HS 1 / 3

Your Target is to secure Good Rank in Pre-Medical 2012

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25
A. 4 2 1 4 2 1 1 3 3 2 1 4 3 2 3 3 2 3 1 2 4 1 1 1 2
Q 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50
A. 2 4 2 4 2 1 3 2 3 3 3 3 3 1 4 4 3 2 3 3 3 2 3 1 1
Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
A. 3 4 2 4 4 1 3 4 4 3 1 4 1 4 2 1 2 2 2 2 4 3 2 2 2
Q. 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100
A. 4 2 1 1 2 3 1 4 4 4 4 1 4 1 2 1 3 2 1 2 4 4 4 4 4
Q. 101 102 103 104105 106107 108109 110 111 112 113 114 115 116 117 118 119 120 121122 123 124 125
A. 4 3 4 2 4 4 2 4 1 3 1 4 2 3 2 1 1 2 4 4 4 3 4 4 1
Q. 126 127 128 129130 131132 133134135 136 137138 139140 141 142 143 144145 146147 148 149 150
A. 2 4 1 4 1 2 1 3 3 2 3 1 4 3 1 1 1 4 1 3 3 1 4 1 4
Q. 151 152 153 154155 156157 158159160 161 162163 164165 166 167 168 169170 171172 173 174 175
A. 3 1 4 3 4 2 2 1 2 1 2 4 4 3 1 3 3 1 2 1 3 2 4 2 4
Q. 176 177 178 179180 181182 183184185 186 187188 189190 191 192 193 194 195 196197 198 199 200
A. 1 3 3 4 2 4 2 2 3 2 3 1 4 3 1 3 2 2 1 2 1 2 2 1 2
HI NT SHEET
DATE : 27 - 04 - 2012 ALLEN AI I MS # 01 (FUL L SY L L ABUS)
TARGET : PRE-MEDICAL 2012
LEADER, ACHIEVER & ENTHUSIAST COURSE
MAJ OR TEST
2. E = f + eV
0
For hydrogen atom, E = +13.6eV
\ +13.6 = 4.2 + eV
0
V
0
=
(13.6 4.2)eV
9.4V
e
-
=
Potential at anode = -9.4V
6.
A 4 A 4
m
n n'
m'
+
Rest
According to conservation of momentum
4n = (A - 4)n'

4
'
A 4
n
n =
-
10. P =
6 19
6
nE n 170 10 1.6 10
300 10
t t
-

=
\ Number of atoms per sec
n
t
= 1.102 10
19
Number of atoms per hour = 1.102 10
19
3600
= 3.97 10
22
.
14. Here
n 1/ 3
0
N 1 1
N 2 2

= =


where n = Number of half lives =
1
3

0
1
N 1.26
N
=

U
Pb U
N 1
N N 1.26
=
+
N
Pb
= 0.26N
U



Pb
U
N
N
= 0.26
22.
AD
IT
final
P
P



=
1
2 P
2
2P
g
g-
=
23. I = I
max
cos
2
f
2
I
max
2
= I
max
cos
2
f
2
\ cos
f
2
=
1
2
f
2
=
p
4
f =
p
2
Path diff. Dx =
l
p 2
F
H
G
I
K
J
Df b g
=
l
p
p
2 2

l
4
Distance x =
DD
d
=
l
4
D
d
27042012
2/3 HS
Your Target is to secure Good Rank in Pre-Medical 2012
MAJOR TEST : AI IMS
TARGET : PRE-MEDI CAL 2012
26. T
m
1
l

sun m star
star m sun
T ( )
T ( )
l
=
l
27. Equivalent figures

K
K
K
K
2
2
2
2
F
H
G
I
K
J
+
( )
=
2
5
K
Time period T = 2
2
5
p
m
K
T = 2
5
2
p
m
K
Frequency =
1
2p

2
5
K
M
33. l =
h
2mE
l
1
m
(K.E. = same)
37. According to Enstein's photoelectric equation
1/ 2
2
hc 1 2(hc )
mv v
2 m
- lf
= f + =

l l
41.

OH CH
3
O
CH MgBr +
3
H O
3

Br CH
3
Mg
HBr
ether
CH
3
MgBr
HCHO
CH
3
CH
2
HI ring
expansion
+ d d
CH
3
CH OH
2

CH
3
CH
3
I
I
42.
PhCCH COOH
2
O
D
PhCCH +CO
3 2
O
b-Keto acid decarboxylation
CHI + PhCONa
3
O
I
2
NaOH
[Iodoform reaction]
46. Reactivity towards Esterification

1
steric hindevance
47. CH
3
COOH

CH
3
COO
-
+ H
+
c 0 0
(-c
a
) c
a
c
a
k
a
=
c c
c(1 )
a a

-a
=
2
c
1
a
-a
a =
m
m

l
l
K
a
=
2
m
m
m
m
c
1

l
l
-

l
53.
CH
3
CH
3
m-xyleme
both CH
3
activates benzene ring at o/p-positions.
57. Symmetrical alkene gives same product in both
three cases.
59. NCERT Page 19
61.
CH
3
OH
CH
3
CH
3
CH
3
H
H O
2

CH
3
CH
3
CH
3
CH
3

CH
3
H
3
CH
3
CH
3
CH
3
CH
3
CH
3
CH
3
CH
3
CH
3

HS 3/3
27042012
Your Target is to secure Good Rank in Pre-Medical 2012
MAJOR TEST : AI IMS
PRE-MEDI CAL : L EADER, ACHI EVER & ENTHUSI AST COURSE
62.
NH
2
CH I
3
(excess)
CH NCH
3 3

CH
3
AgOH
CH NCH OH
3 3

CH
3
D
73. Stability of carbocation
77.
NH
2
CH NCH
3 3
CH I
3
AgOH
(excess)
CH
3

CH NCH OH
3 3
D
CH
3

82. 12
th
NCERT, Page - 83
83. 12
th
NCERT, Page - 174, Table = 9.1
86. 12
th
NCERT, Page - 122
87. 11
th
NCERT, Page - 149, Para. = 4
91. 11
th
NCERT, Page - 152, Line = 4
94. 12
th
NCERT, Page - 200
102. NCERT (XII), Page - 24, Paragraph 3
rd
(E)
Page - 26, (Hindi)
105. NCERT XI
th
, Page No. 12
106. NCERT (XI), Page - 88
109. NCERT XI
th
, Page No. 7
113. Page No. 58 Reptilia Line No. 8
114. 12
th
NCERT, Page - 171, Para. = 2
118. 12
th
NCERT, Page - 173, Para. = 2
143. Pyrolysis of estors follow Hoffman's rule.
145.
2
NH

is stronger base than RO

so
2
NH

is poor leaving group than RO

148. NCERT Page 198

151. Chloral is more reactive than formaldehyde
due to -I-effect of CCl
3
group
153. CH
3
-I is more reactive than CH
3
-F due to
better leaving group [ I

]
171. 12
th
NCERT, Page - 76
172. NCERT (XI), Page - 332, Paragraph 1
st
173. 12
th
NCERT, Page - 183
179. NCERT (XI), Page - 87