ENSINGER essentials. Technical know-how for plastic applications.

Table of Contents
Classification of Plastics High Temperature Plastics Engineering Plastics Water Absorption Modification Options Thermal Resistance Characteristic Mechanical Values Sliding and Abrasive Characteristics Flame Protection Classification Radiation Resistance of Plastics Applications in Electrical Engineering Applications in Foodstuffs and Medical Technology 3 4 5 6 6 7 8 9 10 11 12 13 Processing of Plastics Machining guidelines Annealing specifications Welding Adhesion 14 14 16 17 17

Available Dimensions for Semi-Finished Goods 18 Exclusion from Liability Material Standard Values Note to Material Standard Values ENSINGER High Temperature Plastics ENSINGER Engineering Plastics Chemical Resistance 19 19 19 20 24 26

Classification of Plastics

High temperature plastics

PBI PI PAI

300 C

PEKEKK PEEK PES, PPSU LCP PPS , PEI, PSU PTFE, PFA PPP PC-HT ETFE, PCTFE , PVDF

150 C

Engineering plastics

PA46, PA6/6T PC PET, PA66 PA6-3-T PBT, PA6 POM PMP PA11, PA12

100 C
PPE mod.

Standard plastics

PMMA PP PE PS, ABS, SAN

amorphous

semi-crystalline

Thermoplastic polymers can be divided into amorphous and semi-crystalline on the basis of their structure. Polymers with an amorphous structure are normally transparent and tend to be sensitive to stress cracking. They are suitable for making precision parts due to their high dimensional stability. Semi-crystalline plastics are opaque, mostly tough and show good or very good chemical resistance. Plastics can also be differentiated according to their temperature resistance: High-temperature plastics have long term service temperatures of above 150 C and have a high level of thermo-mechanical properties.

Plastics suitable for the highest application temperatures (PI, PBI, PTFE) cannot be processed using melting processes. Production of parts is carried out by sintering. Engineering plastics can be used permanently at temperatures between 100 C and 150 C. They exhibit good mechanical properties and good chemical resistance. Standard plastics can be used permanently at temperatures below 100 C. The above pyramid of plastic materials shows a detailed overview of thermoplastic polymers on the basis of these criteria.

High Temperature Plastics

I TECASINT (PI) Depending upon the type, provide high strength with a low level of creep and good wear-resistance up to 300 C in continuous use. Dimensional stability, electrical insulation, high purity, low outgassing. Suitable for thermally and mechanically stressed engineering elements and components. Inherently flame retardant. I TECATOR (PAI) Very good physical stability. Low level of creep, high chemical resistance. Tough. Good wear resistance, low thermal expansion coefficient, inherently flame retardant. I TECAPEEK HT (PEK) Increased level of properties compared to TECAPEEK. Very good abrasion characteristics. Suitable for high load sliding applications. Very good chemical resistance. Inherently flame retardant. I TECAPEEK (PEEK) Balanced profile of properties. Low level of creep, high modulus of elasticity. Excellent tribological properties, especially abrasion resistance. Very good resistance to different media, FDA compliant and physiologically harmless. Very good chemical resistance. Inherently flame retardant. I TECATRON (PPS) Very good chemical resistance, low level of creep, high dimensional stability, low moisture absorption, high modulus of elasticity, inherently flame retardant. I TECASON E (PES) Inherently flame retardant, good electrical and dielectric properties and thus well suited for use as electrical insulators. FDA compliant.

I TECASON P (PPSU) Good impact strength, chemical resistance and resistance to hydrolysis. Inherently flame retardant. FDA compliant. I TECASON S (PSU) High strength, rigidity and hardness. Low moisture uptake and very good dimensional stability. Inherently flame retardant. FDA compliant. I TECAPEI (PEI) Very good mechanical and electrical properties. Inherently flame retardant. FDA compliant. I TECAFLON PTFE (PTFE) Highest chemical resistance, permanent service temperature of 260 C. Exceptional sliding characteristics as well as excellent electrical properties. Inherently flame retardant. FDA compliant. I TECAFLON ETFE (E/TFE) Good kinetic friction properties, very good chemical resistance and very good mechanical properties. Inherently flame retardant. FDA compliant. I TECAFLON PVDF (PVDF) Very good chemical resistance, good electrical and thermal properties. Inherently flame retardant. FDA compliant.

Engineering Plastics

I TECAMID 12 (PA12) Very high durability, good chemical resistance, lowest water absorption of all polyamides. FDA compliant. I TECAMID 46 (PA46) Good thermal insulation. Very well suited for sliding and wearing parts which are exposed to raised temperatures. Very tough. I TECAMID 66 (PA66) Good rigidity, hardness, wear-resistance and dimensional stability, good kinetic friction characteristics, types complying to FDA available. For parts which are exposed to higher mechanical and heat loads.

I TECAMID 6 (PA6) Semi-crystalline thermoplastic with good damping capacity, good impact strength and high degree of toughness even at low temperatures, good wear-resistance, especially against rough frictional surfaces. I TECAST 6 (PA6 G) Cast polyamide with similar properties to TECAMID 6. Production of parts with large sizes and large wall thickness possible. I TECARIM (PA6 G) Very tough polyamide 6 block copolymer. Very good strength and toughness to be used advantageously in the low temperature range. Excellent resistance to impact and abrasion, good chemical resistance. Appliction specific adjustability of the material properties possible. I TECANAT (PC) Amorphous, transparent material with excellent impact strength, permanent service temperature 120 C, good mechanical strength, low level of creep and very good dimensional stability. FDA compliant. I TECAPET (PET) Good wear properties in moist or dry surroundings, high dimensional stability due to low thermal expansion, low moisture uptake, good dielectric properties, good chemical resistance. FDA compliant. I TECADUR PBT (PBT) High strength and durability with good dimensional stability, good sliding and wear characteristics, high precision thanks to low water uptake, very high rigidity as well as a low thermal expansion coefficient due to glass-fibre reinforcement.

I TECAFORM AH (POM-C) Semi-crystalline POM-copolymer with good physical properties. Low moisture uptake, good fatigue strength and rigidity, easily machined, good dimensional stability for parts with tight tolerances. Good sliding characteristics. FDA compliant. I TECAFORM AD (POM-H) Slightly higher mechanical values in comparison to TECAFORM AH, very good resilience and high surface hardness, very good kinetic friction properties. I TECARAN ABS (ABS) Very good electrical insulation, low water absorption, good damping capacity, can be bonded, high toughness and rigidity. Resistant to diluted acids and cleaning agents. I TECANYL (PPE) Very good electrical insulation, good welding and bonding characteristics, good strength, high toughness, resistant to hot water. I TECAFINE PE (PE) Very good electrical insulation, very low moisture absorption, good kinetic friction characteristics, good impact strength at low temperatures, good welding characteristics, resistant to various acids and cleaning agents, low density.

Water Absorption

Moisture uptake until saturation in % in standard climatic conditions

5 TECASINT 1011 TECATOR 2 TECAMID 66 GF 30 TECAMID 46 TECAMID 6, TECAMID 66

0,5 TECASON P TECAPEI TECAPET 0,2 TECAPEEK GF 30 0,1 TECAPEEK 0,05 TECATRON GF40 0,02 TECATRON TECAFLON PTFE TECAFINE PE TECADUR PBT TECANAT TECAFORM AH

TECAFLON PVDF

steel STAHL
0,01 0
Sta hl

10

12

14

Coefficient of linear thermal expansion (10 -5 1/K)

Polyamides show increased water absorption in comparison to other engineering plastics. This leads to dimensional changes in finished parts, to a reduction in strength and also changes the electrical insulating characteristics absorption.

Modification Options
Specific fillers can be used to modify the properties of plastics for the required application. I Reinforcing fibres Glass fibres are used mainly to increase the mechanical strength, particularly tensile strength. Other values, such as compression strength and temperature-dependent dimensional stability, are also improved. Carbon fibres may be used as an alternative to glass fibre to increase mechanical strength. Due to the lower density, higher strength values can be achieved using the same proportion by weight. Furthermore, carbon fibres improve the sliding and wear characteristics. I Colour The incorporation of pigments and colorants into technical plastics allows individually customised colour standards to be produced (e.g. according to RAL, Pantone, etc.), although the choice of pigments with high-temperature plastics is limited. I Light stabilization Weathering or continual exposure to high temperatures can lead to discolouration or affect the mechanical properties of many plastics. The addition of UV or thermal stabilisers helps prevent such effects. I Friction and wear-reducing fillers Graphite is pure carbon, which in a finely ground state exhibits high lubricating properties. By incorporating it uniformly into a polymer, the coefficient of friction can be lowered. PTFE is a high temperature fluor polymer. Typical of this material is its remarkable nonstick properties. Under pressure the particles from PTFE filled plastics develop a fine, sliding polymer film on the opposing material surface. Molybdenum disulphide is used primarily as a nucleating agent and forms a uniform fine crystalline structure even when small amounts are added, giving increased abrasion resistance and reduced friction.

Thermal Resistance

C 400 350 300 250 200 150 100 50 0

CA SI N CA T TE CA TO R PE E TE K H TE T CA CA PE PEE EK K TE GF TE 3 CA CAT 0 TR RO O N N TE GF CA 40 S TE ON CA S S TE ON CA E SO N TE T CA EC P FL AP TE EI O CA N FL PT F O N E TE PV CA D M F TE ID TE CA CAM 46 M ID ID 6 6 66 G F3 TE 0 CA TE N CA TE AT D CA U R PB PET T TE GF CA 30 TE FO CA RM F TE IN CA E P P FI N E PE

C 400 350 300 250 200 150 100 50 0

Left column: Heat deflection temperature according to the HDT-A procedure Right column: long term service temperature

The thermal resistance of a plastic is characterised mainly by the heat deflection temperature and the long term service temperature. The heat deflection temperature (HDT) is described as the temperature under which a deflection of 0.2 % is achieved under a specific bending stress. With the frequently used HDT-A procedure the bending stress used is 1,8 MPa.

TE

TE

The heat deflection temperature provides an indication of the maximum temperature in use for mechanically loaded components. The long term service temperature represents the temperature above which material decomposition takes place due to thermal stress. It should be noted that the mechanical properties at this temperature differ considerably from those at room temperature.

Characteristic Mechanical Values

Mechanical characteristics in tensile testing Tensile testing according to DIN EN ISO 527 serves to assess the characteristics of plastics in short-term, single-axle stressing. Important factors for the choice of a plastic, apart from the characteristics under stress and elongation, are the temperature and the time the load is applied. I Tensile stress is the tensile force in relation to the smallest measured initial cross-section of the test specimen at every arbitrary point during the experiment. Tensile strength B B is the tensile stress at maximum force. Tensile strength at break R is the tensile stress at the moment of break. Tensile strength at yield S is the tensile stress at which the slope of the curve describing the change of force versus length (see graph) equals zero for the first time. Elongation Is the change in length L in relation to the original length L0 of the specimen at every arbitrary point during the experiment. The elongation at maximum force is described as B, the elongation at break by R, the yield stress by S.

Stress MPa R B R S
brittle-hard plastics

tough-hard plastics

R
soft, elastic plastics

B R S R S B R S B R R

I I I

maximum stress tensile strength at break tensile strength at yield

elongation at maximum stress elongation at break elongation at yield

Modulus of elasticity E A linear relationship can only be observed in the lower range of the stress-elongation diagram for plastics. In this range Hookes law applies, which says that the ratio of the stress and strain (modulus of elasticity) is constant. E = / in MPa.

