Академический Документы
Профессиональный Документы
Культура Документы
One cause of low-level smog is the reaction of ozone, O3, with ethene, C2H4. The smog
contains methanal, HCHO(g).
The equation for methanal production is shown below.
O3(g) + C2H4(g) 2HCHO(g) + O2(g)
The rate of the reaction was investigated, using a series of different concentrations of
either C2H4(g) or O3(g), by measuring the initial rate of formation of HCHO(g).
The results are shown below.
experiment
[O3(g)]
[C2H4(g)]
/ 10 mol dm
/ 10
mol dm
initial rate
12
3 1
/ 10 mol dm s
0.5
1.0
1.0
2.0
1.0
4.0
4.0
2.0
16.0
(i)
Analyse and interpret the results to deduce the order of reaction of each reactant
and the rate equation.
Explain your reasoning.
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
[5]
Strode's College
(ii)
Calculate the value of the rate constant and state the units.
(iii)
Using the equation above, deduce the initial rate of formation of O2(g) in
experiment 1.
Explain your reasoning.
[1]
(iv)
2.
3.
(i)
Explain what is meant by the terms transition element, complex
ion and ligand,
(ii)
(b)
Describe, using suitable examples and diagrams, the different shapes and
stereoisomerism shown by complex ions.
In your answer you should make clear how your diagrams illustrate the type of
stereoisomerism involved.
[9]
[Total 20 marks]
Strode's College
4.
Mercury thermometers are not used in some laboratories because of the danger of
mercury vapour. This vapour is very easily absorbed through the lungs into the blood.
In the blood, mercury reacts with hydrogen peroxide to form mercury(II) oxide.
Hg + H2O2 HgO + H2O
The mercury(II) oxide formed accumulates within organs in the body.
Use oxidation numbers to show that the reaction between mercury and hydrogen
peroxide is an example of both oxidation and reduction.
.................................................................................................................................
.................................................................................................................................
.................................................................................................................................
[Total 2 marks]
5.
2+
2+
ion
electronic configuration
2+
[Xe]4f 5d 6s
14
2+
[Xe]4f 5d
Hg2
Hg
14
10
10
Use the electronic configurations to explain why mercury is not a transition element.
.................................................................................................................................
.................................................................................................................................
[Total 1 mark]
6.
A sample of iron is heated with a stream of dry hydrogen chloride. A different chloride
2+
of iron is formed that contains the Fe ion. This chloride dissolves in water to form a
pale green solution that contains the hexaaquairon(II) complex ion.
(i)
2+
1s 2s 2p .......................................................................................................
[1]
(ii)
Draw the shape of the hexaaquairon(II) complex ion. Include the bond angles on
your diagram.
[2]
(iii)
2+
7.
Stage 4 The cooled contents of the flask are titrated with aqueous potassium
manganate(VII) in acidic conditions to find the amount of unreacted
2+
Fe .
Strode's College
2+
acidified
(i)
2+
Construct the balanced equation for the redox reaction between Fe (aq),
+
MnO2(s) and H (aq).
........................................................................................................................
........................................................................................................................
........................................................................................................................
[1]
(ii)
In Stage 1 and Stage 2 a student uses a 0.504 g sample of impure MnO2 and
3
2+
Fe .
2+
is
2+
8.
Ruthenium (Ru) is a metal in the second transition series. It forms complex ions with
the following formulae.
3+
= [Ru(H2O)6]
= [Ru(H2O)5Cl]
= [Ru(H2O)4Cl2]
(a)
2+
(i)
(ii)
[2]
(iii)
Strode's College
(b)
3+
2+
(ii)
9.
2+
Cu(s) is +0.34 V.
2+
She decided to measure the concentration of the Cu (aq) ions in the solution by
titration.
3
2+
25.00 cm of the solution containing Cu ions were pipetted into a volumetric flask and
3
she made the volume up to 250.0 cm with distilled water.
3
An excess of aqueous potassium iodide, KI, was added to 25.00 cm of the diluted
solution.
3
The iodine formed was titrated against 0.100 mol dm sodium thiosulphate, Na2S2O3.
3
The equations for the formation and titration of iodine are given below.
2+
(i)
State how the student would identify the end point of the titration.
........................................................................................................................
........................................................................................................................
[1]
(ii)
2+
Show that the concentration of the Cu (aq) ions was 0.93 mol dm .
[4]
(iii)
Explain, in terms of chemical equilibrium, why the emf of this cell was less than
the standard electrode potential.
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
[2]
[Total 7 marks]
10.
Iron forms several complex ions in which the oxidation state of iron is +3.
(i)
3+
1s 2s 2p .......................................................................................................
[1]
Strode's College
(ii)
11.
Iron forms several complex ions in which the oxidation state of iron is +3.
3
One of these complex ions is [Fe(CN)6] . This is called the hexacyanoferrate(III) ion.
(ii)
Draw the expected shape for the complex ion [Fe(CN)6] . Include bond angles
and the name of the shape.
[2]
[Total 3 marks]
12.
Iron forms several complex ions in which the oxidation state of iron is +3.
Excess aqueous sodium hydroxide is added to an aqueous solution containing Fe
(aq).
(i)
3+
(ii)
Write an ionic equation, including state symbols, for the reaction that takes place.
........................................................................................................................
[2]
[Total 3 marks]
13.
An unusual compound of iron has been detected on the surface of the planet Mars.
This compound contains the ferrate(VI) ion.
When chlorine is bubbled through a suspension of iron(III) oxide in concentrated
aqueous sodium hydroxide, a solution of aqueous sodium ferrate(VI) forms.
The two relevant redox systems are shown below.
Cl2(aq) + 2e
2C/ (aq)
Construct the redox equation for the reaction between chlorine, iron(III) oxide and
hydroxide ions.
.................................................................................................................................
.................................................................................................................................
.................................................................................................................................
[Total 2 marks]
Strode's College
11
14.
An unusual compound of iron has been detected on the surface of the planet Mars.
This compound contains the ferrate(VI) ion.
A student uses 1.00 g of iron(III) oxide and makes, on crystallisation, 0.450 g of sodium
ferrate(VI), Na2FeO4.
Calculate the percentage yield, by mass, of sodium ferrate(VI).
Show your working.
Express your answer to an appropriate number of significant figures.
15.
An unusual compound of iron has been detected on the surface of the planet Mars.
This compound contains the ferrate(VI) ion.
Ferrate(VI) ions will decompose in acidic solution as shown in the equation below.
2
3+
16.
An unusual compound of iron has been detected on the surface of the planet Mars.
