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Raw Data obtain from Direct Measurement for Performance Monitoring Activities (Equipment readings, field tests, flow

measurement and laboratory test)


Flowrate
Influent

ORP
(mV)

Effluent

(L/h)

(m3/d)

Group 1

47.50

Group 2

43.00

Group 3
Group 4

*ORP
(mV)

pH

Influent

Tank 1
(Chrome
Reduction)

Tank 2 (pH
Adjustment)

Tank 3 (pH
Adjustment)

Coagulation
tank

Flocculation
tank

250.0

6.28

2.34

7.89

10.85

6.21

6.23

248.0

7.52

2.26

8.25

10.86

6.38

6.29

186.5

249.0

7.63

2.37

8.63

10.91

6.18

6.29

140.1

248.0

7.8

2.27

8.08

11.22

6.46

6.48

Chrome Reduction
Tank

(L/h)

(m3/d)

1.140

70.5

1.692

205.3

1.032

74.00

1.776

160.0

47.70

1.145

72.75

1.746

19.90

0.48

54.00

1.30

Temperature

Influent

Chrome
Reduction
Tank

pH
Adjustment
Tank 1

pH
Adjustment
Tank 2

Coagulation tank

Flocculation
tank

Primary
Clarifier

Final
Discharge

Group 1

25.2

30.5

30.3

29.8

29.6

29.7

31.1

31.1

Group 2

30.4

30.4

30.0

29.5

29.3

29.4

35.8

30.2

Group 3

30.8

30.2

29.7

29.5

29.6

34.1

30.3

Group 4
Average
(true value)

30.5

30.2

29.6

29.4

29.7

35.2

30.2

30.3
30.3

*Analyzer

COD (mg/L)
Influent
Group 1

Secondary

846

CePIETSO (PC) - 16-19 Mac 2010

Final
Discharge
5

Chromium Hexavalent (mg/L)


Final
Discharge
Influent
112

0.01

Nickel (mg/L)

Zinc (mg/l
Influent

Final
Discharge

Influent

Final
Discharge

83

0.37

20.5

0.07

Raw Data obtain from Direct Measurement for Performance Monitoring Activities (Equipment readings, field tests, flow measurement and laboratory test)
Group 2

904

21

104

67

0.56

19.1

0.06

Group 3

944

112

0.01

103

0.69

22.7

0.08

Group 4

833

18

80

0.02

73

0.36

19.6

0.07

Average

Polymer
Dosing Rate
(mL/min)
Group 1
Group 2

Group 3
Group 4
Average

Jar Test Group 1


Sample No.

Initial pH
Initial Cr6+
Adjusted ORP

2.0
250

Volume acid sulphuric 0.1 mL


Volume sodium metabisulphite 0.3 mL

Adjusted pH

9.0

Volume acid sodium hydroxide 1.4 mL

Adjusted pH

PAC (9%)
Polymer

1.5 mL
or
270 mg/L
1.5 mL
or
0.6 mg/L

CePIETSO (PC) - 16-19 Mac 2010

Condition for Cr6+ reduction to Cr3+


Optimum pH for Cr3+ precipitate (after jar test Series 1 )

Rapid mixing
Optimum PAC and Polymer dosage (after jar test Series 2)
Slow mixing

1st Stage

1.5 mL
or
0.6 mg/L

Raw Data obtain from Direct Measurement for Performance Monitoring Activities (Equipment readings, field tests, flow measurement and laboratory test)

Slow mixing

Height of floc
Cr6+ final
Cr3+ final
% Cr6+ removal
pH

Group 1

Jar Test Group 4 (Optimum dosage of coagulant and flocculant Removal 2 metal for optimum Ph 10.5)
Sample
Initial pH
Zinc initial
Ni Initial
Turbiditi Initial
Adjusted pH

1
2.48
93
16.3
1000
10.5

2
2.46
93
16.3
1000
10.5

3
2.46
93
16.3
1000
10.5

4
2.46
93
16.3
1000
10.5

5
2.46
93
16.3
1000
10.5

0.5
90
0.5
90
8.15

1
180
1
180
7.75

2
360
2
360
6.43

2.5
450
2.5
450
5.94

164

103

1.5
270
1.5
270
7.2
0.03
1.1
39
99.97
93.25

54

81

Group 2

Group 4

6
2.46
93
16.3
1000
10.5

10.5

10.5

Actual pH
PAC 9%
Dosage (mg/L)
Polymer 0.02%
Dosage (mg/L)
Ph final
Zinc final
Nickel
Turbiditi (NTU)
% Zn removal
% Nickel removal
Standard B
Zinc

2.0

CePIETSO (PC) - 16-19 Mac 2010

334

2.5

2.5

Raw Data obtain from Direct Measurement for Performance Monitoring Activities (Equipment readings, field tests, flow measurement and laboratory test)
Ni

