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The term geopolymer was firstly applied to describe a family of alkaline Aluminosilicate binders formed by the alkali activation of
The formation of geopolymeric materials is the result of a complicated heterogeneous chemical reaction occurring between Al-Si materials and strongly alkaline silicate solutions.
Source materials
Materials which are rich in aluminum and silica can be used as source material.
Ex: Fly ash, GGBS, Silica fumes, Rice husk ash etc..
Alkaline liquids
The most commonly used alkaline liquids are combinations of sodium
GEOPOLYMER CONCRETE
in the source
In present experimental work, Geopolymer concrete prepared by using fly ash and GGBS as source material
Alkaline solution prepared by using Sodium hydroxide flakes and sodium silicate solution (14M).
GEOPOLYMERIZATION
Geopolymerization can transfer large scale alumino-silicate wastes into valueadded geopolymeric products with sound mechanical strength and high acid, fire and bacterial resistance
used, are generally more durable than OPC mortars (P. Chindaprasirt; T. Chareerat; S. Hatanaka; and T. CaoIn)
The optimal temperature duration of curing at 65C for GPC was 20
hours beyond which the strength increase was marginal. (Ranganath, R.V., and Mohammed Saleh)
The ratio of sodium silicate solution to sodium hydroxide solution
was varied from 0.5 to 4.5. The maximum strength was obtained
when the ratio was 2.5 at one, three and seven days. (Ranganath, R.V.,
and Mohammed Saleh)
compressive strength in the range of 20 to 35 MPa falls between 0.12 and 0.25. These values are similar to those of OPC concrete. (Uma.K, Anuradha.R and Venkatasubramani.R )
The indirect tensile strength of fly ash-based geopolymer concrete is a
fraction of the compressive strength, as in the case of Portland cement concrete. (M. D.J. Sumajouw and B. V. Rangan)
As the longitudinal tensile reinforcement ratio increased, the flexural
The crack patterns and failure modes observed for RGPC beams
were found to be similar to the RPCC beams. The total number of the flexural cracks developed was almost same for all the beams. (Dattatreya, Rajamane, Sabitha, Ambily, and M.C. Nataraja)
The crack widths, crack spacing and no. of cracks were comparable
using ANSYS 12.0 show fair agreement. (Uma.K, Anuradha.R and Venkatasubramani.R )
The present study deals with the preparation of geopolymer concrete using fly ash and GGBS.
To study the optimum usage of GGBS along with fly ash to develop GPC
Based on the above results the study was conducted on reinforced geopolymer concrete beam for the optimum mix.
Casting of geopolymer concrete cubes, cylinders and prisms for the optimum value of fck Testing for compressive strength, split tensile strength &flexural strength from cubes, cylinders and prisms specimens. Casting of six simply supported RGPC beams for the optimum value with longitudinal tensile reinforcement as the variable.
To study the flexural behaviour, crack patterns, surface strain measurement and load deflection behaviour of reinforced geopolymer concrete beams under two point loading.
Fly ash
GGBS
Coarse aggregate
Fine aggregate
Sodium hydroxide Sodium silicate Super plasticizer
Class F fly ash is used in this experiment is brought from RTPS Karnataka.
Sl No 1 Description Values Physical property Specific gravity Fineness (Blains air permeability) m2/Kg 2.10 -----------Requirement as per 3812:2003
480
320
Chemical properties 3 4 5 SiO2 (% by mass) ) (Minimum) SiO2 + Al2O3 + Fe2O3 (% by mass) (Minimum) 61.98 94.24 0.79 35 70 5
Mg O (% by mass) (Maximum)
Total sulphur as sulphur trioxide SO3 (% by mass) (Maximum) LOI (% by mass) (Maximum)
6
7
0.14
0.31
3
5
GGBS used for the experimental work is brought from RMC plant of ultratech in Bangalore.