This compound contains the ferrate(VI) ion.
Aqueous sodium ferrate(VI) is a very powerful oxidising agent.
(i)
Predict what you would see when aqueous sodium ferrate(VI) is added to
aqueous potassium iodide.
Explain your answer.
........................................................................................................................
........................................................................................................................
[1]
(ii)
17.
2+
Under certain conditions, VO can be converted into VO2 by reaction with KMnO4.
The equation for the reaction is shown below.
5VO
2+
VO
2+
2+
+ 2H
into VO2 ?
[Total 3 marks]
Strode's College
13
18.
The ethanedioate ion, C2O4 , can act as a bidentate ligand when it forms complex
ions with a transition metal ion. The structure of the ethanedioate ion is shown below.
O
O
C
(a)
C
O
(b)
3+
[3]
[Total 5 marks]
19.
The Cr
3+
Use this complex to explain what is meant by the term stereoisomerism. Your answer
should contain suitable diagrams.
[7]
Quality of Written Communication [1]
[Total 8 marks]
20.
The compound FeSO4.7H2O can be used to kill moss in grass. Iron(II) ions in a solution
of FeSO4.7H2O are slowly oxidised to form iron(III) ions.
Describe a test to show the presence of iron(III) ions in a solution of FeSO4.7H2O.
.................................................................................................................................
.................................................................................................................................
[Total 1 mark]
Strode's College
15
21.
3+
(i)
2
+
3+
Cr2O7 (aq) + 14H (aq) + 6e
2Cr (aq) + 7H2O(l)
2+
Construct the balanced equation for the redox reaction between Fe (aq),
2
+
Cr2O7 (aq) and H (aq).
..........................................................................................................................
..........................................................................................................................
..........................................................................................................................
[2]
(ii)
Cr2O7
to reach the
2+
22.
2+
ions.
[CuCl4]2(aq) + 6H2O(l)
[Cu(H2O)6] (aq) + 4Cl (aq)
(i)
Describe the observations that would be made during the addition of the
concentrated hydrochloric acid.
...............................................................................................................
[1]
Strode's College
17
(ii)
(b)
23.
H
C
u+
N 1
. 5
H
Explain why the HNH bond angle in the ammonia ligand is 109.5 rather than
107.
.................................................................................................................................
.................................................................................................................................
.................................................................................................................................
.................................................................................................................................
[Total 3 marks]
24.
Cobalt readily forms complex ions in which the cobalt has an oxidation state of +2.
2+
2+
........................................................................................................................
[1]
(ii)
Strode's College
19
25.
Cobalt readily forms complex ions in which the cobalt has an oxidation state of +2.
2+
[Co(H2O)6]
(i)
2+
shape ......................................................................................
2
[CoCl4]
shape ......................................................................................
[1]
(ii)
What colour change would occur on going from left to right in this reaction?
from ..................................................... to .....................................................
[1]
(iii)
2+
reacts with Cl ?
........................................................................................................................
[1]
[Total 3 marks]
26.
2+
[2]
Strode's College
21
(ii)
(b)
[2]
[Total 5 marks]
27.
Cr2O7 ions oxidise I ions to I2 under acid conditions according to the following
equation.
2
(i)
3+
If you carried out this reaction, how could you see that iodine is formed?
........................................................................................................................
........................................................................................................................
[1]
(ii)
How could you use the formation of I2 in this reaction to determine the
2
concentration of a solution of Cr2O7 ions?
In your answer
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
[4]
[Total 5 marks]
28.
Copper and zinc are both d-block elements but only copper is a transition element.
2+
+
Copper forms compounds containing Cu or Cu ions but zinc only forms compounds
2+
containing Zn ions.
(a)
2+
and Zn
2+
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
[2]
Strode's College
23
(b)
2+
and Cu
2+
ions.
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
[2]
[Total 4 marks]
29.
2+
answer .............................................. %
[Total 3 marks]
30.
Artists between the 13th and the 19th Centuries used a green pigment called verdigris.
The artists made the pigment by hanging copper foil over boiling vinegar.
During the preparation of verdigris, copper atoms are oxidised to copper(II) ions.
(i)
Write the oxidation half equation for the conversion of copper atoms into
copper(II) ions.
........................................................................................................................
[1]
Strode's College
25
(ii)
[1]
[Total 2 marks]
31.
Artists between the 13th and the 19th Centuries used a green pigment called verdigris.
The artists made the pigment by hanging copper foil over boiling vinegar.
A sample of verdigris has the formula [(CH3COO)2Cu]2.Cu(OH) 2.xH2O.
Analysis of the sample shows that it contains 16.3% water by mass.
Calculate the value of x in the formula.
answer ...................................................
[Total 3 marks]
32.
In this question, one mark is available for the quality of spelling, punctuation and
grammar.
Iron and its compounds take part in several different types of reaction including ligand
substitution, precipitation and redox.
For each type of reaction
33.
The edta
(a)
2+
2+
ion.
Is 2s 2p ........................................................................................................
[1]
(b)
The edta
O
O
O
O
C
(i)
2H
N
C
2H
H
C
2H
2H
C C
C C
N
H
O
O
O
Put a ring around two different types of atom in the edta ion that are
2+
capable of forming a dative covalent bond with the Ni ion.
[2]
Strode's College
27
(ii)
2+
34.
(i)
...............................................................................................................
...............................................................................................................
[1]
(ii)
(b)
[PtCl4] + 2NH3
(i)
[Pt(NH3)2Cl2] + 2Cl
(ii)
(c)
[2]
(ii)
(iii)
Strode's College
29
35.
vanadium is ammonium vanadate(V) and this contains the ion VO3 . This can be
2+
reduced to V
3
2+
with 0.0500 mol dm MnO4 (aq) and 30.0 cm is required to oxidise the V (aq)
The half equation for acidified MnO4 acting as an oxidising agent is shown
below.
+
2+
MnO4 + 8H + 5e
Mn + 4H2O
Show that the vanadium has changed oxidation state from +2 to +5 in this
titration.
[4]
(b)
2+
Suggest an equation for the oxidation of V (aq) to VO3 (aq) by MnO4 (aq) under
acid conditions.
........................................................................................................................
[2]
[Total 6 marks]
36.
(a)
Complete the electronic configuration for Fe3+ and use it to explain why iron is a
transition element.
3+
Fe :1s 2s 2p ................................................................................................
........................................................................................................................
........................................................................................................................
[2]
(b)
(c)
(d)
Construct the equation for the oxidation of acidified iron(II) ions by oxygen.
