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I.e. Boyles and Charles Laws were combined to create the Combined Gas Law
Similarly, Avogadros Theory and the Mole concept can also be combined:
Avogadro: Equal volumes of any gases at the same temperature and pressure contain equal numbers of entities
Therefore, for all gases at a specific temperature and pressure, there must be a certain volume, the molar volume, that contains one mole of entities
Molar Volume: the volume that one mole of a gas occupies at a specified temperature and pressure
Molar Volume
Molar volume is the same for all gases at the same temperature and pressure (remember, all gases have the same physical properties)
At STP, molar volume = 22.4 L/mol (101.325 kPa and 0C) At SATP, molar volume = 24.8 L/mol (100 kPa and 25C)
At STP, one mole of gas has a volume of 22.4 L, which is approximately the volume of 11 empty 2 L pop bottles.
Chemists created the concept of molar volume to convert between volume and chemical amount
x
V
litres
x
1 mol xL
n
mol
xL
1 mol
Molar Volume
Its a lot easier to measure the volume of a gas than trying to measure its mass. You would have to trap the gas in a container and measure its mass on a balance and them make corrections for the buoyant force of the surrounding air . . . not easy
2.
What chemical amount of oxygen is available for a combustion reaction in a volume of 5.6 L at STP?
nO2 : 5.6 L x ( 1 mol ) = 0.25 mol 22.4 L
Once these calculations are clearly understood, they can be combined into a single calculation using unit analysis. All units except the final unit will cancel.
A propane tank for a barbecue contains liquefied propane. IF the tank mass drops by 9.1 kg after a months use, what volume of propane gas at SATP was used for cooking?
Molar mass (M): C3H8(g) = 44.11 g/mol
Summary
Molar volume: the volume that one mole of a gas occupies at a specified temperature and pressure