Comparison of E-modulus of different plastics (room temperature) in MPa

14000 8000 8000 9500 10000

7000

6000

5000

4000

3000

2000

1000

0
10 1 TE CA 1 CA TO PE R E TE K H TE CA T CA PE PE EK EK TE GF TE 3 CA CAT 0 TR RO O N N TE GF CA 40 S TE ON CA S S TE ON CA E SO N TE T CA EC P FL AP TE EI CA ON FL PT FE O TE N P CA VD F M TE ID TE CA 46 CA M MID * ID 66 66* TE GF CA 30 M * ID TE 6* CA TE N CA TE AT D CA U R P TE PBT ET CA G F3 F TE OR 0 CA M FO AH TE RM CA AD F TE IN CA E P P FI N E PE TE

TE C

AS I

*Left column: Dry

Right column: Moist

Sliding and Abrasive Characteristics

Plastics have proven to be useful in various applications as sliding materials. Particularly advantageous are their dry running properties, low noise and maintenance characteristics, chemical resistance and electrical insulation. The sliding and abrasive behaviour is in this respect not only a material property, but is determined specifically by the tribological system combining various parameters such as material combination, surface roughness, lubricant, load, temperature, etc. The inherently good sliding properties of plastics can also be modified to specific requirements by the use of additives (see section Modification Options page 6). ,

Additives such as glass fibre, glass beads or mineral fillers normally act abrasively on the sliding parts. Cast polyamides are frequently used for slide bearing applications, which is why a large number of dynamic friction optimised materials are also available. If bearings also have to work at high temperatures, high speeds or strong contact pressures, high temperature plastics are used. In the following diagrams, the tribological properties of various materials used for sliding bearings with different degrees of surface roughness are compared.

Coefficient of friction
0,8 TECAMID 66 GF

TECAPEEK TECAPEEK CF30 TECAMID 66 CF TECAMID 66 LA 0,4 0,6 TECAST L 0,2 TECAPEEK PVX 0 1 2 3 5

TECAMID 66 TECADUR PBT Hydex 4101 PBT TECAFORM AH

TECAFINE PE5

Conditions: Load: 1 MPa,, Speed: 0,5 m/s against steel with Rz = 2,5 m

10

20

50

100 Wear rate in m/km

Coefficient of friction
0,8 TECAPEEK CF30 0,6 TECAMID 66 CF 0,4 TECAPEEK 0,2 TECAFINE PE5 TECADUR PBT Hydex 4101 PBT TECAST L TECAMID 66 LA TECAFORM AH TECAMID 66 GF TECAMID 66

Conditions: Load: 1 MPa, Speed: 0,5 m/s, against steel with Rz = 0,2 m
6 Wear rate in m/km

0 0 1 2 3 4 5

Flammability Classification

High standards are set for flammability in various plastic applications. The classification of materials is generally made according to the UL Standard 94 test method of the Underwriters Laboratories. The classification into different fire classes is achieved using two test set-ups: Horizontal ame experiment according to UL 94 HB Material which is classified according to UL 94 HB may not exceed a maximum combustion rate of 76.2 mm/min at a wall thickness of less than 3.05 mm and with horizontal clamping. At a wall thickness of 3.05 12.7 mm this value should not exceed maximum 38.1 mm/min. Materials classified in this way are easily flammable and therefore may not meet the requirements of other flammability tests. Vertical ame experiment according to UL 94 In this experiment a flame is held for ten seconds against the vertically clamped test specimen and then removed. The time taken for the last flame to extinguish itself is measured, and this experiment is repeated ten times. Apart from the combustion time, the classification also takes into consideration whether burning droplets are formed. The various criteria are listed in the following table.

Classication according to UL 94
Classification according to UL 94
V-0 V-1 V-2

Burning time after each flame application Burning time after 10 repetitions Formation of burning droplets

10 s 50 s
no

30 s 250 s
no

30 s 250 s
yes

Oxygen index according to ASTM D 2863 The oxygen index of a material is defined as the minimum concentration of oxygen, expressed in vol.-% of an oxygen/nitrogen mixture, which maintains combustion of a defined material sample.

Material TECASINT 1011 TECASINT 2011 TECATOR TECAPEEK HT TECAPEEK TECAFLON PTFE TECATRON TECATRON GF40 TECASON E TECASON P TECASON S TECAFLON PVDF TECANAT TECANAT GF30 TECAPET

DIN Description PI PI PAI PEK PEEK PTFE PPS PPS PES PPSU PSU PVDF PC PC PET

Fire class acc. to UL 94

V-0 (3,2 mm) V-0 (3,2 mm) V-0 (3,2 mm) V-0 (1,6 mm) V-0 (1,45 mm) V-0 (3,2 mm) V-0 (3,2 mm) V-0 (0,4 mm) V-0 (1,6 mm) V-0 (0,8 mm) V-0 (4,5 mm) V-0 (0,8 mm) V-2 (3,2 mm) V-1 (3,2 mm) HB (3,2 mm)

Oxygen index according to ASTM D 2863

44 51

40 35 95

39

32 43

10

Radiation Resistance of Plastics

Depending upon the area of application, plastics can come into contact with different types of radiation which affect the structure of the material. The spectrum of electromagnetic radiation ranges from radio frequencies, with long wave-lengths, to normal daylight with short wave-length UV radiation to very short wave-length X-rays and gamma radiation. The shorter the wave-length of the radiation the more easily it can damage the plastic.

An important characteristic value in connection with electromagnetic radiation is the dielectric loss-factor, which describes the amount of energy absorbed by the plastic. Plastics with high dielectric loss-factors strongly heat up quickly in an alternating electrical field and are therefore not suitable as high frequency and microwave insulating materials.

Ultraviolet radiation UV radiation from sunlight is particularly effective in unprotected open-air applications. Plastics which are inherently resistant are to be found in the group of fluorinated polymers, e.g. unsurpassed are PTFE and PVDF Without suitable protective . measures, various other plastics begin to yellow and become brittle depending upon the level of irradiation. UV protection is achieved using additives (UV stabilisers) or protective surface coatings (paints, metallization). The addition of carbon black is cost-effective, frequently used and is a very effective method.

Gamma radiation resistance Gamma and X-ray radiation are frequently to be found in medical diagnostics, radiation therapy, in the sterilisation of disposable articles and also in the testing of materials and in test instrumentation. The high energy radiation in these applications often leads to a decrease in the expansion characteristics and the development of brittleness. The overall service life is dependent upon the total amount of radiation absorbed. PEEK HT, PEEK, PI and the amorphous sulphurcontaining polymers, for example, are proved to have very good resistance towards gamma radiation and X-rays. On the other hand, PTFE and POM are very sensitive and therefore are practically unsuitable for this purpose.

Radiation dose in kilogray (kGy) which reduces elongation by less than 25 %.

1600 1400 1200 1000 800 600 400 200 0
EK F PE T N S T 6 PE T PP FI N E TE CA FL O CA AT CA TR O AS I CA SO CA AM N RM CA CA IN R U N PT FE PB N PE PV E N ID AH FO CA TE TE N D AF

40000

20000

TE C

TE

FL O

TE

D TE CA

11

TE

CA

TE C

TE

TE C

TE

TE

Applications in Electrical Engineering

Plastics used in electrical engineering applications are often required to discharge or conduct static electrity. This is achieved by the specific addition of electrically active substances, such as specially conducting carbon blacks, carbon fibres, conducting microfibres with nanostructures or inherently conducting substances. Conducting carbon blacks are used only for applications outside of clean-room production, where the actual semi-conductor structures are closed and sealed. Carbon fibres, nanotubes and inherently conducting substances are more abrasion-resistant and tend to lead to considerably less contamination.

The electrical parameters can thus be kept within better definable limits. A material with a surface resistance of 106 to 1012 is considered to discharge static electricity. If the surface resistance is smaller than 106 , then the material is said to be electrically conducting.

Material TECASINT 5201 TECAFORM AH SD TECAPEEK ELS nano TECAPEEK CF30 TECAFLON PTFE C25 TECAFLON PVDF ELS TECAFLON PVDF CF8 TECAMID 66 CF20 TECAFORM AH ELS TECAFINE PP ELS

DIN Description PAI POM-C PEEK PEEK PTFE PVDF PVDF PA66 POM-C PP

Volume resistivity in cm
109 - 1011 109 - 1011 10 - 10 10 - 10
5 2 4 7

Surface resistivity in
109 - 1011 109 - 1011 101 - 103 105 - 107 102 - 104 102 - 104 105 - 107 102 - 104 102 - 104 103 - 105

102 - 104 102 - 104 103 - 105 102 - 104 102 - 104 10 - 10
3 5

Antistatic Electrically conducting

12

Applications in Foodstuffs and Medical Technology

Special requirements are necessary in the areas of food contact and medical technology with regard to physiological suitability and resistance. FDA conformity The American Food and Drug Administration (FDA) checks the suitability of materials with regard to their contact with foodstuffs. Raw materials, additives and properties of plastics are specified by the FDA in the Code of Federal Regulations CFR 21. Materials which fulfill the respective requirements are considered to be FDA compliant.

Biocompatibility Biocompatibility describes the compatibility of a material to the tissue or the physiological system of the patient. The assessment is performed using various tests according to USP (U.S. Pharmacopoeia) Class VI or according to ISO 10993. Resistance to different sterilisation procedures and chemicals: multiple-use equipment in medical technology has to have good resistance towards preparatory procedures such as sterilisation and disinfection. These requirements are best met with high-performance plastics.

Material

DIN Description

FDA conformity*

Biocompatibility*

Sterilisation Hot steam 134 C Gamma radiation ++ ++ ++ ++ + + + ++ + ++ + + + o o + o ++ + + -

TECAPEEK CLASSIXTM TECAPEEK MT TECAPEEK CF30 MT TECATRON MT TECASON P MT TECAPEI MT TECANYL MT TECAFORM AH MT TECAPRO MT TECAPEEK TECAFLON PTFE TECASON P VF TECASON E TECASON S TECAPEI TECAFLON PVDF TECANAT TECAMID 66 TECAPET TECAFORM AH TECAFINE PMP TECAPEEK CLASSIXTM XRO TECASON P MT XRO TECANYL MT XRO TECAFORM AH SAN TECAPRO SAN x + o (1)

PEEK PEEK PEEK PPS PPSU PEI PPE POM-C PP PEEK PTFE PPSU PES PSU PEI PVDF PC PA66 PET POM-C PMP PEEK PPSU PPE POM-C PP

x x (3) (2) x x x x x x x x x x x x x x x x x x x x x x

x x x (2) x (2) x x x (2) (2) (2) (2) (2) (2) (2) (2) x x x

++ ++ ++ ++ + + + o o ++ + ++ + + + + o ++ + + -

(2) (3)

Material is FDA compliant and biocompatible Resistant Limited resistance Not resistant FDA compliance and biocompatibility apply to natural materials. Pigments used are checked for their suitability according to FDA regulations. Biocompatibility is not a material specification and necessitates prior testing and, if necessary, special production. Please consult your ENSINGER contact No FDA compliance possible. According to FDA regulations carbon fibres are not listed in the positive list. According to the German Federal Institute for Risk Assessment (BfR) carbon fibres are not physiologically unharmful.

The contents of this table are for guidance only. Binding certificates are only issued with an order and are traceable according to EC No. 2023/2006 (Good Manufacturing Practice).