........................................................................................................................
[2]
[Total 8 marks]
Strode's College
31
37.
Stage 2 Copper turnings are added to the acidified sample of moss killer and
the mixture is boiled carefully for five minutes. Copper reduces any iron(III) ions
in the sample to give iron(II) ions.
Stage 3 The reaction mixture is filtered into a conical flask to remove excess
copper.
Stage 4 The contents of the flask are titrated against aqueous potassium
manganate(VII).
(i)
Suggest why it is important to remove all the copper in stage 3 before titrating in
stage 4.
........................................................................................................................
........................................................................................................................
[1]
(ii)
The ionic equation for the redox reaction between acidified MnO4 and Fe
given below.
2+
2+
2+
is
3+
(iii)
A student analyses a 0.675 g sample of moss killer using the method described.
3
percentage ...................................
[4]
[Total 7 marks]
38.
2+
[Cu(NH3)4(H2O)2] (aq) +
2+
2OH (aq)
(a)
Strode's College
33
(b)
2+
[2]
[Total 4 marks]
39.
Water is a simple molecule. The HOH bond angle in an isolated water molecule is
104.5.
2+
2 u+
H
Explain why the HOH bond angle in the water ligand is 107 rather than 104.5.
.................................................................................................................................
.................................................................................................................................
.................................................................................................................................
.................................................................................................................................
[Total 3 marks]
40.
Transition metals readily form complex ions when they are combined with a suitable
ligand.
What is meant by the following terms?
(i)
complex ion
........................................................................................................................
........................................................................................................................
[1]
(ii)
ligand
........................................................................................................................
........................................................................................................................
[2]
[Total 3 marks]
41.
(a) A common ligand which combines with a number of transition metal ions is
ethane-1,2-diamine, H2NCH2CH2NH2. This is a bidentate ligand.
Explain the meaning of the term bidentate.
........................................................................................................................
........................................................................................................................
[1]
Strode's College
35
(b)
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
[7]
[Total 8 marks]
42.
Cr2O7
+ 14H + 6e
I2 + 2e
2Cr
3+
+ 7H2O
2I
E = +1.33 V
E = +0.54 V
(i)
Construct an ionic equation to show the reaction taking place when acidified
potassium dichromate(VI) is added to aqueous potassium iodide.
........................................................................................................................
........................................................................................................................
........................................................................................................................
[2]
(ii)
Strode's College
37
43.
Compound B is an organic base. A student analysed this base by the procedure below.
He first prepared a solution of B by dissolving 4.32 g of B in water and making the
3
3
solution up to 250 cm . The student then carried out a titration in which 25.00 cm of
3
3
this solution of B were neutralised by exactly 23.20 cm of 0.200 mol dm HCl.
1 mole of B reacts with 1 mole of HCl.
Use this information to calculate the molar mass of base B and suggest its identity.
[Total 6 marks]
44.
In this question, one mark is available for the quality of use and organisation of
scientific terms.
Copper and iron are typical transition elements. One of the characteristic properties of
a transition element is that it can form complex ions.
Give an example of a complex ion that contains copper. Draw the three
dimensional shape of the ion and describe the bonding within this complex ion.
Transition elements show typical metallic properties. Describe three other typical
properties of transition elements. Illustrate each property using copper or iron or
their compounds.
[11]
Quality of Written Communication [1]
[Total 12 marks]
45.
(i)
...............................................................................................................
[1]
(ii)
Give one common use for brass and state the property of brass which
makes it ideal for that purpose.
...............................................................................................................
...............................................................................................................
[1]
(b)
During the analysis of brass, 1.65 g of the alloy was reacted with concentrated
nitric acid. The resulting solution was neutralised, transferred to a volumetric flask
3
and made up to 250 cm using distilled water.
3
(i)
(ii)
(iii)
Strode's College
39
(c)
2+
2CuI + I2
2I + S4O6
+ 4I
I2 + 2S2O3
(i)
(ii)
2+
For every one mole of Cu ions present in solution, deduce the amount, in
2
moles, of S2O3 ions needed for the titration.
(iii)
2+
(iv)
answer ...................... % Cu
[3]
[Total 11 marks]
46.
The Co
(a)
2+
(b)
Strode's College
2+
+ 4Cl
[CoCl4]
+ 6H2O
41
(i)
[Co(H2O)6]
2+
[CoCl4]
[2]
(ii)
(iii)
Describe how you would move the position of this equilibrium to the left.
...............................................................................................................
[1]
[Total 6 marks]
47.
In this question, one mark is available for the quality of use and organisation of
scientific terms.
Stereoisomerism is very common in transition metal complexes. Some complexes have
found an important use in the treatment of cancer.
(i)
(ii)
48.
49.
The table below shows the enthalpy changes needed to calculate the lattice enthalpy of
calcium oxide, CaO.
process
+590
+1150
141
+ 791
635
+178
Strode's College
43
+248
(a)
(i)
Explain why the second ionisation energy of calcium is more
endothermic than the first ionisation energy of calcium.
...............................................................................................................
...............................................................................................................
...............................................................................................................
[2]
Strode's College
45
(ii)
(b)
e n
k J
r g y /
o l
( s )
( g
( g
2+
. 5
( g
( s )
2+
. 5
( g
( s )
[5]
Strode's College
47
(c)
The lattice enthalpies of calcium oxide and magnesium oxide are different.
Comment on this difference.
In your answer you should make clear how the sizes of the lattice enthalpies are
related to any supporting evidence.
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
[3]
[Total 12 marks]
50.
Most metals can be extracted by reduction from compounds obtained from their
naturally-occurring ores.
Metals such as calcium and magnesium are normally extracted by electrolysis but it is
feasible that calcium oxide could be reduced by carbon as shown in the equation
below.
CaO(s) + C(s) Ca(s) + CO(g)
Use the data in the table below to help you answer parts (i)(iii) below.
CaO(s)
C(s)
Ca(s)
CO(g)
635
110
39.7
5.7
41.4
197.6
Hf /kJ mol
S /J K
mol
(i)
Calculate the standard enthalpy change for the CaO reduction in the equation.
H = ............................................ kJ mol
[1]
(ii)
Calculate the standard entropy change for the CaO reduction in the equation.
S = ......................................... J K
mol
[1]
(iii)
Calculate the minimum temperature at which the carbon reduction in the equation
is feasible.
Strode's College
49
51.
Use the standard electrode potentials in the table below to answer the questions that
follow.
