Ministry of Water & Irrigation Water Authority of Jordan

Quality Aspects of Reclaimed Domestic Wastewater in Jordan To Water &wastewater Technology Conference Muscat- Sultanate of Oman-(0507) October_2004 By

Engineer Ahmed Ali Ulimat

Quality Aspects of Reclaimed wastewater in Jordan

Prepared By: Eng. AHMAD ALI ULEIMAT. Head, Environmental Monitoring and Assessment Division. WAJ LABS Amman Jordan. Ulimat_ Jor@Yahoo.com. Executive Summary:
Jordan is an arid to semi-arid country with a land area of approximately 89,342 km2. The capital of Jordan, Amman is a city of 1.6 million people located in the northwest portion of the country. More than 90% of Jordan receives less than 200 mm of rainfall per year Approximately 85% of the total average rainfall in Jordan are lost to evaporation. The remaining rainfall recharges ground water and contributes to rivers, wadi flows, and reservoirs. In many Jordanian cities, residents receive water only sporadically, and domestic water consumption is among the lowest in the world, less than 100 liters/capita/ days. The most feasible options for reducing the gap between water demand and supply are improved management of existing water resources, treating wastewater for reuse, and the rehabilitation of existing water sources. Moreover, Optimal development and utilization of water resources in Jordan and the institution of associated Water Policy requires the establishment and Implementation of several integrated resources, information and management systems. The Ministry of Water and Irrigation is responsible at the national level for Administering water policy, pollution control and managing water resources. In fact, with the advent of industrialization and increasing populations, the range of requirements for water have increased together with greater demands for higher quantity and quality of water. Water issues are linked to scarcity of water, which leads to a shift in water planning in Jordan towards, the use of non-conventional water resources mainly reclaimed wastewater. Reclaimed domestic wastewater means wastewater that has been used in the home including toilets, clothes washers, showers and laundry. Wastewater makes up 99.85% of sewage entering the treatment plants, this important resource has been considered from the highest level of Jordan government that it has a full value. In this paper, I will present a summary about Jordan experience as a developing country in quality aspects of reclaimed wastewater. The following subjects will be discussed: wastewater definition, Reclaimed wastewater standard no.893/2002 Means & ways to protect water resources from the effect of waste water quality deterioration, Physical, Chemical & Biological properties of wastewater, monitoring activities, treatment plants efficiencies, and cost of treatment. The paper will be finalized by conclusions and recommendations.

Quality Aspects of Domestic Wastewater In Jordan Prepared By: Eng. AHMAD ALI ULEIMAT. Head, Environmental Monitoring and Assessment Division. WAJ LABS Amman Jordan. Ulimat_ Jor@Yahoo.com. Introduction: The directorate of Laboratories & Quality through the Division of Environmental Monitoring and Assessment monitors wastewater all over the country. Reclaimed wastewater discharged from domestic wastewater treatment plants is an important component of Jordan water budget About 94.0mcm in the year 2003 was treated and discharged into various water course or used directly for irrigation and other intended uses. Effective protection of the environment requires accurate and detailed knowledge of existing environment conditions and the ability to detect and measure the water quality trends. The monitoring of reclaimed wastewater quality involves many distinct activities to give reliable and usable data. A monitoring program for domestic wastewater is designed according to standard no. 893/2002 to collect representative samples through QA and laboratories accreditation process. In fact, sewage treatment is a multi-stage process to renovate wastewater before it reenters a body of water, or it is reused. The goal is to reduce or remove organic matter, Solids, nutrients, disease, causing organisms and other pollutants from wastewater. Treatment plants should reduce pollutants in wastewater to a level nature can handle. What is waste water and why treat it? Wastewater is not just sewage. All the water used in the home that goes down the drains or into the sewage collection systems is wastewater. This includes water from baths, Showers, sinks, dishwashers, washing machines, and toilets. In combined municipal sewage systems, water from storm drains is also added to the municipal wastewater sewer system. The average Jordanian contributes < 100 liters of waste water each day. Wastewater is about (99.85)% water by weight and is generally referred to influent as it enters the treatment plant. Domestic wastewater is wastewater that comes primarily from in dividuals, and doesnt generally include industrial wastewater. Moreover, domestic wastewater in Jordan includes industrial wastewater from industries connected to the public sewer system. Wastewater Treatment: The existing public sector wastewater treatment plants in Jordan are 20 using different type of treatment systems the systems are divided into trickling filters, Activated sludge and waste stabilization ponds as shown in table# 1.