13

TE C TE AMI CA D/ T S T EC AR IM TE CA FIN EP E, PP TE ,P CA MP FO RM AH TE ,A C D TE ADU CA R PE PBT T TE CA NA T

TR TE CA RA N AB TE S CA PV FLO DF N , P ET TF FE, E TE CA SO N S, P, E TE CA PE I

Processing of Plastics
Machining guidelines

2 5

2 5

0 5 500 800 2 5 5 10 15 30

5 8

5 8

5 8

5 8

0 5

5 8

0 4

0 4

0 5 500 800 3 5 5 10 10 30

0 5 500 800 3 5 5 10 10 30

0 3 800 900 10 14 5 10 5 10

0 3 800 900 10 14 5 10 5 10

10 15 200 300 3 5

V t Clearance angle Rake angle Cutting speed Pitch () () m/min mm

V t

500

500

300

300

300

300

300

300

500

500

3 8 5 15 10 20

3 8 5 15 10 20

3 8 5 10 10 20

3 8 8 10 10 20

3 8 8 10 10 20

3 8 8 10 10 20

2 8 8 12 10 30

2 5 10 16 5 20

2 5 3 10 10 20

2 5 3 10 10 20

Drilling

6 5 10

Clearance angle Rake angle Point angle V Cutting speed S Feed () () () m/min mm/U

90

90

90

90

90

90

90

90

130

90

90

90

90

120

120

120

V S V

50 150 0,1 0,3 10 20 5 15 250 500 6 10 0 5 45 60 250 500 0,1 0,5

50 150 0,1 0,3 10 20 5 15 250 500 6 10 0 5 45 60 250 500 0,1 0,5

50 200 0,1 0,3 5 15 5 15 250 500 6 8 0 5 45 60 300 600 0,1 0,4

50 100 0,2 0,3 5 15 5 15

50 100 0,2 0,3 10 20 5 15

50 100 0,2 0,3 10 20 5 15

50 100 0,2 0,3 10 20 5 15

50 200 0,2 0,3 5 10 0 10 300 500 5 15 25 30

150 200 0,1 0,3 5 15 5 15 250 500

20 80 0,1 0,3 2 10 1 5 250 500

20 80 0,1 0,3 2 10 1 5 250 500

50 200 0,1 0,3 5 15 6 10 250 500 6 8 0 5 45 60 250 500 0,1 0,5

50 200 0,1 0,3 5 15 6 10 250 500 6 8 0 5 45 60 250 500 0,1 0,5

80 100

80 100

80 100 0,1 0,3 15 30 6 10 80 100 6 8 2 8 45 60 150 200 0,1 0,5

The twist angle of the drill bit should be approx. 12 to 16

0,02 0,02 0,1 0,1 2 5 0 5 90 100 2 5 0 5 7 10 100 120 2 5 0 5 90 100 2 5 0 5 7 10 100 120

Milling

Clearance angle Rake angle Side angle V Cutting speed () () () m/min

The feed can be up to 0.5 mm/tooth

300

300

300

300

Turning

5 10 0 5 45 60 300 400 0,2 0,4

5 10 6 8 45 60

5 10 6 8 45 60

5 10 6 8 45 60

10

5 8

Clearance angle Rake angle Side angle V Cutting speed S Feed

() () () m/min mm/rpm

V S

15

10

45 60 350 400 0,1 0,3

45 60 350 400 0,1 0,3

300

300

300

200 500 0,2 0,5

150 500 0,1 0,3

The nose radius r must be at least 0.5 mm

0,1 0,5

0,1 0,5

0,1 0,5

0,05 0,05 0,08 0,08

Special measures

Heat before sawing: from 60 mm diameter from 80 mm diameter from 100 mm diameter

Heat before drilling in the centre: TECAPEEK GF/PVX, TECATRON TECAMID 66 GF TECADUR PET/PBT , TECAMID 6 GF 66, 66 MH ,

from 60 mmn diameter from 80 mm diameter from 100 mm diameter

TECAPEEK GF/PVX, TECATRON GF/PVX TECAMID 66 MH, 66 GF TECADUR PET/PBT , TECAMID 6 GF 66, TECAM 6 Mo, TECANYL GF ,

Preheat material to 120 C

Caution when using coolants: susceptible to stress cracking

Use carbide-tipped tools

14

* Reinforcing agents/fillers: Glass fibres, glass beads, carbon fibres, graphite, mica, talcum, etc.

Sawing

20 30

20 30

20 30

15 30

15 30

15 30

15 30

15 30

20 30

15 30

15 30

15 30

15 30

5 10

5 10

CA SI NT ,T Re EC inf AT EN orc OR SIN ed PA GE /fille I Rm d ate ria ls*

TE CA TR ON

TE CA PE EK

TE CA NY L

TE CA MI D

CA TE

SI

TE

NT ,P I

15 30

General information* Non-reinforced thermoplastic polymers can be machined using high speed tools. For reinforced materials, carbide tipped tools are necessary. In all cases, only correctly sharpened tools should be used. Due to the poor thermal conductivity of plastics, good heat flow must be ensured. The best form of cooling is heat dissipation via the chips.

2. Milling For plane surfaces, end-milling is more economical than peripheral milling. For circumferential and profile milling the tools should not have more than two cutting edges so that vibrations caused by the cutters can be kept low and the gaps between the chips is sufficiently large. Optimum cutting performance and surface finish are obtained with single-cutter tools. 3. Drilling Twist drills can generally be used; these should have an angle of twist of 12 to 16 and very smooth spiral grooves for good swarf removal. Larger diameters should have a pilot hole drilled or should be produced using hollow drills or by trepanning. Particular attention should be paid to using properly sharpened drills when drilling into solid material, as otherwise the resulting compression stresses can increase to the extent that the material splits. Reinforced plastics have higher residual processing stresses and a lower impact resistance than non-reinforced plastics and are therefore particularly susceptible to cracking. Where possible, they should be heated to around 120 C before drilling (heating time approx. 1 hour per 10 mm cross-section). This method is also recommended for polyamide 66 and polyester. 4. Sawing Unnecessary heat generation caused by friction must be avoided, as generally thick-walled parts are cut with relatively thin tools during sawing. Well-sharpened and strongly offset saw blades are therefore recommended. 5. Thread cutting Threads are best cut using thread chasers; burring can be avoided by using twin-toothed chasers. Die cutters are not recommended as re-cutting can be expected during removal of the cutter. A machining allowance (dependent on material and diameter; guide value: 0,1 mm) must frequently be taken into account when using tap drills. 6. Safety precautions Failure to observe the machining guidelines can result in localized overheating which can lead to material degradation. Decomposition products which may be released, e.g. from PTFE fillers, should be removed using extraction facilities. In this respect, tobacco products should be kept out of the production area due to the risk of contamination.

Dimensional stability Dimensionally accurate parts presuppose the use of stress relieved semi-finished products. Heat from machining will otherwise unavoidably result in the release of machining stresses and distortion of the part. If large material volumes are to be machined, intermediate annealing may be necessary after rough machining to relieve the resulting thermal stresses. Specific temperatures and times to be used according to material can be obtained from us upon request. Materials with high moisture absorption (e.g. polyamides) may have to be conditioned before processing. Plastics require higher production tolerances than metals. Furthermore, the much higher thermal expansion needs to be taken into consideration.

Machining methods 1. Turning Guide values for tool geometry are given in the table. For surfaces with particularly high quality requirements, the cutting edge must be designed as a broad smoothing tool as shown in Figure 1. For parting off, the lathe tool should be ground as shown in Figure 4 to prevent the formation of burrs. On the other hand, for thin-walled and particularly flexible workpieces, it is better to work with tools that are ground to a knife-like cutting geometry (Figures 2 and 3).

1 Secondary cutter 2 Lathe tool

Figure 1

Grinding prevents burr formation

Figure 4

Stress produced with a blunt drill

Cutting off flexible plastics

Figure 2

Figure 5 Stress produced with a sharp drill *Our application engineering advice, provided both written and orally, is intended to help you in your work. It must be regarded as a recommendation without obligation, also with respect to possible third-party property rights. We can assume no liability for any possible damage which arises during processing.

Parting off flexible plastics

Figure 3

Figure 6

15

Annealing specications When processing plastic semi-finished goods using machining processes it is recommended under certain circumstances, an annealing process is carried out after rough machining, in order to achieve the best dimensional stability and resistance. Annealing is a temperature treatment, which serves the following purposes: I I I Increases the crystallinity to improve the strength and chemical resistance. Reduces internal stress, which can arise through extrusion or machining. Increases the dimensional stability over a broad range of temperatures. The parameters given in the following annealing specification are approximate values and apply up to a wall thickness of 50 mm. For larger wall thicknesses please contact our technical marketing department.

Material TECASINT TECAPEEK TECATRON TECASON E TECASON P TECASON S TECAFLON PVDF TECANAT TECADUR PET TECADUR PBT GF30 TECAMID 6 TECAMID 66 TECAFORM AH TECAFORM AD

DIN-Description PI PEEK PPS PES PPSU PSU PVDF PC PET PBT PA6 PA66 POM-C POM-H

Heating-up phase
2 h to 160 C 6 h to 280 C 3 h to 120 C 4 h to 220 C 3 h to 120 C 4 h to 220 C 3 h to 100 C 4 h to 200 C 3 h to 100 C 4 h to 200 C 3 h to 100 C 3 h to 165 C 3 h to 90 C 3 h to 150 C 3 h to 80 C 3 h to 130 C 3 h to 100 C 4 h to 180 C 3 h to 100 C 4 h to 180 C 3 h to 90 C 3 h to 160 C 3 h to 100 C 4 h to 180 C 3 h to 90 C 3 h to 155 C 3 h to 90 C 3 h to 160 C

Maintaining phase **
2 h at 160 C 10 h at 280 C 1,5 h

Cooling down phase

at 20 C/h to 40 C

at 20 C/h to 40 C

per cm wall thickness

1,5 h at 20 C/h to 40 C

per cm wall thickness

1h at 20 C/h to 40 C

per cm wall thickness

1h at 20 C/h to 40 C

per cm wall thickness

1h at 20 C/h to 40 C

per cm wall thickness

1h at 20 C/h to 40 C

per cm wall thickness

1h at 20 C/h to 40 C

per cm wall thickness

1h at 20 C/h to 40 C

per cm wall thickness

1h at 20 C/h to 40 C

per cm wall thickness

1h at 20 C/h to 40 C

per cm wall thickness

1h at 20 C/h to 40 C

per cm wall thickness

1h at 20 C/h to 40 C

per cm wall thickness

1h at 20 C/h to 40 C

per cm wall thickness

** at maximum temperature, unless otherwise specified.

16

Welding A common technique used to join plastics is welding and heat-sealing. Depending upon the process used, certain design guidelines have to be observed during the construction phase. With high temperature plastics it should be remembered that quite high amounts of energy are required for plasticisation of the material.
Process Heating element and hot gas welding
Heating element

The following table shows different welding processes in comparison.

High-frequency welding
Sonotrode

Vibrational/frictional welding

Laser welding

Carriage with working part

Align / heat up

Joining / cooling down Working parts

Principle Weld-time Advantage

The parts to be joined are heated up using a heating element or with hot gas; join together applying pressure 20 to 40 s High strength, cost-effective

A zone to be joined is heating up (with special geometry) by ultra-sound vibrations 0.1 to 2 s Shortest cycle times, easy to automate

The parts to be joined are heated up using vibration or friction; joined together applying pressure 0.2 to 10 s Suitable for larger parts, oxidation sensitive plastics can be welded

The parts to be joined are heated up using a laser beam

High strength, almost any weld geometry possible, high precision

Adhesive bonding In order to bond plastics there are I I I solvent adhesives hot-melt adhesives epoxy, polyurethane, rubber and cyanoacrylate based adhesive cements In order to improve strength, pre-treatment of the plastic surfaces is recommended to increase the surface activity. For this purpose the following methods are useful: I I I I Flexural, peeling or plain tensile stresses should be avoided. cleaning and de-greasing the material surfaces mechanical surface enlargement by sanding or sand-blasting physical activation of the surface by flame, plasma or corona treatment chemical etching in order to form a defined boundary layer

When bonding plastics, tensional load should be avoided and a pressure or shear load should preferably be applied to the adhesive bond joint.

In general, pre-trials are required for the adhesion of plastics which should be carried out as close to the situation in practice as possible. Furthermore, it is recommended contact is made with experienced adhesive manufacturers.
The following manufacturers provide adhesives for engineering and high-performance plastics: Panacol-Elosol GmbH
Obere Zeil 6-8 61440 Oberursel Telephone: 06171/6202-0, Fax: 06171/6202-90 www.panacol.de

Material TECASINT TECAPEEK TECATRON TECASON E TECASON P TECASON S TECAFLON PVDF TECANAT TECAPET TECADUR PBT TECAMID 6 TECAMID 66 TECAFORM AH TECAFORM AD TECAFINE PP TECAFINE PE

DIN Solvent Description adhesive PI PEEK PPS PES PPSU PSU PVDF PC PET PBT PA6 PA66 POM-C POM-H PP PE

Adhesive cement on the basis of Epoxy resins Polyurethane Rubber Cyanoacrylate

Henkel Loctite Deutschland GmbH

Arabellastrae 17 81925 Mnchen Telephone: 089/9268-0, Fax: 089/9101978 www.loctite.com

x x x x

x x x x x x x x x x x

x x x x x x x x x x x

x x x

x x x

x x x x

x x x x

Dymax Europe GmbH

Trakehner Strae 3 60487 Frankfurt Telephone: 069/7165-3568, Fax: 069/7165-3830 www.dymax.de

x x x x

DELO Industrieklebstoffe GmbH & Co. KG

DELO-Allee 1 86949 Windach Telephone: 08193/9900-131, Fax: 08193/9900-185 www.delo.de

x x

x x

x x

x = suitable adhesives available

17

Available Dimensions for Semi-Finished Goods

Our materials can be produced in the following dimensions. The current availability of certain dimensions should be clarified as required.

