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Asocijacija geofiziara Srbije ZATITA IVOTNE SREDINE U ENERGETICI, RUDARSTVU I PRATEOJ INDUSTRIJI 21 - 23. 9. 2010.

Divibare

ISPITIVANJE KONTAMINIRANIH PODZEMNIH VODA U SLOENIM PROCESNIM SISTEMIMA


SONJA STEFANOV, MIRJANA VOJINOVI MILORADOV,
RADOMIR BIOANIN, SLOBODAN STANIC, IMON BANOV

Lokacija

Eksperiment

Eksperiment

Location number 1 is located some 100 m from the fence of the complex process systems (exemple 1). On location 1 the project anticipated construction of 4 piezometers, depths: 45 m, 25 m, 15 m and 7 m. HDPE pipes, 160mm in diameter, were build-in the piezometer. Around the filter part quartz granulate 1-3 mm was poured in. Above it, a clay tampon was made and the space between the pipes and walls of the hole above the clay tampon was filled with drilled material. All piezometers were washed with pure water by a pump followed by air-lift piezometer compression until the water was completely clear. Also piezometers were secured by protective metal caps and locks. Location number 2 is located 30m from the fence of the complex process systems (exemple 1) near the road towards Starcevo village. On location 1 the project anticipated construction of 4 piezometers, depths: 45 m, 25 m, 15 m and 7 m. HDPE pipes, 160mm in diameter, were build-in the piezometer. Around the filter part quartz granulate 1-3 mm was poured in. Above it, a clay tampon was made and the space between the pipes and walls of the hole above the clay tampon was filled with drilled material. All piezometers were washed with pure water by a pump followed by air-lift piezometer compression until the water was completely clear. Also piezometers were secured by protective metal caps and locks Location number 3 is located 250 m from the complex process systems (exemple 2), next to the road leading towards the Danube. On location 3 the project anticipated construction of 4 piezometers, depths: 45 m, 25 m, 15 m and 7 m. HDPE pipes, 160mm in diameter, were build-in the piezometer. Around the filter part quartz granulate 13 mm was poured in. Above it, a clay tampon was made and the space between the pipes and walls of the hole above the clay tampon was filled with drilled material. All piezometers were washed with pure water by a pump followed by air-lift piezometer compression until the water was completely clear. Also piezometers were secured by protective metal caps and locks. Location number 4 is located 700 m from the complex process systems (exemple 2), next to Danube river. On location 4 the project anticipated construction of 4 piezometers, depths: 35 m, 25 m, 15 m and 7 m. HDPE pipes, 140mm in diameter, were build-in the piezometer. Around the filter part quartz granulate 1-3 mm was poured in. Above it, a clay tampon was made and the space between the pipes and walls of the hole above the clay tampon was filled with drilled material. All piezometers were washed with pure water by a pump followed by air-lift piezometer compression until the water was completely clear.

Rezultati i diskusija
KMnO4
7
depth (m)

Rezultati hemijske analize na lokaciji 1


KMnO 4 DEMAND COMPARATIVE CHART BY DEPTH ON LOCATION NO. 1
0 20 40 60 80 100 120 140 160 180 200 220 240

PCB CONCENTRATION COMPARATIVE CHART BY DEPTH ON LOCATION NO. 1


mg/L 260
0 0.002 0.004 0.006 0.008 0.01 0.012 0.014 0.016 0.018

mg/L 0.02

PCB
7 15

15

depth (m)

25

25
PCB - I sampling PCB - II sampling PCB - III sampling

45

KMnO4 demand - I sampling KMnO4 demand - II sampling KMnO4 demand - III sampling

45

Ukupni ugljovodonici
0

TOTAL HYDROCARBONS CONCENTRATION COMPARATIVE CHART BY DEPTH ON LOCATION NO. 1 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 1.1

mg/L

hlorfenol
7

PHENOL CONCENTRATION COMPARATIVE CHART BY DEPTH ON LOCATION NO. 1


0 0.0005 0.001 0.0015 0.002 0.0025 0.003 0.0035 0.004

mg/L 0.0045

1.2

depth (m)

depth (m)

15

15

25

25

45

Total hydrocarbons - I sampling Total hydrocarbons - II sampling Total hydrocarbons - III sampling

