metal of 280C?

2. Potassium hydrogen phthalate (or KHP) is an organic compound used in titratio n experiments as a standardized acid. A student is asked to prepare a standardized acid solution and titrate it with a base of unknown concentration. a. If the chemical formula of KHP is KHC8H4O4, what is the formula weight of potassium hydrogen phthalate?

b. If the student measures 1.6514 grams of KHP on an analytical balance, how man y moles of KHP were measured?

c. If the mass of KHP measured in Part B above was dissolved in 25 milliliters o f water, what is the resulting concentration of the solution?

3. Hydrochloric acid is a strong acid that dissociates completely in water. a. Write a complete and balanced reaction for the dissociation of hydrochloric a cid in water.

4. Epsom salts are sold commercially as MgSO47H2O. When heated, MgSO47H2O releases water according to the following reaction: MgSO47H2O(s) . MgSO4(s) + 7 H2O(g) a. What is the chemical name of Epsom salts?

b. What is the percent composition of water in MgSO47H2O?

c. If 62.56 grams of MgSO47H2O are heated and 1.776 moles of water are released, what was the mass of MgSO4 produced in the reaction?

5. The element oxygen was first isolated by Joseph Priestley in 1774 by decompos ing HgO according to the following reaction: 2 HgO(s) . 2 Hg(l) + O2(g) a. What is the chemical name of HgO?

b. What is the reaction temperature in degrees K?

c. If 65.00 grams of HgO were decomposed at 250C and 60.20 grams of Hg were produced from the reaction, what was the mass of O2 produced?

d. At the reaction temperature, a volume of 6.44 liters of oxygen was collected. When cooled to room temperature (273.15K), what was the volume of oxygen collected?

6. For the following reactions, balance the chemical equation. Identify the spec ies that corresponds to the acid, base, and salt. a. Ba(OH)2(aq) + H3PO4(aq) Ba2+(aq) + PO43-(aq) + H2O(l) Description: http://ric hardbowles.tripod.com/chemistry/rarrow.gif

Acid => Base => Salt => b. H2SO4(aq) + NH4OH(aq) NH4+(aq) +SO42-(aq) + H2O(l) Description: http://richar dbowles.tripod.com/chemistry/rarrow.gif

Acid => Base => Salt =>

7. Sodium acetate is a salt formed in the neutralization reaction between acetic acid (a weak acid) and sodium hydroxide (a strong base). a. Write a balanced chemical equation for the formation of sodium acetate.

8. For each of the following reactions, balance the chemical equation. Identify the species that was oxidized, the species that was reduced, and the number electrons transf erred. a. Mg (s) + HCl (aq) MgCl2 (aq) + H2 (g) Description: http://richardbowles.tripo d.com/chemistry/rarrow.gif

Oxidized => Reduced => Electrons transferred => b. Fe2O3 (s) + CO (g) Fe (s) + CO2 (g) Description: http://richardbowles.tripod. com/chemistry/rarrow.gif

Oxidized => Reduced => Electrons transferred => 9. For the following molecules or ions, give the name of the species indicated. Indicate the electron geometry and molecular shape of each molecule or ion. (Draw dot structu re if needed) a. NH4+

b. PCl5

c. O3

d. H3O+

10. For the following molecules, give the name of the species and indicate wheth er the molecule is polar or nonpolar. Identify all applicable intermolecular forces. a. PCl3

b. SO2

c. H2S

d. CH2O

11. For the following nuclear equation, complete and balance the equation and pr edict the type of radioactive decay. Description: Picture17 Description: Picture17 Description: Picture17

Description: Picture18 Description: Picture18 Description: Picture18

Description: Picture20 Description: Picture20 Description: Picture20 12. The element chlorine is composed of two stable isotopes, Cl-35 and Cl-37. If the percent abundance of isotope Cl-35 is 75.77% and the percent abundance of isotope Cl-37 is 24.23%, what is the average atomic mass of chlorine?

13. Name the type of the atomic orbital shown and indicate the value of the quan tum number l for the orbital.

Description: 09_09

14. Write the full electron configuration for the following ions. Indicate the n umber of electrons in the ion s valence shell and the atom s effective nuclear charge. a. Se-2

b. Br-

c. Al+3

d. Ca+2

15. Write the chemical formula for the following compounds. a. Tin(II)oxide

b. Copper(II)nitrate

c. Titanium(IV)chloride

d. Iron(III)sulfide

e. Dinitrogen pentoxide

f. Dinitrogen tetroxide

g. Sulfur hexafluoride

h. Boron trichloride

16. From the following data, draw a radioactive decay curve and determine the ha lf-life of the sample in hours. Time (hours) Concentration ( Cu/l) 0 500 6 250 12 125 18 62.5 24 31.3 30 15.6 36 7.8