Material TECASINT TECAPEEK HT TECAPEEK TECAPEEK GF30 TECAPEEK PVX TECAFLON PTFE TECATRON TECATRON GF40 TECATRON PVX TECASON E TECASON P TECASON S TECAFLON PVDF TECANAT TECANAT GF30 TECAPET TECADUR PBT GF30 TECAST TECARIM TECAMID 6 TECAMID 66 TECAMID 66 GF30 TECAFORM AH TECAFORM AD

DIN description PI PEK PEEK PEEK PEEK PTFE PPS PPS PPS PES PPSU PSU PVDF PC PC PET PBT PA6 G PA6 G PA6 PA66 PA66 POM-C POM-H
5 mm 5 mm 5 mm 5 mm 5 mm 4 mm 4 mm 4 mm 4 mm 4 mm 4 mm 4 mm 4 mm 4 mm 4 mm 4 mm 4 mm 20 mm 30 mm 4 mm 4 mm 4 mm 3 mm 3 mm

Rods
100 mm 150 mm 200 mm 100 mm 100 mm 300 mm 60 mm 60 mm 60 mm 150 mm 150 mm 200 mm 300 mm 250 mm 180 mm 200 mm 150 mm 1000 mm 150 mm 300 mm 200 mm 150 mm 250 mm 200 mm 5 mm 5 mm 5 mm 6 mm 5 mm 1 mm 8 mm 8 mm 8 mm 5 mm 5 mm 5 mm 5 mm 1 mm 5 mm 1 mm 5 mm 8 mm 30 mm 1 mm 5 mm 5 mm 1 mm 5 mm

Plates
100 mm 70 mm 100 mm 80 mm 60 mm 150 mm 50 mm 70 mm 50 mm 80 mm 80 mm 80 mm 100 mm 100 mm 100 mm 100 mm 100 mm 200 mm 100 mm 100 mm 100 mm 100 mm 100 mm 100 mm

Tubes
55/30 mm - 125/95 mm

40/25 mm - 300/200 mm

40/25 mm - 250/200 mm

25/18 mm - 300/200 mm

60/30 mm - 710/500 mm

25/18 mm - 300/200 mm

25/18 mm - 505/390 mm

18

Exclusion of liability
Our information and statements do not constitute a promise or guarantee whether these are express or inferred. They are in accordance with the present state of our knowledge and are intended to provide information about our products and the possibilities for their use. Any Information supplied is therefore not intended as a legally binding assurance or guarantee of the chemical resistance, the nature of the products or the marketable nature of the goods. The suitability for the end use of the products are influenced by various factors such as choice of materials, additives to the material, part design and tooling, processing or environmental conditions. Unless otherwise indicated, the measured values are guideline values which are based on laboratory tests under standardised conditions. The information provided does not, alone, form any sufficient basis for component or tool design. The decision as to the suitability of a particular material or procedure or a particular component and tool design for a specific purpose is left exclusively to the customer in question. Suitability for a specific purpose or a particular use is not assured or guaranteed on a legally binding basis, unless we have been informed in writing about the specific purpose and conditions of use and we have confirmed in writing that our product is suitable for this purpose within the conditions notified. Our products conform to statutory provisions valid in Germany at the time of the transfer of risk, in so far as these statutory provisions contain regulations regarding the nature of these products specifically. The customer must expressly point out in writing that he intends to export our products after processing or installation if applicable only then will we confirm the suitability for export expressly in writing. We also ensure compliance with the export regulations of the European Union, its member states, the other states who are signatory to the agreement on the European Economic Area (Norway, Iceland, Liechtenstein) and Switzerland and the USA. We are not obliged to take any steps to comply with the statutory regulations of other states. We are responsible for ensuring that our products are free from any rights or claims by third parties based on commercial or other intellectual property (patents, patented designs, registered designs, authors' rights and other rights). This obligation applies for Germany; it also applies for the other member states of the European Union and the other states who are signatory to the agreement on the European Economic Area and Switzerland and the USA. Only if the customer expressly points out to us in writing that he intends to export our products after processing or installation if applicable - and we expressly confirm in writing that the products can be exported will we accept any liability for states other than those listed. We reserve the right to make changes to the design or form, deviations in colour and changes to the scope of delivery or service in so far as the changes or deviations are reasonable for the customer whilst taking our interests into account. Our products are not destined for use in medical and dental implants.

Note to the material standard values on pages 20 to 25

The information corresponds with current knowledge, and indicates our products and possible applications. We cannot give you a legally binding guarantee of the physical properties or the suitability for a specific application. Existing commercial patents are to be taken into account. A definite quality guarantee is given in our general conditions of sale. Tests are carried out in a standard atmosphere of 23 C 50 RH according to DIN 50 014. We reserve the right to make technical alterations. These values represents the average of a number of individual measurements. Unless otherwise stated the test results apply to injection moulded samples. Remark: For polyamides the values strongly depend on the humidity contents. * humid, after storage in standard atmosphere 23C 50 RH (DIN 50 014) until saturation. n. b. = not broken + = Resistant (+) = Limited resistance = Not resistant (depending on concentration, time and temperature) (1) When plastics are listed under additives and colour as available also in black the electrical properties are not valid for the black variant. , (2) Testing on semi-finished products. (3) Expected values. (4) Impact resistance is measured with different methods. The values in the following tables are marked with the following letters: (c) Charpy impact strength: DIN EN ISO 179: an kJ/m2 (k) Charpy, notched impact strength: DIN EN ISO 179: an kJ/m2 (di) Izod, impact strength: DIN EN ISO 180, an kJ/m2 (ai) Izod, notched impact strength: ASTM D 256: an J/m

19

Mechanical properties

ENSINGER High temperature plastics. Material standard values.

Trade name TECASINT 1011 TECASINT 1021 TECASINT 1031 TECASINT 1041 TECASINT 1061 TECASINT 1611 TECASINT 2011 TECASINT 2021 TECASINT 2031 TECASINT 2061 TECASINT 5011 TECASINT 5051 TECASINT 5201 TECASINT 8001 TECATOR 5013 TECATOR GF30 TECAPEEK ST TECAPEEK HT TECAPEEK CLASSIXTM TECAPEEK TECAPEEK GF30 TECAPEEK CF30 TECAPEEK CF30 MT TECAPEEK PVX TECAPEEK MT TECAPEEK ELS nano TECAPEEK CMF TECAPEEK TF10 TECATRON TECATRON MT sw TECATRON GF40 TECATRON PVX TECATRON GF15 VF TECATRON GF30 VF TECATRON GF40 VF TECASON S TECASON S GF30

Short description PI PI CS15 PI CS40 PI MO PI CS15 TF10 PI TF30 PI PI CS15 PI CS40 PI CS15 TF10 PAI PAI GF30 PAI TF PI PAI PAI GF30 PEKEKK PEK PEEK PEEK PEEK GF30 PEEK CF30 PEEK CF30 PEEK CF CS TF PEEK PEEK PEEK PEEK TF10 PPS PPS PPS GF40 PPS CF CS TF PPS GF15 PPS GF30 PPS GF40 PSU PSU GF30

Additives and/or colour black 15% graphite, black 40% graphite, black 30% Molybdnsulfid, black 15% graphite, 10% PTFE, glossy black 30% PTFE, ochre brown 15% graphite, black 40% graphite, anthracite 15% graphite, 10% PTFE, anthracite light beige 30% glass fibre, dark brown black 20% PI, ochre yellow-brown 30% glass fibre natural black white natural, also black(1) natural, 30% glass fibre 30% carbon fibre, black 30% carbon fibre, black 10% carbon fibre, graphite, PTFE, black coloured, also in black CNT, black white, ceramic PTFE 10%, natural natural black 40% glass fibre, natural 10% carbon fibre, graphite, PTFE, black 15% glass fibre, black 30% glass fibre, black 40% glass fibre, black translucent 30% glass fibre
(1)

Service temperature C long term

g/cm3 1,34 1,42 1,57 1,67 1,48 1,51 1,38 1,45 1,58 1,51 1,38 1,57

300 300 330 330 300 260 300 300 340 300 300 300 300 250 270 270 260(3) 260 260 260 260 260 260 260 260 260 260 260 230 230 230 230 230 230 230 160 160

1,54
1,88 1,42 1,61 1,30 1,32 1,38 1,30 1,51 1,40 1,40 1,48 1,30 1,34 1,60 1,35 1,35 1,35 1,64 1,47 1,44 1,58 1,65 1,24 1,49

20

D e (A nsi ST ty M D Te 79 ns 2, (A il D ST e s IN tr M e EN D ng Te 63 th IS ns O 8, a D il ty IN e 11 D IN ie 83 EN str en ) EN ld IS g El IS O th on O 52 a D g IN at 52 7, t b A re 7) EN ion ST a IS at M k( M A O br o D S 52 ea (A du 17 TM 7, k ST lus 08 D A (A M o ST S (a 6 D fe )) 38 M TM M la 63 s , od D D 8, tic (A u 17 6 D it ST lus 08 38 IN y M o (a , EN aft D fe )) e Ha 79 las IS r t rd O en 0, tic DI nes N s 52 sil D it EN (b IN y 7) e t a IS ll i es EN aft O nd e Im t 86 en IS r fl 8( ta p O ex d) ti se ac , R on 17 ur e tr oc : I 8) al fo es kw SO ot is te el 20 l: A 3 no ta st Cr ST 9/1 e te nc M ,S w ep (4 e D ho ith ru )o 78 re 5 D: s t p tu n ,I A at re SO S pa Ti T ic s ge 20 M m lo tr 39 D 1% e 19 /2 22 ad en yi (r) 40, gt el el d h on af ga lim Co te it e tio r1 v ffic n for 00 = ie af 0, nt 0 6 te h m of r1 fr /s W 00 on icti ea on 0 st (c r h ee P on l, = 0 ha ,0 di tio rd 5 en n/ ns ed mm as an d pr gr ev ou io nd us )

S MPa

R MPa 116 97 65 82 77 82 118 101 65 63 110 94

R % 9 2,8 2,2 2,8 2,9 4,1 4,5 3,7 2,1 2,7 5,5 3,4 4 200

EZ MPa 4000 4000

EB MPa 3448 4000

HK MPa 90 (d) 88 (d) 85 (d) 75 (c) 35 (ai) 16,5 (c) 29,6 (c) 25,8 (c)

B/1000 MPa

1/1000 MPa 12

0,8 0,27 0,37

V /km

Trade name TECASINT 1011 TECASINT 1021 TECASINT 1031 TECASINT 1041 TECASINT 1061 TECASINT 1611

4340

4330

89 (d) 85 (d) 84 (d)

3700 4400 6300 6900 4500 5800 4500

3600 4050 5207 3400 4240 6625 4200

90 (d) 87 (d) 84 (d) 84 (d) 91 (d) 92 (d) 93 (d) 65 (d)

87,9 (c) 20,6 (c) 14,2 (c) 19,4 (c) 37 ,4 (c) 27,3 (c) 17,3 (c)

TECASINT 2011 TECASINT 2021 TECASINT 2031 TECASINT 2061 TECASINT 5011 TECASINT 5051 TECASINT 5201 TECASINT 8001

85 15 147 137 205 130(2) 110 95 95 130 215 160 130 95 100 86 80 75 75 185 115 120 160 185 80 125

21 7 11(2) 20 >25 25 2,5 1,5 3 1,5

3800

3750

E 86 E 94 248

142 (ai) 79 (ai) 10 (k) 52 (ai) 7 ,6 (d)