I
Fe (aq) + 2e
II
V (aq) + e
III
2H (aq) + 2e
IV
O2(g) + 4H (aq) + 4e
2+
3+
Fe(s)
E = 0.44 V
2+
V (aq)
E = 0.26 V
H2(g)
E = 0.00 V
2H2O(l)
E = +0.40 V
(i)
Write half-equations to show what has been oxidised and what has been reduced
in this cell.
oxidation:
reduction:
[2]
(ii)
Ecell = ......................................................... V
[1]
[Total 3 marks]
52.
Use the standard electrode potentials in the table below to answer the questions that
follow.
I
Fe (aq) + 2e
II
V (aq) + e
III
2H (aq) + 2e
IV
O2(g) + 4H (aq) + 4e
2+
3+
Fe(s)
E = 0.44 V
2+
V (aq)
E = 0.26 V
H2(g)
E = 0.00 V
2H2O(l)
E = +0.40 V
An electrochemical fuel cell was set up based on systems III and IV.
(i)
Construct an equation for the spontaneous cell reaction. Show your working.
[2]
(ii)
Fuels cells based on systems such as III and IV are increasingly being used to
generate energy.
Discuss two advantages and two disadvantages of using fuels cells for energy
rather than using fossil fuels.
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
[4]
[Total 6 marks]
Strode's College
51
53.
In this question, one mark is available for the quality of spelling, punctuation and
grammar.
The lattice enthalpy of magnesium chloride, MgCl2, can be determined using a BornHaber cycle and the following enthalpy changes.
name of process
641
+148
+738
+1451
+123
349
Define, using an equation with MgCl2 as an example, what is meant by the term
lattice enthalpy.
Construct a Born-Haber cycle for MgCl2, including state symbols, and calculate
the lattice enthalpy of MgCl2.
Explain why the lattice enthalpy of NaBr is much less exothermic than that of
MgCl2.
[11]
Quality of Written Communication [1]
[Total 12 marks]
54.
2+
Cu(s) is +0.34 V.
(b)
Cu (aq) + 2e
Cu(s) could be measured.
c o
2 u (+
r o
[3]
[Total 6 marks]
55.
(i)
Give one use of chromium metal and state the property of
chromium that makes it suitable for this use.
...............................................................................................................
...............................................................................................................
[1]
Strode's College
53
(ii)
1s 2s 2p ..............................................................................................
[1]
(b)
The following equations relate to half-cells involving iron and chromium ions.
Fe
3+
+e
2
Cr2O7
Fe
+
2+
+ 14H + 6e
E = +0.77 V
2Cr
3+
+ 7H2O
E = +1.33
V
A cell was set up by combining these two half-cells.
(i)
Derive a balanced equation for the reaction that would occur when the cell
is in use.
Explain your reasoning in terms of oxidation and reduction.
...............................................................................................................
...............................................................................................................
...............................................................................................................
...............................................................................................................
...............................................................................................................
...............................................................................................................
[3]
(ii)
emf = ...................................................... V
[1]
[Total 6 marks]
56.
In order to obtain full marks in this question, you must show all your working clearly.
In its reactions, sulphuric acid, H2SO4, can behave as an acid, an oxidising agent and
as a dehydrating agent.
The displayed formula of pure sulphuric acid is shown below.
H
O
S
Concentrated sulphuric acid will readily oxidise halide ions to the halogen.
The equation below represents the unbalanced equation for the oxidation of iodide ions
by sulphuric acid.
H
(i)
+ SO4
I2
H2S
H2O
Write the oxidation numbers of sulphur and iodine in the boxes above the
equation.
[2]
(ii)
[1]
[Total 3 marks]
Strode's College
55
57.
The table below shows the enthalpy changes needed to calculate the enthalpy change
of formation of calcium oxide.
process
3459
+590
+1150
141
+798
+249
+178
(a)
(i)
Explain why the first ionisation energy of calcium is
endothermic.
...............................................................................................................
...............................................................................................................
[1]
(ii)
(b)
(i)
Include
[3]
(ii)
(iii)
Strode's College
57
58.
The standard electrode potentials for some redox systems involving vanadium are
shown below.
These are labelled A, B, C and D.
E /V
(a)
VO2 + 2H + e
3+
+e
2+
+ 2e
VO
2+
VO
2+
2+
+ H2O
+1.00
0.26
V 1.20
+
+ 2H + e
3+
+ H2O
+0.34
(b)
(ii)
Complete the labelling of the following diagram which shows the cell with a
standard cell potential of 0.60V.
V
[4]
(iii)
The emf of this cell is only 0.60 V under standard conditions. What do you
understand by the expression standard conditions?
...............................................................................................................
...............................................................................................................
...............................................................................................................
[1]
[Total 7 marks]
Strode's College
59
59.
Concentrated nitric acid is a powerful oxidising agent. Concentrated nitric acid oxidises
sulphur to sulphuric acid. Nitrogen dioxide and another product are also formed.
(i)
(ii)
60.
The standard electrode potential of the 2 Cl2/ Cl half-cell may be measured using the
following apparatus.
C
s a
H
( g
lt
r i d
e
D
( a
(a)
(b)
1
2 Cl2 + e
1
2 H2
H +e
(i)
Cl
E = +1.36 V
E = 0.00V
Use an arrow to show the direction of flow of electrons in the diagram of the
apparatus. Explain your answer.
...............................................................................................................
...............................................................................................................
[2]
(ii)
The values of E are measured under standard conditions. What are the
standard conditions?
...............................................................................................................
...............................................................................................................
...............................................................................................................
[2]
Strode's College
61
(c)
ClO3
ClO3 /
+ 6H + 5e
1
2 Cl2 is shown below.
1
2 Cl2 + 3H2OE = +1.47 V
What does this tell you about the oxidising ability of ClO3 compared with Cl2?
Explain your answer.
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
[2]
[Total 8 marks]
61.
The table below shows the enthalpy changes needed to construct a Born-Haber cycle
for sodium oxide, Na2O.
process
+495
141
+791
416
+109
+247
(a)
Use the table of enthalpy changes to complete the Born-Haber cycle by putting in
the correct numerical values on the appropriate dotted line.
N+ a
N+ a
( g
H
H
. . . . . . . . . . k J
2
2
( g
( g
)
)
+
+
2
( g
+( g
( g
( 12 sO 2) ( g + )
. . . . . . . . . . k J
N
2a
( s )
[4]
(b)
Use the Born-Haber cycle to calculate the lattice enthalpy of sodium oxide.