Sl No
Values
Sl No 1
Description
Values
Chemical Composition
SiO2 (silicon dioxide) Al2O3 (Aluminum oxide) CaO (Calcium oxide) Mg O (Magnesium oxide) 33.78% 17.08% 39.87% 7.10% 2.10 480 2.9 % 2 3 4
1 2 3
Specific gravity Fineness (Blains air permeability) m2/Kg Wet sieve analysis % retained on (45)
Coarse aggregate
The locally available crushed granite of 20mm down size was used as the coarse aggregate.
Fine aggregate
Locally available clean river sand was used as fine aggregate Fineness modules of fine aggregate = 3.07
Sodium hydroxide
Sodium silicate
Commercially
used for
the
and specific
Super plasticizer
Percentage variation of Fly ash and GGBS in the total binder content
DESIGN PARAMETERS The wet density of geopolymer concrete Ratio of Sodium silicate to Sodium Hydroxide solution VALUE 2400 2.5 UNIT Kg/m3 Constant Exp.. work Constant Constant Constant Constant Variable Variable Variable Constant Constant Constant Constant
140
39.42% 23% to 29% 100% to 70% 0% to 30% 56% 44% 14M 2%
Litres
Percentage Percentage Percentage Percentage Percentage Percentage Molarity Percentage
Total
Mix proportions
Total Binder content Kg/m3
Proportion of Binder
Fly ash 100% 95% 90% 85% 80% 75% 70% GGBS 0% 05% 10% 15% 20% 25% 30%
Fly ash
Kg/m3 482.6 458.47 434.34 410.21 386.08 361.95 337.25
GGBS
Kg/m3
Alkali Solution(kg/m3)
NaOH 86.21 86.21 86.21 86.21 86.21 86.21 86.21 Na2Sio3 215.53 215.53 215.53 215.53 215.53 215.53 215.53
23%
0 710.89 904.77 24.13 710.89 904.77 48.26 710.89 904.77 72.39 710.89 904.77 96.52 710.89 904.77 120.65 710.89 904.77 144.78 710.89 904.77 Geopolymer concrete 140 liter mix GGBS Kg/m3 0 26.23 52.46 78.69 104.92 131.15 157.38 Fine Aggregate Kg/m3 692.41 692.41 692.41 692.41 692.41 692.41 692.41 Coarse Aggregate Kg/m3 881.25 881.25 881.25 881.25 881.25 881.25 881.25
Proportion of Binder Fly ash 100% 95% 90% 85% 80% 75% 70% GGBS 0% 05% 10% 15% 20% 25% 30%
Fly ash Kg/m3 524.6 498.37 472.14 445.91 419.68 393.45 367.22
Alkali Solution(kg/m3) NaOH 86.21 86.21 86.21 86.21 86.21 86.21 86.21 Na2Sio3 215.53 215.53 215.53 215.53 215.53 215.53 215.53
25%
Proportion of Binder Fly ash 100% 95% 90% GGBS 0% 05% 10% 15% 20%
Fly ash Kg/m3 566.5 538.175 509.85 481.525 453.2 424.875 396.55
Fine Aggregate Kg/m3 673.97 673.97 673.97 673.97 673.97 673.97 673.97
Coarse Aggregate Kg/m3 857.79 857.79 857.79 857.79 857.79 857.79 857.79
Alkali Solution(kg/m3) NaOH 86.21 86.21 86.21 86.21 86.21 Na2Sio3 215.53 215.53 215.53 215.53 215.53
27%
85% 80%
75%
70%
25%
30%
86.21
86.21
215.53
215.53
Geopolymer concrete 140 liter mix Fine Aggregate Kg/m3 655.50 655.50 Coarse Aggregate Kg/m3 834.27 834.27
Proportion of Binder Fly ash 100% 95% 90% GGBS 0% 05% 10% 15% 20% 25% 30%
Alkali Solution(kg/m3) NaOH 86.21 86.21 86.21 86.21 86.21 86.21 86.21 Na2Sio3 215.53 215.53 215.53 215.53 215.53 215.53 215.53
547.641
517.217
60.85
91.274
655.50
655.50
834.27
834.27
29%
486.792
456.368 425.943
121.698
152.123 182.547
655.50
655.50 655.50
834.27
834.27 834.27
Mixing
First aggregates and binder ( fly ash and GGBS) are mixed in tilting drum mixer for about 3 minutes.