TECATOR 5013 TECATOR GF30 TECAPEEK ST TECAPEEK HT TECAPEEK CLASSIXTM 0,300,38 36 0,380,46 TECAPEEK TECAPEEK GF30 TECAPEEK CF30 TECAPEEK CF30 MT 0,11 0,300,38 TECAPEEK PVX TECAPEEK MT TECAPEEK ELS nano TECAPEEK CMF 0,08 TECAPEEK TF10 TECATRON TECATRON MT sw TECATRON GF40 0,21 0,69 TECATRON PVX TECATRON GF15 VF TECATRON GF30 VF

10800 11700 4400(2) 3800 4100 4200 3000 8000 4100

108 (r)

M99

n. b. (c) 60 (c) 35 (c) 50 (c)

10000 M103

18500 20000 256(2) 14500 9500 3000 8100 4100 208(2) M99 (r)

30 (c) n. b. (c) 50 (c)

15 7 15 4 4 1,9 1,5 2 2 1,9 > 50 1,8

4100 4500 3000 3700 3700 3600 3600 190 190 320 203(2) 7500 4500 263

50 (c) n. b. (c) 50 (c) 50 (c) 45 (c) 20 (c) 32 (c)

14000 13000 10000 7700 11000 14000 14000 2600 9900

320 147 202

45 (c) n. b. (c) 20 (di) 42 22 0,4

TECATRON GF40 VF TECASON S TECASON S GF30

Thermal properties

Electrical properties(1)

Miscellaneous data

Trade name TECASINT 1011 TECASINT 1021 TECASINT 1031 TECASINT 1041 TECASINT 1061 TECASINT 1611 TECASINT 2011 TECASINT 2021 TECASINT 2031 TECASINT 2061 TECASINT 5011 TECASINT 5051 TECASINT 5201 TECASINT 8001 TECATOR 5013 TECATOR GF30 TECAPEEK ST TECAPEEK HT TECAPEEK CLASSIXTM TECAPEEK TECAPEEK GF30 TECAPEEK CF30 TECAPEEK CF30 MT TECAPEEK PVX TECAPEEK MT TECAPEEK ELS nano TECAPEEK CMF TECAPEEK TF10 TECATRON TECATRON MT sw TECATRON GF40 TECATRON PVX TECATRON GF15 VF TECATRON GF30 VF TECATRON GF40 VF TECASON S TECASON S GF30

Tm O C

387 374 343 343 343 343 343 343 343 343

343 280 280 280 280 280 280 280

21

M e (D ltin IN g 53 po 76 int G la 5, ss (D D IN IN tra EN 53 ns 76 itio IS H e O 5, n 31 D at d D te IN i IN m 46 st EN o EN pe ) r ra IS tio IS tu H ea O n O re 75 tem 31 D td IN i 46 m p ENsto et er ) r ho at IS tio Se d ure O n rv A te 75 m sh ic or e m p t t tem et er ho at er p m e Th d ure ra B e tu (2 rm re 3 a C) l c on Sp du ct (2 ecif iv 3 ic ity C) h ea t Co (2 effi 3 ci C, en A to ST f D ie M lin (1 lec D ea 0 6 tr 69 r t H ic 6, he z, co D rm A n D IN a ST st ie le 53 l e M an (1 c 75 xp 0 6 tr D t 2, an 15 H ic z, lo A sio 0, ST n A ss Sp D ST f M IN ac ec M t (A if E 53 D or 83 ST ic 48 15 1) M vo 3, D lum 0, D IE Su 25 e -2 IN 50 7, re (A rfac 53 EC s ) ST e i 48 93 sta M res 3, , D nc D ist IE D e 25 an IN ie -2 50 7, ce (A lec IE EC ) C ST tri 60 93 M cs 09 ,D D tre Re 3) 14 ng IN si 9, th (D st IE D C IN an IN 60 EN ce EN 09 to M 60 t 3) 60 oi 11 ra 09 23 st 2, ck ur 3) V in C e D g /5 ab E 0% s 03 W o 03 a re rpt (D ter pa l. io hu n IN ab rt m to 1) EN so id e rp ity qu Re IS ti ili O on s (D b w ist 62 a IN riu as an ) ts hi c EN m at ng e t ur IS Fl at so o h O am io da ot 62 n U m w ) L- a at St bi er an lit Re da y a s rd cc w ist 94 . to ea an th ce er t in o g
O

Tg C

HDT/A HDT/B O O C C 368 300 300

W/(Km) 0,22 0,53

c J/(gK) 1,04 1,13

10-5 1/K 4,3 3,8 3,1 6,5 5,1 5,0

r 3,1

tan 0,003

rD cm 1017

RO 1016 107 103

Ed grade kV/mm 20

W(H2O) % 2,6 2,3

WS % 3,6

(+) (+) (+) (+) (+)

V0 V0 V0 V0 V0 V0 V0 V0 V0 V0 V0 V0 V0

(+) (+) (+) (+) (+) (+) (+) (+) (+) (+) (+) (+) (+)

Trade name TECASINT 1011 TECASINT 1021 TECASINT 1031 TECASINT 1041 TECASINT 1061 TECASINT 1611 TECASINT 2011 TECASINT 2021 TECASINT 2031 TECASINT 2061 TECASINT 5011 TECASINT 5051 TECASINT 5201 TECASINT 8001

368 330 330 330 330 330 370 360 370 370 340 340 340 -20 275 275 162 157 143 143 143 143 143 143 143 143 143 143 90 90 90 90 90 90 90 180 188

350 350 350 350 350

1017 1015

1016 1015 21,8

(+) (+) (+) (+) (+) (+)

325 370 384

400 400

0,22

0,925 1,05

5,4 4,1 3,0 4,0 4,8 3,3

1014 109-1011 1018 3,9 4,2 0,031 0,05 >1018 1017 >1018 1018 23,6 34 2,5 2,5 4,5 3,5 0,05 2,1

(+) (+)

320 0,25 278 282 172 165 300 300 152 315 315 315 277 152 182 182 300 300 300 300 300 300 300 219 260 300 300 110 110 260 260 260 260 260 220 255 260 169 183 181 186 260 180 180 0,25 0,25 1,18 1 0,25 0,25 0,25 1,18 0,24 0,25 0,4 0,43 1,04 0,32 0,25 0,43 0,92 0,32 270 0,26 0,37 1 0,24 0,23

3,3 14,4 3,1 1,6 4,9 5,7 3,3 0,0035

V0 V0

TECATOR 5013 TECATOR GF30 TECAPEEK ST

1015-1016 1013-1014 1016 1011-1012

+ + + V0 V0 V0 V0 V0 V0 V0 V0 V0 V0 V0 V0 V0 V0 V0 V0 V0 V0 V0 + + + + +

TECAPEEK HT TECAPEEK CLASSIXTM TECAPEEK TECAPEEK GF30 TECAPEEK CF30 TECAPEEK CF30 MT TECAPEEK PVX TECAPEEK MT TECAPEEK ELS nano TECAPEEK CMF TECAPEEK TF10 TECATRON TECATRON MT sw TECATRON GF40 TECATRON PVX TECATRON GF15 VF TECATRON GF30 VF TECATRON GF40 VF TECASON S TECASON S GF30

5 2 1,5(2)

3,2-3,3

0,0010,004 0,004

1016 1015 105107(2)

1015 1015 105107(2)

20 24,5

0,1 0,1 0,1 0,1

0,5 0,1 0,1 0,1 0,1 0,5 0,2

+ + + + + + + +

2,2 5 1,9 4,4 4,1 3,2-3,3 0,0010,004

105-106 106-107 1016 1015 20

0,1 0,1 0,1 15,2 <0,1 0,1

102-104 101-103 < 0,0050 >1014 >1014

0,1

+ + +

5 5 ca. 3 3-4(2) 4 0,004

1013 1013 1013 105105(2)

1015 1015 1015 105106(2) 1015 20 KC 175

0,01 0,01 0,02 0,02 0,02 0,02 20 42 >60 KC 175 KA 1 KB 175 0,02 0,2 0,1 0,8 0,5 0,1

+ + + + + + +

1015 ca. 3 5,5 2,1 4 3,1 3,7 0,004 0,005 0,006 1013 1016 1016

1015 1015 1014 1014

Mechanical properties

ENSINGER High temperature plastics. Material standard values.

Trade name TECASON E TECASON E GF30 TECASON P MT TECASON P MT XRO TECASON P VF TECAPEI TECAPEI GF30 TECAFLON PTFE TECAFLON PFA TECAFLON ETFE TECAFLON PVDF TECAFLON PVDF ELS TECAFLON ECTFE TECAFLON PCTFE TECAMID PPA GF33 TECAMID 46 TECAMID 46 GF30 TECAMID 66/ X GF50 sw TECAMID 66 TECAMID 66 HI TECAMID 66 GF30 TECAMID 66 CF20 TECAMID 66 SF20 TECAMID 66 LA TECAMID 66 MH TECAST T TECAST TM TECAST L TECAGLIDE TECAST GX TECARIM 1500 TECARIM 4000 TECAM 6 MO TECAMID 6 TECAMID 6 GF30 TECAMID 6 GF12 VF

Short description PES PES GF30 PPSU PPSU PPSU PEI PEI GF30 PTFE PFA E/TFE PVDF PVDF E/CTFE PCTFE PPA GF33 PA46 PA46 GF30 PA66 + PA63/6T PA66 PA66 PA66 GF30 PA66 CF20 PA66 SF20 PA66 PA66 PA6 G PA6 G PA6 G PA6 G PA6 G PA6 G PA6 G PA6 PA6 PA6 GF30 PA6 GF12

Additives and/or colour translucent 30% glass fibre coloured coloured coloured translucent 30% glass fibre natural

Service temperature C long term

g/cm3 1,37 1,60 1,29 1,30 1,29 1,27 1,51 2,18 2,18 1,73 1,78 1,83 1,68 2,09 1,43 1,18 1,41 1,56 1,14 1,14 1,35 1,23 1,2 1,11 1,14 1,15 1,15 1,15 1,13 1,13 1,12 1,13 1,14 1,13 1,35 1,22

180 180 170 170 170 170 170 260 260 150 150

conductive carbon, black(1)

150 150

natural 33% glass fibre

150 160 130

30% glass fibre 50% glass fibre, partly aromatic, black(1) natural heat stabilisator, brown 30% glass fibre, black 20% carbon fibre, black 20% aramid fibre, black lubricant MoS2, black(1) natural MoS2, anthracite lubricant solid lubricant, green lubricant, grey 15% elastomere natural 40% elastomere natural MoS2, black natural 30% glass fibre, black 12% glass fibre, black

140 130 100 115 110 110 110 90 100 100 100 100 100 100 95 95 100 100 100 100

22

D e (A nsi ST ty M D Te 79 ns 2, (A il e D ST s IN tr M e EN D ng Te 63 th IS ns O 8, a D il ty IN e 11 D IN ie 83 EN str en ) EN ld IS g El IS O th on O 52 a D g IN at 52 7, t b A re 7) EN ion ST a IS at M k( M A O br od D S 52 ea (A u 17 TM 7, k ST lus 08 D A (A M o ST S (a 6 D fe )) 38 M TM M la 63 s , od D D 8, tic (A u 17 6 D it ST lus 08 38 IN y M o af (a , EN t D fe )) e Ha 79 las IS r t rd O en 0, tic DI nes N s 52 sil D it EN (b IN y 7) e t a IS ll i es EN aft O nd e Im t 86 en IS r fl 8( ta p O ex d) ti se ac , R on 17 ur e tr oc : I 8) al fo es kw SO ot is te el 20 l: A 3 no ta st Cr ST 9/1 e te nc M ,S w ep (4 e D ho ith ru )o 78 re 5 D: s t p tu n ,I A at re SO S pa Ti T ic s ge 20 M m lo tr 39 D 1% e 19 /2 22 ad en yi (r) 40, gt el eld h on lim af ga Co te it e tio r1 v ffic n for 00 = ie af 0, nt 0 6 te h m of r1 fr /s W 00 on icti ea on 0 st (c r h ee P on l, = 0 ha ,0 di tio rd 5 en n/ ns ed mm as an d pr gr ev ou io nd us )

S MPa 90

R MPa

R % 40

EZ MPa 2700 10200 2350 2000 2350 3200 9500 700

EB MPa

HK MPa 148 221 n. b. (c) 35 (c) n. b. (c)

