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What is REDOX?
Many of the reactions you have performed this year have been REDOX reactions even though you may not have known it. So, now you may well ask,what are they?
REDOX reactions are those in which electrons are transferred from one species to another (i.e. atom, ion, etc.). Electron transfer involves, you guessed it, production of electricity.
RED = reduction, which occurs when a species (ion or atom) gains an electron
OX = oxidation, which occurs when a species (ion or atom) loses an electron
Note in #1 that the oxidation number (charge) for the iron (Fe) has gone from zero to 2+. Note in #1 that the oxidation number (charge)for the hydrogen (H) has gone from 1+ to zero. Your task is to determine the oxidation number changes in #2 and #3.
Fe + 2HCl H2 + FeCl2
The iron atom has LOST two electrons, therefore,it has oxidized (LEO).
2H1+ + 2e H2 The hydrogen ions have GAINED two electrons, therefore,they have reduced (GER).
NOTE: The chlorine ions have not changed; they are spectator ions.
Just as all reactions must balance, so too the number of electrons transferred must balance.
Fe + 2HCl + 2e H2 + FeCl2 + 2e
There can be no REDUCTION without OXIDATION. You can't have one without the other. There is no net change in the number of electrons in a REDOX reaction. NOTE: The species that accepts the electrons is the oxidizing agent. Why? Because is is facilitating the oxidation of some other species.
NOTE: The species that donates the electrons is the reducing agent. Why? Because is is facilitating the reduction of some other species.
Where do I find REDOX reactions? Are they only in the lab? No!
Fire is a REDOX reaction. Rusting is a REDOX reaction.
The copper carbonate and copper hydroxide are both insoluble in water.
It is possible to balance REDOX reactions and half reactions through a series of steps that are found on p. 90 of Masterson and Hurley. You will not be expected t o balance these equations here, but expect to do lots of them if you take chemistry in college. You should be able to tell whether a half reaction is oxidation (LEO) or reduction (GER).
ELECTROCHEMISTRY
Electrochemistry is the study of the interconversion between electrical and chemical energy. All the reactions in electrochemistry are REDOX reactions. Electrochemistry takes place in one of two types of electrochemical cells.
VOLTAIC
ELECTROLYTIC
Voltaic cell ~ a spontaneous reaction that generates electrical energy. The cell must be designed so that oxidation occurs at one electrode (anode) and reduction occurs at the other electrode (cathode). Notice the salt bridge connecting the two halves and completing the circuit.
Electrolytic cell ~a non-spontaneous redox reaction made to occur by pumping electricity into the system The electron pump (electrical source) pushes electrons into the system at the cathode and removes them from the anode.
People often bronze their childrens baby shoes or otherwise have them coated with a metallic coating for posterity. The shoes are covered with a graphite paste which acts as the cathode and dipped in a metallic ion solution.