Академический Документы
Профессиональный Документы
Культура Документы
D-1
CET - 2012
KEY ANSWERS
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
Boscoss, Gopal Nivas Compound, Vriddashram Road, Near Sharada Vidyalaya, Mangalore-3, Ph: 0824-4272728, 9972458537/CET-2012
CHEMISTRY
CET - 2012
1. Ans(3)
80% petrol + 20% ethanol + small quantity of benzene
2. Ans(4)
A = Cumene B= Cumene hydroperoxide C= acetone
3. Ans (1)
CH4 +
2O2
CO2 +2H2O
t=0
20
50
0
0
t= t 20-20
50-40
20
volume
0
10 + 20 = 30
1 mol CH4 reacts with 2 mole of O2 to give one mole of CO2
Ans (2)
No of gram equivalents of acetic acid =
100 0.1
= 0.01
1000
0.5 10 2 22400
= 112 cm3
1
5. Ans (3)
Toluene
D-1
6. Ans (1)
order of reactivity 30>20>10
7. Ans (2)
Oil of winter green is an ester
8. Ans (3)
Acetophenone
9. Ans (2)
Rate = k [A]x x [B]y
Exptl no 2
Exptl no1
x
y
4 k [0.2] [0.4]
=
2 k [0.2] x [0.2] y
2 = 2y y =1
Exptl no 3
Exptl no 2
36 k [0.6] x [0.4] y
=
4 k [0.2] x [0.4] y
9 = 3x x =2
Rate = k [A] x [B]1
2
KK< 2s2 < *2s2 < 2p2z< [ 2p2x = 2p2y] < [ *2p2x = *2p2y]
11. Ans (4)
Na3[Co(N02)4Cl2] x= 3
EAN =Z-X+Y = 27-3+12 =36
12. Ans (1)
Ni[Ar] 3d84s2
Ni +2[Ar] 3d84s0 n =2
Magnetic moment = n( n + 2) = 8
13. Ans (3)
For a given value of n=3 the possible l values are 0,1,2 3f impossible
14. Ans (4)
1mol of water contains 6.022 x 1023 x10 electrons
15. Ans (2)
Linseed oil
16. Ans (4)
Amalgamating sodium
17. Ans (3)
low osmotic pressure
18. Ans (4)
Has crystal structure similar to dry ice (solid CO2 )
19. Ans (2)
Go = -2.303 RT log Kp
-2.303 x 8.314 x 298 x log 0.008
=
= 11.96 KJ
20. Ans (3)
water repellent
21. Ans (4)
F>O>N>P
22. Ans (1)
Buna-S (sodium)
23. Ans (3)
No definite geometry
24. Ans (4)
0.2 x V = 20 x 0.025 x 5
V = 12.5 ml
25. Ans (1)
Lewis base
0.0591
pH
n
= 0.0177V
32.
33.
34.
35.
36.
20/H
CH3MgI + HCHO CH3-CH2-O-MgI H
CH3-CH2-OH
Ans (3)
Ans (1)
O-toluic acid > benzoic acid > p-toluic acid o- toluic acid stronger than benzoic acid due to ortho effect.
Ans (2)
CH3-CH3
sp3-s and sp3-sp3
Ans (2)
4-Hydroxy -2-pentanone
Ans (4)
2.303
100 2.303
100
=
log
log
t
40
t
16
2.303
2.303
log 2.5 =
log 6.25
20
t
t= 40 mins
K2
T T1
Ea
=
x 2
K1 2.303 R
T1T2
Log 10=
Ea
300 270
x
Ea =2.303 x R x 2.7
2.303 R 300 270
2 .4
=1.2
2
48. Ans (3)
49. Ans (1) NaNC
50. Ans (4)
Glucose and protein
51. Ans (4)
100
=33.3 x2 (two p orbitals)=67
3
100
Diamond sp3 =
=25
4
graphite sp2 =
P0 P
=
P0
x
40
0.2 =
x + 40
40
n2
n1
x =10
20 --------96500
30 ----------- ?
Q = 144750
Q =I .t
144750 = 5 x t x 60 x 60 t = 8
56. Ans (4)
[H+]=
100 10 3 + 400 10 4
500
=0.00028
pH = 4 log 2.8
57. Ans (2)
log Kp =
nFE 0
2.303 R T
log Kp =
2 0.0295
0.059
log Kp =1 Kp =10
Boscoss, Gopal Nivas Compound, Vriddashram Road, Near Sharada Vidyalaya, Mangalore-3, Ph: 0824-4272728, 9972458537/CET-2012