CHM12-3 Exam No.

5 4th Term 2011-2012

School of Chemical Engineering and Chemistry

Name: _________________________________________ Student Number: ________________________________ Professor: ______________________________________

HONESTY PLEDGE: I have been totally honest during the conduct of and I have neither given nor received unauthorized aid on this exam.

______________________________________ Student Signature

Write the CAPITAL letter of your choice in the appropriate box.

1. 2. 3. 4. 5. 6. 7. 8. 9. 10.
CUT HERE. Submit this portion together with your yellow test booklet.

11. 12. 13. 14. 15. 16. 17. 18. 19. 20.

I. Principles of Thermochemistry. Write the CAPITAL letter of your choice on the appropriate box above. 1) Which of the following statements is FALSE? A) E is a state function B) The actual numerical value of E can be measured C) E= Efinal - Einitial D) E = q + w E) When a system undergoes a process in which it gains energy from the surroundings, the E for the process is positive 2) The internal energy of a system is always increased by A) adding heat to the system B) having the system do work on the surroundings C) withdrawing heat from the system D) adding heat to the system and having the system do work on the surroundings E) a volume compression 3) Which of the following conditions would always result in an increase in the internal energy of a system? A) The system loses heat and does work on the surroundings. B) The system gains heat and does work on the surroundings. C) The system loses heat and has work done on it by the surroundings. D) The system gains heat and has work done on it by the surroundings. E) None of the above is correct. 4) When a system _________, E is always negative. A) absorbs heat and does work B) gives off heat and does work C) absorbs heat and has work done in it D) gives off heat and has work done on it E) none of the above, E is always positive. 5) Which one of the following is an exothermic process? A) ice melting B) water evaporating C) boiling soup D) condensation of water vapour E) ammonium thiocyanate and barium hydroxide are mixed at 25oC: the temperature drops

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CHM12-3 Exam No. 5 4th Term 2011-2012

School of Chemical Engineering and Chemistry

6) Of the following, which one is a state function A) H D) heat B) q E) none of the above C) w 7) Which one of the following statements is true? A) Enthalpy is an intensive property. B) The enthalpy change for a reaction is independent of the state of the reactants and products C) Enthalpy is a state function D) H is the value of q measured under conditions of constant volume. E) The enthalpy change of a reaction is the reciprocal of the H of the reverse reaction. 8) H for an endothermic process is _________ while H for an exothermic process is ___________. A) zero, positive B) zero, negative C) positive, zero D) negative, positive E) positive, negative 9) The internal energy can be increased by i. transferring heat from the surroundings to the system ii. transferring heat from the system to the surroundings iii. doing work on the system A) i only D) i and iii B) ii only E) ii and iii C) iii only 10) Objects can possess energy as i. endothermic energy ii. potential energy iii. kinetic energy A) i only D) i and iii B) ii only E) ii and iii C) iii only II. PROBLEM SOLVING. Write the capital letter of your choice on the appropriate box above. Show your calculations on your yellow testbooklet. NO SOLUTION, NO CREDIT. 11) The value of E for a system that performs 213kJ of work on its surroundings and loses 79 kJ of heat is ________ kJ. A) +292 D) -134 B) -292 E) -213 C) +134 12) Calculate the value of E in joules for a system that loses 50 J of heat and has 150J of work performed on it by the surroundings. A) 50 D) -200 B) 100 E) +200 C) -100 13) The value of Ho for the reaction below is -790 kJ. The enthalpy change accompanying the reaction of 0.95g of S is ______________ kJ. 2S (s) + 3 O2 (g) 2SO3 (g) A) 23 D) 12 B) -23 E) -790 C) -12

14) The value of Ho for the reaction below is 482 kJ. Calculate the heat (kJ) released to the surroundings when 12g of CO(g) reacts completely 2CO(g) + O2(g) 2CO2(g) A) 2.89 x 103 D) 65.7 B) 207 E) -482 C) 103 15) The enthalpy change for the following reaction is -486.3 kJ. 2H2(g) + O2(g) 2H2O (g) Therefore, the enthalpy change for the following reaction is ___________ kJ. 4H2O (g) 4H2(g) + 2O2(g) A) 483.6 B) 2.34 x 105 C) 967.2 D) -967.2 E) -483.6 16) A sample of aluminum metal absorbs 9.86 J of
heat, upon which the temperature of the sample increases from 23.2oC to 30.5oC. Since the specific heat capacity of aluminum is 0.90 J/g-K, the mass of the sample is _______ g. A) 72 D) 8.1 B) 1.5 E) 6.6 C) 65 17) The temperature of a 15-g sample of lead metal increases from 22oC to 37oC upon the addition of 29.0J of heat. The specific heat capacity of the lead is __________ J/g-K. A) 7.8 D) 0.13 B) 1.9 E) -29 C) 29 18) Given the following reactions

Fe2O3(s) + 3CO(s) 2Fe(s) + 3CO2(g) H= -28.0kJ 3Fe(s) + 4CO2(s) 4CO(g) + Fe3O4(s) H= +12.5kJ the enthalpy of the reaction of Fe2O3 with CO 3 Fe2O3(s) + CO(s) CO2(s) + 2Fe3O4(s) is ______________ kJ. A) -59.0 D) -109 B) 40.5 E) +109 C) -15.5

19) Using the standard enthalpy of formation data, o determine the H rxn for the reaction 4NH3(g) + 5O2(g) 4NO(g) + 6H2O(l) A) -1172 D) -1892 o B) -150 E) The H f of O2(g) C) -1540 is needed 20) The combustion of titanium with oxygen produces
titanium dioxide: Ti(s) + O2(g) TiO2 (s) When 0.721 g of titanium is combusted in a bomb calorimeter, the temperature of the calorimeter increases from 25.00oC to 53.80oC. In a separate experiment , the heat capacity of the calorimeter is measured to be 9.84 kJ/K. The heat of reaction for the combustion of a mole of Ti in this calorimeter is ____________kJ/mol. A) 2.67 D) -0.154 B) 4.98 E) -1.49 x 104

C) -311
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