1.0

Method 3: Based on Std Dev


Influent
Sample
1
2.39
2
2.58
3
2.55
4
2.52

2.65
2.6
2.55
p
H

2.5
2.45

CePIETSO (PC) - 16-19 Mac 2010

Mean
2.5
2.5
2.5
2.5

Std Dev
0.1
0.1
0.1
0.1

UCL
2.6
2.6
2.6
2.6

LCL
2.4
2.4
2.4
2.4
Column1

Column1
Mean
Standard Error
Median
Mode
Standard Deviation
Sample Variance
Kurtosis

2.5
0.0
2.5
#N/A
0.1
0.0
2.4

Mean
2.51
Standard Error 0.041833
Median
2.535
Mode
#N/A
Standard Deviation
0.083666
Sample Variance
0.007
UCL
Kurtosis
2.41428571
-1.5025731
LCL Skewness

Raw Data obtain 2.45


from Direct Measurement for Performance Monitoring Activities (Equipment readings,LCL
field tests, flow measurement and laboratory test)

2.4
2.35
0

CePIETSO (PC) - 16-19 Mac 2010

Skewness
Range
Minimum
Maximum
Sum
1
2
3
Count
Sample Group
Confidence Level(95.0%)

-1.5
0.2
2.4
2.6
10.04
4.0
0.1

Range
0.19
Minimum
2.39
Maximum
2.58
Sum
10.04
Count
4
Confidence Level(95.0%)
0.13313128

Activities (Equipment readings, field tests, flow measurement and laboratory test)

pH

CePIETSO (PC) - 16-19 Mac 2010

Primary
Clarifier

Final
Discharge

6.88

7.26

6.64

7.62

6.5

7.64

6.86

7.67

Activities (Equipment readings, field tests, flow measurement and laboratory test)

2nd Stage

CePIETSO (PC) - 16-19 Mac 2010

Activities (Equipment readings, field tests, flow measurement and laboratory test)

CePIETSO (PC) - 16-19 Mac 2010

Activities (Equipment readings, field tests, flow measurement and laboratory test)

CePIETSO (PC) - 16-19 Mac 2010

Activities (Equipment readings, field tests, flow measurement and laboratory test)

CePIETSO (PC) - 16-19 Mac 2010

pH
Influent
(L/h)

Effluent
(L/h)

Chrome Reduction
Tank (mV)

Influent

Tank 1
(Chrome
Reduction)

Group 1

47.50

70.5

205.3

250.0

6.28

2.34

Group 2

43.00

74.00

160.0

248.0

7.52

2.26

Group 3

47.70

72.75

186.5

249.0

7.63

2.37

Group 4

19.90

54.00

140.1

248.0

7.8

2.27
pH

Influent
(L/h)

Effluent
(L/h)

Chrome Reduction
Tank (mV)

Influent

Column1
Mean
Standard Error
Median
Mode
Standard Deviation
Sample Variance
Kurtosis
Skewness
Range
Minimum
Maximum
Sum
Count
Largest(1)
Smallest(1)
Confidence Level(95.0%)

Mean
Standard Error
Median
Mode
Standard Deviation
Sample Variance
Kurtosis
Skewness
Range
Minimum
Maximum
Sum
Count
Largest(1)
Smallest(1)
Confidence Level(95.0%)

39.53
6.63
45.25
#N/A
13.26
175.88
3.42
-1.85
27.80
19.90
47.70
158.10
4.00
47.70
19.90
21.10

67.81
4.66
71.63
#N/A
9.32
86.89
3.50
-1.86
20.00
54.00
74.00
271.25
4.00
74.00
54.00
14.83

172.98
14.37
173.25
#N/A
28.73
825.65
-2.15
-0.04
65.20
140.10
205.30
691.90
4.00
205.30
140.10
45.72

248.75
0.48
248.50
248.00
0.96
0.92
-1.29
0.85
2.00
248.00
250.00
995.00
4.00
250.00
248.00
1.52

7.31
0.35
7.58
#N/A
0.69
0.48
3.49
-1.83
1.52
6.28
7.80
29.23
4.00
7.80
6.28
1.11

Tank 1
(Chrome
Reduction)

2.31
0.03
2.31
#N/A
0.05
0.00
-4.34
0.23
0.11
2.26
2.37
9.24
4.00
2.37
2.26
0.09

* Average value
* Plus/Minus of the average value
*

* Peakness
* Stiffness
* Maximum - Minimum

* Size of population
* Largest unit in the population
* Smallest unit in the population
* Reliability

pH
Tank 2 (pH Tank 3 (pH Coagulation Flocculation
Adjustment) Adjustment)
tank
tank

Primary
Clarifier

Final
Discharge

7.89

10.85

6.21

6.23

6.88

7.26

8.25

10.86

6.38

6.29

6.64

7.62

8.63

10.91

6.18

6.29

6.5

7.64

8.08

11.22

6.46

6.48

6.86

7.67

Primary
Clarifier

Final
Discharge

pH
Tank 2 (pH Tank 3 (pH Coagulation Flocculation
Adjustment) Adjustment)
tank
tank