45

Phenol - I sampling Phenol - II sampling Phenol - III sampling

Rezultati I diskusija
Rezultati hemijske analize na lokaciji 2
KMnO4 DEMAND COMPARATIVE CHART BY DEPTH ON LOCATION NO. 2
0 25 50 mg/L

TOTAL HYDROCARBONS CONCENTRATION COMPARATIVE CHART BY DEPTH ON LOCATION NO. 2 0 0.1 0.2 0.3 0.4 0.5 0.6

mg/L 0.7

75 100 125 150 175 200 225 250 275 300 325 350 375

depth (m)

depth (m)

15

15

25

25

45

KMnO4 demand - I sampling KMnO4 demand - II sampling KMnO4 demand - III sampling

45

Total hydrocarbons - I sampling Total hydrocarbons - II sampling Total hydrocarbons - III sampling

KMnO4

Ukupni ugljovodonici

Rezultati i diskusija
Rezultati hemisje analize na lokaciji 3
KMnO4
0 10 7
15

KMnO4 DEMAND COMPARATIVE CHART BY DEPTH ON LOCATION NO. 3


20 30 40 50 60 70

mg/L 80

PCB
7

PCB CONCENTRATION COMPARATIVE CHART BY DEPTH ON LOCATION NO. 3


0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09

mg/L 0.1

depth (m)

15

depth (m)

25

25
45 PCB - I sampling PCB - II sampling PCB - III sampling

45

KMnO4 demnad - I sampling KMnO4 demand - II sampling KMnO4 demand - III sampling

EDC
7

1,2-DICHLORE THANE COMPARATIVE CHART BY DE PTH ON LOCATION NO. 3 0 25 50 75 100 125 150 175 200 225 250 275

CHCl3 COMPARATIVE CHART BY DE PTH ON LOCATION NO. 3

mg/L 300

CHCl3
7

mg/L 0 50 100 150 200 250 300 350 400 450 500 550 600 650 700

depth (m)

15
depth (m)

15

25

25

45 1,2-dichloethane - I sampling 1,2-dichloethane - II sampling 1,2-dichloethane - III sampling


Chloroform - I sampling Chloroform - II sampling Chloroform - III sampling

45

Rezultati i diskusija
Analize na nekim loakcijama u blizini naseljenih mesta
KMnO4
KMnO4 DEMAND COMPARATIVE CHART ON CHOSEN LOCATION IN THE DIRECTION OF STARCEVO
0 5 10 15 20 25 30 35 40 45 50 55 60 mg/L 65
0

PCB
TOTAL HYDROCARBONS (C5-C20) COMPARATIVE CHART ON CHOS E N LOCATION IN THE DIRE CTION OF S TARCE VO
0.02 0.04 0.06 0.08 0.1 0.12 0.14 mg/L 0.16

P-738

P-738

Location

P-739

Location

P-739

^ esma

^ esma

KMnO4 demand - I sampling KMnO4 demand- II sampling

Total hydrocarbons - I sampling Total hydrocarbons - II sampling

EDC
PHENOL COM PARATIVE CHART ON CHOSEN LOCATION IN THE DIRECTION OF STARCEVO
0 0.001 0.002 0.003 0.004 mg/L 0.005

CHCl3
P-738

CHCl3 COMPARATIVE CHART ON CHOSEN LOCATION IN THE DIRECTION OF STARCEVO


0 2 4 6 8

g/L

10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40

P-738

Location

Location

P-739

P-739

^ esma

^ esma

Phenol - I sampling Phenol - II sampling

Chloroform - I sampling Chloroform - II sampling

Zakljuci

Preiavanje kontaminaranih podruja je sloen proces, poto je izvesna koliina iscurelih toksinih supstanci transformisana ili su posluili kao reagens za nastajanje drugih jedinjenja. Preiavanje velikog lokaliteta je neizvesan posao. U medjuvremenu zagaenje se iri i unitava podzemne vode i izvore odakle tako ili kroz lanac ishrane negativno utice na zdravlje ljudi.

Projekat za lokalizaciju zagaenja treba da uradi hidroloke barijere sa postojeim piezometrima I bunara I na keraju I buenje novih bunara