A common Set of processes that might be found at a municipal treatment plant would be: Preliminary treatment to remove large or hard solids that might clog or damage other equipment. Primary settling basins, where the water flows for up to a few hours, to allow organic suspended matter to settle out or float to the surface and these settling tank can be rectangular or circular. Secondary treatment, a type of wastewater treatment used to convert dissolved and suspended pollutants into a form that can be removed, producing a relatively highly treated effluent. It utilizes biological treatment processes follow by settling tanks and will remove approximately 85% of the BOD and TSS in wastewater. Secondary treatment for municipal wastewater is the minimum level of treatment required. Tertiary treatment: any level of treatment beyond secondary treatment, which could include filtration, nutrient removal (removal of nitrogen and phosphoras) and removal of toxic chemicals or metals. This type of treatment will be used in the new Aqaba treatment plant under construction.

Jordanian Waste water Quality Standards: WAJ Follows national legislation that has been issued by the Jordanian Institute of Standards and Metrology (JSIM) and regulations issued by the Minister of Water and Irrigation. The most important standards which wastewater Quality is governed by can be summarized into:

1. JS 893/2002: This Jordanian standard addresses the standard requirements and quality control for reclaimed water. It deals with requirements and properties that domestic wastewater must meet before being discharged to any receiving body or reused for agriculture or other intended uses. 2. JS 202/91: This standard deals with the industrial wastewater, which is produced after being used for industrial purposes. The aim of implementing Industrial wastewater monitoring program is to protect the environment, Water resources, Safeguard health and human safety. In case of discharging the industrial wastewater or reuse, it should meet and comply with the above standard that has been renewed.

3. Regulations issued by the Ministry of Water and Irrigation according to WAJ Law no 18/1988. These regulations deal with industries to be connected to public sewer systems in order to control releases of wastewater to sewer pipelines and treatment systems. Each industrial establishment should get a permission to connect its effluent to sewer system.

MONITORING ACTIVITIES: Waste water Monitoring Programs at labs & Water Quality Control department can be summarized as follows: A) Domestic wastewater quality monitoring program: 1) This program focuses on monitoring the effluents & influents from the public Treatment plants, which are operated by WAJ. These treatment plants are all mainstream technologies that are in common use throughout the world and would be classified into: Activated sludge system: Jerash, Salt, Abunussier, Irbid, Douqara, WadiHasan, Wadi Mousa, and Fuhes Madaba. Biological contractors: Karak, Baqa, Tafila, and Ajlun. Stabilization ponds system: As samra, Mafraq, Maan, Aqaba, WadiEsseer &Ramtha. 2-This program focuses on monitoring the effluents of 20 Treatment plants that are operated by private sector such as Muta T.P effluent Maeen T.P and others. The basic objective of the implementation of this program is to control the pollution loads and minimize their effects on ground water and surface water, which can be achieved by having a well design operational system so that its effluent complies with the Jordan standards to be used for the recommended application since the water strategy gives a high priority and a full value for the reclaimed water in the water budget. A. B) Streams, Wadis, Dams and reservoirs Monitoring Program: The number of sites to be monitored is about (60). This program is designed to monitor selected sites Such as King Talal dam, Wadi Arab Dam, and others, which receive direct flow from domestic wastewater treatment plant. This will measure the pollution loads and effects on water resources and the environment. The generated water quality data will be evaluated and decided its suitability for irrigation. D. Industrial Waste Water Monitoring Program : This program focuses on monitoring the effluents of more than 175 industrial establishments. These factories are classified as Follows: 1) Connected Industries to the sewer system: the evaluation is based on WAJ regulations in order to protect the sewer pipelines and the treatment plant system. 2) Non-connected industries to the sewer system: the evaluation of the water quality is based on the Jordanian standard 202 witch is specified for factories dumping their waste in to the environment. The over all value of implementing this monitoring program is to protect the water resources from the toxic materials and pollution loads resulting from the industrial emissions. New approach for monitoring mechanism:

The role of government in monitoring is being reevaluated in Jordan. The old model government does every thing and pays for every thing, is being replaced by private sector participation. The countries of USA, Canada and European counties are using this mechanism. In fact, this means that Jordan government will focus in setting and enforcing rules and standards. Waste Water Analysis: Various types of pollutants are present in domestic wastewater that can be measured by many different parameters as shown in table (2,3). The most important class of wastewater contaminants are compounds that react with oxygen which are characterized by COD,BOD and the second class is suspended solids . Wastewater Evaluation: The generated water quality data will be evaluated according to the reclaimed wastewater standard no 893/2002. After the evaluation process the directorate issues monthly, quarterly, biannual, annual reports that show treatment plants violating the standard. The objective of issuing these reports is to address the problems and asking for correction to protect and minimize their effects on resources and the anvironment more over, the water quality differs from treatment to another depending on the operation conditions and the treatment system. For example the BOD5 measures the amount of oxygen microorganisms require in five days to break down sewage. Untreated sewage has a BOD5 ranging from (475mg/l at WadiArab T.P to 1137 mg/l Madaba T.P that means that it is a strong sewage comparing it with raw sewage at USA, which ranges from (100300) mg/l. Table 4 no.# will show the difference of untreated wastewater concentration from govern orate to another. Treatment plants efficiency: The efficiency of 20 treatment plants as shown in table # 5 measured by BOD5 as an indicator of removing dissolved organic matter from treated sewage it ranges from 71% for maan T.P to 99% for Wadi Arab T.P. The efficiency for the wastewater treatment plants& the operation systems used in Jordan is shown in figure NO(1,2) for the year2003. The above figures clarify that the activated sludge is very effective in removing dissolved organic matter and WAJ can rely on it as a first choice and after that the trickling filter. The historical data show that the wastewater stabilization ponds have a low efficiency in removing dissolved organic matter. which is clear from figure no .1 reclaimed wastewater standard 893/2002. How well are we doing? WAJ so far has provided the service on sewer and treatment systems. 20 treatment plants exist all over the country working 24 hours a day. The number of carried out connections is (172133) at the end of the year 2003, 67% of these connections flow to SAMRA T.P wastewater treatment plants operate at a critical point of the water cycle, helping nature defend water from excessive pollution.

Treated wastewater quantity: The wastewater quantity flows to treatment plant plants is about 94.1 MCM for the year 2003 as shown in table # 6 and it was increased by (6.27%) from the year 2002(88.6) MCM. More over, 72.5% of wastewater quantity was treated at Sammra T.P. The quantity of reclaimed water is about (74) MCM for the year 2003.In fact, WAJ has a goal of attaining total water reuse by having highly treated effluent to be used in the required aspects according to Jordan Water Strategy.

Cost of Treatment: The treatment cost differs from treatment plant to another, the minimum cost was (16.2) fils /m3 at Aqaba T.P and the maximum cost was (798.4) fils / m3 for Wadi Musa table No.7 will show the cost of treatment for 19 T.P for the year 2003.

Conclusions: 1. Water reclamation and reuse water expanded so rapidly in recent year. It is a clear indication that the highest level of government in Jordan recognizes the full value of reclaimed water to the over all water resources of the country. 2. Current reclaimed wastewater standard regulate water reuse and environmental discharges to ensure optimal performance of the wastewater treatmentplants. 3. Reclaimed water used for irrigation shall be used with use are controls that protect the heath and safety of worker and the general public who may be exposed to the water. 4. Planned reuse programs should be created to stop discharging wastewater effluent to streams and catchments areas. 5. There is a need for active and collaborative involvement of another ministries and agencies and public participation to make use of reclaimed wastewater in different aspects. 6. Reclaimed wastewater monitoring program should be implemented according to standard 893/2002 from both the regulatory body and the operational agency. 7. There is a need to conduct research projects based on actual uses of reclaimed water. 8. Public awareness program should be implemented all over the country to let the people accept the reuse of reclaimed wastewater in irrigation and other uses.

