RATE OF REACTION

How does the size of reactant affects the rate of reaction?

2 4

Total surface area

=
2

4(4x2) + 2(2x2) = 40 cm2

2

2 2

2 2

Total surface area

6(2x2) + 6(2x2) = 48 cm2

Summary : The smaller the size , the bigger the total surface area

Reaction between calcium carbonate & hydrochloric acid

CaCO3 + 2HCl

CaCl2 + H2O + CO2

Volume, concentration & temperature are fixed

CaCO3 + 2HCl
Manipulate its size

CaCl2 + H2O + CO2

Measure volume of CO2

Statement of Problem
How does the size of calcium carbonate affects the rate of reaction between calcium carbonate and hydrochloric acid?

Aim
To investigate the effect of size of reactant on the rate of reaction

Hypothesis
The smaller the size of reactant, the higher the rate of reaction Or The bigger the total surface area, the higher the rate of reaction

Variables
Manipulated : Size of calcium carbonate Responding : Rate of Reaction Fixed : Volume , concentration , temperature of HCl

RADAS DAN BAHAN

KAEDAH
1. 2. 3. 4. 5.

Big size

Result
0 30 60 90 120

Time(s)

Burette reading (cm3) Volume of gas CO2 (cm3)

x 50.00 x-x 0.00

y 48.00 x-y 2.00

z 42.00 x-z 8.00

p q 38.00 35.00 x-p x-q 12.00 15.00

Big size

Result
0 15 30 45 60

Time(s)

Burette reading (cm3) Volume of gas CO2 (cm3)

x 50.00 x-x 0.00

y 48.00 x-y 2.00

z 42.00 x-z 8.00

p q 38.00 35.00 x-p x-q 12.00 15.00

Keputusan
Small Size

Time(s)

15

30

45

60

Burette reading (cm3) Volume of CO2(cm3)

x 50.00 x-x 0.00

y z 45.00 38.00 x-y 5.00 x-z 12.00

p q 35.00 35.00 x-p x-q 15.00 20.00

Keputusan
Time(s) Volume of CO2 (cm3) Big Size Volume of CO2 (cm3) Small Size 0 15 30 45 60

0.00

2.00

8.00 12.00

15.00

0.00

5.00 12.00 15.00

20.00

Interpret the Data

Interpret the Data Volume of CO2 (cm3)

Small size

D A

Big size Gradient AB > Gradient CD

Rate of reaction for small size is HIGHER than big size 150 s Time (s)

Conclusion
When the size of CaCO3 is smaller,the rate of reaction is higher When the total surface area is bigger,..

Hipotesis di ____________

diterima

A. Ketulan kasar

Masa / s 0

30
2.2

60
5.0

90
7.6

120 150 180

9.4 12.6 15.2

210
17.5

Isipadu 0 gas / cm3

240 270 300 330 360

19.7 21.5 23.8

24.9 25.5

A. Ketulan Halus

Masa / s 0

30
4.1

60
9.2

90

120 150 180

23.8

210
25.8

Isipadu 0 gas / cm3

13.9 18.0 21.2

240 270 300 330 360

27.5 29.0 30.0

30.8 31.8

Based on collision theory, explain the effect of size of reactant to the rate of reaction.
1.3.1.2 Effect of size of reactant on the rate of reaction based on the collision theory. a) When the size of reactant is smaller , the total surface area is .. b) So the frequency of collisions between the particles ; . is higher. c) Thus the frequency of the effective collision also become or increases. d) Thus the rate of reaction ..