[2]
Strode's College
. . . . . . . . . . k J
2
( 12 gO 2 )
la t t ic e
e n t h a lp y
o f
s o d i u m
o x i d
. . . . . . . . . . k J
2
. . . . . . . . . . k J
N+ a
) 12 O+ 2
N + ( ag
) = + . . 2 . . e . . . . . . k J
O (H g
=
( g
63
(c)
Which one of the following compounds has the most exothermic lattice enthalpy?
calcium bromide
calcium chloride
potassium bromide
potassium chloride
62.
Ag + e
1
2 Cl2 + e
2+
Cu + 2e
3+
Fe + e
1
2 I2 + e
E /V
+ 0.80
Ag
Cl
+ 1.36
Cu
2+
Fe
+ 0.34
+ 0.77
+ 0.54
(a)
(b)
2+
and Ag/Ag
( s )
(i)
+g
( a
Complete and label the diagram to show how the cell potential of this cell
could be measured.
[2]
(ii)
On the diagram, show the direction of electron flow in the circuit if a current
was allowed.
[1]
Strode's College
65
(iii)
(iv)
(c)
2+
3+
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
[2]
[Total 10 marks]
63.
NO2 reacts with oxygen and water to form nitric acid, HNO3. In the atmosphere, this
contributes to acid rain. Construct a balanced equation for this formation of nitric acid
and use oxidation numbers to show that this is a redox reaction.
.................................................................................................................................
.................................................................................................................................
.................................................................................................................................
.................................................................................................................................
.................................................................................................................................
[Total 2 marks]
64.
The table below shows the enthalpy changes needed to calculate the lattice enthalpy of
calcium chloride, CaCl2.
process
Strode's College
+590
+1150
348
enthalpy change of
formation for calcium
chloride
796
enthalpy change of
atomisation for calcium
+178
enthalpy change of
atomisation for chlorine
+122
67
(a)
The Born-Haber cycle below can be used to calculate the lattice enthalpy for
calcium chloride.
2 a+
C
H
. . . . . . . . . . . . . 1. . . . . . .
C
H
. . . . . . . . . . . . . 1. . . . . . .
C
H
C
H
. . . . . . . . . . . . . 1. . . . . . .
2+
m
2+
k J
k J
H =
2 e
2 a+
C
+
( g
. . . . . . . . . . . . . 1. . . . . . .
l a t t ic e
e
c a l c i u m
( g
l
C
o
2
( g
l( g
)C
( s 2)
( g l 2 ) ( +g
( g
k J
(i)
k J
. . . . . . . . . . . . . 1. . . . . . .
+ a( g
C
H
k J
a +( g
. . . . . . . . . . . . . 1. . . . . . .
( g
( g
t h a l p y
o
c h l o r i d e
l
l
( s )
(ii)
[2]
(iii)
Describe how, and explain why, the lattice enthalpy of magnesium fluoride
differs from that of calcium chloride.
.................................................................................................................
.................................................................................................................
.................................................................................................................
.................................................................................................................
.................................................................................................................
[3]
Strode's College
69
(b)
Explain why the first ionisation energy of calcium is less positive than the second
ionisation energy.
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
[2]
[Total 10 marks]
65.
Barium nitrate decomposes when heated to make barium oxide, nitrogen dioxide
and oxygen.
2Ba(NO3)2(s) 2BaO(s) + 4NO2(g) + O2(g)
(i)
(ii)
Calculate the enthalpy change of reaction, Hr, in kJ mol , for the thermal
decomposition of barium nitrate using the enthalpy changes of formation,
Hf, given in the table.
compound
Hf /kJ mol
Ba(NO3)2(s)
992
BaO(s)
558
NO2(g)
+33
[3]
(b)
A student investigates the volume of gas formed when barium nitrate is heated.
The diagram shows the apparatus the student uses.
Strode's College
r i u
i t r a
03 c m
s y r in
t e
71
(i)
answer ......................... cm
[3]
(ii)
Suggest one problem that the student may encounter when carrying out
the investigation.
...............................................................................................................
...............................................................................................................
[1]
[Total 10 marks]
66.
Chlorine gas may be prepared in the laboratory by reacting hydrochloric acid with
potassium manganate(VII). The following standard electrode potentials relate to this
reaction.
1
2 Cl2 + e
Cl
+
MnO4 + 8H + 5e
Mn
2+
E = +1.36 V
+ 4H2O
E = +1.52 V
(a)
(b)
Determine the standard cell potential for a cell constructed from these two redox
systems.
[1]
[Total 4 marks]
67.
Chlorine gas may be prepared in the laboratory by reacting hydrochloric acid with
potassium manganate(VII). The following standard electrode potentials relate to this
reaction.
1
2 Cl2 + e
Cl
+
MnO4 + 8H + 5e
(a)
Mn
2+
E = +1.36 V
+ 4H2O
E = +1.52 V
construct an ionic equation for the reaction between hydrochloric acid and
potassium manganate(VII);
.................................................................................................................
.................................................................................................................
.................................................................................................................
[2]
Strode's College
73
(ii)
(iii)
(b)
If potassium manganate(VII) and very dilute hydrochloric acid are mixed, there is
no visible reaction. Suggest why there is no visible reaction in this case.
........................................................................................................................
........................................................................................................................
[1]
[Total 7 marks]
68.
10
Ka = 1.3 10
mol dm
A BrnstedLowry acid,
........................................................................................................................
[1]
(ii)
A weak acid.
........................................................................................................................
[1]
[Total 2 marks]
69.
When phenol is mixed with aqueous sodium hydroxide, an acidbase reaction takes
place.
C6H5OH(aq)
......................
OH (aq)
.....................
C6H5O (aq) +
.......................
H2O(l)
.....................
70.
[1]
Strode's College
75
(ii)
[5]
[Total 6 marks]
71.
[Total 3 marks]
72.
Syngas is a mixture of carbon monoxide and hydrogen gases, used as a feedstock for
the manufacture of methanol.
A dynamic equilibrium was set up between carbon monoxide, CO, hydrogen, H2, and
3
CH3OH(g)
(a)
CO(g)
H2(g)
3
6.20 10
CH3OH(g)
2
4.80 10
5.20 10
(b)
(i)
[1]
(ii)
Kc = ... units:....
[4]
Strode's College
77
(c)
The pressure was increased whilst keeping the temperature constant. The
mixture was left to reach equilibrium.
The equilibrium position above shifted to the right.
(i)
(ii)
(d)
The temperature was increased whilst keeping the pressure constant. The
mixture was left to reach equilibrium.
The value of Kc for the equilibrium above decreased.
(i)
(ii)
Deduce the sign of the enthalpy change for the forward reaction shown in
the equilibrium above.