Technical References: 1-Jordanian Reclaimed wastewater standard 893/2002. 2-FAO Guidelines for Agriculture,1991. 3-Reuse of Effluents,Methods of Wastewater Treatment &Health Safeguards WHO,1989. 4-STANDARD,REGULATIONS& LEGISLATION FOR WATER REUSE IN JORDAN/USAID/ARD-JANUARY 2002. 5-WASTEWATER ANNUAL REPORT 2003/DEPT OF WASTEWATER SYSTEMS-WAJ. 6-Wastewater Treatment by K.Stenstorm/www.ioe.ucla.edu/report 98/wastewater. Michael

7-Wastewater Treatment www.ohioline.osu.edu.

Principles

by

Karen

Mancl-

8-Labs Annual report for the year 2002 & 2003.

9-Operation of Wastewater Treatment Plants,volume 1 EPA,Kenneth D.Kerri,1998.

*** APENDIX 1 DATA & FIGURES .

CONTAINS WATER QUALITY

APENDIX 1:

WASTEWATER TREATMENT

PLANTS
No.

TABLE(1 )
OERATION SYSTEM Activated sludge
Activated Sludge

TREATMENT PLANT Irbid treatment plant 1

Jerrash treatment plant Activated Sludge Salt treatment plant Activated Sludge Abu nussier treatment plant Activated Sludge Madaba treatment plant Activated Sludge Fuhes treatment plant Activated Sludge Wadi arab treatment plant Activated Sludge Wadihassan treatmentplant Activated Sludge Wadimussa treatment plant WSP Ramtha treatment plantnt WSP Mafraq treament plant WSP Maan treatment plant WSP Aqaba treatment plant WSP Wadi essier treatment plant WSP Samra treatment plant Tickling filter Kufranja treatment plant Tickling filter Karak treatment plant Tickling filter Taffila treatment plant Tickling filter Baqa treatment plant Activated Sludge TEL MANTEH plant Microbiological Analysis for Water and Wastewater

2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

Analysis Total Coliforms

Fecal Coliforms (Total Thermo tolerant Colifroms) 2 Escherishia coli 2 Fecal Coliforms (Total Thermotolerant Colifroms ) Direct Test Total Coliforms & Escherishia coli

Total Coliforms & Escherishia coli

Pseudomonas aeruginosa Fecal Streptococcus & Enterococcus groups Clostridium perfringes

Method Used Standard Total Coliform Fermentation Technique Multiple Tube Fermentation Technique Multiple Tube Fermentation Technique Using EC MUG Medium Multiple Tube Fermentation Technique Presence/Absence Enzyme Substrate Test by Colilert Quantitative Enzyme Substrate Test by Colilert (Quanti-Tray) Multiple Tube Technique Multiple Tube Technique Most Probable Number (MPN) and Most Probable Range (MPR) / 100 ml Pour Plate Spread Plate Membrane Filtration

Reference & Method Number Standard Methods 20th edition 9221 A, B Standard Methods 20th edition 9221 E(1) Standard Methods 20th edition 9221 F,1 Standard Methods 20th edition 9221 E (2) Standard Methods 20th edition 9223 B Standard Methods 20th edition 9223 B Standard Methods 20th edition 9213 F Standard Methods 20th edition 9230 A, B The Microbiology of Water Drinking Water 1994. Report on Public Health and Medical Subject No. 71 London (HMS0) Standard Methods 20th edition 9215 A Standard Methods 20th edition 9215 C Standard Methods 20th edition 9215 D Standard Methods 20th edition 9260 In-house Standard Operating Procedure /User Manual American Water Works Association (AWWA )Manual Chapter 5, 1995 & Standard Methods 20th edition 10200 C 2