Then alkaline liquid is added to the dry mix and mixing is continued
for about 4 minutes.
Total Binder content 27% Proportion of Binder Fly ash 100% 95% 90% 85% 80% 75% GGBS 0% 05% 10% 15% 20% 25%
Total Binder content 29% Proportion of Binder Fly ash GGBS 0% 05% 10% 15% 20% 25%
70%
30%
158
70%
30%
150
Slump test
250 200 Slump mm Slump mm 150 100 50 0 100;0 95;5 90;10 85;15 80;20 75;25 70;30 variation of fly ash to GGBS 250 200 150
100
50
0
100;0 95;5 90;10 85;15 80;20 75;25 70;30
150
100
50
0 100;0 95;5 90;10 85;15 80;20 75;25 70;30 Variation of fly ash to GGBS
0
100;0 95;5 90;10 85;15 80;20 75;25 70;30 Variation of fly ash to GGBS
Casting of specimens
Cube (150mmx150mmx150mm): 90 Nos Prism (100mmx100mmx500mm) :9 Nos
after mixing.
Compaction is achieved by giving sixty manual strokes for each layer by using tamping rod.
After casting, all the specimens were covered using plastic cover to avoid the quick evaporation of water.
One days rest period was given for initial hardening of specimen. After one day, specimens were kept in HACC (Hot air curing
After heat curing, specimens were kept in room temperature until the date of testing.
Less maintenance.
Easy to carry, dismantle and install.
Casting of specimens
Curing in HACC
1. 2. 3.
Compressive strength test Split tensile strength test Flexural strength test
Tests are conducted according to the IS: 516-1959 All the specimens were tested after 7th day from the date of casting the specimen.
Compression strength
Flexural strength
2345
2293 23% 70 30 2289 2348
1350
1100 1180 1250
58.86
47.96 51.45 54.50 51.30
2297
740
32.26
25%
100
2288
2285 2265
830
780 1010 820 1070 1080 1050 1040 1220 1200 1100 1460 1330
36.19
34.08 44.04 35.75 46.65 47.09 45.78 45.34 53.19 52.32 47.96 63.66 57.99
34.18
25%
95
05
41.42
25%
90
10
46.07
25%
85
15
51.16
25%
80
20
2330
58.86
2315
2320 25% 75 25 2351 2322 2375 25% 70 30 2327
1300
1340 1560 1490 1430 1210
56.68
58.42 68.02 64.96 62.35 52.76 56.54 63.81
Density
Kg/m3
Average compressive
strength N/mm2
2216 27% 100 0 2297 2270 2327 27% 95 05 2317 2316 2359 27% 90 10 2372 2346
36.19 39.24 40.11 47.96 45.78 42.73 46.65 54.94 47.09 49.56 45.49 38.51
2267
27% 85 15 2281 2276 2260 27% 80 20 2306 2274 2262 27% 75 25 2297 2334 2312 27% 70 30 2341
1200
1320 1280 1360 1520 1430 1490 1540 1590 1390 1480
52.38
57.55 55.81 59.30 66.27 62.35 64.96 67.14 69.32 60.60 64.53 60.17 67.85 62.67 55.52
2309
1270
55.37
2320
1000
43.60
29%
100
2319
2316 2286
900
960 1170 1100 1190 1230 1190 1270 1410 1220 1320 1490 1450 1470 1620 1560 1600
39.24
41.85 51.01 47.96 51.88 53.63 51.88 55.37 61.48 53.19 57.55 64.96 63.22 64.09 70.63 68.02 69.76
41.56
29%
95
05
50.28
29%
90
10
53.63
29%
85
15
57.41
29%
80
20
64.09
29%
75
25
2352 2372
69.47
2356
29% 70 30 2351 2320
1490
1440 1390
64.96
62.78 60.60 62.78
70 60 50 40 30 20
60
50 40 30 20 10 0 100;0 95;5 90;10 85;15 80;20 75;25 70;30
10
0 100;0 95;5 90;10 85;15 80;20 75;25 70;30
80
27%binder Content
Compressive Strength N/mm2
80 70 60 50 40 30 20 10 0 100;0
95;5
90;10
85;15
80;20
75;25
70;30
80
70
60 50 40 30 20 10
0
23% 25% 27% 29%
Binder Content
Based on the higher compressive strength 29% binder content i.e., (75:25) mix were selected for the split tensile strength and flexural strength test.