Explain your reasoning.
...............................................................................................................
...............................................................................................................
[1]
(e)
(ii)
73.
experiment
[NO]
3
/ mol dm
0.10
0.20
2.6
0.10
0.50
6.5
0.30
0.50
58.5
/ mol dm
initial rate
3 1
/ mol dm s
In this question, one mark is available for the quality of spelling, punctuation and
grammar.
Strode's College
79
(i)
For each reactant, deduce the order of reaction. Show your reasoning.
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
[4]
Quality of Written Communication [1]
(ii)
(iii)
Calculate the rate constant, k, for this reaction. State the units for k.
74.
Nitrogen monoxide, NO, is involved in formation of ozone at low levels and the
breakdown of ozone at high levels.
(i)
(ii)
slow
fast
Suggest the rate equation for this process. Explain your reasoning.
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
[2]
[Total 5 marks]
Strode's College
81
75.
PCl3(g) + Cl2(g)
A chemist placed a mixture of the three gases into a container. The initial concentration
3
of each gas was the same: 0.30 mol dm . The container was left until equilibrium had
been reached.
3
[1]
(b)
Use the value of Kc for this equilibrium to deduce whether the concentration of
each gas increases, decreases or stays the same as the mixture approaches
equilibrium.
(i)
Show your answer by placing a tick in the appropriate cells in the table
below.
initial concentration
3
/ mol dm
PCl5
0.30
PCl3
0.30
Cl2
0.30
greater than
0.30 mol dm
3
less than
3
0.30 mol dm
equal to
3
0.30 mol dm
[1]
(ii)
[1]
(c)
(ii)
(d)
The chemist heated the equilibrium mixture and the equilibrium moved to the left.
(i)
(ii)
Strode's College
83
76.
In sewage plants, biological activity can be reduced by increasing the pH of the water.
This is achieved by adding small amounts of solid calcium hydroxide, Ca(OH)2, to the
sewage water.
In all parts of this question, assume that measurements have been made at 25 C.
(a)
mol dm
at 25 C.
(ii)
(b)
mol dm
hydrochloric acid.
The chemist titrated 25.0 cm of the sewage water with 21.35 cm of HCl to reach
the endpoint of the titration.
3
[3]
(c)
The chemist analysed a sample of water from another part of the sewage works
3
3
and he found that the calcium hydroxide concentration was 2.7 10 mol dm .
When solid calcium hydroxide dissolves in water, its ions completely dissociate.
2+
[3]
(d)
After further treatment, the water could be used for drinking. In the drinking water
+
produced, the OH concentration was 100 times greater than the H
concentration.
What was the pH of this drinking water?
[1]
[Total 9 marks]
Strode's College
85
77.
Ca(H2PO4)2 dissociates forming H2PO4 ions which are easily taken up by plants.
(a)
(b)
(c)
(ii)
(iii)
78.
In order to obtain full marks in this question, you must show all your working clearly.
In its reactions, sulphuric acid, H2SO4, can behave as an acid, an oxidising agent and
as a dehydrating agent.
The displayed formula of pure sulphuric acid is shown below.
H
O
S
Dilute sulphuric acid takes part in the typical acid reactions, reacting with metals,
carbonates and bases.
Write balanced equations for the reaction of sulphuric acid with
a metal, ...................................................................................................................
a carbonate, ............................................................................................................
a base. ....................................................................................................................
[Total 3 marks]
Strode's College
87
79.
On the axes below, sketch a graph to show how [C2H4Br2] changed during
the course of the reaction.
[ C2
/ m
H4
B 2r ]
o l3 d m
0
0
t i m
/ s
[2]
(ii)
Show on the graph how you would measure the initial rate of the reaction.
[1]
(iii)
How would you use the graph to show that the reaction is first order with
respect to C2H4Br2?
................................................................................................................
[1]
(iv)
i n i t i a l r a
m
o l 3 d m 1
t e
/
s
0
[ C2
H4
m
[1]
(b)
In a second experiment, the initial concentration of KI was varied and the initial
rate was measured. The results are shown in the table below.
experiment
[C2H4Br2]
/mol dm
[KI]
3
/mol dm
initial rate
3 1
/mol dm s
0.50
0.18
0.027
0.50
0.72
0.108
Deduce the order of reaction with respect to KI. Show your reasoning.
.........................................................................................................................
.........................................................................................................................
[2]
Strode's College
89
(c)
(i)
................................................................................................................
[1]
(ii)
Calculate the rate constant, k, for this reaction. State the units for k.
80.
Some ammonia plants are run at 200300 atm and 500 C, with an iron catalyst.
(a)
The hydrogen for the plants is obtained by reacting methane with steam.
Construct a possible equation for this reaction.
.........................................................................................................................
[1]
(b)
Nitrogen gas and hydrogen gas produce ammonia gas as shown below.
N2(g) + 3H2(g)
(i)
H = 92 kJ mol
2NH3(g)
[1]
(ii)
At 500 C, Kc = 8.00 x 10
dm mol .
and the
concentration of H2 is 2.00moldm .
Calculate the equilibrium concentration of ammonia under these conditions.
[3]
(c)
In this question one mark is available for the quality of the use and organisation
of scientific terms.
Discuss the advantages and disadvantages of running this reaction
at a temperature of 500C;
Strode's College
91
81.
nitric acid, HNO3, a strong acid which can also act as a powerful oxidising agent.
82.
pH = ............................
[Total 3 marks]
83.
(ii)
(iii)
84.
pH = ....................................
[Total 3 marks]
Strode's College
93
85.
86.
When nitric acid is added to methanoic acid, the acid-base equilibrium below is set up.
HNO3 + HCOOH
NO3 + HCOOH2
Use this equilibrium to explain what is meant by the term conjugate acid-base pairs.
..................................................................................................................................
..................................................................................................................................
..................................................................................................................................
..................................................................................................................................
[Total 3 marks]
87.
[Total 8 marks]
88.
Methanoic acid, HCOOH, is a weak organic acid which occurs naturally in ants and
stinging nettles.
(a)
Use an equation for the dissociation of methanoic acid to show what is meant by
a weak acid.
........................................................................................................................
........................................................................................................................
[1]
Strode's College
95
(b)
A 1.50 10
(i)
mol dm
mol dm .
Calculate the pH of this solution and give one reason why the pH scale is a
more convenient measurement for measuring acid concentrations than
+
[H ].
...............................................................................................................
...............................................................................................................
...............................................................................................................