Heterotrophic Plate Count

Pathogenic Bacteria 3 Bacterial Identification to Species

Detection of Pathogenic Bacteria API Method by Biomerieux System

Free-Living Organisms/Nematodes

Membrane Filtration Technique

Protozoa:Giardia & Cryptosporidium

Well Slide

Proposed by EPA & Standard Methods 19 th edition 1995, 9711 B Modified from ICR/EPA by Clancey Group

Table No (2)

Wastewater Chemistry

Analysis pH Turbidity Biological Oxygen Demand Biological Oxygen Demand (filtered) Chemical Oxygen Demand Total Suspended Solids Total Dissolved Solids Total Solids Total Volatile Solids Total Volatile Suspended Solids Total Fixed Solids Total Fixed Suspended Solids Total Phosphate Phosphate Ammonium Nitrate Nitrite

Method Used Electrometric Nephelometric 5 Day BOD Test 5 Day BOD Test Closed Reflux, Titrimetric Dried at 103 105 Co Dried at 180 Co Dried at 103 105 Co

Reference & Method Number Standard Methods 20th edition 4500 H+ Standard Methods 20th edition 2130 B Standard Methods 20th edition 5210 B Standard Methods 20th edition 5210 B Standard Methods 20th edition 5220 C Standard Methods 20th edition 2540 D Standard Methods 20th edition 2540 C Standard Methods 20th edition 2540 B Standard Methods 20th edition 2540 E Standard Methods 20th edition 4500 PD Standard Methods 20th edition 4500 G / P Standard Methods 20th edition 4500 H / NH3 Standard Methods 20th edition 4500 I / NO3 Standard Methods 20th edition 4500 I / NO2

Ignition at 550 Co

Stannous Chloride Flow Injection Flow Injection Cadmium Reduction Flow Injection Cadmium Reduction Flow Injection

Table No (3)

Analysis

Method Used

Reference & Method

Total Nitrogen

Chemiluminescences Gas Analyzer Calculation

Kjeldahl Nitrogen

Boron

Flow Injection

Chloride

Argenometric

Sulfate Sodium, Potassium, Calcium, Magnesium Oil & Grease Anionic Surfactants Iron, Manganese, Copper, Chromium, Cadmium, Nickel, Lead, Zinc, Vanadium, Cobalt, Aluminum, Silver, Tin, Lithium, Molybdenum, Barium, Beryllium Zinc, Iron, Manganese, Copper, Chromium, Cadmium, Nickel Arsenic, Selenium Mercury Chromium +6

Turbidimetric

Ion Chromatographic Partition Gravimetric Surfactants MBAS

Number In-house Standard Operating Procedure /User Manual In-house Standard Operating Procedure /User Manual In-house Standard Operating Procedure /User Manual Standard Methods 20th edition 4500 B / Cl Standard Methods 20th edition 4500 E / SO4 In-house Standard Operating Procedure /User Manual Standard Methods 20th edition 5520 B In-house Standard Operating Procedure /User Manual

Inductively Coupled Plasma/ Atomic Emission Spectroscopy Direct Air Acetylene Flame Hydride Generation System Polarographic

Standard Methods 20th edition 3120 B

Polarographic

Cyanide

Polarographic Gas Chromatographic /Flame Ionization Detector

Phenol

Standard Methods 20th edition 3111 B Standard Methods 20th edition 3114 C In-house Standard Operating Procedure /User Manual In-house Standard Operating Procedure /User Manual In-house Standard Operating Procedure /User Manual In-house Standard Operating Procedure /User Manual

Table No (3)
Ministry of Water & Irrigation

Water Authority of Jordan Laboratories & Quality Department

Table (7): Cost of Treatment. * source: Wastewater Department

wwtp
Aqaba wsp As-samra wsp wadiessir Ramtha Mafraq Baqaa Jerash Maan Irbid Kufranja Salt Abu-nuseir Karak Madaba wsp Wadi arab Fuheis Tafila Wadi hassan Wadi mousa