B/1000 MPa

1/1000 MPa 20

V /km

Trade name TECASON E TECASON E GF30 TECASON P MT TECASON P MT XRO TECASON P VF

140 70 70 70 105 165 25 20 45 50 55 43 32 35 193* 100/ 65* 210/ 120* 210 80/60* 80/60* 160/ 130* 190/ 150* 100/ 83* 60/50* 75 85/60* 75 70 84/64* 84/64* 54/44* 26/22* 75 85/60* 140/ 110* 110/ 60* 105/ 55*

2 > 50 > 50 > 50 > 50 2 > 50 300 40 > 30 25 200 > 50 2,5 40/ 280* 4/8* 3 40/ 150* 50/ 150* 3/5* 2,5/6* 3/7 ,5* 10/40* > 25 30/50* 40/60* 50 40 40 90/ 320* 420/ 420* > 25 70/ 200* 2,5/5* 5/19*

2600 2100 2600 3300 9000

31 122,5 (r)

140 165 30

4 (c) 40 (c) n. b. (c) n. b. (c) n. b. (c) n. b. (c) 60 (ai) 34 3 5 1,58 0,080,1 0,200,3 0,4 0,3 0,23 21

TECAPEI TECAPEI GF30 TECAFLON PTFE TECAFLON PFA TECAFLON ETFE TECAFLON PVDF TECAFLON PVDF ELS TECAFLON ECTFE

600 800 2000 4200 1700 1400 11400* 3300/ 1200* 10000/ 4500* 17000 3100/ 2000* 2700/ 1600* 8000/ 7500* 13500/ 11000* 3500 2000/ 1600* 2500 3300/ 1700* 3200/ 2800* 3200 3400 3400 2100/ 900* 450/ 230* 2700 3000/ 1800* 8500/ 6000* 5400*/ 4650/ 2500 2100* 3010 4800/ 3100* 2830 2000 4500 1700

28 60 (d) 80 82 (d) 50 70

n. b. (c) 41* (c)

0,35

TECAFLON PCTFE TECAMID PPA GF33

90 (d) 90 (d)

n. b. (c) 80 (c) 85 (c)

0,200,45

TECAMID 46 TECAMID 46 GF30 TECAMID 66/ X GF50 sw

170/ 100* 170/ 100* 175(2) 187/ 200*

n. b. (c) n. b. (c) 70 (c) 45 (c) 50/ 70*(di)

55

8 6 40

0,350,42

0,9

TECAMID 66 TECAMID 66 HI

0,450,5 0,160,2 0,39 0,7

TECAMID 66 GF30 TECAMID 66 CF20 TECAMID 66 SF20 0,08 0,08 TECAMID 66 LA TECAMID 66 MH TECAST T TECAST TM TECAST L

117/ 100* 107(2) 160/ 90* 145 125 80-85

50 (c) n. b. (c) n. b. (c) n. b. (c) n. b. (c) 7 ,3 (k) 7 ,3 (k) 50

3 8,5 5

0,180,20 0,200,25 0,4

0,12 0,08

< 0,1 TECAGLIDE TECAST GX TECARIM 1500 TECARIM 4000

2280/ 77/ 20/42* 1100* 73*(d) (k) 500/ 59/52* 240* (d) 107/ 85*(2) 160/ 70* 147(2) 140 n. b. (c) n. b. (c) 55 (c) 70/ 105*(c) 45 5 4,5 21-35 0,320,37 0,380,45 0,460,52 0,16 0,23

TECAM 6 MO TECAMID 6 TECAMID 6 GF30 TECAMID 6 GF12 VF

Thermal properties

Electrical properties(1)

Miscellaneous data

Trade name TECASON E TECASON E GF30 TECASON P MT TECASON P MT XRO TECASON P VF TECAPEI TECAPEI GF30 TECAFLON PTFE TECAFLON PFA TECAFLON ETFE TECAFLON PVDF TECAFLON PVDF ELS TECAFLON ECTFE TECAFLON PCTFE TECAMID PPA GF33 TECAMID 46 TECAMID 46 GF30 TECAMID 66/X GF50 sw TECAMID 66 TECAMID 66 HI TECAMID 66 GF30 TECAMID 66 CF20 TECAMID 66 SF20 TECAMID 66 LA TECAMID 66 MH TECAST T TECAST TM TECAST L TECAGLIDE TECAST GX TECARIM 1500 TECARIM 4000 TECAM 6 MO TECAMID 6 TECAMID 6 GF30 TECAMID 6 GF12 VF

Tm O C

327 305 267 172 174 240 216 312 295 295 260 260 260 260 260 260 260 260 220 210 220 >216 220 214 214 220 220 220 222

23

M e (D ltin IN g 53 po 76 int G la 5, ss (D D IN IN tra EN 53 ns 76 itio IS H e O 5, n 31 D at d D te IN i IN m 46 st EN o EN pe ) r ra IS tio IS tu H ea O n O re 75 tem 31 D td IN i 46 m p ENsto et er ) r ho at IS tio Se d ure O n rv A te 75 m sh ic or e m p t t tem et er ho at er p m e Th d ure ra B e tu (2 rm re 3 a C) l c on Sp du ct (2 ecif iv 3 ic ity C) h ea t Co (2 effi 3 ci C, en A to ST f D ie M lin (1 lec D ea 0 6 tr 69 r t H ic 6, he z, co D rm A n D IN a ST st ie le 53 l e M an (1 c 75 xp 0 6 tr D t 2, an 15 H ic z, lo A sio 0, ST n A ss Sp D ST f M IN ac ec M t (A if E 53 D or 83 ST ic 48 15 1) M vo 3, D lum 0, D IE Su 25 e -2 IN 50 7, re (A rfac 53 EC s ) ST e i 48 93 sta M res 3, , D nc D ist IE D e 25 an IN ie -2 50 7, ce (A lec IE EC ) C ST tri 60 93 M cs 09 , D tre Re 3) 14 ng DIN si 9, th (D st IE D C IN an IN 60 EN ce EN 09 to M 60 t 3) 60 oi 11 ra 09 23 st 2, ck ur 3) V in C e D g /5 ab E 0% s 03 W o 03 a re rpt (D ter pa l. io hu n IN ab rt m to 1) EN so id e rp ity qu Re IS ti ili O on s (D b w ist 62 a IN riu as an ) ts hi c EN m at ng e t ur IS Fl at so o h O am io da ot 62 n U m w ) L- a at St bi er an lit Re da y a s rd cc w ist 94 . to ea an th ce er t in o g (5
O

Tg C

HDT/A HDT/B OC OC 204 212 207 207 207 180 210 55 48 214 215 214 214 214 200 215 121 74 105 140

W/(Km) 0,18

c J/(gK) 1,12

10-5 1/K 5,5 2,1

r 3,5 4 3,45 3,45 3,45 3,15 3,7 2,1 2,04 2,6 8

tan 0,005 0,004

rD cm 1016 1016 1015

RO 1014 1014 1013

W(H2O) Ed grade kV/mm % 40 20 15 15 KB 200 KC 175 0,7 0,5 0,37 0,37 0,37 0,7 0,5 KA 3c <0,05 KB>600 KA 3c KB>600 <0,05 KA 1

WS % 2,1 1,5 1,1 1,1

+ + + + +

V0 V0 V0 V0 V0 V0 V0 V0 V0 V0 V0 V0 V0 V0 HB HB HB

Trade name TECASON E TECASON E GF30

225 225 220 220 220 217 217 -20

220 220 190 190 190 200 200 260 260 150 150 150 180

0,35

5,6 5,6

+ + + + + + +

TECASON P MT TECASON P MT XRO TECASON P VF TECAPEI TECAPEI GF30 TECAFLON PTFE TECAFLON PFA TECAFLON ETFE TECAFLON PVDF TECAFLON PVDF ELS TECAFLON ECTFE TECAFLON PCTFE TECAMID PPA GF33 TECAMID 46 TECAMID 46 GF30 TECAMID 66/X GF50 sw TECAMID 66 TECAMID 66 HI TECAMID 66 GF30 TECAMID 66 CF20 TECAMID 66 SF20 TECAMID 66 LA TECAMID 66 MH TECAST T TECAST TM TECAST L TECAGLIDE TECAST GX TECARIM 1500 TECARIM 4000

0,35 0,22 0,23 0,25 0,25 0,24 0,11 1 1,12 0,9 1,2

5,6 5 2 12 13 13 13 1,2-1,4

1015 0,001 0,007 0,0002 0,0002 0,001 0,06 1015 1015 1016 1018 >1016 1014

1013 1015 1015 1016

15 33 30 48 55

1,25 0,9

+ + +

0,03 0,03

+ + + +

-100 -41 -30

71 95

> 1016 1013

40 10-60

<0,05 <0,05 0,07

102-104 102-104 2,5 2,5 4,2 0,009 0,02 0,017 1015 1016 1016 1015 1014 1012 3,6-5 3,2-5 0,0260,200 0,0250,200 1012 1012 10131014(2) 102104(2) 1015 3,3 0,015 10 1014(2) 10131014(2) 3,7 0,030,30 1012 1014
13

0,13 0,24 0,9

5 6,5 2,4-6

1015 1016

40 55-81 21,6 KA 3c <0,05 KB>600

0,1

+ + -

52 126 75 75 285 160

126 297

180 180 220 220 200

0,3 0,33

2,1 1,7

8 2 1,5

9,4-1,1/ 0,21 9,4* 0,35 4,1 0,013

1016 1016 1013 1010 1010 10131014(2) 102104(2) 1013

>20 20

KC >425

3,7 2,6 1,3

14 10

(+) (+) (+)

72/5* 72/5* 72/5* 72/5* 72/5* 72/5* 72/5* 40/5* 40/5* 40/5* 40/5* 40

100 100 250 245 222 85 105 95

>200 200 250 250 250 185 >200 195

170 180 170 170 170 120 170 170 170 170 130 130 160

0,23 0,23 0,27 0,43

1,7 1,7 1,5 1,8

8 8 2-3(2) 5,5(2) 4

28*/ 30

CTI 600

2,8 2,8 1,5 2,2 2,2

8,5 8,5 5,5 6,5 6-7 7,5 7 6,0-7 6 6 6 6

(+) (+) (+) (+) (+) (+) (+) (+) (+) (+) (+)

V2 HB HB HB HB HB HB HB HB HB

+ + + + + -

80*/ KB>600 100 KC>600

0,23 0,23 0,24

1,7 1,8 1,7

15(2) 12(2) 9,5 9,5 9

1014(2) 80-120 10131014(2) 1012 25-50

CT >600

2,5 2,6

KA 3c KA 3b

2,5 2,5

10 1013* 3,7 3,7 4,2* 4,8* 0,1* 0,1* 10141012 1014-1015/ 1012-1013* 109 1010 10 1010 1013(2)1014 3,7-7 0,0310,300 1013 10 1014 >1013
13 9

12

0,24 0,24

9 9 ca. 7-8 ca. 7-8

HB

108 109 1013(2)1014 1012 10 1014 >1013

13

500 600

2,5 1,6 3 8-9 9,5 6,6 (+) (+) (+) HB HB HB HB + + +

40 60/5* 60/5*

100 75 210 170

195 190 220 205

160 160 180 160

0,23 0,23 0,28

1,7 1,7 1,5

18(2) 8 2-3(2) 4

TECAM 6 MO TECAMID 6 TECAMID 6 GF30 TECAMID 6 GF12 VF

20-50

CTI 600

3 2,1 2,3

Mechanical properties

ENSINGER High temperature plastics. Material standard values.