[2]
(ii)
[1]
(iii)
[3]
(iv)
[1]
[Total 8 marks]
89.
A student titrated the 1.50 10 mol dm methanoic acid with aqueous sodium
hydroxide.
3
A 25.00 cm sample of the HCOOH(aq) was placed in a conical flask and the
NaOH(aq) was added from a burette until the pH no longer changed.
(i)
Write a balanced equation for the reaction between HCOOH(aq) and NaOH(aq).
........................................................................................................................
[1]
Strode's College
97
(ii)
1 4
1 3
1 2
1 1
1 0
9
8
H 7
6
5
4
3
2
1
0
0
1
v o
0
l u
53
1
m
0
a
03
H3
( a
5
q
54
4
e
c m
concentration = ......................mol dm
[3]
(iii)
pH = .......................................
[2]
(iv)
The pH ranges in which colour changes for three acid-base indicators are shown
below.
indicator
pH range
metacresol purple
2,4,6-trinitrotoluene
ethyl orange
7.4 9.0
11.5 13.0
3.4 4.8
90.
The preparation of hydrogen iodide, HI(g), from hydrogen and iodine gases is a
reversible reaction which reaches equilibrium at constant temperature.
H2(g) + I2(g)
(a)
2HI(g)
[1]
(b)
A student mixed together 0.30 mol H2(g) with 0.20 mol I2(g) and the mixture was
allowed to reach equilibrium. At equilibrium, 0.14 mol H2(g) was present.
(i)
Complete the table below to show the amount of each component in the
equilibrium mixture.
component
H2(g)
I2(g)
HI(g)
0.30
0.20
Strode's College
99
[2]
(ii)
Kc = ...........................................
units, if any ...........................................................................................
[3]
(c)
The student compressed the equilibrium mixture so that its volume was reduced.
The temperature was kept constant.
Comment on the value of Kc and the composition of the equilibrium mixture
under these new conditions.
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
[2]
[Total 8 marks]
91.
Hydroiodic acid, HI(aq), is a strong acid that is an aqueous solution of hydrogen iodide.
In the laboratory, hydroiodic acid can be prepared by the method below.
3
A mixture of 480 g of iodine and 600 cm of water was put into a flask. The
mixture was stirred and hydrogen sulphide gas, H2S(g), was bubbled
through for several hours.
The mixture became yellow as sulphur separated out. The sulphur was
filtered off and the solution was purified by fractional distillation. A fraction of
3
HI(aq) was collected containing 440 g of HI in a total volume of 750 cm .
(i)
(ii)
[3]
(iii)
[2]
[Total 7 marks]
92.
In this question, one mark is available for the quality of use and organisation of
scientific terms.
Propanone reacts with iodine in the presence of dilute hydrochloric acid.
A student carried out an investigation into the kinetics of this reaction.
He measured how the concentration of propanone changes with time. He also
investigated how different concentrations of iodine and hydrochloric acid affect the
initial rate of the reaction.
Strode's College
101
[ C
CH
t im
[CH3COCH3]
/ mol dm
[I2]
/ mol dm
initial rate
3 1
/ mol dm s
[H ]
3
/ mol dm
1.5 10
0.0300
0.0200
2.1 10
1.5 10
0.0300
0.0400
4.2 10
1.5 10
0.0600
0.0400
4.2 10
What conclusions can be drawn about the kinetics of this reaction from the
students investigation? Justify your reasoning.
Suggest the equations for a possible two-step mechanism for this reaction. Label
the rate-determining step and explain your reasoning.
Quality of Written Communication [1]
[Total 14 marks]
93.
(ii)
[1]
(b)
(i)
[1]
Strode's College
103
(ii)
[2]
(c)
concentration = ......................mol dm
[3]
(d)
[5]
[Total 13 marks]
94.
Nitrogen dioxide is one of the major pollutants in air, formed by reaction of nitrogen
monoxide with oxygen.
2NO(g) + O2(g) 2NO2(g)
(a)
Strode's College
105
(b)
A series of experiments was carried out to investigate the kinetics of this reaction.
The results are shown in the table below.
Experiment
(i)
[O2]
3
/ mol dm
[NO]
3
/ mol dm
initial rate
3 1
/ mol dm s
0.00100
0.00100
7.10
0.00400
0.00100
28.4
0.00400
0.00300
256
For each reactant, deduce the order of reaction. Show your reasoning.
O2(g) .....................................................................................................
...............................................................................................................
...............................................................................................................
...............................................................................................................
NO(g) ....................................................................................................
...............................................................................................................
...............................................................................................................
...............................................................................................................
[4]
(ii)
(iii)
Calculate the rate constant, k, for this reaction. State the units for k.
95.
Nitrogen dioxide reacts with carbon monoxide emitted from car exhausts in the
following reaction.
NO2 + CO NO + CO2
2
(i)
(ii)
Suggest a two-step reaction mechanism for this reaction that is consistent with
the kinetic data and the overall reaction.
[2]
[Total 3 marks]
Strode's College
107
96.
The Ka values for three acids are shown in the table below.
acid
(a)
Ka / mol dm
ethanoic acid
CH3COOH
1.70 10
phenol
C6H5OH
1.28 10
sulphurous acid
H2SO3
1.50 10
10
2
(b)
When sulphurous acid and ethanoic acid are mixed together, an acid-base
reaction takes place.
H2SO3(aq)
+ CH3COOH(aq)
HSO 3 (aq)
+
CH3COOH2 (aq)
.......................
(i)
.......................
.......................
......................
(ii)
Predict and explain the acid-base reaction that would take place if ethanoic
acid were mixed with phenol. Include an equation in your answer.
...............................................................................................................
...............................................................................................................
...............................................................................................................
...............................................................................................................
[2]
(c)
Calculate the pH values of these two acids. Show all your working.
[5]
[Total 10 marks]
Strode's College
109
97.
98.
Chocolate mousse contains gelatine and a compound to promote fast setting of the
mousse.
Compound A is such a setting agent. It has two acidic hydrogen atoms per molecule
and is one of the six acids listed below.
oxalic acid
HOOCCOOH
malonic acid
HOOCCH2COOH
succinic acid
HOOC(CH2)2COOH
glutaric acid
HOOC(CH2)3COOH
adipic acid
HOOC(CH2)4COOH
pimelic acid
HOOC(CH2)5COOH
[Total 5 marks]
99.
In the UK, almost all the sulphuric acid, H2SO4, is manufactured by the Contact
process.
One stage in the Contact process involves the reaction between sulphur dioxide and
oxygen.