Cost of treatment* Fils/m3

16.2 18.6 39.6 46.7 57.5 65.3 69.3 69.5 75.4 100.0 107.0 119.6 142.0 142.7 145.4 164.5 232.7 484.1 798.4

Ministry of Water & Irrigation Water Authority of Jordan Laboratories & Quality Department Table(6): Treated Water quantity. 1996 1997 1998 1999 2000
M3/day M3/day M3/day M3/day M3/day

Year

1994
M3/day

1995
M3/day

2001
M3/day M3/day

2003
M3/day

Samra Aqaba Irbid Salt Jerash Mafraq

129177

143441

148795

156746

168857

166844

170752

186081

178902

186823

5488 7238 3761 1354 1317

6014 7620 3870 1450 1290 6920 1165 1497 1013 1431 1530 2440 730 -------------

6666 8149 4053 1524 2379 6891 1266 1463 966 1414 1672 2693 1517 -------------

7341 9287 4077 1555 2638 7301 1164 1486 747 1675 1802 3309 1649 856 410 -------

8219 8474 3825 1804 2297 8783 1122 1499 862 1617 1923 3219 2240 819 847 -------

8774 4612 3166 1603 1933

8804 4610 3403 2072 1847

9310 5081 3598 2743 1889

9329 7121 3898 2913 1805

10332 8103 4248 4359 2189 12052 1574 2215 844 3071 2119 4422 2787 2445 1944 6667 900

Baqa a 5214 Karak 1071 Abo Nuseir 1532 Tafila Ramtha Ma an 936 1247 1350

10284 11185 11516 11768 1146 1231 1275 1508 1411 1617 1800 1977 851 2174 1738 3609 1734 914 1019 5993 ---707 2340 1892 4266 1889 1113 1218 5985 ---736 1889 1556 4611 1864 1402 1217 5735 532 740 2300 2155 4178 2223 1917 1523 7063 866

Madaba 2077 Kufranja 690 Wadi Alsee ----Fuhis ----Wadi Arab ----Wadi Mous -----

Wadi ------------------------280 423 725 Hassan Total m3 \ d 162452 180411 189448 202043 216407 217805 224931 243115 242609.9 257819 Total(MCM 59.3 65.9 69.3 73.7 79.0 79.5 82.3 88.7 88.6 94.1 M3 \yr|

* source: Wastewater Department

Ministry of Water & Irrigation Water Authority of Jordan

Laboratories & Quality Organic Loads

Plant* Madaba Jerash Kufranja Irbid Baqaa Salt Wadi Hassan Mafraq Wadi Arab Ramtha As-samra Tafila Karak Maan Fuhis Wadi Alseer Wadi Mousa Abu-Nusir Aqaba BOD5(mg/l) 1137 1114 1076 1066 986 848 802 728 709 696 693 691 654 607 604 538 527 525 475

Table(4)

 2002
0001

( 5BOD mg

001

01

001 08

06 04 02 0

0002

1002

2002

2002
0.59 3.69 0.59 8.69 5.69 0.76 0.89 9.69 3.59 4.39 8.29 5.88 0.88

0.001 0.08

4.48

2.59 8.57 8.27 5.96

6.68

0.06 0.04 0.02 0.0

18

Domestic Waste Water Treatment Plant Efficiencies in 2003

100.0 95.1 95.0 90.0 85.0 80.0 75.0
Sa lt uf ra nj eh K he rb B it aq A a lS am A ra bu N us ei W r ad iS ei r Ja ra sh K Fu he is

96.4 93.8 94.7

97.5 95.4

89.6

Efficiency

83.2

Waste Water Treatment Plant

Domestic Waste Water Treatment Plant Efficiencies in 2002

100.0 98.0 96.0 94.0 92.0 90.0 88.0 86.0 84.0 82.0 80.0
Sa K lt uf ra nj eh K he rb B it aq A a lS am A ra bu N us ei W r ad iS ei r Ja ra sh Fu he is