Trade name TECAMID TR TECAMID 12 TECAMID 12 GF30 TECAMID 11 TECAMID 11 GF30 TECANAT HT TECANAT TECANAT GF30 TECAFINE PMP TECAPET TECAPET TF TECADUR PBT TECADUR PBT GF30 TECAFORM AH TECAFORM AH GF25 TECAFORM AH LA TECAFORM AH ELS TECAFORM AH SD TECAFORM AH TF 10 TECAFORM AH MT farbig TECAFORM AD TECAFORM AD AF TECAFORM AD GF20 TECAFORM AD CL TECAPRO MT TECAFINE PP TECAFINE PP ELS TECAFINE PP GF30 TECAFINE PE10 TECAFINE PE5 TECAFINE PE TECACRYL TECARAN ABS TECANYL TECANYL MT TECANYL GF30

Short description PA 6-3-T PA12 PA12 GF30 PA11 PA11 GF30 PC-HT PC PC GF30 PMP PET PET PBT PBT GF30 POM-C POM-C GF25 POM-C POM-C POM-C POM-C POM-C POM-H POM-H POM-H GF20 POM-H PP PP PP PP GF30 PE-UHMW PE-HMW PE-HD PMMA ABS PPE PPE PPE GF30

Additives and/or colour transparent natural 30% glass fibre natural 30% glass fibre transparent transparent 30% glass fibre transparent natural, also in black (1) solid lubricant, grey natural 30% glass fibre grey white natural, also in black (1) 25% glass fibre lubricant, blue conductive carbon, black beige natural also in black(1) natural PTFE, brown 20% glass fibre lubricant heat stabilisator, also in black(1) also in black(1) and grey conductive carbon, black 30% glass fibre natural natural also in black(1) transparent grey grey coloured 30% glass fibre, beige

Service temperature C long term

g/cm3 1,12 1,02 1,24 1,04 1,26 1,15 1,20 1,42 0,83 1,35 1,44 1,31 1,53 1,41 1,58 1,35 1,45 1,33 1,44 1,41 1,42 1,54 1,56 1,42 0,92 0,91 0,98 1,14 0,93 0,95 0,96 1,18 1,06 1,06 1,08 1,29

100 110 110 80 80 140 120 120 120 110 110 110 110 100 100 100 100 100 100 100 110 110 110 100 100 100 100 100 90 90 90 100 75 85 95(3) 85

24

D e (A nsi ST ty M D Te 79 ns 2, (A il e D ST s IN tr M e EN D ng Te 63 th IS ns O 8, a D il ty IN e 11 D IN ie 83 EN str en ) EN ld IS g El IS O th on O 52 a D g IN at 52 7, t b A re 7) EN ion ST a IS at M k( M A O br od D S 52 ea (A u 17 TM 7, k ST lus 08 D A (A M o ST S (a 6 D fe )) 38 M TM M la 63 s , od D D 8, tic (A u 17 6 D it ST lus 08 38 IN y M o af (a , EN t D fe )) e Ha 79 las IS r t rd O en 0, tic DI nes N s 52 sil D it EN (b IN y 7) e t a IS ll i es EN aft O nd e Im t 86 en IS r fl 8( ta p O ex d) ti se ac , R on 17 ur e tr oc : I 8) al fo es kw SO ot is te el 20 l: A 3 no ta st Cr ST 9/1 e te nc M ,S w ep (4 e D ho ith ru )o 78 re 5 D: s t p tu n ,I A at re SO S pa Ti T ic s ge 20 M m lo tr 39 D 1% e 19 /2 22 ad en yi (r) 40, gt el eld h on lim af ga Co te it e tio r1 v ffic n for 00 = ie af 0, nt 0 6 te h m of r1 fr /s W 00 on icti ea on 0 st (c r h ee P on l, = 0 ha ,0 di tio rd 5 en n/ ns ed mm as an d pr gr ev ou io nd us )

S MPa 90 40

R MPa

R % > 50 240

EZ MPa 2800 1200 5900 1000 5000 2300 2300 7500 1500 3200 2900 2500

EB MPa

HK MPa 100 72 (d) 113 R (r) 90 n. b. (c) n. b. (c) 70 (c) n. b. (c) 70 (c) n. b. (c) n. b. (c) 55 (c) n. b. (c) n.b. 40 (c) 125 190 145 195 n. b. (c) 60 (c) n. b. (c) 40 (c) > 40 (c) >1000 (di) 100 (ai) 81(d) 145 n. b. n. b. (c) n. b. (c) 36 (c) 40 (c)

B/1000 MPa 50 23

1/1000 MPa 12 3,5 28

V /km

Trade name TECAMID TR

0,320,38

0,8

TECAMID 12 TECAMID 12 GF30

105 40/42* 100/ 95* 65 60 130 15 88 73 55 135 62 130 45 50 45 50 55 70 50 55 70 35 30 26 18 85 17 25 25 60 50 55 67 55 105 40 40

6 230/ 280* 6/4* 7 130 2,5

23

3,5 28

0,320,38

0,8

TECAMID 11 TECAMID 11 GF30 TECANAT HT

3200 2200

115 R (r) 115 100 148(2) 85 170

48 >50

18

0,520,58

22

TECANAT TECANAT GF30 TECAFINE PMP

36

13

0,25 0,1

0,35

TECAPET TECAPET TF

36

12 57

0,24 0,24 0,32

0,2

TECADUR PBT TECADUR PBT GF30

2,5 30 3

10000 2700 9000 1600 2100

40

13

8,9

TECAFORM AH TECAFORM AH GF25

90(2) M97(r)

~0,2

TECAFORM AH LA TECAFORM AH ELS

15 > 25 12 30 25 8 10 20

2000 1400 2300 2100 3000 2800 6000 3100 1300 2760 1470 2620 2400 1450

0,18

TECAFORM AH SD TECAFORM AH TF10

40 40

13 13

0,32 0,34 0,08

8,9 4,6

TECAFORM AH MT farbig TECAFORM AD TECAFORM AD AF TECAFORM AD GF20 TECAFORM AD CL TECAPRO MT

170

28

0,35 0,1

M92 (r) 100 (r) 80 71 110

n. b. (c) 41,9 (ai) n. b. (c) n. b. (di) 40 (c) n. b. (c) n. b. (c) n. b. (c) 18 (c) n. b. (c) n. b. (c) 293 (ai) 30 (c) 47 28 17 21 12,5 3 22 4

> 50 27 3 > 50 > 50

1600 1200 5500 650 1100 1000 800 900 10001400

0,3

11

TECAFINE PP TECAFINE PP ELS

0,5 0,29 0,29 0,29

8,4

TECAFINE PP GF30 TECAFINE PE10 TECAFINE PE5 TECAFINE PE TECACRYL

35 52 50 180 85 125

3-8

3000 2400 2300

0,5 0,4

8,4 90

TECARAN ABS TECANYL TECANYL MT TECANYL GF30

16,3 2

3240 8000

2540

Thermal properties

Electrical properties(1)

Miscellaneous data

Trade name TECAMID TR TECAMID 12 TECAMID 12 GF30 TECAMID 11 TECAMID 11 GF30 TECANAT HT TECANAT TECANAT GF30 TECAFINE PMP TECAPET TECAPET TF TECADUR PBT TECADUR PBT GF30 TECAFORM AH TECAFORM AH GF25 TECAFORM AH LA TECAFORM AH ELS TECAFORM AH SD TECAFORM AH TF10 TECAFORM AH MT farbig TECAFORM AD TECAFORM AD AF TECAFORM AD GF20 TECAFORM AD CL TECAPRO MT TECAFINE PP TECAFINE PP ELS TECAFINE PP GF30 TECAFINE PE10 TECAFINE PE5 TECAFINE PE TECACRYL TECARAN ABS TECANYL TECANYL MT TECANYL GF30

Tm O C

175 175 183 185

245 255 255 225 225 165 165 165 165 165 165 165 175 175 175 175 163 165 165 165 135 136 130

25

M e (D ltin IN g 53 po 76 int G la 5, ss (D D IN IN tra EN 53 ns 76 itio IS H e O 5, n 31 D at d D te IN i IN m 46 st EN o EN pe ) r ra IS tio IS tu H ea O n O re 75 tem 31 D td IN i 46 m p ENsto et er ) r ho at IS tio Se d ure O n rv A te 75 m sh ic or e m p t t tem et er ho at er p m e Th d ure ra B e tu (2 rm re 3 a C) l c on Sp du ct (2 ecif iv 3 ic ity C) h ea t Co (2 effi 3 ci C, en A to ST f D ie M lin (1 lec D ea 0 6 tr 69 r t H ic 6, he z, co D rm A n D IN a ST st ie le 53 l e M an (1 c 75 xp 0 6 tr D t 2, an 15 H ic z, lo A sio 0, ST n A ss Sp D ST f M IN ac ec M t (A if E 53 D or 83 ST ic 48 15 1) M vo 3, D lum 0, D IE Su 25 e -2 IN 50 7, re (A rfac 53 EC s ) ST e i 48 93 sta M res 3, , D nc D ist IE D e 25 an IN ie -2 50 7, ce (A lec IE EC ) C ST tri 60 93 M cs 09 , D tre Re 3) 14 ng DIN si 9, th (D st IE D C IN an IN 60 EN ce EN 09 to M 60 t 3) 60 oi 11 ra 09 23 st 2, ck ur 3) V in C e D g /5 ab E 0% s 03 W o 03 a re rpt (D ter pa l. io hu n IN ab rt m to 1) EN so id e rp ity qu Re IS ti ili O on s (D b w ist 62 a IN riu as an ) ts hi c EN m at ng e t ur IS Fl at so o h O am io da ot 62 n U m w ) L- a at St bi er an lit Re da y a s rd cc w ist 94 . to ea an th ce er t in o g (5
O

Tg C

HDT/A HDT/B OC OC 130 50 120 55 120 161-197 135 142 51 95 85 170 140 140 165 150 165 173195 140

W/(Km) 0,23 0,23 0,23 0,23 0,23

c J/(gK) 1,45 2,1 1,7 2,1

10-5 1/K 5 10 5 10 5 7

r 3-4

tan 0,020,03

rD cm 1015 1014 1013 10132x1015 1014

RO 1015 1014 1014 1014 > 1014 1015 1015 1014 (2) 1013 1015

W(H2O) Ed grade kV/mm % 25 KC>600 3 0,7 0,4 0,9 0,45 0,2 0,15 0,1

WS % 5,6-6,4 1,6 1 1,9 1,3

(+) + (+) + (+)

HB HB HB HB HB HB

Trade name TECAMID TR TECAMID 12 TECAMID 12 GF30 TECAMID 11 TECAMID 11 GF30 TECANAT HT TECANAT TECANAT GF30 TECAFINE PMP TECAPET TECAPET TF

150 45 45 43 43 180 148 148 20 70 70 60 60 -60 -60 -60 -60 -60 -60 -60 -60 -60 -60 -60

120 150 150 150 150 170 140 140

0,033,1-3,6 0,04 4 3,2-3,6 < 0,04 0,030,08

KA 38 24-30 CTI 600 >45 40 45 35 27 30 65 60 KB 400 CTI 600 KC 600 KB 600 KC 600 CTI 600 KA 1 KB 160

2,9 3 3,3 2,12 3,2

0,01 0,006 0,009

> 1016 1013 1016 (2) 1014

0,19 0,26 0,17

1,2

7 3 (2)

0,36 0,28 0,01 0,5 0,5 0,4 0,35 0,5

+ -

HB HB HB HB

2,18 1,1

12 7

KA 3c KB>600 <0,05 KC>600 KC 350 0,25 0,25

170 170

0,24

0,0021

1013

80 210 110

165 225 160

170 200 140 140

0,21

1,21 1,5

8 3,5 10 3

3 3,8 3,5 4,8

(2)

0,012 0,009 0,003 0,005 0,007

>1013 1013 1014 1014 10131014(2)

> 1015 1015 1014 1012 10131014(2)

>45 50 >50 >50 35

KB 425 KC>600 KB 225 KC 550 KA 3c

0,25 0,15 <0,3 0,15

(+)

HB HB HB

TECADUR PBT TECADUR PBT GF30 TECAFORM AH TECAFORM AH GF25

0,31

1,5

88 89 88

140 140 140 140 0,3

1,5

16

3,8

CTI 600

0,2 <0,3 0,25

0,8 0,5 ~0,8

(+) (+) (+) (+)

HB HB HB HB HB HB HB HB HB

+ -

TECAFORM AH LA TECAFORM AH ELS TECAFORM AH SD TECAFORM AH TF10 TECAFORM AH MT farbig TECAFORM AD TECAFORM AD AF TECAFORM AD GF20 TECAFORM AD CL TECAPRO MT