2SO2(g) + O2(g)
2SO3(g)
The table below shows values of the equilibrium constant, Kp, for this equilibrium at
different temperatures.
Strode's College
temperature / C
Kp / kPa
25
4.0 10
200
2.5 10
800
1.3 10
22
8
111
(a)
[2]
(b)
In this question, one mark is available for the quality and use of scientific terms.
Deduce the sign of H for the forward reaction in the equilibrium. Explain
your reasoning carefully.
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
..........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
[6]
Quality of Written Communication [1]
Strode's College
113
(c)
Kp = 3.0 10 kPa .
Calculate the equilibrium partial pressure of SO3 at 400 C. Hence determine the
percentage of SO3 in the equilibrium mixture at this temperature.
answer ..................................%
[3]
(d)
In the UK, almost all the sulphuric acid manufactured uses sulphur as a starting
material for SO2 production. In some countries, metal ores such as zinc sulphide,
ZnS, are used instead to form SO2 by heating with air.
(i)
Construct a balanced equation to show the reaction that takes place when
zinc sulphide is heated in air.
...............................................................................................................
[2]
(ii)
100. One cause of low-level smog is the reaction of ozone, O3, with ethene. The smog
contains methanal, CH2O(g), and the equation for its production is shown below.
1
O3(g) + C2H4(g) 2CH2O(g) + 2 O2(g)
(a)
equation 1
The rate of the reaction doubles when the initial concentration of either O3(g) or
C2H4(g) is doubled.
(i)
(ii)
(iii)
(b)
Strode's College
115
(ii)
Calculate the value of the rate constant and state the units.
(iii)
(iv)
101. In the stratosphere, ozone forms when oxygen free radicals react with oxygen
molecules.
O2 + O O3
The oxygen free radicals are initially formed as diradicals when oxygen gas, O2, is
dissociated by strong ultraviolet radiation,
O2(g) 2O(g)
(i)
(ii)
[2]
Strode's College
117
(iii)
Chlorine free radicals formed from CFCs deplete the ozone layer in a chain
reaction.
Typically, 1 g of chlorine free radicals destroys 150 kg of ozone during the
atmospheric lifetime of the chlorine free radical (one to two years).
Calculate how many ozone molecules are destroyed in this chain reaction by a
single chlorine free radical before the free radical is destroyed.
answer........................................
[3]
[Total 6 marks]
102. Phenol, C6H5OH, is a powerful disinfectant and antiseptic. Phenol is a weak BrnstedLowry acid.
What is meant by the following terms;
(i)
a Brnsted-Lowry acid;
........................................................................................................................
[1]
(ii)
a weak acid?
........................................................................................................................
........................................................................................................................
[1]
[Total 2 marks]
103. When phenol is mixed with aqueous sodium hydroxide, an acid-base reaction takes
place.
C6H5OH(aq)
......................
OH (aq)
C6H5O (aq)
.....................
.......................
H2O(l)
.....................
[1]
Strode's College
119
(ii)
answer........................................
[5]
[Total 6 marks]
O
C
2 H(
)H
H
4
[Total 2 marks]
Strode's College
121
106. Compound B is an organic base. A student analysed this base by the procedure below.
He first prepared a solution of B by dissolving 4.32 g of B in water and making the
3
3
solution up to 250 cm . The student then carried out a titration in which 25.00 cm of
3
3
this solution of B were neutralised by exactly 23.20 cm of 0.200 mol dm HCl.
1 mole of B reacts with 1 mole of HCl.
Use this information to calculate the molar mass of base B and suggest its identity.
[Total 6 marks]
was decomposed at
(i)
How can you tell that this reaction is first order with respect to N2O5?
........................................................................................................................
........................................................................................................................
[1]
(ii)
Strode's College
123
(iii)
Complete the graph below to show how the [N2O5] changes over the first 3600 s
of the reaction.
[ N2 O 5 ]
o 3 l
m
0 .6 0
0 .5 0
0 .4 0
0 .3 0
0 .2 0
0 .1 0
0
0
400
800
1200
1600
2000
t im e / s
2400
2800
3200
3600
[2]
(iv)
(v)
The rate can also be calculated from the rate equation. The rate constant for this
4 1
reaction is 6.2 10 s .
Calculate the initial rate of this reaction. State the units.
(i)
Strode's College
125
(ii)
(iii)
(iv)
Use the mechanism above to suggest the rate equation for this hydration.
........................................................................................................................
[1]
[Total 5 marks]
CH3OH(g)
H = 91 kJ mol
In this question, one mark is available for the quality of use and organisation of
scientific terms.
Explain the advantages and disadvantages of running this reaction
at a high pressure,
at a high temperature.
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
[5]
Quality of Written Communication [1]
Strode's College
127
(b)
This equilibrium reaction is normally carried out at 10MPa pressure and 550 K,
and starting with a 1 : 2 CO : H2 mixture. At equilibrium, only 10% of the CO has
reacted.
(i)
H2
CH3OH
1.0
2.0
0.0
0.9
mole fraction at
equilibrium
partial pressure at
equilibrium /MPa
[4]
(ii)
[2]
(iii)
(iv)
Kp = ............................. units.............................
[2]
(c)
In the UK, the annual production of methanol is 500 000 tonnes. Methanol has
many uses in fuels as a reliable and low pollution form of energy.
Suggest an equation for the combustion of methanol.
........................................................................................................................
[1]
[Total 18 marks]
Strode's College
129
110. A student carried out an investigation with aqueous solutions of nitric acid, sodium
hydroxide, ethanoic acid and water.
Nitric acid, HNO3, is a strong Brnsted-Lowry acid.
(i)
(ii)
111. A student carried out an investigation with aqueous solutions of nitric acid, sodium
hydroxide, ethanoic acid and water.
3
The student diluted 0.015 mol dm nitric acid with an equal volume of water and
measured the pH of the diluted acid at 25 C.
(i)
nitric acid.
[2]
(ii)
[1]
[Total 3 marks]
Kw = 1.0 10
(i)
mol dm
at 25 C.
Write down an expression for the ionic product, Kw, for water.
........................................................................................................................
[1]
(ii)
[2]
[Total 3 marks]
(i)
Strode's College
131
(ii)
114. A student measured the pH of water as 7.0 at 25 C. The student then warmed the
water to 40 C and measured the pH as 6.7.
What do these results tell you about the tendency of water to ionise as it gets warmer?
Explain your reasoning in terms of equilibrium.
.................................................................................................................................
.................................................................................................................................
.................................................................................................................................
.................................................................................................................................
[Total 2 marks]