98.0 96.3 95.0 95.0 95.2 93.4

Efficiency

88.0 86.6

Waste Water Treatment Plant

Domestic Wastewater Samples ResultsEflluents for 2003 (BOD) mg/L 60 29 10 12 14 20 11 7.0 6.0 5.00 13.0 13 13.0 7 4 38.0 22.0 <5.0 <5 11.0 <5.0 14 19.0 18.0 (COD) Chloride Phosphate T.D.S mg/L mg/L mg/l as P mg/L pH unit 3.0 7.2 7.0 2.5 4.1 3.2 3.6 6.8 6.89 6.80 7.30 6.80 7.30 6.2 8.0 7.5 6.90 7.80 7.00 6.70 7.50 8.00 6.00 6.5 6.8

Abu Nusseir T.P Abu Nusseir T.P Abu Nusseir T.P Abu Nusseir T.P Abu Nusseir T.P Abu Nusseir T.P Abu Nusseir T.P Abu Nusseir T.P Abu Nusseir T.P Abu Nusseir T.P Abu Nusseir T.P Abu Nusseir T.P Abu Nusseir T.P Abu Nusseir T.P Abu Nusseir T.P Abu Nusseir T.P Abu Nusseir T.P Abu Nusseir T.P Abu Nusseir T.P Abu Nusseir T.P Abu Nusseir T.P Abu Nusseir T.P Abu Nusseir T.P Abu Nusseir T.P Chloraniation Abu Nusseir T.P Chlorination

Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent /After

02/01/2003 21/01/2003 03/02/2003 11/03/2003 20/03/2003 28/03/2003 01/04/2003 03/05/2003 15/05/2003 11/06/2003 25/06/2003 01/07/2003 19/07/2003 05/08/2003 21/08/2003 06/09/2003 16/09/2003 01/10/2003 11/10/2003 01/11/2003 15/11/2003 04/12/2003 16/12/2003 19/04/2003

00:00 00:00 00:00 00:00 00:00 00:00 00:00 00:00 00:00 00:00 00:00 00:00 00:00 00:00 00:00 00:00 00:00 00:00 00:00 00:00 00:00 00:00 00:00 00:00

60 92 94 96 55.0 84 57 376.9

14.6 14.5 15.93

1172 1136 956 1128 1077 1262 1298 1001 976 1371 1596

Effluent /Before 19/04/2003 00:00

Alkherbeh Effluent Alkherbeh Effluent Alkherbeh Effluent Alkherbeh Effluent Alkherbeh Effluent Alkherbeh Effluent Alkherbeh

Alsamra (site 4.0)T.P 07/01/2003 00:00 Alsamra (site 4.0)T.P 15/01/2003 00:00 Alsamra (site 4.0)T.P 06/03/2003 00:00 Alsamra (site 4.0)T.P 11/03/2003 00:00 Alsamra (site 4.0)T.P 31/03/2003 00:00 Alsamra (site 4.0)T.P 08/04/2003 00:00 Alsamra (site 4.0)T.P 08/05/2003 00:00

(BOD) mg/L 186 177 132 90 146 108 102.0

(COD) Chloride Phosphate T.D.S mg/L mg/L mg/l as P mg/L

pH unit 8.1 8.6 8.2 8.0 8.1 8.2 8.00

Effluent Alkherbeh Alsamra Effluent Alkherbeh Alsamra Effluent Alkherbeh Alsamra Effluent Alkherbeh Alsamra Effluent Alkherbeh Alsamra Effluent Alkherbeh Alsamra Effluent Alkherbeh Alsamra Effluent Alkherbeh Alsamra Effluent Alkherbeh Alsamra Effluent Alkherbeh Alsamra Effluent Alkherbeh Alsamra Effluent Alkherbeh Alsamra Effluent Alkherbeh Alsamra Effluent Alkherbeh Alsamra Effluent Alkherbeh Alsamra Effluent/s.1 Baqaa T.P Effluent Baqaa T.P Effluent Baqaa T.P Effluent Baqaa T.P Effluent Baqaa T.P Effluent Baqaa T.P Effluent Baqaa T.P Effluent Baqaa T.P Effluent Baqaa T.P Effluent Baqaa T.P Effluent Baqaa T.P Effluent Baqaa T.P Effluent