4.46
75%
25%
with beam
290
270 300 Casted along
4.62
4.29 4.77 4.93 5.25
4.30
75%
310 330
4.98
6.4
4.8 5.6 6.4 6.0 4.8 5.73 5.60
75%
25%
with beam
12
14 16 Casted along
75%
15 12
Based on the higher compressive strength i.e., optimum fck was selected
Beam details
Mix used Beam 29%Binder Beam Dimension Reinforcement Compression Tension Tensile Reinforcement ratio (%)
B1,B2,B3
B4,B5,B6
75:25
75:25
125X200X1300
125X200X1300
2#8
2#8
2 # 10
2 # 12
0.75
1.08
Casting of beams
Beam
% of tensile Reinforcement
Ratio Mc/Mr
B1 B2 B3 B4 B5 B6
69.17
5.82
8.82
4.85
1.82
10
Beam
B1
0.75
72
4.602
4.6
B2
0.75
72
4.603
4.6
B3
0.75
84
4.550
4.6
Beam
B4
1.08
92
4.578
4.6
B5
1.08
104
4.993
4.6
B6
1.08
100
5.030
4.6
B5
B6
104
100
0.000595
0.000742
0.002042
0.001751
B1,B2,B3
B4,B5,B6
The average density of geopolymer concrete is very similar to that of normal conventional concrete.
The experimental investigation have shown that using Fly ash along with GGBS as source material, it is possible to produce geopolymer concrete of compressive strengths (7 days) in the range of 44-70 N/mm2.
GGBS as a source materials results in early initial strength and it makes possible to de-mould the specimens very early. This is an important applications of geopolymer concrete in the industry.
As the total binder content increases the compressive strength also increases.
By using 25% GGBS (75% fly ash) in the total binder content
Reinforced geopolymer concrete beams crack pattern shows most of the cracks in the pure bending zone and all the beams failed in flexure.
The flexural capacity of the beam increases with the increase in longitudinal tensile reinforcement ratio, the tested ultimate moment capacity of beams were found 2.4 times more than theoretical ultimate moment capacity.
The experimental value of the ultimate load is much higher than the calculated load for all the geopolymer concrete beams.
The further study on the geopolymer concrete can be focused on trying with different water content of the mix. For finding the optimum percentage of binder content.
Investigation has to be made with the use of different fibers in reinforced geopolymer concrete.
The work has to be carried out on the long term properties of the
geopolymer concrete.
The study can be conducted using 100% GGBS for the manufacture of geopolymer concrete under ambient curing
References
Hardjito, D. and Rangan, B.V. (2005). "Development and Properties of
low calcium fly ash based geopolymer concrete." Research report GC 1, Curtin University of technology Perth, Australia.
Wallah, S.E., and Rangan, B.V. (2006). "Low calcium fly ash based
Geopolymer concrete: Long term properties." Research report GC2, Curtin University of technology Perth, Australia.
Sumajouw, M.D.J., and Rangan, B.V. (2006). "Low calcium fly ash
based Geopolymer concrete: Reinforced beams and columns." Research report GC 3, Curtin University of technology Perth, Australia.
Balaguru, P.N., Kurtz, s., and Jon Rudoph. (1997). "Geopolymer for
repair and rehabilitation of reinforced concrete beams." Rutgers the state University of new jersey, USA.