11 6,5

102-104 102-104 109-1011 109-1011

110 124 92 158

160 170 160 174

140 150 150 150 150

0,31 0,31

1,5 1,5

10 10 10 6

3,5 3,7 3,1 3,9 3,5

0,003 0,005 0,009 0,005 0,006

1014 >1014 >1015 > 1015 1015

1014 > 1014 > 1015 > 1015 1015

> 50 >50 15 19 15

KA 3c KA 3c

< 0,3 <0,3 0,18 0,1 0,24

0,5 0,5 0,72 1 1

(+) -

0,37

1,47

10

-18 -18 -18

65

105 90

130 120 140 120 120 90 100 100 110 140

0,22 0,2 0,27 0,41 0,41 0,350,43 0,19 0,17 0,22

1,7

17

2,25

0,0002 >1014 <103

> 1013 <104 >1013 1012 1013 > 1013

>40

KA 3c

<0,1 <0,1

<0,1 <0,1 <0,1 0,02

+ (+) + +

HB HB HB HB HB

TECAFINE PP TECAFINE PP ELS TECAFINE PP GF30 TECAFINE PE10 TECAFINE PE5

120 42 44

155 ~70 ~70 70-85 100

1,47 1,84 1,84 1,7-2 1,47 1,2 1,2

6 20 20 13-15 7 8-11 7 9

2,64 3 2,9 2,4 3,4 3,3 2,6 0,0004

>1014 1014 1015

45 50 >50 > 45

KA3c KB>600 KC>600 KA3c KB>600 KC>600

<0,1 0,01 0,01

KC>600

-95 105 115 150

42-49 60

0,0002 >1015 0,004 0,015 0,001 1015 1015 1013

KA 3c <0,05 <0,02 KB>600 KC>600 KA 3b KA 1 1 0,4 0,1 0,06 2 0,7 0,2 0,23 0,18

+ + + (+)

HB HB HB HB

TECAFINE PE TECACRYL TECARAN ABS TECANYL TECANYL MT

82-104 96-108 130 147 138

1013 1015

>22 50

150

135

143

110

1,34

3,1

0,0021

1015

1015

50

KB 250 0,05

HB

TECANYL GF30

Chemical Resistance
Factors like temperature, concentration of the chemical, duration and mechanical load are important criterions for the examination of chemical resistance. In the following table, you can see the materials resistance to different chemicals. These details correspond to the present state of our knowledge and are meant to provide information about our products and their applications. They do not mean that the chemical resistance of products or their suitability for a particular purpose is guaranteed in a legally binding way. Any existing commercial proprietary rights are to be taken into account. We guarantee perfect quality within the scope of our general terms and conditions. For specific applications it is recommended to establish suitability first. Standard testing is performed in normal climatic conditions 23/50 according to DIN 50 014.

E) PP S) L( (AB NY BS CA TE NA ) RA PE E( CA TE E P P) FIN P -H) P( CA TE E P (POM FIN C) AD CA MTE RM (PO T) FO AH CA , PB TE (PET RM FO PET CA ECA P) TE BT T (PM RP ADU MP TEC EP ) FIN ) 6G CA PC (PA TE T( ) NA RIM 12 CA CA 11, TE /TE (PA 6) ST 12 ,6 CA 1, 46 TE D1 (PA MI 66 CA 6, TE D 4 6) E) MI TF (PA CA PC TE D6 E( MI ) TF CA DF PC TE (PV ON FL DF E) CA PV TF TE (E/ ON FL FE ) CA ET FE TE (PT ON FL FE CA PT TE ON U) FL (PS CA TE N S SU) SO (PP CA TE N P S) SO (PE CA TE NE S) SO CA (PP TE ON TR CA EI) TE I (P ) PE EK CA (PE TE K) EK PE (PE CA HT TE EK PE CA PI) TE T( SIN CA TE

Acetamide 50% Acetone Formic acid, aqueous solution 10% Ammonia solution 10% Anone Benzine Benzene Bitumen Boric acid, aqueous solution 10% Butyl acetate Calcium chloride, solution 10% Chlorbenzene Chloroform Clophene A60, 50% Cyclohexane Cyclohexanone Decalin Diesel oil Dimethyl formamide Diocthyl phthalate Dioxane Acetic acid, concentrated Acetic acid, aqueous solution 10% Acetic acid, aqueous solution 5% Etanolo 96% Etilacetato Etiletere Cloruro di etilene Hydrofluoric acid, 40% Formaldehyde, aqueous solution 30% Formamide Freon, Frigen, liquid Fruit juices Glykol Glysantin, aqueous solution 40% Glycerine Urea, aqueous solution Heating oil Heptane, Hexane Iso-octane Isopropanol Iodine solution, alcohol solution Potassium Iye, aqueous 50% 1) Potassium Iye, aqueous 10% Potassium dichromate, aqueous solution 10% Potassium permaganate, aqueous solution 1% Cupric sulphate 10% + + + + + + + + + + + (+) + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + (+) + + + + + + + + + + + + + (+) + + + + + + + (+) + + + + + + + + + + + + (+) + + + (+) + + + + + + + (+) + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + (+) (+) + (+) + + (+) + + + + + (+) + + + + + + + + + + + + (+) + + + (+) + (+) -

+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +

+ + + + + +

+ (+) + + (+) + + + + + + + +

+ + + + + + + + + (+) + + + + + + + + + + + + + + + + + + + + + + +

+ + + + + + + + + (+) + + + + + + + + + + + + + + + + + + + + + + + + + + + + +

+ + + + + + + + + + + (+) (+) (+) (+) (+) (+) (+) + + + + + + + + + + + + + (+) + (+) + (+) (+) + + + + + + + + + + + + + + + + + + + + + + + + (+) (+) + + + + + + + + + + + + + + (+) + + + + + (+) + + + + + + + + + (+) + + + + + + + + + + + + + (+) (+) (+) + + + + + (+) + + + + + + + + + + + + + + + + + + + + (+) + + (+) (+) + + + (+) (+) (+) + + + + + + + + + (+) + + (+) + +

+ + (+) + + + + + + (+) + (+) + + + + + + (+) (+) + + + (+) + + + + + + + + + (+) (+) (+)

-

+ + + + + (+) + + (+) + + + + + (+) + + + + + + + + (+) + + + + + + + + + + + + (+) (+) + + + (+) + + + + + + + + + + + + + + + + + + + + +

(+) (+) (+) (+)

(+) (+) (+) (+) (+) (+) (+) + + + (+) + + + (+) + + + + + + + + + + + + + + + + + (+) + + + + + + + + + + + + + + + + + + (+) + + + + + + (+) + + (+) (+) (+) + + + + + + + + + + + + + + + + (+) (+)

(+) (+) (+) + + + + + + + + + + + + (+) + + + + + + + + + + + + + + + + + + (+) + + + + + + + + (+) + + + (+)

(+) (+) (+)

+ + + + + + + + + + + +

26

E) PP S) L( (AB NY BS CA TE NA ) RA PE E( CA TE E P P) FIN P H) P( CA MTE EP (PO FIN C) AD CA MTE RM (PO BT) FO P AH CA ET, TE RM PET (P FO CA CA , TE P) TE BT (PM RP ADU MP TEC EP ) FIN ) 6G CA PC (PA TE T( ) NA RIM 12 CA CA 11, TE /TE (PA 6) ST 12 ,6 CA 1, 46 TE D1 (PA MI 66 CA 6, TE D 4 6) E) MI TF (PA CA PC TE D6 E( MI ) TF CA DF PC TE (PV ON FL DF E) CA PV TF TE (E/ ON FL FE ) CA ET FE TE (PT ON FL FE CA PT TE ON U) FL (PS CA TE N S SU) SO (PP CA TE N P S) SO (PE CA TE NE S) SO CA (PP TE ON TR CA EI) TE I (P ) PE EK CA (PE TE K) EK PE (PE CA HT TE EK PE CA PI) TE T( SIN CA TE

Linseed oil Methanol Methyl ethyl ketone Methylene chloride Milk Lactic acid, aqueous solution 90% Lactic acid, aqueous solution 10% Sodium bisulphite, aqueous solution 10% Sodium carbonate, aqueous solution 10% Sodium chloride, aqueous solution 10% Sodium nitrate, aqueous solution 10% Sodium thiosulphate 10% Soda Iye, aqueous 50% Soda Iye, aqueous 5% Nitrobenzene Oxalic acid, aqueous solution 10% Ozone Paraffin oil Perchlorethylene Petroleum Phenol, aqueous solution Phosphoric acid, concentrated Phosphoric acid, aqueous solution 10% Propanol Pyridine Pyridine 3 solution, aqueous solution Salicylc acid Nitric acid, aqueous solution 2% Hydrochloric acid, aqueous solution 36% Hydrochloric acid, aqueous solution 2% Sulphur dioxide Sulphuric acid, concentrated 98% Sulphuric acid, aqueous solution 2% Hydrogen sulphide, saturated Soap solution, aqueous solution Silicone oils Soda solution, aqueous solution 10% Edible fats, Edible oils Styrene Tar Carbon tetrachloride Tetrahydrofurane Tetralin Ink Toluene Transformer oil Triethanolamine Trichlorethylene Trilon B, aqueous solution 10% Vaseline Wax, molten Water, cold Water, warm Hydrogen peroxide, aqueous solution 30% Hydrogen peroxide, aqueous solution 0,5% Wine, Brandy Tartaric acid Xylene Zink chloride, aqueous solution 10%
+ = Resistant

+ + + + + + + + (+) + + + (+) + + (+) + + + + (+) (+) + + + + + + (+) + (+) + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +

+ + + (+) + + + + + + + + + (+)

+ + + (+) + (+) (+) + -

+ + + + + + + + + + +

+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + (+) + + + + + + + + + + + + + + + + + + + + + + + + + (+) (+)

+ + + + + + + + + + + +

+ + + + + + + + + + + +

+ (+) + + (+) + + + + + + + + + + + + + (+) + (+) + + + + + + + + + + + + + + + + + (+)

+ + + +

+ + + + +

+ + (+) + +

+ + + -

+ + (+) + + +

+ + + + (+) (+) + + + (+) + + + + (+)

+ + + + + + + + + + + + + + + + + + +

+ + + (+) + + + + + + + + + + + + (+) + + + + +

+ (+) + + + + + + + + + + (+) (+) (+) + +

+ + + + + +

(+) (+) (+)

(+) (+)

+ + + +

+ + + + + -

+ + + + + + -

+ + +

+ +

+ + +

+ + + + + +

+ + + + + + + + + + + + +

+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + (+) -

+ + + +

+ + + + +

(+) (+) (+) (+) (+) + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +

(+) (+)

+ (+) + + + (+) +

+ + + (+) + + +

(+) + (+) + + (+)

(+) (+)

+ +

+ +

+ + +

(+) (+) (+)

+ (+) (+)

+ + + (+) -

+ +

+ (+) + -

+ + + + + + + + + + + +

+ + + + + + +

+ + + + + +

+ + + +

+ + + + + + +

+ + + + + + + + + + + + -

+ + + (+) (+) + + + + + +

+ + + + + +

+ + + + + + + -

+ + + +

+ +

+ + + (+)

(+) (+) (+) + + (+) + + (+) + + + + + + + + + + + + + + + + (+) + (+) + + + + + + + + + + -

(+) (+) (+) + + + + + + + + + + + + + + + + + + + + + + + + + + (+) + + + + (+) + + + + + + + + + + + + + + + + + + (+) + + + (+) + + + + + + + (+) + + + + + + (+) + + + + (+) + (+) +

+ + + +

(+) + + + + + + (+) + + -

(+) (+)

(+) + (+) (+)

+ + +

(+) +

+ -

+ + + + + + +

+ -

(+) (+) (+)

(+) (+) + +

+ + + + + + + + +

+ + (+) +

+ + + + +

+ (+) +

+ + + + + +

(+) (+)

(+) (+) (+) (+) (+)

(+) (+)

(+) (+)

+ +

(+) + +

+ +

+ +

(+) (+) (+)

27

Citric acid, aqueous solution 10% + + + (+) = Limited resistance - = Not resistant

+ + + + (+) (+) (+) + + + + (also dependent on concentration, time and temperature)

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