(site 4.0)T.P 02/06/2003 00:00 (site 4.0)T.P 11/06/2003 00:00 (site 4.0)T.P 05/07/2003 00:00 (site 4.0)T.P 29/07/2003 00:00 (site 4.0)T.P 11/08/2003 00:00 (site 4.0)T.P 17/08/2003 00:00 (site 4.0)T.P 04/09/2003 00:00 (site 4.0)T.P 29/09/2003 00:00 (site 4.0)T.P 06/10/2003 00:00 (site 4.0)T.P 14/10/2003 00:00 (site 4.0)T.P 04/11/2003 00:00 (site 4.0)T.P 16/11/2003 00:00 (site 4.0)T.P 02/12/2003 00:00 (site 4.0)T.P 28/12/2003 00:00 (site 4.0)T.P 29/04/2003 00:00 02/01/2003 21/01/2003 03/02/2003 11/03/2003 20/03/2003 28/03/2003 01/04/2003 19/04/2003 03/05/2003 15/05/2003 11/06/2003 25/06/2003 00:00 00:00 00:00 00:00 00:00 00:00 00:00 00:00 00:00 00:00 00:00 00:00

118

8.10 8.20 7.90 1220 8.03 7.5 8.0 8.3 241.4 18.6 1290 1124 236 293.3 11.36 1361 1428 17.92 19.91 400.2 1188 1324 1299 7.80 7.60 7.90 7.80 7.60 7.60 7.52 7.80 8.3 8.0 8.0 7.8 8.2 7.0 8.3 8.1 7.90 7.48 8.10 8.0 (COD) Chloride Phosphate T.D.S mg/L mg/L mg/l as P mg/L 1232 1192 1336 1268 1382 pH unit 7.90 7.70 7.5 8.0 7.5 7.7

92 240 48.0 69.0 143 297 403.6 6.75

1282 1284

94.0

324.0 336

84.0

321

76.0 74 36 21 42 27 9 47 62.0 21.0 9.00 42.0 27.0 (BOD) mg/L 14 25.0 26 21 16 7 39.0

Baqaa Baqaa Baqaa Baqaa Baqaa Baqaa Baqaa Baqaa

T.P T.P T.P T.P T.P T.P T.P T.P

Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent

01/07/2003 19/07/2003 05/08/2003 21/08/2003 25/08/2003 26/08/2003 26/08/2003 27/08/2003

00:00 00:00 00:00 00:00 12:00 00:00 10:30 00:00

99 84 24 95.0

Baqaa T.P Effluent Baqaa T.P Effluent Baqaa T.P Effluent Baqaa T.P Effluent Baqaa T.P Effluent Baqaa T.P Effluent Baqaa T.P Effluent Baqaa T.P Effluent Baqaa T.P Effluent Baqaa T.P Effluent Baqaa T.P Effluent Jarash T.P Effluent Jarash T.P Effluent Jarash T.P Effluent Jarash T.P Effluent Jarash T.P Effluent Jarash T.P Effluent Jarash T.P Effluent Jarash T.P Effluent

27/08/2003 12:00 06/09/2003 00:00 16/09/2003 00:00 01/10/2003 00:00 06/10/2003 00:00 11/10/2003 00:00 28/10/2003 00:00 01/11/2003 00:00 15/11/2003 00:00 04/12/2003 00:00 16/12/2003 00:00 13/01/2003 00:00 25/01/2003 00:00 17/02/2003 00:00 08/03/2003 00:00 22/03/2003 00:00 24/03/2003 00:00 07/04/2003 00:00 26/04/2003 00:00

13.0 35.0 41.0 36.0 6 37.0 18.0 97 60 51 92 30 14 28 34 5.0

152.0 75 92

1480.0 1280 1240 1364 1509 15.72 16.7 17.92 306 1322 1213 1699 1584

7.60 8.2 7.40 7.80 7.50 7.50 7.80 8.30 7.60 8.1 7.0 8.0 7.3 7.6 8.0 7.3 8.0

139 168.0 140 112