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# An Introduction to Solutions and Solubility

## 8. Electrolyte: a substance that, when in solution, will conduct an electric current.

9. Non-Electrolyte: a solution that does not conduct electricity and thus is not ionized.

## UNIT 3: SOLUTIONS AND SOLUBILITY PAGE 1 OF 7

1. Potassium nitrate is added to four flasks of pure water until no more will dissolve. Each
mixture is sealed and stirred at different temperatures. The same volume of each solution is
removed and evaporated to crystallize the solid. The results are shown on the following graph.

## Solubility Of Potassium Nitrate At Various Temperatures

TEMPERATURE VOLUME OF SOLUTION MASS OF EMPTY BEAKER MASS OF BEAKER, PLUS SOLID

## (a). Plot a graph of solubility (g/ml) VS. Temperature.

(b). What can you generalize about the effect of temperatures on solubility?

1(a). You can find the graph for solubility (g/ml) VS. Temperature below.

1(b). The generalization that one can perceive from the effect that temperature has on solubility
is quite clear: as temperatures rise, an increase in solubility will result; however, an increase in
temperature may decrease solubility.

## UNIT 3: SOLUTIONS AND SOLUBILITY PAGE 2 OF 7

UNIT 3: SOLUTIONS AND SOLUBILITY PAGE 3 OF 7
Molar Concentration (Molarity)
Molarity is the number of mols of solute dissolved per litre of solution.

## Number of moles of solute

Molarity =
Volume of solution

Where “M” is the molarity, “moles” is the number of mols, and L is the volume in litres.

## The Molarity Diagram

Cover what you are looking for. If you cover “moles”,
then you are going to multiply “M” by “L”, but if you
cover “M” or “L”, then you will be dividing “moles” by “M”
or “L”, depending on what is not covered.

Things to Remember:
• Molarity is expressed in units of mols/L, or M.
• You will sometimes have to use “KHD[ ]dcm” when dealing with molarity.

• When dealing with molarity problems, you will only use grams when it is asking for the mass
of the chemical formula, so you may need to convert from mols to grams, or vice-versa.

## UNIT 3: SOLUTIONS AND SOLUBILITY PAGE 4 OF 7

Questions for Molar Concentration (Molarity)
1. If 0.0877 mols of Copper (II) Sulfate, CuSO4, are dissolved in 0.07 L of a solution, then find
the molarity of the solution.

## mols = 0.0877 mols

L = 0.07 L
M = ?  1.3 mols/L

## Number of moles of solute

Molarity =
Volume of solution

0.0877 mols
Molarity = = 1.3 mols/L
0.07 L

## UNIT 3: SOLUTIONS AND SOLUBILITY PAGE 5 OF 7

Dilutions
Often, you are required to lessen the concentration of a solution before starting a lab. You can
accomplish this by adding more solvent to the solution.

V1 V2
M1 M2

M = concentration V = volume

Since the amount of solute remains constant on both solutions, they both contain the same
number of mols.

M1 = moles/V1 M2 = moles/V2
moles = M1V1 moles = M2V2

## Therefore: M1V1 = M2V2

This above equation is known as the dilution formula and it is very useful when doing labs.

Things to Remember:
• I = initial and F = final
• M1 and V1 are of the original solution, while M2 and V2 are the new products of dilution.
• You will sometimes have to use “KHD[ ]dcm” when dealing with Dilutions, as you must use
only “L” and not “mL”.

## UNIT 3: SOLUTIONS AND SOLUBILITY PAGE 6 OF 7

Questions for Dilutions
1. Determine the concentration of the solution when 25 mL of 3.0 M HCl (aq) is diluted to 65.0
mL.

## The formula: M1V1 = M2V2

M1 = 3.0 M (initial)
V1 = 25 mL (initial)
M2 = ?  1.15 M (final)
V2 = 65.0 mL (final)

(3.0 M)(0.025 L)
M2 = = 1.15 M
(0.065 L)