8.21
0.16
8.17
#N/A
0.31
0.10
0.59
0.79
0.74
7.89
8.63
32.85
4.00
8.63
7.89
0.50

10.96
0.09
10.89
#N/A
0.18
0.03
3.52
1.87
0.37
10.85
11.22
43.84
4.00
11.22
10.85
0.28

* Average value
* Plus/Minus of the average value

* Peakness
* Maximum - Minimum

* Size of population
* Largest unit in the population
* Smallest unit in the population
* Reliability

6.31
0.07
6.30
#N/A
0.13
0.02
-4.10
0.25
0.28
6.18
6.46
25.23
4.00
6.46
6.18
0.21

6.32
0.05
6.29
6.29
0.11
0.01
2.97
1.58
0.25
6.23
6.48
25.29
4.00
6.48
6.23
0.17

6.72
0.09
6.75
#N/A
0.18
0.03
-3.23
-0.47
0.38
6.50
6.88
26.88
4.00
6.88
6.50
0.29

7.55
0.10
7.63
#N/A
0.19
0.04
3.78
-1.93
0.41
7.26
7.67
30.19
4.00
7.67
7.26
0.31

** if mean = median = mode, standard error = 0.

Flowrate
ORP

pH

Parameter

Unit

Mean

Standard
Error

Median

Influent
Effluent
Chrome Reduction Tank (Portable)
Chrome Reduction Tank (Standing)
Influent
Tank 1 (Chrome Reduction)
Tank 2 (pH Adjustment)
Tank 3 (pH Adjustment)
Coagulation tank
Flocculation tank
Primary Clarifier
Final Discharge

L/h
L/h
mV
mV

39.525
67.8125
172.975
248.75
7.3075
2.31
8.2125
10.96
6.3075
6.3225
6.72
7.5475

6.631035
4.660757
14.36706
0.478714
0.347308
0.026771
0.157394
0.087655
0.067253
0.054371
0.091287
0.096382

45.25
71.625
173.25
248.5
7.575
2.305
8.165
10.885
6.295
6.29
6.75
7.63

Mode

Standard
Deviation

Sample
Variance

Kurtosis Skewness

#N/A
#N/A
#N/A
248
#N/A
#N/A
#N/A
#N/A
#N/A
6.29
#N/A
#N/A

13.26207
9.321514
28.73411
0.957427
0.694616
0.053541
0.314788
0.175309
0.134505
0.108743
0.182574
0.192765

175.8825
86.89063
825.6492
0.916667
0.482492
0.002867
0.099092
0.030733
0.018092
0.011825
0.033333
0.037158

3.416357
3.502793
-2.14751
-1.28926
3.486259
-4.341
0.591557
3.518624
-4.09892
2.967322
-3.23088
3.780762

-1.84714
-1.859
-0.04114
0.854563
-1.83441
0.234551
0.789867
1.87088
0.254271
1.579653
-0.47323
-1.93154

Range
27.8
20
65.2
2
1.52
0.11
0.74
0.37
0.28
0.25
0.38
0.41

Minimum Maximum
19.9
54
140.1
248
6.28
2.26
7.89
10.85
6.18
6.23
6.5
7.26

47.7
74
205.3
250
7.8
2.37
8.63
11.22
6.46
6.48
6.88
7.67

Sum

Count

158.1
271.25
691.9
995
29.23
9.24
32.85
43.84
25.23
25.29
26.88
30.19

4
4
4
4
4
4
4
4
4
4
4
4

Confidenc
Smallest(
e
Largest(1)
1)
Level(95.0
%)
47.7
19.9
21.10291
74
54
14.83261
205.3
140.1
45.72238
250
248
1.52348
7.8
6.28
1.105289
2.37
2.26
0.085196
8.63
7.89
0.500898
11.22
10.85
0.278956
6.46
6.18
0.214028
6.48
6.23
0.173034
6.88
6.5
0.290516
7.67
7.26
0.306732

Sample
Group

Y-axis
1
2
3
4

Mean
6.3
7.5
7.6
7.8

7.3
7.3
7.3
7.3

pH of Sample
10.0
9.0

pH

8.0
7.0
6.0
5.0
4.0
0

0.5

1.5

2.5

3.5

4.5

3.5

4.5

Sample

pH of Sample
10.0
9.0

pH

8.0
7.0
6.0
5.0
4.0
0

0.5

1.5

2.5
Sample

** DOE way of setting UCL and LCL


UCL = mean + (standard deviation)*2
LCL = mean - (standard deviation)*2
2 sigma

Standard Dev
2
2
2
2

Data

UCL1

LCL1

0.7
0.7
0.7
0.7

8.7
8.7
8.7
8.7

5.9
5.9
5.9
5.9

UCL
LCL

** Other way of setting UCL and LCL


UCL = Mean + A*R
LCL = Mean - A*R
A = Tabulation of factorA for X chart
R = Range
Data
UCL
LCL

Range
0.73
0.73
0.73
0.73

UCL2
1.5
1.5
1.5
1.5

LCL2
8.41
8.41
8.41
8.41

6.19
6.19
6.19
6.19

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